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arXiv 2104.02241cond-mat.supr-concond-mat.str-el
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BiS2-based超导体NdO1-xFxBiS2中无公度电荷密度波的直接观测

Direct Observation of an Incommensurate Charge Density Wave in the BiS2-based Superconductor NdO1-xFxBiS2

Jooseop Lee, Masanori Nagao, Yoshikazu Mizuguchi, Jacob Ruff

摘要:

BiS $_2$基超导体的超导电性的本质一直是有争议的,而从头计算提出了这个系统非常接近电荷密度波(CDW)相。利用高能高通量X射线衍射,我们揭示了NdO $_{1-x}$ F $_{x}$ BiS $_2$超导体($x$ = 0.37和0.3)中与超导性共存的本征长程CDW相。NdO $_{0.63}$ F $_{0.37}$ BiS $_2$中的CDW波矢对应于Q $_{\rm{CDW}}$ =(0.17,0.17,0.5),并与横向原子位移有关。有趣的是,这个波矢不符合基于声子软化或费米表面嵌套的理论预期。在超导转变温度最高的NdO $_{0.7}$ F $_{0.3}$ BiS $_2$中,CDW伴线比NdO $_{0.63}$ F $_{0.37}$ BiS $_2$稍宽、稍弱,可能与超导竞争.最后,我们测量了整个超导转变温度的热漫散射,并没有发现有意义的变化,有利于非常规的配对机制。我们的结果表明,了解CDW的重要性,这可能持有的关键BiS $_2$为基础的超导体的超导电性。

英文摘要:

The nature of superconductivity in BiS$_2$-based superconductors has been controversial while ab-initio calculations proposed this system in close proximity to a charge-density-wave (CDW) phase. Using high-energy high-flux X-ray diffraction, we reveal an intrinsic and long-range CDW phase coexisting with superconductivity in NdO$_{1-x}$F$_{x}$BiS$_2$ superconductor ($x$ = 0.37 and 0.3). The CDW wavevector in NdO$_{0.63}$F$_{0.37}$BiS$_2$ correspond Q$_{\rm{CDW}}$ = (0.17, 0.17, 0.5) and is associated with transverse atomic displacements. Interestingly, this wavevector does not match theoretical expectations based on either phonon softening or Fermi surface nesting. In NdO$_{0.7}$F$_{0.3}$BiS$_2$, where the superconducting transition temperature is highest, the CDW satellites are slightly broader and weaker compared to NdO$_{0.63}$F$_{0.37}$BiS$_2$, possibly suggesting the competition with the superconductivity. Lastly, we measure a thermal diffuse scattering across the superconducting transition temperature and find no meaningful changes in favor of the unconventional pairing mechanism. Our result suggests the importance of understanding CDW which might hold a key to the superconductivity in the BiS$_2$-based superconductor.

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