We analyze the effect of realistic noise sources for an atomic clock consisting of a local oscillator that is actively locked to a spin-squeezed (entangled) ensemble of $N$ atoms. We show that the use of entangled states can lead to an improvement of the long-term stability of the clock when the measurement is limited by decoherence associated with instability of the local oscillator combined with fluctuations in the atomic ensemble's Bloch vector. Atomic states with a moderate degree of entanglement yield the maximal clock stability, resulting in an improvement that scales as $N^{1/6}$ compared to the atomic shot noise level.
We discuss the possibility of synchronising two atomic clocks exchanging entangled photon pairs through a quantum channel. A proposal for implementing practically such a scheme is discussed.
We report a proof-of-principle experiment on distant clock synchronization. Besides the achievement of picosecond resolution at 3 kilometer distance, this experiment demonstrated a novel concept for high accuracy non-local timing and positioning based on the quantum feature of entangled states.
We report that entangled pairs of quantum clocks (non-degenerate quantum bits) can be used as a specialized detector for precisely measuring difference of proper-times that each constituent quantum clock experiences. We describe why the proposed scheme would be more precise in the measurement of proper-time difference than a scheme of two-separate-quantum-clocks. We consider possibilities that the proposed scheme can be used in precision test of the relativity theory.
We present an algorithm for synchronizing two clocks based on second-order quantum interference between entangled photons generated by parametric down-conversion. The procedure is distinct from the standard Einstein two-way clock synchronization method in that photon correlations are used to define simultaneous events in the frame of reference of a Hong-Ou-Mandel (HOM) interferometer. Once the HOM interferometer is balanced, by use of an adjustable optical delay in one arm, arrival times of simultaneously generated photons are recorded by each clock. Classical information on the arrival times …
Entangled states of light exhibit measurable correlations between light detections at separated locations. These correlations are exploited in entangled-state quantum key distribution. To do so involves setting up and maintaining a rhythm of communication among clocks at separated locations. Here, we try to disentangle our thinking about clocks as used in actual experiments from theories of time, such as special relativity or general relativity, which already differ between each other. Special relativity intertwines the concept of time with a particular definition of the synchronization of clo…
Quantum networks are essential for realising distributed quantum computation and quantum communication. Entangled photons are a key resource, with applications such as quantum key distribution, quantum relays, and quantum repeaters. All components integrated in a quantum network must be synchronised and therefore comply with a certain clock frequency. In quantum key distribution, the most mature technology, clock rates have reached and exceeded 1GHz. Here we show the first electrically pulsed sub-Poissonian entangled photon source compatible with existing fiber networks operating at this clock…
We present a quantum-enhanced atomic clock protocol based on groups of sequentially larger Greenberger-Horne-Zeilinger (GHZ) states, that achieves the best clock stability allowed by quantum theory up to a logarithmic correction. The simultaneous interrogation of the laser phase with such a cascade of GHZ states realizes an incoherent version of the phase estimation algorithm that enables Heisenberg-limited operation while extending the Ramsey interrogation time beyond the laser noise limit. We compare the new protocol with state of the art interrogation schemes, and show that entanglement all…
Realizing long distance entanglement swapping with independent sources in the real-world condition is important for both future quantum network and fundamental study of quantum theory. Currently, demonstration over a few of tens kilometer underground optical fiber has been achieved. However, future applications demand entanglement swapping over longer distance with more complicated environment. We exploit two independent 1-GHz-clock sequential time-bin entangled photon-pair sources, develop several automatic stability controls, and successfully implement a field test of entanglement swapping o…
Atomic clocks are typically operated by locking a local oscillator (LO) to a single atomic ensemble. In this article we propose a scheme where the LO is locked to several atomic ensembles instead of one. This results in an exponential improvement compared to the conventional method and provides a stability of the clock scaling as $(αN)^{-m/2}$ with $N$ being the number of atoms in each of the $m$ ensembles and $α$ is a constant depending on the protocol being used to lock the LO
A frequency stabilized laser referenced to an unperturbed atomic two level system acts as the most accurate clock with femtosecond clock ticks. For any meaningful use, a Femtosecond Laser Frequency Comb (FLFC) is used to transfer the atomic clock accuracy to electronically countable nanosecond clock ticks. Here we propose an alternative clockwork based on the phenomenon that when an atomic system is slowly evolved in a cyclic path, the atomic energy levels gather some phase called the geometric phase. This geometric phase dependent energy shift has been used here to couple the two frequency re…
We show that the sensitivity of an atomic clock can be enhanced below the shot-noise level by initially squeezing, and then measuring in output, the population of a single atomic level. This can simplify current experimental protocols which requires squeezing of the relative number of particles of the two populated states. We finally study, as a specific application, the clock sensitivity obtained with a single mode quantum non-demolition measurement.
We propose a hybrid quantum-classical atomic clock protocol where the interrogation of an ensemble of uncorrelated atoms in a spin-coherent state is used to feedback one (or more) spin-squeezed atomic ensembles toward their optimal phase sensitivity point. This protocol overcomes the stability of a single Ramsey clock and it reaches a Heisenberg-limited stability while avoiding non-destructive measurements. Analytical predictions are compared with numerical simulations of clocks operations including correlated 1/f local oscillator noise.
We study experimentally the lifetime of a special class of entangled states in an atomic clock, squeezed spin states. In the presence of anisotropic noise, their lifetime is strongly dependent on squeezing orientation. We measure the Allan deviation spectrum of a clock operated with a phase-squeezed input state. For integration times up to 50 s the squeezed clock achieves a given precision 2.8(3) times faster than a clock operating at the standard quantum limit.
Distributed g(2) Retrieval with Atomic Clocks: Eliminating Conventional Sync Protocols
Department of Physics & Astronomy, University of Tennessee, Knoxville（田纳西大学诺克斯维尔分校物理与天文学系）；Department of Physics & Astronomy, University of Tennessee, Chattanooga（田纳西大学查塔努加分校物理与天文学系）；UTC Quantum Center, University of Tennessee, Chattanooga（田纳西大学查塔努加分校UTC量子中心）
A method is proposed to employ entangled and squeezed light for determining the position of a party and for synchronizing distant clocks. An accuracy gain over analogous protocols that employ classical resources is demonstrated and a quantum-cryptographic positioning application is given, which allows only trusted parties to learn the position of whatever must be localized. The presence of a lossy channel and imperfect photodetection is considered. The advantages in using partially entangled states is discussed.
Gravitational time dilation in quantum clock interferometry with entangled multi-photon states and quantum memories
Humboldt-Universität zu Berlin（柏林洪堡大学）；ZARM, Unversität Bremen（不来梅大学ZARM中心）；Vienna Center for Quantum Science and Technology, Atominstitut, TU Wien（维也纳量子科学与技术中心，原子物理研究所，维也纳工业大学）
The ultimate stability of atomic clocks is limited by the quantum noise of the atoms. To reduce this noise it has been suggested to use entangled atomic ensembles with reduced atomic noise. Potentially this can push the stability all the way to the limit allowed by the Heisenberg uncertainty relation, which is denoted the Heisenberg limit. In practice, however, entangled states are often more prone to decoherence, which may prevent reaching this performance. Here we present an adaptive measurement protocol that in the presence of a realistic source of decoherence enables us to get near Heisenb…
Fundamental low-energy limits to the accuracy of quantum clock and stopwatch models in which the clock hand motion is activated by the presence of a particle in a region of space have been studied in the past, but their relevance for actual atomic clocks had not been assessed. In this work we address the effect of slow atomic quantum motion on Rabi and Ramsey resonance fringe patterns, as a perturbation of the results based on classical atomic motion. We find the dependence of the fractional error of the corresponding atomic clocks on the atomic velocity and interaction parameters.
We use a quantum non-demolition measurement to generate a spin squeezed state and to create entanglement in a cloud of 10^5 cold cesium atoms, and for the first time operate an atomic clock improved by spin squeezing beyond the projection noise limit in a proof-of-principle experiment. For a clock-interrogation time of 10 μ\s the experiments show an improvement of 1.1 dB in the signal-to-noise ratio, compared to the atomic projection noise limit.
We use a quantum nondemolition measurement to probe the collective pseudospin of an atomic ensemble in a high-finesse optical cavity. We analyze the backaction antisqueezing produced by the measurement process to show that our protocol could create conditional spin squeezing in the atomic ensemble.
High-precision nonlocal temporal correlation identification in the entangled photon pairs is critical to measure the time offset between remote independent time scales for many quantum information applications. The first nonlocal correlation identification was reported in 2009, which extracts the time offset via the algorithm of iterative fast Fourier transformations (FFTs) and their inverse. The least identification resolution is restricted by the peak identification threshold of the algorithm, and thus the time offset calculation precision is limited. In this paper, an improvement for the id…
We propose a multi party quantum clock synchronization protocol that makes optimal use of the maximal multipartite entanglement of GHZ-type states. To realize the protocol, different versions of maximally entangled eigenstates of collective energy are generated by local transformations that distinguish between different groupings of the parties. The maximal sensitivity of the entangled states to time differences between the local clocks can then be accessed if all parties share the results of their local time dependent measurements. The efficiency of the protocol is evaluated in terms of the s…
Optical atomic clocks are our most precise tools to measure time and frequency. They enable precision frequency comparisons between atoms in separate locations to probe the space-time variation of fundamental constants, the properties of dark matter, and for geodesy. Measurements on independent systems are limited by the standard quantum limit (SQL); measurements on entangled systems, in contrast, can surpass the SQL to reach the ultimate precision allowed by quantum theory - the so-called Heisenberg limit. While local entangling operations have been used to demonstrate this enhancement at mic…
A Mølmer-Sørensen entangling gate is realized for pairs of trapped $^{111}$Cd$^+$ ions using magnetic-field insensitive "clock" states and an implementation offering reduced sensitivity to optical phase drifts. The gate is used to generate the complete set of four entangled states, which are reconstructed and evaluated with quantum-state tomography. An average target-state fidelity of 0.79 is achieved, limited by available laser power and technical noise. The tomographic reconstruction of entangled states demonstrates universal quantum control of two ion-qubits, which through multiplexing can …
The coherent population trapping (CPT) effect is used for making compact atomic clocks. There are two types of CPT clocks: the one in which the Raman beams are applied continuously and the one in which two CPT pulses separated by a dark period are applied (Ramsey scheme). It is obvious that the technique of spin squeezing can only be applied to the Ramsey CPT clock to enhance the sensitivity. However, it is not apparent how to adapt to the CPT clock the protocols for the microwave clock using one-axis-twist squeezing (OATS), since the Ramsey CPT clock is not trivially equivalent to the Ramsey …
A technique is demonstrated that allows free space atomic fountain clocks and interferometers to utilize optical cavity generated spin-squeezed states with over $390\,000$ ${}^{87}\text{Rb}$ atoms. Fluorescence imaging is used for population spectroscopy, after a free fall time of 4 milliseconds, to resolve a single-shot phase sensitivity of $814 (61)$ microradians, which is $5.8(0.6)$ decibels (dB) below the quantum projection limit. The dynamic range is observed to be 100 milliradians. When operating as a microwave atomic clock with $240\,000$ atoms at a 3.6 ms Ramsey time, a single-shot fra…
A clock steps a computer through a cycle of phases. For the propagation of logical symbols from one computer to another, each computer must mesh its phases with arrivals of symbols from other computers. Even the best atomic clocks drift unforeseeably in frequency and phase; feedback steers them toward aiming points that depend on a chosen wave function and on hypotheses about signal propagation. A wave function, always under-determined by evidence, requires a guess. Guessed wave functions are coded into computers that steer atomic clocks in frequency and position---clocks that step computers t…
Improving the clock stability is of fundamental importance for the development of quantum-enhanced metrology. One of the main limitations arises from the randomly-fluctuating local oscillator (LO) frequency, which introduces "phase slips" for long interrogation times and hence failure of the frequency-feedback loop. Here we propose a strategy to improve the stability of atomic clocks by interrogating two out-of-phase state sharing the same LO. While standard Ramsey interrogation can only determine phases unambiguously in the interval $[-π/2,π/2]$, the joint interrogation allows for an extensio…
We propose an optical scheme to generate genuine entangled states of four atomic qubits in optical cavities using a single-photon source, beam splitters and single photon detectors. We show how to generate deterministically sixteen orthonormal and independent genuine entangled states of four atomic qubits. It is found that the sixteen genuine entangled states form a new type of representation of the four-atomic-qubit system, i.e., the genuine entangled-state representation. This representation brings new interesting insight onto better understanding multipartite entanglement.
We present a physical scheme for entanglement concentration of unknown atomic entangled states via cavity decay. In the scheme, the atomic state is used as stationary qubit and photonic state as flying qubit, and a close maximally entangled state can be obtained from pairs of partially entangled states probabilistically.
Introducing classical fields, we can transfer entanglement completely from discrete qubits into entangled coherent state. The entanglement also can be retrieved from the continuous-variable state of the cavities to the atomic qubits. Via postselection measure, atomic entangled state and entangled coherent state can be mutual transformed fully.
We develop a formalism to incorporate exchange symmetry considerations into the calculation of collisional frequency shifts and blackbody radiation effects for atomic clock transitions using a density matrix formalism. The formalism is developed for both fermionic and bosonic atomic clocks. Results for a finite temperature ${}^{87}$Sr ${}^1S_0$ ($F = 9/2$) atomic clock in a magic wavelength optical lattice are presented.
It is shown how possible corrections to ordinary quantum mechanics described by the Lindblad equation might be detected by exploiting the great precision of atomic clocks.
We consider possible extensions to quantum mechanics proposed by Steven Weinberg, and re-analyze his prediction of a new test based upon three atomic clocks in the same atom. We propose realistic experimental systems where this hypothesis can be tested. Two systems already set limits on deviations from quantum mechanics, while with another system, one would be able to search for new physics at the limit of sensitivity of the best atomic clocks.
Atomic clocks use atomic transitions as frequency references. The susceptibility of the atomic transition to external fields limits clock stability and introduces systematic frequency shifts. Here, we propose to realize an atomic clock that utilizes an entangled superposition of states of multiple atomic species, where the reference frequency is a sum of the individual transition frequencies. The superposition is selected such that the susceptibilities of the respective transitions, in individual species, destructively interfere leading to improved stability and reduced systematic shifts. We p…
Quantum generalisation of Einstein's Equivalence Principle can be verified with entangled clocks as quantum reference frames
Università degli Studi di Milano（米兰大学）；University of Vienna（维也纳大学）；Austrian Academy of Sciences（奥地利科学院）；Perimeter Institute for Theoretical Physics（理论物理珀米特研究所）；ETH Zürich（苏黎世联邦理工学院）
Based on the second-order quantum interference between frequency entangled photons that are generated by parametric down conversion, a quantum strategic algorithm for synchronizing two spatially separated clocks has been recently presented. In the reference frame of a Hong-Ou-Mandel (HOM) interferometer, photon correlations are used to define simultaneous events. Once the HOM interferometer is balanced by use of an adjustable optical delay in one arm, arrival times of simultaneously generated photons are recorded by each clock. The clock offset is determined by correlation measurement of the r…
Motivated by the ideas of using cold alkaline earth atoms trapped in an optical lattice for realization of optical atomic clocks, we investigate theoretically the perturbative effects of atom-atom interactions on a clock transition frequency. These interactions are mediated by the dipole fields associated with the optically excited atoms. We predict resonance-like features in the frequency shifts when constructive interference among atomic dipoles occur. We theoretically demonstrate that by fine-tuning the coherent dipole-dipole couplings in appropriately designed lattice geometries, the undes…
We have investigated the benefits of spin squeezed states for clocks operated with typical Brownian frequency noise-limited laser sources. Based on an analytic model of the closed servo-loop of an optical atomic clock, we can give quantitative predictions on the optimal clock stability for a given dead time and laser noise. Our analytic predictions are in very good agreement with numerical simulations of the closed servo-loop. We find that for usual cyclic Ramsey interrogation of single atomic ensembles with dead time, even with the current most stable lasers spin squeezing can only improve th…
We propose a novel class of atomic clocks based on highly charged ions. We consider highly-forbidden laser-accessible transitions within the $4f^{12}$ ground-state configurations of highly charged ions. Our evaluation of systematic effects demonstrates that these transitions may be used for building exceptionally accurate atomic clocks which may compete in accuracy with recently proposed nuclear clock.
We discuss perspectives for new tests of general relativity which are based on recent technological developments as well as new ideas. We focus our attention on tests performed with atomic clocks and do not repeat arguments present in the other contributions to the present volume. In particular, we present the scientific motivations of the space projects ACES and SAGAS.
We describe a collective state atomic clock with Ramsey fringes narrowed by a factor of $\sqrt{N}$ compared to a conventional clock, N being the number of non-interacting atoms, without violating the uncertainty relation. This narrowing is explained as being due to interferences among the collective states, representing an effective $\sqrt{N}$ fold increase in the clock frequency, without entanglement. The detection process, which measures a collective state, can be used to increase the quantum efficiency of detection significantly, yielding a net improvement in stability by as much as a facto…
We demonstrate agreement between measurements and ab initio calculations of the frequency shifts caused by distributed cavity phase variations in the microwave cavity of a primary atomic fountain clock. Experimental verification of the finite element models of the cavities gives the first quantitative evaluation of this leading uncertainty and allows it to be reduced to delta nu / nu = 8.4\times10^-17. Applying these experimental techniques to clocks with improved microwave cavities will yield negligible distributed cavity phase uncertainties, less than \pm1\times10^-17.
We investigate the feasibility of precision frequency metrology with large ion crystals. For clock candidates with a negative differential static polarisability, we show that micromotion effects should not impede the performance of the clock. Using Lu+ as a specific example, we show that quadrupole shifts due to the electric fields from neighbouring ions do not significantly affect clock performance. We also show that effects from the tensor polarisability can be effectively managed with a compensation laser at least for a small number of ions (<1000). These results provide new possibilities f…
We report the operation of a dual Rb/Cs atomic fountain clock. 133Cs and 87Rb atoms are cooled, launched, and detected simultaneously in LNE-SYRTE's FO2 double fountain. The dual clock operation occurs with no degradation of either the stability or the accuracy. We describe the key features for achieving such a simultaneous operation. We also report on the results of the first Rb/Cs frequency measurement campaign performed with FO2 in this dual atom clock configuration, including a new determination of the absolute 87Rb hyperfine frequency.
Optical lattice clocks can now resolve the height difference below 1 mm within an atomic ensemble by means of gravitational redshift with integration over sufficient amount of time. Further improvement in the stability enables the clocks to resolve the height difference of subsystems within an atomic ensemble that is conventionally interrogated as a single coherent spin state in a single Ramsey sequence, resulting in the dephasing of the coherent spin state. This effect is observable with a clock of a stability of $\lesssim 10^{-21}$ by introducing a single-layer-resolved imaging system for a …
We discuss quantum variational optimization of Ramsey interferometry with ensembles of $N$ entangled atoms, and its application to atomic clocks based on a Bayesian approach to phase estimation. We identify best input states and generalized measurements within a variational approximation for the corresponding entangling and decoding quantum circuits. These circuits are built from basic quantum operations available for the particular sensor platform, such as one-axis twisting, or finite range interactions. Optimization is defined relative to a cost function, which in the present study is the Ba…
We theoretically discuss an implementation of a Sagnac interferometer with cold atoms. In contrast to currently existing schemes our protocol does not rely on any free propagation of atoms. Instead it is based on superpositions of fully confined atoms and state-dependent transport along a closed path. Using Ramsey sequences for an atomic clock, the accumulated Sagnac phase is encoded in the resulting population imbalance between two internal (clock) states. Using minimal models for the above protocol we analytically quantify limitations arising from atomic dynamics and finite temperature. We d…
Spin squeezing is a form of entanglement that can improve the stability of quantum sensors operating with multiple particles, by inducing inter-particle correlations that redistribute the quantum projection noise. Previous analyses of potential metrological gain when using spin squeezing were performed on theoretically ideal states, without incorporating experimental imperfections or inherent limitations which result in non-unitary quantum state evolution. Here, we show that potential gains in clock stability are substantially reduced when the spin squeezing is non-unitary, and derive analytic…
Atomic clocks have been transformational in science and technology, leading to innovations such as global positioning, advanced communications, and tests of fundamental constant variation. Next-generation optical atomic clocks can extend the capability of these timekeepers, where researchers have long aspired toward measurement precision at 1 part in $\bm{10^{18}}$. This milestone will enable a second revolution of new timing applications such as relativistic geodesy, enhanced Earth- and space-based navigation and telescopy, and new tests on physics beyond the Standard Model. Here, we describe…
Optical atomic clocks using highly-charged ions hold an intriguing promise of metrology at the 19th significant figure. Here we study transitions within the $4f^{12}$ ground-state electronic configuration of highly charged ions. We consider isotopes lacking hyperfine structure and show that the detrimental effects of coupling of electronic quadrupole moments to gradients of trapping electric field can be effectively reduced by using specially chosen virtual clock transitions. The estimated systematic fractional clock accuracy is shown to be below $10^{-19}$.
