We study a single particle which obeys non-relativistic quantum mechanics in R^N and has Hamiltonian H = -Delta + V(r), where V(r) = sgn(q)r^q. If N \geq 2, then q > -2, and if N = 1, then q > -1. The discrete eigenvalues E_{n\ell} may be represented exactly by the semiclassical expression E_{n\ell}(q) = min_{r>0}\{P_{n\ell}(q)^2/r^2+ V(r)}. The case q = 0 corresponds to V(r) = ln(r). By writing one power as a smooth transformation of another, and using envelope theory, it has earlier been proved that the P_{n\ell}(q) functions are monotone increasing. Recent refinements to the comparison theorem of QM in which comparison potentials can cross over, allow us to prove for n = 1 that Q(q)=Z(q)P(q) is monotone increasing, even though the factor Z(q)=(1+q/N)^{1/q} is monotone decreasing. Thus P(q) cannot increase too slowly. This result yields some sharper estimates for power-potential eigenvlaues at the bottom of each angular-momentum subspace.
Essential properties of semiclassical approximation for quantum mechanics are viewed as axioms of an abstract semiclassical mechanics. Its symmetry properties are discussed. Semiclassical systems being invariant under Lie groups are considered. An infinitesimal analog of group relation is written. Sufficient conditions for reconstructing semiclassical group transformations (integrability of representation of Lie algebra) are discussed. The obtained results may be used for mathematical proof of Poincare invariance of semiclasical Hamiltonian field theory and for investigation of quantum anomali…
A class of singular integral operators, encompassing two physically relevant cases arising in perturbative QCD and in classical fluid dynamics, is presented and analyzed. It is shown that three special values of the parameters allow for an exact eigenfunction expansion; these can be associated to Riemannian symmetric spaces of rank one with positive, negative or vanishing curvature. For all other cases an accurate semiclassical approximation is derived, based on the identification of the operators with a peculiar Schroedinger-like operator.
A non-associative algebra of observables cannot be represented as operators on a Hilbert space, but it may appear in certain physical situations. This article employs algebraic methods in order to derive uncertainty relations and semiclassical equations, based on general properties of quantum moments.
Recently Ohsawa has studied the Marsden-Weinstein-Meyer quotient of the manifold $T^*\mathbb{R}^n\times T^*\mathbb{R}^{2n^2}$ under a $\operatorname{O}(2n)$-symmetry, and has used this quotient to describe the relationship between two different parametrisations of Gaussian wave packet dynamics commonly used in semiclassical mechanics. In this paper we suggest a new interpretation of (a subset of) the unreduced space as being the frame bundle $\mathcal{F}(T^*\mathbb{R}^n)$ of $T^*\mathbb{R}^n$. We outline some advantages of this interpretation, and explain how it can be extended to more general…
The semiclassical mechanics of the Wigner 6j-symbol is examined from the standpoint of WKB theory for multidimensional, integrable systems, to explore the geometrical issues surrounding the Ponzano-Regge formula. The relations among the methods of Roberts and others for deriving the Ponzano-Regge formula are discussed, and a new approach, based on the recoupling of four angular momenta, is presented. A generalization of the Yutsis-type of spin network is developed for this purpose. Special attention is devoted to symplectic reduction, the reduced phase space of the 6j-symbol (the 2-sphere of K…
We study a special kind of semiclassical limit of quantum dynamics on a circle and in a box (infinite potential well with hard walls) as the Planck constant tends to zero and time tends to infinity. The results give detailed information about all stages of evolution of quantum wave packets: semiclassical motion, collapses, revivals, as well as intermediate stages. In particular, we rigorously justify the fact that the spatial distribution of a wave packet is most of the time close to uniform. This fact was previously known only from numerical calculations. We apply the obtained results to a pr…
Exact procedures that follow Dirac's constraint quantization of gauge theories are usually technically involved and often difficult to implement in practice. We overview an "effective" scheme for obtaining the leading order semiclassical corrections to the dynamics of constrained quantum systems developed elsewhere. Motivated by the geometrical view of quantum mechanics, our method mimics the classical Dirac-Bergmann algorithm and avoids direct reference to a particular representation of the physical Hilbert space. We illustrate the procedure through the example of a relativistic particle in M…
The Gutzwiller semiclassical trace formula links the eigenvalues of the Scrodinger operator ^H with the closed orbits of the corresponding classical mechanical system, associated with the Hamiltonian H, when the Planck constant is small ("semiclassical regime"). Gutzwiller gave a heuristic proof, using the Feynman integral representation for the propagator of ^H. Later on mathematicians gave rigorous proofs of this trace formula, under different settings, using the theory of Fourier Integral Operators and Lagrangian manifolds. Here we want to show how the use of coherent states (or gaussian be…
The exactness of the semiclassical method for three-dimensional problems in quantum mechanics is analyzed. The wave equation appropriate in the quasiclassical region is derived. It is shown that application of the standard leading-order WKB quantization condition to this equation reproduces exact energy eigenvalues for all solvable spherically symmetric potentials.
We present several recent results concerning the transition between quantum and classical mechanics, in the situation where the underlying dynamical system has an hyperbolic behaviour. The special role of invariant manifolds will be emphasized, and the long time evolution will show how the quantum non-determinism and the classical chaotic sensitivity to initial conditions can be compared, and in a certain sense overlap.
In accordance with the Keller-Maslov global WKB theory, a semiclassical scalar wave field is best encoded as a triple consisting of (i) a Lagrangian submanifold $Λ$ in the ray phase space, (ii) a density $μ$ on $Λ$, and (iii) an overall phase factor $ϕ$. We present the Hamiltonian structure of the Cauchy problem for such a "geometric semiclassical state" in the special case where the wave operator is Hermetian. Variational, symplectic, and Poisson formulations of the time evolution equations for $(Λ,μ,ϕ)$ are identitfied. Because we work in terms of the Keller-Maslov global WKB ansatz, as oppo…
We compute the semiclassical formulas for the partition functions obtained using two different Lagrangians: the Chern-Simons functional and the symplectic action functional.
We prove a version of the Feynman-Kac formula for Levy processes and integro-differential operators, with application to the momentum representation of suitable quantum (Euclidean) systems whose Hamiltonians involve Lévy-type potentials. Large deviation techniques are used to obtain the limiting behavior of the systems as the Planck constant approaches zero. It turns out that the limiting behavior coincides with fresh aspects of the semiclassical limit of (Euclidean) quantum mechanics. Non-trivial examples of Levy processes are considered as illustrations and precise asymptotics are given for …
We present the analytical solution in closed form for the semiclassical limit of the quantum mechanical Coulomb Green function in position space in n dimensions. We utilize a projection method which has its roots in Lambert's theorem and which allows us to treat the system as an essentially one dimensional problem. The semiclassical result assumes a simple analytical form and is well suited for a numerical evaluation. The method can also be extended to classically forbidden space regions. Already for moderately large principal quantum numbers nu >= 5, the semiclassical Green function is found …
We investigate the particle and kinetic-energy densities for a system of $N$ fermions bound in a local (mean-field) potential $V(\bfr)$. We generalize a recently developed semiclassical theory [J. Roccia and M. Brack, Phys. Rev.\ Lett. {\bf 100}, 200408 (2008)], in which the densities are calculated in terms of the closed orbits of the corresponding classical system, to $D>1$ dimensions. We regularize the semiclassical results $(i)$ for the U(1) symmetry breaking occurring for spherical systems at $r=0$ and $(ii)$ near the classical turning points where the Friedel oscillations are predominant…
We formulate a semiclassical theory for systems with spin-orbit interactions. Using spin coherent states, we start from the path integral in an extended phase space, formulate the classical dynamics of the coupled orbital and spin degrees of freedom, and calculate the ingredients of Gutzwiller's trace formula for the density of states. For a two-dimensional quantum dot with a spin-orbit interaction of Rashba type, we obtain satisfactory agreement with fully quantum-mechanical calculations. The mode-conversion problem, which arose in an earlier semiclassical approach, has hereby been overcome.
We investigate symmetric oscillators, and in particular their quantization, by employing semiclassical and quantum phase functions introduced in the context of Liouville-Green transformations of the Schrödinger equation. For anharmonic oscillators, first order semiclassical quantization is seldom accurate and the higher order expansions eventually break down given the asymptotic nature of the series. A quantum phase that allows in principle to retrieve the exact quantum mechanical quantization condition and wavefunctions is given along with an iterative scheme to compute it. The arbitrariness …
In quantum mechanics, systems can be described in phase space in terms of the Wigner function and the star-product operation. Quantum characteristics, which appear in the Heisenberg picture as the Weyl's symbols of operators of canonical coordinates and momenta, can be used to solve the evolution equations for symbols of other operators acting in the Hilbert space. To any fixed order in the Planck's constant, many-body potential scattering problem simplifies to a statistical-mechanical problem of computing an ensemble of quantum characteristics and their derivatives with respect to the initial…
The semiclassically scaled time-dependent multi-particle Schrödinger equation describes, inter alia, quantum dynamics of nuclei in a molecule. It poses the combined computational challenges of high oscillations and high dimensions. This paper reviews and studies numerical approaches that are robust to the small semiclassical parameter. We present and analyse variationally evolving Gaussian wave packets, Hagedorn's semiclassical wave packets, continuous superpositions of both thawed and frozen Gaussians, and Wigner function approaches to the direct computation of expectation values of observabl…
The Newton--Hooke duality and its generalization to arbitrary power laws in classical, semiclassical and quantum mechanics are discussed. We pursue a view that the power-law duality is a symmetry of the action under a set of duality operations. The power dual symmetry is defined by invariance and reciprocity of the action in the form of Hamilton's characteristic function. We find that the power-law duality is basically a classical notion and breaks down at the level of angular quantization. We propose an ad hoc procedure to preserve the dual symmetry in quantum mechanics. The energy-coupling e…
