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arXiv 1107.5210cond-mat.mtrl-sci
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沉积温度对原子层沉积ZnCoO薄膜的影响-Co分布均匀性、结构、光学、电学和磁学性能

Effects related to deposition temperature of ZnCoO films grown by Atomic Layer Deposition - uniformity of Co distribution, structural, optical, electrical and magnetic properties

Malgorzata I. Lukasiewicz, Bartlomiej Witkowski, Marek Godlewski, Elzbieta Guziewicz, Maciej Sawicki, Wojciech Paszkowicz, Rafal Jakiela, Tomasz A. Krajewski, Grzegorz Luka

摘要:

在本研究中,我们报告的ZnCoO薄膜在相对较低的温度下生长的原子层沉积,使用两个反应性的有机锌前体(二甲基锌和二乙基锌)的属性。使用这些前体使我们能够将生长温度显著降低到300 ℃以下。采用二次离子质谱、扫描电子显微镜、阴极荧光、能量色散X射线谱、X射线衍射和超导量子干涉仪等研究了生长条件对ZnCoO薄膜中Co的分布、结构和磁性能的影响。我们在160°C下生长的薄膜具有很高的均匀性。这种薄膜是顺磁性的。在200°和更高温度下生长的薄膜是不均匀的。用高分辨EDX方法检测了薄膜中杂质相的形成。这些样品不是纯顺磁性的,并且在低温下显示出弱的铁磁响应。

英文摘要:

In the present study we report on properties of ZnCoO films grown at relatively low temperature by the Atomic Layer Deposition, using two reactive organic zinc precursors (dimethylzinc and diethylzinc). The use of these precursors allowed us the significant reduction of a growth temperature to below 300oC. The influence of growth conditions on the Co distribution in ZnCoO films, their structure and magnetic properties was investigated using Secondary Ion Mass Spectroscopy, Scanning Electron Microscopy, Cathodoluminescence, Energy Dispersive X-ray Spectrometry (EDX), X-ray diffraction and Superconducting Quantum Interference Device magnetometry. We achieved high uniformity of the films grown at 160°C. Such films are paramagnetic. Films grown at 200° and at higher temperature are nonuniform. Formation of foreign phases in such films was detected using high resolution EDX method. These samples are not purely paramagnetic and show weak ferromagnetic response at low temperature.

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