The large-deviation method can be used to study the measurement trajectories of open quantum systems. For optical arrangements this formalism allows to describe the long time properties of the (non-equilibrium) photon counting statistics in the context of a (equilibrium) thermodynamic approach defined in terms of dynamical phases and transitions between them in the trajectory space [J.P. Garrahan and I. Lesanovsky, Phys. Rev. Lett. 104, 160601 (2010)]. In this paper, we study the thermodynamic approach for fluorescent systems coupled to complex reservoirs that induce stochastic fluctuations in their dynamical parameters. In a fast modulation limit the thermodynamics corresponds to that of a Markovian two-level system. In a slow modulation limit, the thermodynamic properties are equivalent to those of a finite system that in an infinite-size limit is characterized by a first-order transition. The dynamical phases correspond to different intensity regimes, while the size of the system is measured by the transition rate of the bath fluctuations. As a function of a dimensionless intensive variable, the first and second derivative of the thermodynamic potential develop an abrupt change and a narrow peak respectively. Their scaling properties are consistent with a double-Gaussian probability distribution of the associated extensive variable.
We consider quantum trajectories of composite systems as generated by the stochastic unraveling of the respective Lindblad-master-equation. Their classical limit is taken to correspond to local jumps between orthogonal states. Based on statistical distributions of jump- and inter-jump-distances we are able to quantify the non-classicality of quantum trajectories. To account for the operational effect of entanglement we introduce the novel concept of "co-jumps".
It is problematic to interpret the quantum jumps of an atom interacting with thermal light in terms of counts at detectors monitoring the atom's inputs and outputs. As an alternative, we develop an interpretation based on a self-consistency argument. We include one mode of the thermal field in the system Hamiltonian and describe its interaction with the atom by an entangled quantum state while assuming that the other modes induce quantum jumps in the usual fashion. In the weak-coupling limit, the photon number expectation of the selected mode is also seen to execute quantum jumps, although mor…
We demonstrate with an experiment how molecules are a natural test-bed for probing fundamental quantum thermodynamics. Single-molecule spectroscopy has undergone transformative change in the past decade with the advent of techniques permitting individual molecules to be distinguished and probed. By considering the time-resolved emission spectrum of organic molecules as arising from quantum jumps between states, we demonstrate that the quantum Jarzynski equality is satisfied in this set-up. This relates the heat dissipated into the environment to the free energy difference between the initial a…
We apply the large-deviation method to study trajectories in dissipative quantum systems. We show that in the long time limit the statistics of quantum jumps can be understood from thermodynamic arguments by exploiting the analogy between large-deviation and free-energy functions. This approach is particularly useful for uncovering properties of rare dissipative trajectories. We also prove, via an explicit quantum mapping, that rare trajectories of one system can be realized as typical trajectories of an alternative system.
The quantum jump approach, where pairs of state vectors follow Stochastic Schroedinger Equation (SSE) in order to treat the exact quantum dynamics of two interacting systems, is first described. In this work the non-uniqueness of such stochastic Schroedinger equations is investigated to propose strategies to optimize the stochastic paths and reduce statistical fluctuations. In the proposed method, called the 'adaptative noise method', a specific SSE is obtained for which the noise depends explicitly on both the initial state and on the properties of the interaction Hamiltonian. It is also show…
We introduce jumptime unraveling as a distinct description of open quantum systems. As our starting point, we consider quantum jump trajectories, which emerge, physically, from continuous quantum measurements, or, formally, from the unraveling of Markovian quantum master equations. If the stochastically evolving quantum trajectories are ensemble-averaged at specific times, the resulting quantum states are solutions to the associated quantum master equation. We demonstrate that quantum trajectories can also be ensemble-averaged at specific jump counts. The resulting jumptime-averaged quantum st…
For classical nonequilibrium systems, the separation of the total entropy production into the adiabatic and nonadiabatic contributions is useful for understanding irreversibility in nonequilibrium thermodynamics. In this article, we formulate quantum analogs for driven open quantum systems describable by quantum jump trajectories by applying a quantum stochastic thermodynamics. Our main conclusions are based on a quantum formulation of the local detailed balance condition.
We consider Markovian open quantum systems subject to stochastic resetting, which means that the dissipative time evolution is reset at randomly distributed times to the initial state. We show that the ensuing dynamics is non-Markovian and has the form of a generalized Lindblad equation. Interestingly, the statistics of quantum-jumps can be exactly derived. This is achieved by combining techniques from the thermodynamics of quantum-jump trajectories with the renewal structure of the resetting dynamics. We consider as an application of our analysis a driven two-level and an intermittent three-l…
We study the dynamics of quantum systems interacting with a stream of entangled qubits. Under fairly general conditions, we present a detailed framework describing the conditional dynamical maps for the system, called quantum trajectories, when the qubits are measured. Depending on the measurement basis, these quantum trajectories can be jump-type or diffusive-type, and they can exhibit features not present with quantum optical and single-qubit trajectories. As an example, we consider the case of two remote atoms, where jump-type quantum trajectories herald the birth and death of entanglement.
Every open-system dynamics can be associated to infinitely many stochastic pictures, called unravelings, which have proved to be extremely useful in several contexts, both from the conceptual and the practical point of view. Here, focusing on quantum-jump unravelings, we demonstrate that there exists inherent freedom in how to assign the terms of the underlying master equation to the deterministic and jump parts of the stochastic description, which leads to a number of qualitatively different unravelings. As relevant examples, we show that a fixed basis of post-jump states can be selected unde…
Exceptional points (EPs) are degeneracies of classical and quantum open systems, which are studied in many areas of physics including optics, optoelectronics, plasmonics, and condensed matter physics. In the semiclassical regime, open systems can be described by phenomenological effective non-Hermitian Hamiltonians (NHHs) capturing the effects of gain and loss in terms of imaginary fields. The EPs that characterize the spectra of such Hamiltonians (HEPs) describe the time evolution of a system without quantum jumps. It is well known that a full quantum treatment describing more generic dynamic…
We give an explicit stochastic Hamiltonian model of discontinuous unitary evolution for quantum spontaneous jumps like in a system of atoms in quantum optics, or in a system of quantum particles that interacts singularly with "bubbles" which admit a continual counting observation. This model allows to watch a quantum trajectory in a photodetector or in a cloud chamber by spontaneous localisations of the momentums of the scattered photons or bubbles. Thus, the continuous reduction and spontaneous localization theory is obtained from a Hamiltonian singular interaction as a result of quantum filt…
Quantum open systems are described in the Markovian limit by master equations in Lindblad form. I argue that common ``quantum trajectory'' techniques corresponding to continuous measurement schemes, which solve the master equation by unraveling its evolution into stochastic trajectories in Hilbert space, correspond closely to particular sets of decoherent (or consistent) histories. This is illustrated by a simple model of photon counting. An equivalence is shown for these models between standard quantum jumps and the orthogonal jumps of Diósi, which have already been shown to correspond to dec…
We consider an open quantum system for which only a subset of all possible transitions are accessible, while the remaining ones are hidden from direct observation. Using a modification of the notion of quantum jump trajectories we introduce the coarse-grained hidden entropy, which quantifies the entropy production in the hidden subsystem conditioned on our observations of the visible part. The entropy production consisting of the sum of visible and coarse-grained hidden entropy is shown to satisfy an integral fluctuations theorem. Depending on the nature of the continuously occurring measureme…
Here, we are concerned with comparing estimation schemes for the quantum state under continuous measurement (quantum trajectories), namely quantum state filtering and, as introduced by us [Phys. Rev. Lett. 115, 180407 (2015)], quantum state smoothing. Unfortunately, the cumulative errors in the most typical simulations of quantum trajectories with a total time of simulation $T$ can reach orders of $T Δt$. Moreover, these errors may correspond to deviations from valid quantum evolution as described by a completely positive map. Here we introduce a higher-order method that reduces the cumulative…
The dynamics of open quantum systems is often modelled using master equations, which describe the expected outcome of an experiment (i.e., the average over many realizations of the same dynamics). Quantum trajectories, instead, model the outcome of ideal single experiments -- the ``clicks'' of a perfect detector due to, e.g., spontaneous emission. The correct description of quantum jumps, which are related to random events characterizing a sudden change in the wave function of an open quantum system, is pivotal to the definition of quantum trajectories. In this article, we extend the formalism…
Recent progress in the study of dynamical phase transitions has been made with a large-deviation approach to study trajectories of stochastic jumps using a thermodynamic formalism. We study this method applied to an open quantum system consisting of a superconducting single-electron transistor, near the Josephson quasiparticle resonance, coupled to a resonator. We find that the dynamical behavior shown in rare trajectories can be rich even when the mean dynamical activity is small and thus the formalism gives insights into the form of fluctuations. The structure of the dynamical phase diagram …
We investigate theoretically the emergence of classical statistical physics in a finite quantum system that is either totally isolated or otherwise subjected to a quantum measurement process. We show via a random matrix theory approach to nonintegrable quantum systems that the set of outcomes of the measurement of a macroscopic observable evolve in time like stochastic variables, whose variance satisfies the celebrated Einstein relation for Brownian diffusion. Our results show how to extend the framework of eigenstate thermalization to the prediction of properties of quantum measurements on an…
We describe how to characterize dynamical phase transitions in open quantum systems from a purely dynamical perspective, namely, through the statistical behavior of quantum jump trajectories. This approach goes beyond considering only properties of the steady state. While in small quantum systems dynamical transitions can only occur trivially at limiting values of the controlling parameters, in many-body systems they arise as collective phenomena and within this perspective they are reminiscent of thermodynamic phase transitions. We illustrate this in open models of increasing complexity: a th…
Solution of free particle quantum master equation with spatial decoherence can be unravelled into stochastic quantum trajectories in many ways. The first example, published in 1985, proposed a piecewise deterministic jump process for the wave function. While alternative unravellings, diffusive ones in particular, proved to be tractable analytically, the jump process 1985, also called orthojump, allows for few analytic results, it needs numeric methods as well. Here we prove that, similarly to diffusive unravellings, it is localizing the quantum state.
A recent experiment by Minev et. al [arXiv:1803.00545] demonstrated that in a dissipative (artificial) 3-level atom with strongly intermittent dynamics it is possible to "catch and reverse" a quantum jump "mid-flight": by the conditional application of a unitary perturbation after a fixed time with no jumps, the system was prevented from getting shelved in the dark state, thus removing the intermittency from the dynamics. Here we offer an interpretation of this phenomenon in terms of the dynamical large deviation formalism for open quantum dynamics. In this approach, intermittency is seen as t…
We present a method to study rare nonadiabatic dynamics in open quantum systems using transition path sampling and quantum jump trajectories. As with applications of transition path sampling to classical dynamics, the method does not rely on prior knowledge of transition states or reactive pathways, and thus can provide mechanistic insight into ultrafast relaxation processes in addition to their associated rates. In particular, we formulate a quantum path ensemble using the stochastic realizations of an unravelled quantum master equation, which results in trajectories that can be conditioned o…
We present a means of studying rare reactive pathways in open quantum systems using Transition Path Theory and ensembles of quantum jump trajectories. This approach allows for elucidation of reactive paths for dissipative, nonadiabatic dynamics when the system is embedded in a Markovian environment. We detail the dominant pathways and rates of thermally activated processes, as well as the relaxation pathways and photoyields following vertical excitation in a minimal model of a conical intersection. We find that the geometry of the conical intersection affects the electronic character of the tr…
It is shown that many dissipative phenomena of "old" quantum mechanics which appeared 100 years ago in the form of the statistics of quantum thermal noise and quantum spontaneous jumps, have never been explained by the "new" conservative quantum mechanics discovered 75 years ago by Heisenberg and Schroedinger. This led to numerous quantum paradoxes which are reconsidered in this paper. The development of quantum measurement theory, initiated by von Neumann, indicated a possibility for resolution of this interpretational crisis by divorcing the algebra of the dynamical generators from the algeb…
The equivalence of thermodynamic ensembles is at the heart of statistical mechanics and central to our understanding of equilibrium states of matter. Recently, it has been shown that there is a formal connection between the dynamics of open quantum systems and the statistical mechanics in an extra dimension. This is established through the fact that an open system dynamics generates a Matrix Product state (MPS) which encodes the set of all possible quantum jump trajectories and permits the construction of generating functions in the spirit of thermodynamic partition functions. In the case of c…
We may infer a transition $|n \rangle \to |m \rangle$ between energy eigenstates of an open quantum system by observing the emission of a photon of Bohr frequency $ω_{mn} = (E_n-E_m) / \hbar$. In addition to the "collapses" to the state $|m\rangle$, the measurement must also have brought into existence the pre-measurement state $|n \rangle$. As quantum trajectories are based on past observations, the condition state will jump to $| m \rangle$, but the state $|n\rangle$ does not feature in any essential way. We resolve this paradox by looking at quantum smoothing and derive the time-symmetric m…
We propose a piecewise deterministic Markovian jump process in Hilbert space such that the covariance matrix of this stochastic process solves the thermodynamic quantum master equation. The proposed stochastic process is particularly simple because the normalization of the vectors in Hilbert space is preserved only on average. As a consequence of the nonlinearity of the thermodynamic master equation, the construction of stochastic trajectories involves the density matrix as a running ensemble average. We identify a principle of detailed balance and a fluctuation-dissipation relation for our Ma…
Permanent Thermodynamic Mpemba Inversion from Quantum-Jump Feedback
Key Laboratory of Intelligent Optoelectronic Devices and Chips of Jiangsu Higher Education Institutions, School of Physical Science and Technology, Suzhou University of Science and Technology（江苏高校智能光电技术与芯片重点实验室，苏州科技大学物理科学与技术学院）；Advanced Technology Research Institute of Taihu Photon Center, School of Physical Science and Technology, Suzhou University of Science and Technology（太湖光子中心先进技术研究院，苏州科技大学物理科学与技术学院）；Department of Physics, Zhejiang Normal University（浙江师范大学物理系）
We present a stepwise adaptive-timestep version of the Quantum Jump (Monte Carlo wave-function) algorithm. Our method has proved to remain robust even for problems where the integrating implementation of the Quantum Jump method is numerically problematic. The only specific parameter of our algorithm is the single a priori parameter of the Quantum Jump method, the maximal allowed total jump probability per timestep. We study the convergence of ensembles of trajectories to the solution of the full master equation as a function of this parameter. This study is expected to pertain to any possible …
This article sets up a new formalism to investigate stochastic thermodynamics of out-of-equilibrium quantum systems, where stochasticity primarily comes from quantum measurement. In the absence of any bath, we define a purely quantum component to heat exchange, that corresponds to energy fluctuations induced by measurement back-action. By providing a central position to quantum measurement, our formalism bridges the gap between quantum optics and quantum thermodynamics: Thermal signatures of measurement induced irreversibility are identified in a simple implementation of Jarzynski equality, wh…
Recently it has been shown that the evolution of open quantum systems may be ``unraveled'' into individual ``trajectories,'' providing powerful numerical and conceptual tools. In this letter we use quantum trajectories to study mesoscopic systems and their classical limit. We show that in this limit, Quantum Jump (QJ) trajectories approach a diffusive limit very similar to the Quantum State Diffusion (QSD) unraveling. The latter follows classical trajectories in the classical limit. Hence, both unravelings show the rise of classical orbits. This is true for both regular and chaotic systems (wh…
A quantum system subjected to a strong continuous monitoring undergoes quantum jumps. This very well known fact hides a neglected subtlety: sharp scale-invariant fluctuations invariably decorate the jump process even in the limit where the measurement rate is very large. This article is devoted to the quantitative study of these remaining fluctuations, which we call spikes, and to a discussion of their physical status. We start by introducing a classical model where the origin of these fluctuations is more intuitive and then jump to the quantum realm where their existence is less intuitive. We…
We first use the quantum method to replicate the well-known results of a single atom relaxing, whilst demonstrating the intuitive picture it provides for dissipative dynamics. By use of individual "quantum trajectories", the method allows for simulation of systems inaccessible to ensemble treatments. This is shown by replicating resonance fluorescence, allowing us to concurrently demonstrate the method's facilitation of calculating photon statistics by the creation of discrete photon streams. To analyse these, we solidify the theoretical basis for, and implement, a computational method of calc…
The quantum jump approach allows to characterize the stochastic dynamics associated to an open quantum system submitted to a continuous measurement action. In this paper we show that this formalism can consistently be extended to non-Markovian system dynamics. The results rely in studying a measurement process performed on a bipartite arrangement characterized by a Markovian Lindblad evolution. Both a renewal and non-renewal extensions are found. The general structure of non-local master equations that admit an unravelling in terms of the corresponding non-Markovian trajectories are also found…
We present a general method to undertake a thorough analysis of the thermodynamics of the quantum jump trajectories followed by an arbitrary quantum harmonic network undergoing linear and bilinear dynamics. The approach is based on the phase-space representation of the state of a harmonic network. The large deviation function associated with this system encodes the full counting statistics of exchange and also allows one to deduce for fluctuation theorems obeyed by the dynamics. We illustrate the method showing the validity of a local fluctuation theorem about the exchange of excitations betwe…
On the basis of information theory, a new formalism of classical non-relativistic mechanics of a mass point is proposed. The particle trajectories of a general dynamical system defined on an (1+n)-dimensional smooth manifold are treated geometrically as dynamical variables. Statistical mechanics of particle trajectories are constructed in a classical manner. Thermodynamic variables are introduced through a partition function based on a canonical ensemble of trajectories. Within this theoretical framework, classical mechanics can be interpreted as an equilibrium state of statistical mechanics. …
Feedback-Enhanced Quantum Metrology and Clock Precision under Thermodynamic Uncertainty
Key Laboratory of Intelligent Optoelectronic Devices and Chips of Jiangsu Higher Education Institutions, School of Physical Science and Technology, Suzhou University of Science and Technology（江苏高校智能光电器件与芯片重点实验室，苏州科技大学物理科学与技术学院）；Advanced Technology Research Institute of Taihu Photon Center, School of Physical Science and Technology, Suzhou University of Science and Technology（太湖光子中心先进技术研究院，苏州科技大学物理科学与技术学院）；Department of Physics, Zhejiang Normal University（浙江师范大学物理系）
Thermodynamics of trajectories promises to make possible the thorough analysis of the dynamical properties of an open quantum system, a sought-after goal in modern physics. Unfortunately, calculation of the relevant quantities presents severe challenges. Determining the large-deviation function that gives access to the full counting statistics associated with a dynamical order parameter is challenging, if not impossible, even for systems evolving in a restricted Liouville space. Acting on the realisation that the salient features of most dynamical systems are encoded in the first few moments o…
We study the back-action of a single photon detector on the electromagnetic field upon a photodetection by considering a microscopic model in which the detector is constituted of a sensor and an amplification mechanism. Using the quantum trajectories approach we determine the Quantum Jump Superoperator (QJS) that describes the action of the detector on the field state immediately after the photocount. The resulting QJS consists of two parts: the bright counts term, representing the real photoabsorptions, and the dark counts term, representing the amplification of intrinsic excitations inside t…
Time-evolution of open, dissipative quantum system is a stochastic process that consists of a series of quantum jumps that take place at random times. Between quantum jumps quantum system idles for some time in a particular quantum state. Based on superfermion/superboson formalism and general Kossakowski- Lindblad master equation for an open quantum system we develop a method to compute distribution of waiting times between quantum jumps. We illustrate the use of the theory by computing waiting time distribution for model Fermi-system in thermodynamic equilibrium.
We apply a large-deviation method to study the diffusive trajectories of the quadrature operators of light within a reservoir connected to dissipative quantum systems. We formulate the study of quadrature trajectories in terms of characteristic operators and show that in the long time limit the statistics of such trajectories obey a large-deviation principle. We take our motivation from homodyne detection schemes which allow the statistics of quadrature operator of the light field to be measured. We illustrate our approach with four examples of increasing complexity: a driven two-level system,…
Non-Markovian evolution of an open quantum system can be `unraveled' into pure state trajectories generated by a non-Markovian stochastic (diffusive) Schrödinger equation, as introduced by Diósi, Gisin, and Strunz. Recently we have shown that such equations can be derived using the modal (hidden variable) interpretation of quantum mechanics. In this paper we generalize this theory to treat jump-like unravelings. To illustrate the jump-like behavior we consider a simple system: A classically driven (at Rabi frequency $Ω$) two-level atom coupled linearly to a three mode optical bath, with a cent…
We undertake a thorough analysis of the thermodynamics of the trajectories followed by a quantum harmonic oscillator coupled to $N$ dissipative baths by using a new approach to large-deviation theory inspired by phase-space quantum optics. As an illustrative example, we study the archetypal case of a harmonic oscillator coupled to two thermal baths, allowing for a comparison with the analogous classical result. In the low-temperature limit, we find a significant quantum suppression in the rate of work exchanged between the system and each bath. We further show how the presented method is capab…
Quantum open systems are described in the Markovian limit by master equations in Lindblad form. I argue that common ``quantum jumps'' techniques, which solve the master equation by unraveling its evolution into stochastic trajectories in Hilbert space, correspond closely to a particular set of decoherent histories. This is illustrated by a simple model of a photon counting experiment.
Small quantum systems can now be continuously monitored experimentally which allows for the reconstruction of quantum trajectories. A peculiar feature of these trajectories is the emergence of jumps between the eigenstates of the observable which is measured. Using the Stochastic Master Equation (SME) formalism for continuous quantum measurements, we show that the density matrix of a system indeed shows a jumpy behavior when it is subjected to a tight measurement (even if the noise in the SME is Gaussian). We are able to compute the jump rates analytically for any system evolution, i.e. any Li…
We study the dynamics of the single atom maser, or micromaser, by means of the recently introduced method of thermodynamics of quantum jump trajectories. We find that the dynamics of the micromaser displays multiple space-time phase transitions, i.e., phase transitions in ensembles of quantum jump trajectories. This rich dynamical phase structure becomes apparent when trajectories are classified by dynamical observables that quantify dynamical activity, such as the number of atoms that have changed state while traversing the cavity. The space-time transitions can be either first-order or conti…
We consider quantum stochastic processes and discuss a level 2.5 large deviation formalism providing an explicit and complete characterisation of fluctuations of time-averaged quantities, in the large-time limit. We analyse two classes of quantum stochastic dynamics, within this framework. The first class consists of the quantum jump trajectories related to photon detection; the second is quantum state diffusion related to homodyne detection. For both processes, we present the level 2.5 functional starting from the corresponding quantum stochastic Schrödinger equation and we discuss connection…
I formulate a quantum stochastic thermodynamics for the quantum trajectories of a continuously-monitored forced harmonic oscillator coupled to a thermal reservoir. Consistent trajectory-dependent definitions are introduced for work, heat, and entropy, through engineering the thermal reservoir from a sequence of two-level systems. Within this formalism the connection between irreversibility and entropy production is analyzed and confirmed by proving a detailed fluctuation theorem for quantum trajectories. Finally, possible experimental verifications are discussed.
We consider Markovian dynamics of a finitely dimensional open quantum system featuring a weak unitary symmetry, i.e., when the action of a unitary symmetry on the space of density matrices commutes with the master operator governing the dynamics. We show how to encode the weak symmetry in quantum stochastic dynamics of the system by constructing a weakly symmetric representation of the master operator: a symmetric Hamiltonian, and jump operators connecting only the symmetry eigenspaces with a fixed eigenvalue ratio. In turn, this representation simplifies both the construction of the master op…
We discuss topology in dissipative quantum systems from the perspective of quantum trajectories. The latter emerge in the unraveling of Markovian quantum master equations and/or in continuous quantum measurements. Ensemble-averaging quantum trajectories at the occurrence of quantum jumps, i.e., the jump times, gives rise to a discrete, deterministic evolution which is highly sensitive to the presence of dark states. We show for a broad family of translation-invariant collapse models that the set of dark state-inducing Hamiltonians imposes a nontrivial topological structure on the space of Hami…
