It is proved here that, as a consequence of the unitary quantum evolution, the expectation value of a properly defined quantum entropy operator (as opposed to the non-evolving von Neumann entropy) can only increase during non adiabatic transformations and remains constant during adiabatic ones. Thus Clausius formulation of the second law is established as a theorem in quantum mechanics, in a way that is equivalent to the previously established formulation in terms of minimal work principle [A. E. Allahverdyan and T. M. Nieuwenhuizen, Phys. Rev. E 71, 046107 (2005)]. The corresponding Quantum Mechanical Principle of Entropy Increase is then illustrated with an exactly solvable example, namely the driven harmonic oscillator. Attention is paid to both microcanonical and canonical initial condition. The results are compared to their classical counterparts.
The nonadiabatic entropy production is a useful tool for the thermodynamic analysis of continuously dissipating, nonequilibrium steady states. For open quantum systems, two seemingly distinct definitions for the nonadiabatic entropy production have appeared in the literature, one based on the quantum relative entropy and the other based on quantum trajectories. We show that these two formulations are equivalent. Furthermore, this equivalence leads us to a proof of the monotonicity of the quantum relative entropy under a special class of completely-positive, trace-preserving quantum maps, which…
The physical foundations of a variety of emerging technologies --- ranging from the applications of quantum entanglement in quantum information to the applications of nonequilibrium bulk and interface phenomena in microfluidics, biology, materials science, energy engineering, etc. --- require understanding thermodynamic entropy beyond the equilibrium realm of its traditional definition. This paper presents a rigorous logical scheme that provides a generalized definition of entropy free of the usual unnecessary assumptions which constrain the theory to the equilibrium domain. The scheme is base…
In the article, on a new definition of quantum entropy, Campisi has explained an operator for entropy based on quantum number operator. It has been claimed that the expectation values for this operator increases for every non-quasi-static time dependent perturbations. We have found an example for a case that entropy with this definition does not increase through a spontaneous process.
Deriving the laws of thermodynamics from a microscopic picture is a central quest of statistical mechanics. This tutorial focuses on the derivation of the first and second law for closed and open quantum systems far from equilibrium, where such foundational questions also become practically relevant for emergent nanotechnologies. The derivation is based on a microscopic definition of five essential quantities: internal energy, thermodynamic entropy, work, heat and temperature. These definitions are shown to satisfy the phenomenological laws of nonequilibrium thermodynamics for a large class of…
The example provided in the comment [arXiv:0803.2241] concerns a situation where the system is initially at negative temperature. It is known that in such cases the Law of Entropy Decrease holds. Nevertheless, this does not challenge the validity of the Second Law of Thermodynamics.
We propose a definition for the entanglement entropy of a gauge theory on a spatial lattice. Our definition applies to any subset of links in the lattice, and is valid for both Abelian and Non-Abelian gauge theories. For $\mathbb{Z}_N$ and $U(1)$ theories, without matter, our definition agrees with a particular case of the definition given by Casini, Huerta and Rosabal. We also argue that in general, both for Abelian and Non-Abelian theories, our definition agrees with the entanglement entropy calculated using a definition of the replica trick. Our definition, however, does not agree with some…
In this paper, we review the concept of entropy in connection with the description of quantum unstable systems. We revise the conventional definition of entropy due to Boltzmann and extend it so as to include the presence of complex-energy states. After introducing a generalized basis of states which includes resonances, and working with amplitudes instead of probabilities, we~found an expression for the entropy which exhibits real and imaginary components. We discuss the meaning of the imaginary part of the entropy on the basis of the similarities existing between thermal and time evolutions.
The postulates of thermodynamics were originally formulated for macroscopic systems. They lead to the definition of the entropy, which, for a homogeneous system, is a homogeneous function of order one in the extensive variables and is maximized at equilibrium. We say that the macroscopic systems are extensive and so it is also the entropy. For a mesoscopic system, by definition, the size and the contacts with other systems influence its thermodynamic properties and therefore, if we define an entropy, this cannot be a homogeneous of order one function in the extensive variables. So, mesoscopic …
A formulation of the generalized minimal output entropy conjecture for Gaussian channels is presented. It asserts that, for states with fixed input entropy, the minimal value of the output entropy of the channel (i.e. the minimal output entropy increment for fixed input entropy) is achieved by Gaussian states. In the case of centered channels (i.e. channels which do not add squeezing to the input state) this implies that the minimum is obtained by thermal (Gibbs) inputs. The conjecture is proved to be valid in some special cases.
In [Gallego and Aolita, Physical Review X 5, 041008 (2015)], the authors proposed a definition for the relative entropy of steering and showed that the resulting quantity is a convex steering monotone. Here we advocate for a different definition for relative entropy of steering, based on well grounded concerns coming from quantum Shannon theory. We prove that this modified relative entropy of steering is a convex steering monotone. Furthermore, we establish that it is uniformly continuous and faithful, in both cases giving quantitative bounds that should be useful in applications. We also cons…
From a new rigorous formulation of the general axiomatic foundations of thermodynamics we derive an operational definition of entropy that responds to the emergent need in many technological frameworks to understand and deploy thermodynamic entropy well beyond the traditional realm of equilibrium states of macroscopic systems. The new treatment starts from a previously developed set of carefully worded operational definitions for all the necessary basic concepts, and is not based on the traditional ones of "heat" and of "thermal reservoir." It is achieved in three steps. First, a new definitio…
We focus on the issue of proper definition of entanglement entropy in lattice gauge theories, and examine a naive definition where gauge invariant states are viewed as elements of an extended Hilbert space which contains gauge non-invariant states as well. Working in the extended Hilbert space, we can define entanglement entropy associated with an arbitrary subset of links, not only for abelian but also for non-abelian theories. We then derive the associated replica formula. We also discuss the issue of gauge invariance of the entanglement entropy. In the $Z_N$ gauge theories in arbitrary spac…
A definition for the entanglement entropy in a gauge theory was given recently in arXiv:1501.02593. Working on a spatial lattice, it involves embedding the physical state in an extended Hilbert space obtained by taking the tensor product of the Hilbert space of states on each link of the lattice. This extended Hilbert space admits a tensor product decomposition by definition and allows a density matrix and entanglement entropy for the set of links of interest to be defined. Here, we continue the study of this extended Hilbert space definition with particular emphasis on the case of Non-Abelian…
We review Wehrl's definition of a semiclassical entropy in terms of coherent states and give an introductory overview of Lieb's conjecture, its proof (including earlier results), generalizations, and the role of covariant quantum channels in this context. These structures motivate an alternative definition of coherent states and have interesting physical applications and implications.
The valence-bond structure of spin-1/2 Heisenberg antiferromagnets is closely related to quantum entanglement. We investigate measures of entanglement entropy based on transition graphs, which characterize state overlaps in the overcomplete valence-bond basis. The transition graphs can be generated using projector Monte Carlo simulations of ground states of specific hamiltonians or using importance-sampling of valence-bond configurations of amplitude-product states. We consider definitions of entanglement entropy based on the bonds or loops shared by two subsystems (bipartite entanglement). Re…
The properties of an alternative definition of quantum entropy, based on Wigner functions, are discussed. Such definition emerges naturally from the Wigner representation of quantum mechanics, and can easily quantify the amount of entanglement of a quantum state. It is shown that smoothing of the Wigner function induces an increase in entropy. This fact is used to derive some simple rules to construct positive definite probability distributions which are also admissible Wigner functions
For quantum systems with externally time-varied Hamiltonians a definition of operators of system's energy change rate (work per unit time) and entropy production observables is suggested and discussed in the context of rigorous statistical equalities (generalized fluctuation-dissipation relations) under the Jordan-symmetrized chronological operator ordering rule.
It is well known that a Shannon based definition of information entropy leads in the classical case to the Boltzmann entropy. It is tempting to regard the Von Neumann entropy as the corresponding quantum mechanical definition. But the latter is problematic from quantum information point of view. Consequently we introduce a new definition of entropy that reflects the inherent uncertainty of quantum mechanical states. We derive for it an explicit expression, and discuss some of its general properties. We distinguish between the minimum uncertainty entropy of pure states, and the excess statistic…
We describe some basic results for Quantum Stochastic Processes and present some new results about a certain class of processes which are associated to Quantum Iterated Function Systems (QIFS). We discuss questions related to the Markov property and we present a definition of entropy which is induced by a QIFS. This definition is a natural generalization of the Shannon-Kolmogorov entropy from Ergodic Theory. This definition is different from the one in the paper "A Thermodynamic Formalism for density matrices in Quantum Information" by the same authors.
We show that the rate of increase of von Neumann entropy computed from the reduced density matrix of an open quantum system is an excellent indicator of the dynamical behavior of its classical hamiltonian counterpart. In decohering quantum analogs of systems which exhibit classical hamiltonian chaos entropy production rate quickly tends to a constant which is given by the sum of the positive Lyapunov exponents, and falls off only as the system approaches equilibrium. By contrast, integrable systems tend to have entropy production rate which decreases as $t^{-1}$ well before equilibrium is atta…
The study of mutual entropy (information) and capacity in classica l system was extensively done after Shannon by several authors like Kolmogor ov and Gelfand. In quantum systems, there have been several definitions of t he mutual entropy for classical input and quantum output. In 1983, the autho r defined the fully quantum mechanical mutual entropy by means of the relati ve entropy of Umegaki, and he extended it to general quantum systems by the relative entropy of Araki and Uhlmann. When the author introduced the quantu m mutual entropy, he did not indicate that it contains other definitions…
We address in this paper how tightly the composability nature of systems: $S_{A+B} =Ω(S_A, S_B)$ constrains definition of generalized entropies and investigate explicitly the composability in some ansatz of the entropy form.
Unified entropy production in finite quantum systems
Independent Researcher（独立研究者）；Department of Information and Communication Engineering, Graduate School of Information Science and Technology, The University of Tokyo（东京大学信息理工学系研究科信息通信工程学系）
According to the first and second laws of thermodynamics and the definitions of work and heat, microscopic expressions for the non-equilibrium entropy production have been achieved. Recently, a redefinition of heat has been presented in [\href{Nature Communicationsvolume 8, Article number: 2180 (2017)}{Nat. Commun. 8, 2180 (2017)}]. We are going to determine how this redefinition of heat could affect the expression of the entropy production. Utilizing this new definition of heat, it could be found out that there is a new expression for the entropy production for thermal operations. It could be…
Entropy is one of the most basic concepts in thermodynamics and statistical mechanics. The most widely used definition of statistical mechanical entropy for a quantum system is introduced by von Neumann. While in classical systems, the statistical mechanical entropy is defined by Gibbs. The relation between these two definitions of entropy is still not fully explored. In this work, we study this problem by employing the phase-space formulation of quantum mechanics. For those quantum states having well-defined classical counterparts, we study the quantum-classical correspondence and quantum cor…
We extend the definition of the recently introduced valence bond entanglement entropy to arbitrary SU(2) wave functions of S=1/2 spin systems. Thanks to a reformulation of this entanglement measure in terms of a projection, we are able to compute it with various numerical techniques for frustrated spin models. We provide extensive numerical data for the one-dimensional J1-J2 spin chain where we are able to locate the quantum phase transition by using the scaling of this entropy with the block size. We also systematically compare with the scaling of the von Neumann entanglement entropy. We fina…
Regarding the strange properties of quantum entropy and entanglement, e.g., the negative quantum conditional entropy, we revisited the foundations of quantum entropy, namely, von Neumann entropy, and raised the new method of quantum fine-grained entropy. With the applications in entanglement theory, quantum information processing, and quantum thermodynamics, we demonstrated the capability of quantum fine-grained entropy to resolve some notable confusions and problems, including the measure of entanglement and quantumness, the additivity conjecture of entanglement of formation etc, and the defi…
We show that a recent definition of relative Rényi entropy is monotone under completely positive, trace preserving maps. This proves a recent conjecture of Müller-Lennert et al.
In this paper a general definition of quantum conditional entropy for infinite-dimensional systems is given based on recent work of Holevo and Shirokov arXiv:1004.2495 devoted to quantum mutual and coherent informations in the infinite-dimensional case. The properties of the conditional entropy such as monotonicity, concavity and subadditivity are also generalized to the infinite-dimensional case.
The notion of a holographic entropy cone has recently been introduced and it has been proven that this cone is polyhedral. However, the original definition was fully geometric and did not strictly require a holographic duality. We introduce a new definition of the cone, insisting that the geometries used for its construction should be dual to states of a CFT. As a result, the polyhedrality of this holographic cone does not immediately follow. A numerical evaluation of the Euclidean action for the geometries that realize extremal rays of the original cone indicates that these are subdominant bu…
What are the conditions on a field theoretic model leading to a finite entanglement entropy density? We prove two very general results: 1) Ultraviolet finiteness of a theory does not guarantee finiteness of the entropy density; 2) If the spectral dimension of the spatial boundary across which the entropy is calculated is non-negative at all scales, then the entanglement entropy cannot be finite. These conclusions, which we verify in several examples, negatively affect all quantum-gravity models, since their spectral dimension is always positive. Possible ways out are considered, including aban…
The Copenhagen interpretation of quantum mechanics, which first took shape in Bohr's landmark 1928 paper on complementarity, remains an enigma. Although many physicists are skeptical about the necessity of Bohr's philosophical conclusions, his pragmatic message about the importance of the whole experimental arrangement is widely accepted. It is, however, generally also agreed that the Copenhagen interpretation has no direct consequences for the mathematical structure of quantum mechanics. Here I show that the application of Bohr's main concepts of complementarity to the subsystems of a closed …
The aim of this work is to compute the entanglement entropy of real and virtual particles by rewriting the generating functional of $ϕ^{4}$ theory as a mean value between states and observables defined through the correlation functions. Then the von Neumann definition of entropy can be applied to these quantum states and in particular, for the partial traces taken over the internal or external degrees of freedom. This procedure can be done for each order in the perturbation expansion showing that the entanglement entropy for real and virtual particles behaves as $\ln (m_{0})$. In particular, e…
Several ways have been proposed in the literature to define a coherence measure based on Tsallis relative entropy. One of them is defined as a distance between a state and a set of incoherent states with Tsallis relative entropy taken as a distance measure. Unfortunately, this measure does not satisfy the required strong monotonicity, but a modification of this coherence has been proposed that does. We introduce three new Tsallis coherence measures coming from a more general definition that also satisfy the strong monotonicity, and compare all five definitions between each other. Using three c…
We demonstrate a generalization of quantum discord using a generalized definition of von-Neumann entropy, which is Sharma-Mittal entropy; and the new definition of discord is called Sharma-Mittal quantum discord. Its analytic expressions are worked out for two qubit quantum states as well as Werner, isotropic, and pointer states as special cases. The R{é}nyi, Tsallis, and von-Neumann entropy based quantum discords can be expressed as limiting cases for of Sharma-Mittal quantum discord. We also numerically compare all these discords and entanglement negativity.
This thesis investigates the connection between quantum theory, thermodynamics and information theory. Theories with structure similar to that of quantum theory are considered, mathematically described by the framework of "Generalized Probabilistic Theories". For these theories, a thought experiment by von Neumann is adapted to obtain a natural thermodynamic entropy definition, following a proposal by J. Barrett. Mathematical properties of this entropy are compared to physical consequences of the thought experiment. The validity of the second law of thermodynamics is investigated. In that cont…
The ${\bf f}(R)$ gravity field equations are derived as an equation of state of local space-time thermodynamics. Jacobson's arguments are non-trivially extended, by means of a more general definition of local entropy, for which Wald's definition of dynamic black hole entropy is used, as well as the concept of an effective Newton constant for graviton exchange, recently appeared in the literature.
