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arXiv 2205.04772cond-mat.mtrl-sci
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La2-xCaxCoMnO6系列的自发交换偏置效应

The spontaneous exchange bias effect in La2-xCaxCoMnO6 series

J. R. Jesus, L. Bufaiçal, E. M. Bittar

摘要:

用X射线衍射和磁谱仪研究了La_(2-x)Ca_xCoMnO_6(0 $\leq$ x $\leq$ 0.75)多晶化合物的结构、电子和磁性。所有的样品都具有正交结构,并显示出与Ca掺杂的晶胞略有下降。随温度变化的磁化强度测量揭示了一个复杂的磁性行为与两个铁磁转变。这些转变归因于Co2+-Mn 4+和Co 3 +-Mn 3+耦合,并建议在这些无序化合物中存在额外的反铁磁耦合。在零外部磁场中冷却样品后测量的场依赖磁化曲线揭示了Ca掺杂样品的自发交换偏置(SEB)效应。在界面处的未补偿的磁耦合的加强,所造成的反铁磁相的增加,解释了增加的SEB与增加的Ca-含量。

英文摘要:

Structural, electronic and magnetic properties of polycrystalline La2-xCaxCoMnO6 (0 $\leq$ x $\leq$ 0.75) compounds are investigated by x-ray diffraction and magnetometry. All the samples have an orthorhombic structure and show a slight decrease in the unit cell with Ca-doping. Temperature-dependent magnetization measurements reveal a complex magnetic behavior with two ferromagnetic transitions. These transitions are ascribed to Co2+--Mn4+ and Co3+--Mn3+ couplings and suggest the presence of additional antiferromagnetic couplings in these disordered compounds. Field-dependent magnetization curves, measured after cooling the samples in a zero external magnetic field, reveal the spontaneous exchange bias (SEB) effect for the Ca-doped samples. The strengthening of the uncompensated magnetic coupling at the interfaces, caused by the increased antiferromagnetic phase, explains the increase of SEB with increasing the Ca-content.

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