Hard spheres are ubiquitous in condensed matter: they have been used as models for liquids, crystals, colloidal systems, granular systems, and powders. Packings of hard spheres are of even wider interest, as they are related to important problems in information theory, such as digitalization of signals, error correcting codes, and optimization problems. In three dimensions the densest packing of identical hard spheres has been proven to be the FCC lattice, and it is conjectured that the closest packing is ordered (a regular lattice, e.g, a crystal) in low enough dimension. Still, amorphous packings have attracted a lot of interest, because for polydisperse colloids and granular materials the crystalline state is not obtained in experiments for kinetic reasons. We review here a theory of amorphous packings, and more generally glassy states, of hard spheres that is based on the replica method: this theory gives predictions on the structure and thermodynamics of these states. In dimensions between two and six these predictions can be successfully compared with numerical simulations. We will also discuss the limit of large dimension where an exact solution is possible. Some of the results we present here have been already published, but others are original: in particular we improved the discussion of the large dimension limit and we obtained new results on the correlation function and the contact force distribution in three dimensions. We also try here to clarify the main assumptions that are beyond our theory and in particular the relation between our static computation and the dynamical procedures used to construct amorphous packings.
We discuss a microscopic scheme to compute the rigidity of glasses or the plateau modulus of supercooled liquids by twisting replicated liquids. We first summarize the method in the case of harmonic glasses with analytic potentials. Then we discuss how it can be extended to the case of repulsive contact systems : the hard sphere glass and related systems with repulsive contact potentials which enable the jamming transition at zero temperature. For the repulsive contact systems we find entropic rigidity which behaves similarly as the pressure in the low temperature limit: it is proportional to …
Amorphous solids, such as glasses, have complex responses to deformations, with significant consequences in material design and applications. In this respect two intertwined aspects are important: stability and reversibility. It is crucial to understand on the one hand how a glass may become unstable due to increased plasticity under shear deformations; on the other hand, to what extent the response is reversible, meaning how much a system is able to recover the original configuration once the perturbation is released. Here we focus on assemblies of hard spheres as the simplest model of amorph…
Glasses are amorphous solids whose constituent particles are caged by their neighbors and thus cannot flow. This sluggishness is often ascribed to the free energy landscape containing multiple minima (basins) separated by high barriers. Here we show, using theory and numerical simulation, that the landscape is much rougher than is classically assumed. Deep in the glass, it undergoes a "roughness transition" to fractal basins. This brings about isostaticity at jamming and marginality of glassy states near jamming. Critical exponents for the basin width, the weak force distribution, and the spat…
We present a novel mechanism for the anomalous behaviour of the specific heat in low-temperature amorphous solids. The analytic solution of a mean-field model belonging to the same universality class as high-dimensional glasses, the spherical perceptron, suggests that there exists a crossover temperature above which the specific heat scales linearly with temperature while below it a cubic scaling is displayed. This relies on two crucial features of the phase diagram: (i) The marginal stability of the free-energy landscape, which induces a gapless phase responsible for the emergence of a power-…
We report an analytical study of the vibrational spectrum of the simplest model of jamming, the soft perceptron. We identify two distinct classes of soft modes. The first kind of modes are related to isostaticity and appear only in the close vicinity of the jamming transition. The second kind of modes instead are present everywhere in the glass phase and are related to the hierarchical structure of the potential energy landscape. Our results highlight the universality of the spectrum of normal modes in disordered systems, and open the way towards a detailed analytical understanding of the vibr…
We study the effect of thermalization on the rigidity of a randomly packed soft repulsive sphere system around the jamming point by analyzing the shear-modulus using the cloned liquid theory with the 1 step replica symmetry breaking ansatz and molecular dynamics simulations. Contrarily to the usual harmonic picture for solids, we found that the thermalized jamming system is anomalously softer than at zero temperature such that the shear-modulus becomes as small as the pressure down to vanishingly low temperatures.
The concept of jamming has attracted great research interest due to its broad relevance in soft matter such as liquids, glasses, colloids, foams, and granular materials, and its deep connection to the sphere packing problem and optimization problems. Here we show that the domain of amorphous jammed states of frictionless spheres can be significantly extended, from the well-known jamming-point at a fixed density, to a jamming-plane that spans the density and shear strain axes. We explore the jamming-plane, via athermal and thermal simulations of compression and shear jamming, with a help of an …
We compute the shear modulus of amorphous hard and soft spheres, using the exact solution in infinite spatial dimensions that has been developed recently. We characterize the behavior of this observable in the whole phase diagram, and in particular around the glass and jamming transitions. Our results are consistent with other theoretical approaches, that are unified within this general picture, and they are also consistent with numerical and experimental results. Furthermore, we discuss some properties of the out-of-equilibrium dynamics after a deep quench close to the jamming transition, and…
We numerically study the relaxation dynamics and associated criticality of non-Brownian frictionless spheres below jamming in spatial dimensions $d=2$, $3$, $4$, and $8$, and in the mean-field Mari-Kurchan model. We discover non-trivial finite-size and volume fraction dependences of the relaxation time associated to the relaxation of unjammed packings. In particular, the relaxation time is shown to diverge logarithmically with system size at any density below jamming, and no critical exponent can characterise its behaviour approaching jamming. In mean-field, the relaxation time is instead well…
We study the influence of particle size asymmetry on structural evolution of randomly jammed binary sphere mixtures with varying large-sphere/small-sphere composition. Simulations of jammed packings are used to assess the transition from large-sphere dominant to small-sphere dominant mixtures. For weakly asymmetric particle sizes, packing properties evolve smoothly, but not monotonically, with increasing small sphere composition, $f$. Our simulations reveal that at high values of ratio $α$ of large to small sphere radii, ($α\geq α_c \approx 5.75$) evolution of structural properties such as pac…
We numerically analyse the landscape governing the evolution of the vibrational dynamics of hard disk glasses as the density increases towards jamming. We find that the dynamics becomes slow, spatially correlated, and starts to display aging dynamics across an avoided Gardner transition, with a phenomenology that resembles three dimensional observations. We carefully analyse the behaviour of single glass samples, and find that the emergence of aging dynamics is controlled by the apparition of a complex organisation of the landscape that splits into a remarkable hierarchy of minima as jamming i…
The jamming transition of particles with finite-range interactions is characterized by a variety of critical phenomena, including power law distributions of marginal contacts. We numerically study a recently proposed simple model of jamming, which is conjectured to lie in the same universality class as the jamming of spheres in all dimensions. We extract numerical estimates of the critical exponents, θ = 0.451 $\pm$ 0.006 and γ = 0.404 $\pm$ 0.004, that match the exponents observed in sphere packing systems. We analyze finite-size scaling effects that manifest in a subcritical cutoff regime an…
We review the physics of jamming from the theoretical, experimental and numerical perspectives. We summarize the mean-field theory of jamming and the marginally stable solid phase, with particular emphasis on the connection with the Replica Symmetry Breaking theory of glasses. We report validations of the mean-field theory of jamming from experimental and numerical studies of critical behaviors near the transition. In particular, we describe the physics of jamming of frictionless, spherical particles, as well as more recent work on jamming of frictionless, non-spherical particles and frictiona…
The response of amorphous solids to an applied shear deformation is an important problem, both in fundamental and applied research. To tackle this problem, we focus on a system of hard spheres in infinite dimensions as a solvable model for colloidal systems and granular matter. The system is prepared above the dynamical glass transition density, and we discuss the phase diagram of the resulting glass under compression, decompression, and shear strain, expanding on previous results [P. Urbani and F. Zamponi, Phys.Rev.Lett. 118, 038001 (2017)]. We show that the solid region is bounded by a "shea…
We show that non-Brownian suspensions of repulsive spheres below jamming display a slow relaxational dynamics with a characteristic time scale that diverges at jamming. This slow time scale is fully encoded in the structure of the unjammed packing and can be readily measured via the vibrational density of states. We show that the corresponding dynamic critical exponent is the same for randomly generated and sheared packings. Our results show that a wide variety of physical situations, from suspension rheology to algorithmic studies of the jamming transition are controlled by a unique diverging…
We numerically produce fully amorphous assemblies of frictionless spheres in three dimensions and study the jamming transition these packings undergo at large volume fractions. We specify four protocols yielding a critical value for the jamming volume fraction which is sharply defined in the limit of large system size, but is different for each protocol. Thus, we directly establish the existence of a continuous range of volume fraction where nonequilibrium jamming transitions occur. However, these jamming transitions share the same critical behaviour. Our results suggest that, even in the abse…
We discuss the analytical solution through the cavity method of a mean field model that displays at the same time an ideal glass transition and a set of jamming points. We establish the equations describing this system, and we discuss some approximate analytical solutions and a numerical strategy to solve them exactly. We compare these methods and we get insight into the reliability of the theory for the description of finite dimensional hard spheres.
We investigate the dynamics of soft sphere liquids through computer simulations for spatial dimensions from $d =3$ to $8$, over a wide range of temperatures and densities. Employing a scaling of density-temperature dependent relaxation times, we precisely identify the density $ϕ_0$ which marks the ideal glass transition in the hard sphere limit, and a crossover from sub- to super-Arrhenius temperature dependence. The difference between $ϕ_0$ and the athermal jamming density $ϕ_J$, small in 3 and 4 dimensions, increases with dimension, with $ϕ_0 > ϕ_J$ for $d > 4$. We compare our results with r…
We review the field of the glass transition, glassy dynamics and aging from a statistical mechanics perspective. We give a brief introduction to the subject and explain the main phenomenology encountered in glassy systems, with a particular emphasis on spatially heterogeneous dynamics. We review the main theoretical approaches currently available to account for these glassy phenomena, including recent developments regarding mean-field theory of liquids and glasses, novel computational tools, and connections to the jamming transition. Finally, the physics of aging and off-equilibrium dynamics e…
We develop a microscopic theory to analyze the phase behaviour and compute correlation functions of dense assemblies of soft repulsive particles both at finite temperature, as in colloidal materials, and at vanishing temperature, a situation relevant for granular materials and emulsions. We use a mean-field statistical mechanical approach which combines elements of liquid state theory to replica calculations to obtain quantitative predictions for the location of phase boundaries, macroscopic thermodynamic properties and microstructure of the system. We focus in particular on the derivation of …
We determine the form of the complex shear modulus $G^*$ in soft sphere packings near jamming. Viscoelastic response at finite frequency is closely tied to a packing's intrinsic relaxational modes, which are distinct from the vibrational modes of undamped packings. We demonstrate and explain the appearance of an anomalous excess of slowly relaxing modes near jamming, reflected in a diverging relaxational density of states. From the density of states, we derive the dependence of $G^*$ on frequency and distance to the jamming transition, which is confirmed by numerics.
We present the study of the landscape structure of athermal soft spheres both as a function of the packing fraction and of the energy. We find that, on approaching the jamming transition, the number of different configurations available to the system has a steep increase and that a hierarchical organization of the landscape emerges. We use the knowledge of the structure of the landscape to predict the values of thermodynamic observables on the edge of the transition.
In a recent publication we established an analogy between the free energy of a hard sphere system and the energy of an elastic network [1]. This result enables one to study the free energy landscape of hard spheres, in particular to define normal modes. In this Letter we use these tools to analyze the activated transitions between meta-bassins, both in the aging regime deep in the glass phase and near the glass transition. We observe numerically that structural relaxation occurs mostly along a very small number of nearly-unstable extended modes. This number decays for denser packing and is sig…
In this Letter, we analyze the quantum dynamics of the perceptron model: a particle is constrained on a $N$-dimensional sphere, with $N\to \infty$, and subjected to a set of randomly placed hard-wall potentials. This model has several applications, ranging from learning protocols to the effective description of the dynamics of an ensemble of infinite-dimensional hard spheres in Euclidean space. We find that the jamming transition with quantum dynamics shows critical exponents different from the classical case. We also find that the quantum jamming transition, unlike the typical quantum critica…
Amorphous packings of spheres have been intensely investigated in order to understand the mechanical and flow behaviour of dense granular matter, and to explore universal aspects of the transition from fluid to structurally arrested or jammed states. Considerable attention has recently been focussed on anisotropic packings of frictional grains generated by shear deformation leading to shear jamming, which occurs below the jamming density for isotropic packings of frictionless grains. With the aim of disentangling the role of shear deformation induced structures and friction in generating shear…
We present a theoretical prediction on random close packing factor ϕ_RCP^b of binary granular packings based on the hard-sphere fluid theory. An unexplored regime is unravelled, where the packing fraction ϕ_RCP^b is smaller than that of the mono-sized one ϕ_RCP^m, i.e., the so-called loose jamming state. This is against our common perception that binary packings should always reach a denser packing than mono-sized packings at the jamming state. Numerical evidence further supports this prediction and confirms the regime location in the size ratio and mole fraction (R_r-X_s) space, where the siz…
The problem of finding the most efficient way to pack spheres has an illustrious history, dating back to the crystalline arrays conjectured by Kepler and the random geometries explored by Bernal in the 60's. This problem finds applications spanning from the mathematician's pencil, the processing of granular materials, the jamming and glass transitions, all the way to fruit packing in every grocery. There are presently numerous experiments showing that the loosest way to pack spheres gives a density of ~55% (RLP) while filling all the loose voids results in a maximum density of ~63-64% (RCP). W…
Critical jamming transitions are characterized by an astonishing degree of universality. Analytic and numerical evidence points to the existence of a large universality class that encompasses finite and infinite dimensional spheres and continuous constraint satisfaction problems (CCSP) such as the non-convex perceptron and related models. In this paper we investigate multilayer neural networks (MLNN) learning random associations as models for CCSP which could potentially define different jamming universality classes. As opposed to simple perceptrons and infinite dimensional spheres, which are …
Mechanically stable sphere packings are generated in three-dimensional space using the discrete element method, which span a wide range in structural order, ranging from fully amorphous to quasi-ordered structures, as characterized by the bond orientational order parameter. As the packing pressure, $p$, varies from the marginally rigid limit at the jamming transition ($p \approx 0$) to that of more robust systems ($p \gg 0$), the coordination number, $z$, follows a familiar scaling relation with pressure, namely, $Δz = z - z_c \sim p^{1/2}$, where $z_c = 2d = 6$ ($d=3$ is the spatial dimension…
I describe the classic circle-packing problem on a sphere, and the analytic and numerical approaches that have been used to study it. I then present a very simple Markov-chain Monte Carlo algorithm, which succeeds in finding the best solutions known today. The behavior of the algorithm is put into the context of the statistical physics of glasses.
We introduce a new model of hard spheres under confinement for the study of the glass and jamming transitions. The model is an one-dimensional chain of the $d$-dimensional boxes each of which contains the same number of hard spheres, and the particles in the boxes of the ends of the chain are quenched at their equilibrium positions. We focus on the infinite dimensional limit ($d \to \infty$) of the model and analytically compute the glass transition densities using the replica liquid theory. From the chain length dependence of the transition densities, we extract the characteristic length scal…
We study the glass and jamming transition of finite-dimensional models of simple liquids: hard- spheres, harmonic spheres and more generally bounded pair potentials that modelize frictionless spheres in interaction. At finite temperature, we study their glassy dynamics via field-theoretic methods by resorting to a mapping towards an effective quantum mechanical evolution, and show that such an approach resolves several technical problems encountered with previous attempts. We then study the static, mean-field version of their glass transition via replica theory, and set up an expansion in term…
Apart from not having crystallized, supercooled liquids can be considered as being properly equilibrated and thus can be described by a few thermodynamic control variables. In contrast, glasses and other amorphous solids can be arbitrarily far away from equilibrium and require a description of the history of the conditions under which they formed. In this paper we describe how the locality of interactions intrinsic to finite-dimensional systems affects the stability of amorphous solids far off equilibrium. Our analysis encompasses both structural glasses formed by cooling and colloidal assembl…
We study by molecular dynamics the interplay between arrest and crystallization in hard spheres. For state points in the plane of volume fraction ($0.54 \leq phi \leq 0.63$) and polydispersity ($0 \leq s \leq 0.085$), we delineate states that spontaneously crystallize from those that do not. For noncrystallizing (or precrystallization) samples we find isodiffusivity lines consistent with an ideal glass transition at $ϕ_g \approx 0.585$, independent of $s$. Despite this, for $s<0.05$, crystallization occurs at $ϕ> ϕ_g$. This happens on time scales for which the system is aging, and a diffusive …
Jamming in hard-particle packings has been the subject of considerable interest in recent years. In a paper by Torquato and Stillinger [J. Phys. Chem. B, 105 (2001)], a classification scheme of jammed packings into hierarchical categories of locally, collectively and strictly jammed configurations has been proposed. They suggest that these jamming categories can be tested using numerical algorithms that analyze an equivalent contact network of the packing under applied displacements, but leave the design of such algorithms as a future task. In this work we present a rigorous and efficient algo…
In order to develop a toy model for car's traffic in cities, in this paper we analyze, by means of numerical simulations, the transition among fluid regimes and a congested jammed phase of the flow of "kinetically constrained" hard spheres in planar random networks similar to urban roads. In order to explore as timescales as possible, at a microscopic level we implement an event driven dynamics as the infinite time limit of a class of already existing model (e.g. "Follow the Leader") on an Erdos-Renyi two dimensional graph, the crossroads being accounted by standard Kirchoff density conservati…
We show that soft spheres interacting with a linear ramp potential when overcompressed beyond the jamming point fall in an amorphous solid phase which is critical, mechanically marginally stable and share many features with the jamming point itself. In the whole phase, the relevant local minima of the potential energy landscape display an isostatic contact network of perfectly touching spheres whose statistics is controlled by an infinite lengthscale. Excitations around such energy minima are non-linear, system spanning, and characterized by a set of non-trivial critical exponents. We perform …
We study a well known machine learning model -the perceptron- as a simple model of jamming of hard objects. We exhibit two regimes: 1) a convex optimisation regime where jamming is hypostatic and non-critical. 2) a non convex optimisation regime where jamming is isostatic and critical. We characterise the critical jamming phase through exponents describing the distributions law of forces and gaps. Surprisingly we find that these exponents coincide with the corresponding ones recently computed in high dimensional hard spheres. In addition, modifying the perceptron to a random linear programming…
We perform extensive numerical simulations of a paradigmatic model glass former, the hard-sphere fluid with 10% polydispersity. We sample from the ensemble of trajectories with fixed observation time, whereby single trajectories are generated by event-driven molecular dynamics. We show that these trajectories can be characterized in terms of local structure, and we find a dynamical-structural (active-inactive) phase transition between two dynamical phases: one dominated by liquid-like trajectories with low degree of local order and one dominated by glassy-like trajectories with a high degree o…
Jamming is a phenomenon shared by a wide variety of systems, such as granular materials, foams, and glasses in their high density regime. This has motivated the development of a theoretical framework capable of explaining many of their static critical properties with a unified approach. However the dynamics occurring in the vicinity of the jamming point has received little attention and the problem of finding a connection with the local structure of the configuration remains unexplored. Here we address this issue by constructing physically well defined structural variables using the informatio…
We study Harmonic Soft Spheres as a model of thermal structural glasses in the limit of infinite dimensions. We show that cooling, compressing and shearing a glass lead to a Gardner transition and, hence, to a marginally stable amorphous solid as found for Hard Spheres systems. A general outcome of our results is that a reduced stability of the glass favors the appearance of the Gardner transition. Therefore using strong perturbations, e.g. shear and compression, on standard glasses or using weak perturbations on weakly stable glasses, e.g. the ones prepared close to the jamming point, are the…
Despite decades of work, gaining a first-principle understanding of amorphous materials remains an extremely challenging problem. However, recent theoretical breakthroughs have led to the formulation of an exact solution in the mean-field limit of infinite spatial dimension, and numerical simulations have remarkably confirmed the dimensional robustness of some of the predictions. This review describes these latest advances. More specifically, we consider the dynamical and thermodynamic descriptions of hard spheres around the dynamical, Gardner and jamming transitions. Comparing mean-field pred…
