From the thermodynamic equilibrium properties of a two-level system with variable energy-level gap $Δ$, and a careful distinction between the Gibbs relation $dE = T dS + (E/Δ) dΔ$ and the energy balance equation $dE = δQ^\leftarrow - δW^\to$, we infer some important aspects of the second law of thermodynamics and, contrary to a recent suggestion based on the analysis of an Otto-like thermodynamic cycle between two values of $Δ$ of a spin-1/2 system, we show that a quantum thermodynamic Carnot cycle, with the celebrated optimal efficiency $1 - (T_{low}/T_{high})$, is possible in principle with no need of an infinite number of infinitesimal processes, provided we cycle smoothly over at least three (in general four) values of $Δ$, and we change $Δ$ not only along the isoentropics, but also along the isotherms, e.g., by use of the recently suggested maser-laser tandem technique. We derive general bounds to the net-work to high-temperature-heat ratio for a Carnot cycle and for the 'inscribed' Otto-like cycle, and represent these cycles on useful thermodynamic diagrams.
Unbounded Work Extraction and Zero Work Fluctuations in a Super-Carnot Otto Information Engine
College of Physics, Jilin University（吉林大学物理学院）；Department of Chemistry and Department of Physics and Astronomy, State University of New York at Stony Brook（纽约州立大学石溪分校化学系和物理与天文学系）
The optimization of finite-time thermodynamic heat engines was intensively explored recently, yet limited to few cycles, e.g. finite-time Carnot-like cycle. In this paper, we supplement a new type of finite-time engine with quantum Otto cycle and show the better performance. The current model can be widely utilized benefited from the general \mathcal{C}/τ^{2} scaling of extra work for finite-time adiabatic process with long control time τ. Such scaling allows analytical optimization of the generic finite-time quantum Otto cycle to surpass the efficiency at maximum power for the Carnot-like eng…
Recent theoretical and experimental studies in quantum heat engines show that, in the quasi-static regime, it is possible to have higher efficiency than the limit imposed by Carnot, provided that engineered reservoirs are used. The quasi-static regime, however, is a strong limitation to the operation of heat engines, since infinitely long time is required to complete a cycle. In this paper we propose a two-level model as the working substance to perform a quantum Otto heat engine surrounded by a cold thermal reservoir and a squeezed hot thermal reservoir. Taking advantage of this model we show…
In order to describe quantum heat engines, here we systematically study isothermal and isochoric processes for quantum thermodynamic cycles. Based on these results the quantum versions of both the Carnot heat engine and the Otto heat engine are defined without ambiguities. We also study the properties of quantum Carnot and Otto heat engines in comparison with their classical counterparts. Relations and mappings between these two quantum heat engines are also investigated by considering their respective quantum thermodynamic processes. In addition, we discuss the role of Maxwell's demon in quan…
Lipkin-Meshkov-Glick model of two anisotropically interacting spins in a magnetic field is proposed as a working substance of a quantum Otto engine to explore and exploit the anisotropy effects for the optimization of engine operation. Three different cases for the adiabatic branches of the cycle have been considered. In the first two cases, either the magnetic field or coupling strength are changed; while in the third case, both the magnetic field and the coupling strength are changed by the same ratio. The system parameters for which the engine can operate similar to or dramatically differen…
Heat engines extract work by running cyclically between two heat reservoirs. When the two reservoirs are thermal and at different temperatures, the maximum efficiency of the engine is given by the Carnot limit. Here we consider a quantum Otto cycle for a time-dependent harmonic oscillator coupled to an engineered squeezed thermal reservoir. We show that the efficiency at maximum power increases with the degree of squeezing, exponentially approaching unity for large squeezing parameters $r$. Furthermore, we propose an experimental scheme to implement such a system by using a single trapped ion …
We construct an entangled quantum Otto engine based on spin-1/2 systems undergoing Dzyaloshinski-Moriya (DM) interaction within a varying magnetic field. We investigate the influence of the DM interaction on basic thermodynamic quantities, including heat transfer, work done, and efficiency and find that the DM interaction importantly influences the engine's thermodynamics. We obtain an expression for engine efficiency, finding it to yield the same efficiency for antiferromagnetic and ferromagnetic coupling. A new upper bound, nontrivially consistent with the second law of thermodynamics, is de…
Recent experimental breakthroughs produced the first nano heat engines that have the potential to harness quantum resources. An instrumental question is how their performance measures up against the efficiency of classical engines. For single ion engines undergoing quantum Otto cycles it has been found that the efficiency at maximal power is given by the Curzon-Ahlborn efficiency. This is rather remarkable as the Curzon-Alhbron efficiency was originally derived for endoreversible Carnot cycles. Here, we analyze two examples of endoreversible Otto engines within the same conceptual framework as…
Effects of Magnetic Anisotropy on 3-Qubit Antiferromagnetic Thermal Machines
Pontificia Universidad Católica de Valparaíso（天主教瓦爾帕萊索大學）；Universidad Técnica Federico Santa María（費德里科·聖塔瑪麗亞理工大學）；Millennium Nucleus in NanoBioPhysics (NNBP)（納米生物物理千年核）；Universidad Mayor（馬約爾大學）；Ohio University（俄亥俄大學）
We investigate the quantum thermodynamic cycle of a quantum heat engine carrying out an Otto thermodynamic cycle. We use the thermal properties of a moving heat bath with relativistic velocity with respect to the cold bath. As a working medium, we use a two-level system and a harmonic oscillator that interact with a moving heat bath and a static cold bath. In the current work, the quantum heat engine is studied in the high and low temperatures regime. Using quantum thermodynamics and the theory of open quantum system we obtain the total produced work, the efficiency and the efficiency at maxim…
To reveal the role of the quantumness in the Otto cycle and to discuss the validity of the thermodynamic uncertainty relation (TUR) in the cycle, we study the quantum Otto cycle and its classical counterpart. In particular, we calculate exactly the mean values and relative error of thermodynamic quantities. In the quasistatic limit, quantumness reduces the productivity and precision of the Otto cycle compared to that in the absence of quantumness, whereas in the finite-time mode, it can increase the cycle's productivity and precision. Interestingly, as the strength (heat conductance) between t…
We consider a finite-time quantum Otto heat engine that consists of two isochoric (thermal-contact) process, where the system is alternatively coupled to a hot squeezed and a cold thermal reservoir, and two unitary driven strokes, where the system is isolated from these two baths and its von Neumann entropy keeps constant. Both quantum inner friction and coherence are generated along the driven stroke and coherence cannot be fully erased after the finite-time hot isochore. Using full counting statistics, we present the probability distribution functions of heat injection and total work per cyc…
Gauge-invariant thermodynamics of a finite-time quantum Otto engine
Institute of Physics, Federal University of Goiás（戈亚斯联邦大学物理研究所）；Instituto de Física, Universidade Federal Fluminense（弗鲁米嫩塞联邦大学物理研究所）；Instituto de Física de São Carlos, Universidade de São Paulo（圣保罗大学圣卡洛斯物理研究所）
We study two-mode bosonic engines undergoing an Otto cycle. The energy exchange between the two bosonic systems is provided by a tunable unitary bilinear interaction in the mode operators modeling frequency conversion, whereas the cyclic operation is guaranteed by relaxation to two baths at different temperature after each interacting stage. By means of a two-point-measurement approach we provide the joint probability of the stochastic work and heat. We derive exact expressions for work and heat fluctuations, identities showing the interdependence among average extracted work, fluctuations and…
The stochastic efficiency [G. Verley et al., Nat. Commun. 5, 4721 (2014)] was introduced to evaluate the performance of energy-conversion machines in micro-scale. However, such an efficiency generally diverges when no heat is absorbed while work is produced in a thermodynamic cycle. As a result, any statistical moments of the efficiency do not exist. In this study, we come up with a different version of the definition for the stochastic efficiency which is always finite. Its mean value is equal to the conventional efficiency, and higher moments characterize the fluctuations of the cycle. In ad…
The availability of controllable macroscopic devices, which maintain quantum coherence over relatively long time intervals, for the first time allows an experimental realization of many effects previously considered only as Gedankenexperiments, such as the operation of quantum heat engines. The theoretical efficiency ηof quantum heat engines is restricted by the same Carnot boundary η_C as for the classical ones: any deviations from quasistatic evolution suppressing ηbelow η_C. Here we investigate an implementation of an analog of the Otto cycle in a tunable quantum coherent circuit and show t…
We study the 1-d isotropic Heisenberg model of two spin-1/2 systems as a quantum heat engine. The engine undergoes a four-step Otto cycle where the two adiabatic branches involve changing the external magnetic field at a fixed value of the coupling constant. We find conditions for the engine efficiency to be higher than the uncoupled model; in particular, we find an upper bound which is tighter than the Carnot bound. A new domain of parameter values is pointed out which was not feasible in the interaction-free model. Locally, each spin seems to effect the flow of heat in a direction opposite t…
We consider a finite-time Otto engine operating on a quantum harmonic oscillator and driven by shortcut-to-adiabaticity (STA) techniques to speed up its cycle. We study its efficiency and power when internal friction, time-averaged work, and work fluctuations are used as quantitative figures of merit, showing that time-averaged efficiency and power are useful cost functions for the characterization of the performance of the engine. We then use the minimum allowed time for validity of STA protocol relation to establish a physically relevant bound to the efficiency at maximum power of the STA-dr…
The Carnot statement of the second law of thermodynamics poses an upper limit on the efficiency of all heat engines. Recently, it has been studied whether generic quantum features such as coherence and quantum entanglement could allow for quantum devices with efficiencies larger than the Carnot efficiency. The present study shows that this is not permitted by the laws of thermodynamics. In particular, we will show that rather the definition of heat has to be modified to account for the thermodynamic cost for maintaining coherence and entanglement. Our theoretical findings are numerically illus…
The quantum Otto cycle serves as a bridge between the macroscopic world of heat engines and the quantum regime of thermal devices composed from a single element. We compile recent studies of the quantum Otto cycle with a harmonic oscillator as a working medium. This model has the advantage that it is analytically trackable. In addition, an experimental realization has been achieved employing a single ion in a harmonic trap. The review is embedded in the field of quantum thermodynamics and quantum open systems. The basic principles of the theory are explained by a specific example illuminating …
The quantum heat engines have drawn much attention due to miniaturization of devices recently. We study the dynamics of the quantum Otto heat engine using the driven-dissipative Schrödinger equation. Starting from different initial states, we simulate the time evolutions of the internal energy, power and heat-work conversion efficiency. The initial state impacts on these thermodynamic quantities before the Otto cycle reaches stable. In the transition period, the efficiency and power may be higher or lower than the corresponding values in the cyclostationary state. Remarkably, the efficiency co…
The Filtering Demon: Beyond Standard Thermodynamic Bounds and Harnessing Measurement Error and Quantum Friction
College of Physics, Jilin University（吉林大学物理学院）；Department of Chemistry and Department of Physics and Astronomy, State University of New York at Stony Brook（纽约州立大学石溪分校化学系和物理与天文学系）
We study a four-stroke Otto engine whose working fluid is a quantum Ising chain. The thermodynamic cycle consists in sweeps of the transverse magnetic field occurring in thermal isolation, alternated by thermalisation strokes with reservoirs at different temperatures. The system-environment coupling is modelled in a thermodynamically consistent way by means of a nonlocal Lindblad master equation. We show that the engine may operate in four different operation modes, depending on the various parameters, in particular it can act as a heat engine and as a refrigerator. We detect an enhancement of…
Similarity between quantum mechanics and thermodynamics is discussed. It is found that if the Clausius equality is imposed on the Shannon entropy and the analogue of the heat quantity, then the value of the Shannon entropy comes to formally coincide with that of the von Neumann entropy of the canonical density matrix, and pure-state quantum mechanics apparently transmutes into quantum thermodynamics. The corresponding quantum Carnot cycle of a simple two-state model of a particle confined in a one-dimensional infinite potential well is studied, and its efficiency is shown to be identical to th…
It is possible to extract work from a quantum-mechanical system whose dynamics is governed by a time-dependent cyclic Hamiltonian. An energy bath is required to operate such a quantum engine in place of the heat bath used to run a conventional classical thermodynamic heat engine. The effect of the energy bath is to maintain the expectation value of the system Hamiltonian during an isoenergetic expansion. It is shown that the existence of such a bath leads to equilibrium quantum states that maximise the von Neumann entropy. Quantum analogues of certain thermodynamic relations are obtained that …
Incorporating time into thermodynamics allows addressing the tradeoff between efficiency and power. A qubit engine serves as a toy model to study this tradeoff from first principles, based on the quantum theory of open systems. We study the quantum origin of irreversibility, originating from heat transport, quantum friction and thermalization in the presence of external driving. We construct various finite-time engine cycles based on the Otto and Carnot templates. Our analysis highlights the role of coherence and the quantum origin of entropy production.
A cyclic thermodynamic heat engine runs most efficiently if it is reversible. Carnot constructed such a reversible heat engine by combining adiabatic and isothermal processes for a system containing an ideal gas. Here, we present an example of a cyclic engine based on a single quantum-mechanical particle confined to a potential well. The efficiency of this engine is shown to equal the Carnot efficiency because quantum dynamics is reversible. The quantum heat engine has a cycle consisting of adiabatic and isothermal quantum processes that are close analogues of the corresponding classical proce…
Quantum thermal machines make use of non-classical thermodynamic resources, one of which is interactions between elements of the quantum working medium. In this paper, we examine the performance of a quasi-static quantum Otto engine based on two spins of arbitrary magnitudes subject to an external magnetic field and coupled via an isotropic Heisenberg exchange interaction. It has been earlier shown that the said interaction provides an enhancement of cycle efficiency for two spin-1/2 particles, with an upper bound which is tighter than the Carnot efficiency. However, the necessary conditions g…
The efficiency of cyclic heat engines is limited by the Carnot bound. This bound follows from the second law of thermodynamics and is attained by engines that operate between two thermal baths under the reversibility condition whereby the total entropy does not increase. By contrast, the efficiency of engines powered by quantum non-thermal baths has been claimed to surpass the thermodynamic Carnot bound. The key to understanding the performance of such engines is a proper division of the energy supplied by the bath to the system into heat and work, depending on the associated change in the sys…
We define thermodynamic configurations and identify two primitives of discrete quantum processes between configurations for which heat and work can be defined in a natural way. This allows us to uncover a general second law for any discrete trajectory that consists of a sequence of these primitives, linking both equilibrium and non-equilibrium configurations. Moreover, in the limit of a discrete trajectory that passes through an infinite number of configurations, i.e. in the reversible limit, we recover the saturation of the second law. Finally, we show that for a discrete Carnot cycle operati…
Cross-Spectral Reservoir Correlations as a Resource for Finite-Time Quantum Otto Engines
Ramakrishna Mission Vivekananda Educational and Research Institute（拉马克里希纳使命维韦卡南达教育研究所）；TCG CREST；Academy of Scientific and Innovative Research (AcSIR)（科学与创新研究学院）
We discuss a model of a closed quantum evolution of two-qubits where the joint Hamiltonian is so chosen that one of the qubits acts as a bath and thermalize the other qubit which is acting as the system. The corresponding exact master equation for the system is derived. Interestingly, for a specific choice of parameters the master equation takes the Gorini-Kossakowski-Lindblad-Sudarshan (GKLS) form with constant coefficients, representing pumping and damping of a single qubit system. Based on this model we construct an Otto cycle connected to a single qubit bath and study its thermodynamic pro…
We introduce a quantum heat engine performing an Otto cycle by using the thermal properties of the quantum vacuum. Since Hawking and Unruh, it has been established that the vacuum space, either near a black hole or for an accelerated observer, behaves as a bath of thermal radiation. In this work, we present a fully quantum Otto cycle, which relies on the Unruh effect for a single quantum bit (qubit) in contact with quantum vacuum fluctuations. By using the notions of quantum thermodynamics and perturbation theory we obtain that the quantum vacuum can exchange heat and produce work on the qubit…
Thermodynamics is traditionally concerned with systems comprised of a large number of particles. Here we present a framework for extending thermodynamics to individual quantum systems, including explicitly a thermal bath and work-storage device (essentially a `weight' that can be raised or lowered). We prove that the second law of thermodynamics holds in our framework, and give a simple protocol to extract the optimal amount of work from the system, equal to its change in free energy. Our results apply to any quantum system in an arbitrary initial state, in particular including non-equilibrium…
In order to build a quantum analog of traditional Carnot engine, a common choice is replacing the two thermodynamic adiabatic processes with two quantum mechanical adiabatic processes. In general, such quantum Carnot engine has six strokes. We analyze the efficiency of such six-stroke quantum Carnot engine in a perturbative way.
