We demonstrate the first implementation of a quantum algorithm on a liquid state nuclear magnetic resonance (NMR) quantum computer using almost pure states. This was achieved using a two qubit device where the initial state is an almost pure singlet nuclear spin state of a pair of 1H nuclei arising from a chemical reaction involving para-hydrogen. We have implemented Deutsch's algorithm for distinguishing between constant and balanced functions with a single query.
This thesis addresses the problems of initialization and separability in liquid state NMR based quantum information processors. We prepare pure quantum states lying above the entanglement threshold. Our pure state quantum computer derives its purity from the highly polarized nuclear spin states in the para-hydrogen molecule. The thesis begins with a critique of conventional NMR based quantum information processing outlining the major strengths and weaknesses of the technology. We describe the enhanced magnetic ordering of the nuclear spin states in para-hydrogen and an initialization experimen…
In conventional NMR experiments, the Zeeman energy gaps of the nuclear spin ensembles are much lower than their thermal energies, and accordingly exhibit tiny polarizations. Generally such low-purity quantum states are devoid of quantum entanglement. However, there exist certain nonclassical correlations which can be observed even in such systems. In this chapter, we discuss three such quantum correlations, namely, quantum contextuality, Leggett-Garg temporal correlations, and quantum discord. In each case, we provide a brief theoretical background and then describe some results from NMR exper…
Geometric phase has been proposed as one of the promising methodologies to perform fault tolerant quantum computations. However, since decoherence plays a crucial role in such studies, understanding of mixed state geometric phase has become important. While mixed state geometric phase was first introduced mathematically by Uhlmann, recently Sjoqvist et al. [Phys. Rev. Lett. 85(14), 2845 (2000)] have described the mixed state geometric phase in the context of quantum interference and shown theoretically that the visibility as well as the shift of the interference pattern are functions of geomet…
Theoretical explorations have revealed that quantum batteries can exploit quantum correlation to achieve faster charging, thus promising exciting applications in future technologies. Using NMR architecture, here we experimentally investigate various aspects of quantum battery with the help of nuclear spin systems in star-topology configuration. We first carry out numerical analysis to study how charging a quantum battery depends on the relative purity factors of charger and battery spins. By experimentally measuring the polarization of the battery spin undergoing charging, we estimate the batt…
Here we demonstrate how para-hydrogen can be used to prepare a two-spin system in an almost pure state which is suitable for implementing nuclear magnetic resonance (NMR) quantum computation. A 12ns laser pulse is used to initiate a chemical reaction involving pure para-hydrogn (the nuclear spin singlet of H2). The product, formed on the microsecond timescale, contains a hydrogen derived two-spin system with an effective spin-state purity of 0.916. To achieve a comparable result by direct cooling would require an unmanageable (in the liquid state) effective spin temperature of 6.4mK or an impr…
NMR quantum information processing studies rely on the reconstruction of the density matrix representing the so-called pseudo-pure states (PPS). An initially pure part of a PPS state undergoes unitary and non-unitary (relaxation) transformations during a computation process, causing a "loss of purity" until the equilibrium is reached. Besides, upon relaxation, the nuclear polarization varies in time, a fact which must be taken into account when comparing density matrices at different instants. Attempting to use time-fixed normalization procedures when relaxation is present, leads to various an…
Quantum coherence is a crucial resource for quantum information processing. By employing the language of coherence orders largely applied in NMR systems, quantum coherence has been currently addressed in terms of multiple quantum coherences (MQCs). Here we investigate the $α$-MQCs, a novel class of multiple quantum coherences which is based on $α$-relative purity, an information-theoretic quantifier analogous to quantum fidelity and closely related to Rényi relative entropy of order $α$. Our framework enables linking $α$-MQCs to Wigner-Yanase-Dyson skew information (WYDSI), an asymmetry monoto…
We investigate evolution of quantum correlations in ensembles of two-qubit nuclear spin systems via nuclear magnetic resonance techniques. We use discord as a measure of quantum correlations and the Werner state as an explicit example. We first introduce different ways of measuring discord and geometric discord in two-qubit systems and then describe the following experimental studies: (a) We quantitatively measure discord for Werner-like states prepared using an entangling pulse sequence. An initial thermal state with zero discord is gradually and periodically transformed into a mixed state wi…
We experimentally demonstrate in NMR a quantum interferometric multi-meter for extracting certain properties of unknown quantum states without resource to quantum tomography. It can perform direct state determinations, eigenvalue/eigenvector estimations, purity tests of a quantum system, as well as the overlap of any two unknown quantum states. Using the same device, we also demonstrate one-qubit quantum fingerprinting.
Hadamard spectroscopy has earlier been used to speed-up multi-dimensional NMR experiments. In this work we speed-up the two-dimensional quantum computing scheme, by using Hadamard spectroscopy in the indirect dimension, resulting in a scheme which is faster and requires the Fourier transformation only in the direct dimension. Two and three qubit quantum gates are implemented with an extra observer qubit. We also use one-dimensional Hadamard spectroscopy for binary information storage by spatial encoding and implementation of a parallel search algorithm.
We demonstrate the implementation of Grover's quantum search algorithm on a liquid state nuclear magnetic resonance (NMR) quantum computer using essentially pure states. This was achieved using a two qubit device where the initial state is an essentially pure ($ε=1.06\pm0.04$) singlet nuclear spin state of a pair of 1H nuclei arising from a chemical reaction involving para-hydrogen. We have implemented Grover's search to find one of four inputs which satisfies a function.
We investigate the dynamics of entanglement and quantum discord of two qubits in liquid state homonuclear NMR. Applying a phenomenological description for NMR under relaxation process, and taking a group of typical parameters of NMR, we show that when a zero initial state $|00> $ experiences a relaxation process, its entanglement disappears completely after a sequence of so-called sudden deaths and revivals, while the quantum discord retains remarkable values after a sequence of oscillations. That is to say, the quantum discord is more robust than entanglement.
An efficient quantum algorithm is proposed to solve in polynomial time the parity problem, one of the hardest problems both in conventional quantum computation and in classical computation, on NMR quantum computers. It is based on the quantum parallelism principle in a quantum ensemble, the selective decoherence manipulation, and the NMR phase-sensitive measurement. The quantum circuit for the quantum algorithm is designed explicitly.
The position-momentum uncertainty relations containing the dependence of their quantum bounds on state purity parameter $μ$ are discussed in context of possibilities to influence on the potential barrier transparency by means of decoherence processes. The behavior of barrier transparency $D$ is shown to satisfy the condition $μ^{-1}\ln D=const$. The particular case of thermal state with temperature $T$ where the purity parameter is a function of temperature is considered. For large temperature the condition for the barrier transparency is shown to be $T\ln D=const$.
The generalized purity is employed for investigating the process of coherence loss and delocalization of the Q-function in the Bloch sphere of a two-mode Bose-Einstein condensate in a symmetrical double well with cross-collision. Quantum phase transition of the model is signaled by the generalized purity as a function of an appropriate parameter of the Hamiltonian and the number of particles (N). A power law dependence of the critical parameter with N is derived.
We experimentally verify uncertainty relations for mixed states in the tomographic representation by measuring the radiation field tomograms, i.e. homodyne distributions. Thermal states of single-mode radiation field are discussed in details as paradigm of mixed quantum state. By considering the connection between generalised uncertainty relations and optical tomograms is seen that the purity of the states can be retrieved by statistical analysis of the homodyne data. The purity parameter assumes a relevant role in quantum information where the effective fidelities of protocols depend critical…
We give a general method of construting quantum circuit for random \QTR{it}{satisfiability} (SAT) problems with the basic logic gates such as multi-qubit controlled-NOT and NOT gates. The sizes of these circuits are almost the same as the sizes of the SAT formulas. Further, a parallelization scheme is described to solve random SAT problems efficiently through these quantum circuits in \QTR{it}{nuclear magnetic resonance} (NMR) ensemble quantum computing. This scheme exploits truly mixed states as input states rather than pseudo-pure states, and combines with the topological nanture of the NMR …
A detailed description of the development of a three qubit NMR realization of the Deutsch-Jozsa algorithm [Collins et.al., Phys. Rev. A 62, 022304 (2000)] is provided. The theoretical and experimental techniques used for the reduction of the algorithm's evolution steps into a sequence of NMR pulses are discussed at length. This includes the description of general pulse sequence compilation techniques, various schemes for indirectly coupled gate realizations, experimental pulse parameterization techniques and bookkeeping methods for pulse phases.
While quantum information processing by nuclear magnetic resonance (NMR) with small number of qubits is well established, implementation of lengthy computations have proved to be difficult due to decoherence/relaxation. In such circumstances, shallow circuits (circuits using parallel computation) may prove to be realistic. Parity and fanout gates are essential to create shallow circuits. In this article we implement inversion-on-equality gate, followed by parity gate and fanout gate in 3-qubit systems by NMR, using evolution under indirect exchange coupling Hamiltonian.
Algorithmic Cooling is a method that uses novel data compression techniques and simplecquantum computing devices to improve NMR spectroscopy, and to offer scalable NMR quantum computers. The algorithm recursively employs two steps. A reversible entropy compression of the computation quantum-bits (qubits) of the system and an irreversible heat transfer from the system to the environment through a set of reset qubits that reach thermal relaxation rapidly. Is it possible to experimentally demonstrate algorithmic cooling using existing technology? To allow experimental algorithmic cooling, the the…
This article deals with non-adiabatic processes (i.e. processes excluded by the adiabatic theorem) from the geometrical (group-theoretical) point of view. An approximated formula for the probabilities of the non-adiabatic transitions is derived in the adiabatic regime for the case when the parameter-dependent Hamiltonian represents a smooth curve in the Lie algebra and the quantal dynamics is determined by the corresponding Lie group evolution operator. We treat the spin precession in a time-dependent magnetic field and the over-barrier reflection problem in a uniform way using the first-order…
We demonstrate a five-bit nuclear-magnetic-resonance quantum computer that distinguishes among various functions on four bits, making use of quantum parallelism. Its construction draws on the recognition of the sufficiency of linear coupling along a chain of nuclear spins, the synthesis of a suitably coupled molecule, and the use of a multi-channel spectrometer.
Quantum channels depending on a number of classical control parameters are considered. Assuming the stochastic fluctuations of the control parameters in the small errors limit it is shown that the channel fidelity is equal to the average value of the channel purities calculated in the cases of the control errors presence and absence respectively. The result validity is demonstrated on two particular examples, namely, one-qubit quantum gates implemented in the framework of the ion trap setup and the single qubit anisotropic depolarizing quantum channel.
DNA computation could in principle solve the satisfiability (SAT) problem due to the operations in parallel on extremely large numbers of strands. We demonstrate some quantum gates corresponding to the DNA ones, based on which an implementation of DNA algorithm for SAT problem is available by quantum mechanical way. Since quantum computation owns the favorable feature of operations in parallel on 2$^{n}$ states by using only n qubits, instead of 2$^{n}$ strands in DNA computation, computational complexity is much reduced in treating the SAT problem quantum mechanically. We take a three-clause …
Repeated observations of a quantum system interacting with another one can drive the latter toward a particular quantum state, irrespectively of its initial condition, because of an {\em effective non-unitary evolution}. If the target state is a pure one, the degree of purity of the system approaches unity, even when the initial condition of the system is a mixed state. In this paper we study the behavior of the purity from the initial value to the final one, that is unity. Depending on the parameters, after a finite number of measurements, the purity exhibits oscillations, that brings about a…
Recent technological advances may lead to the development of small scale quantum computers capable of solving problems that cannot be tackled with classical computers. A limited number of algorithms has been proposed and their relevance to real world problems is a subject of active investigation. Analysis of many-body quantum system is particularly challenging for classical computers due to the exponential scaling of Hilbert space dimension with the number of particles. Hence, solving problems relevant to chemistry and condensed matter physics are expected to be the first successful applicatio…
Advanced photonic quantum technology relies on multi-photon interference which requires bright sources of high-purity single photons. Here, we implement a novel domain-engineering technique for tailoring the nonlinearity of a parametric down-conversion crystal. We create pairs of independently-heralded telecom-wavelength photons and achieve high heralding, brightness and spectral purities without filtering.
Finding the factors of an integer can be achieved by various experimental techniques, based on an algorithm developed by Schleich et al., which uses specific properties of Gaußsums. Experimental limitations usually require truncation of these series, but if the truncation parameter is too small, it is no longer possible to distinguish between factors and so-called "ghost" factors. Here, we discuss two techniques for distinguishing between true factors and ghost factors while keeping the number of terms in the sum constant or only slowly increasing. We experimentally test these modified algorit…
Knowledge of the relationships among different features of quantumness, like entanglement and state purity, is important from both fundamental and practical viewpoints. Yet, this issue remains little explored in dynamical contexts for open quantum systems. We address this problem by studying the dynamics of entanglement and purity for two-qubit systems using paradigmatic models of radiation-matter interaction, with a qubit being isolated from the environment (spectator configuration). We show the effects of the corresponding local quantum channels on an initial two-qubit pure entangled state i…
It is considered the indirect inter-qubit coupling in 1D chain of atoms with nuclear spins 1/2, which plays role of qubits in the quantum register. This chain of the atoms is placed by regular way in easy-axis 3D antiferromagnetic thin plate substrate, which is cleaned from the other nuclear spin containing isotopes. It is shown that the range of indirect inter-spin coupling may run to a great number of lattice constants both near critical point of quantum phase transition in antiferromagnet of spin-flop type (control parameter is external magnetic field) and/or near homogeneous antiferromagne…
Various quantum technology applications require high-purity single photons with high generation rate. Although different methods are employed to generate such photons, heralded single photons from spontaneous parametric down-conversion (SPDC) is the most commonly used approach. Photon generation rate from the heralded single-photon sources are limited by the efficiency of the detectors to record coincidence detection of the photon pairs which are lower than the single-photon counts recorded separately on each detector. In this paper we present a revised expression to calculate second-order tem…
Reconstruction of density matrices is important in NMR quantum computing. An analysis is made for a 2-qubit system by using the error matrix method. It is found that the state tomography method determines well the parameters that are necessary for reconstructing the density matrix in NMR quantum computations. Analysis is also made for a simplified state tomography procedure that uses fewer read-outs. The result of this analysis with the error matrix method demonstrates that a satisfactory accuracy in density matrix reconstruction can be achieved even in a measurement with the number of read-ou…
Squeezed light has evolved into a powerful tool for quantum technology, ranging from quantum enhanced sensing and quantum state engineering based on partial post-selection techniques. The pulsed generation of squeezed light is of particular interest, as it can provide accurate time stamp and physically defined temporal mode, which are highly preferred in complex communication networks and large-scale information processing. However, the multimode feature of pulsed squeezing in conventional single-pass configuration limits the purity of the output state, negatively impacting its application in …
We theoretically and experimentally investigate the spectral tunability and purity of photon pairs generated from spontaneous parametric down conversion in periodically poled $\mathrm{KTiOPO_4}$ crystal with group-velocity matching condition. The numerical simulation predicts that the purity of joint spectral intensity ($P_{JSI}$) and the purity of joint spectral amplitude ($P_{JSA}$) can be kept higher than 0.98 and 0.81, respectively, when the wavelength is tuned from 1460 nm to 1675 nm, which covers the S-, C-, L-, and U-band in telecommunication wavelengths. We also directly measured the j…
