This paper deals with the first analysis of the neutron and gamma time series measured with organic scintillators from plutonium samples by using information measures. Fast neutron detection with organic scintillators has been widely used for various nuclear applications and homeland security. One of the significant attributes of special nuclear materials (SNM) is the high multiplicity events in a short period of time. The time distributions of neutron and gamma-rays events for the plutonium metal plates designed as fuel plates for the Idaho National Laboratory (INL) Zero Power were measured with the Fast Neutron Multiplicity Counter (FNMC) consisting of 8 EJ-309 liquid scintillators and 8 stilbene detectors. Since the neutron correlated counts within the coincidence window of 40 ns are related to 240Pu effective mass of plutonium metal plates we investigated the randomness of the measured neutron and gamma-rays events. To access such information, we resort to complexity measures in the hope of being able to connect complexity values with the reliability of detection. That was done through (i) application of Kolmogorov complexity (KC) and its derivatives [Kolmogorov spectrum and its highest value (KCM) and running complexity (RKC)] and (ii) establishing the breaking point after which there exists a sharp drop in the running Kolmogorov complexity of the neutron and gamma-rays time series. It was found that the complexity of all the time series detected from the sample with 5, 9, 11, 13, and 15 plutonium plates had the high almost identical values of KC while the sample with 3 plates had by one-third smaller KC values than all the others. These calculations were supplemented by the Lypaunov exponents for a time series and the NIST tests. The low KC values can be addressed to the different sources of uncertainties in measuring procedure with the sample consisting of three plates.
Organic liquid scintillators have been used for decades in many neutrino physics experiments. They are particularly suited for the detection of low-energy neutrinos where energy and timing information is required. Organic liquid scintillators exhibit advantages such as high light yield, cost effectiveness, radio purity, and more. However, they also entail disadvantages, most prominently a lack of vertex resolution and particle identification. In recent years, various novel ideas have emerged to improve the performance of organic liquid scintillators. In this review, novel approaches to organic…
Over the course of several decades, organic liquid scintillators have formed the basis for successful neutrino detectors. Gadolinium-loaded liquid scintillators provide efficient background suppression for electron antineutrino detection at nuclear reactor plants. In the Double Chooz reactor antineutrino experiment, a newly developed beta-diketonate gadolinium-loaded scintillator is utilized for the first time. Its large scale production and characterization are described. A new, light yield matched metal-free companion scintillator is presented. Both organic liquids comprise the target and "G…
Organic liquid scintillators are used in many neutrino physics experiments of the past and present. In particular for low energy neutrinos when realtime and energy information are required, liquid scintillators have several advantages compared to other technologies. In many cases the organic liquid needs to be loaded with metal to enhance the neutrino signal over background events. Several metal loaded scintillators of the past suffered from chemical and optical instabilities, limiting the performance of these neutrino detectors. Different ways of metal loading are described in the article wit…
Background: Organic scintillators are widely used for neutron detection in both basic nuclear physics and applications. While the proton light yield of organic scintillators has been extensively studied, measurements of the light yield from neutron interactions with carbon nuclei are scarce. Purpose: Demonstrate a new approach for the simultaneous measurement of the proton and carbon light yield of organic scintillators. Provide new carbon light yield data for the EJ-309 liquid and EJ-204 plastic organic scintillators. Method: A 33~MeV $^{2}$H$^{+}$ beam from the 88-Inch Cyclotron at Lawrence …
Several liters of an organic liquid scintillator (LS) loaded with Nd have been made. We report on performances of this scintillator in terms of optical properties, radiopurity and light yield for a Nd concentration of 6.5 g/l. A possible application to search for the 150Nd neutrinoless double beta decay with a 10-ton scale LS detector is discussed together with further improvements.
Scintillators with pulse-shape discrimination (PSD) capability are of great interest to many fields in the scientific community. The ability to discern a gamma ray from a neutron using PSD varies between different types of scintillator materials and dopants. A new generation of organic scintillator materials with PSD capability were studied to determine their radiation hardness to ionizing and non-ionizing radiation. The PSD capability, average pulse shapes, and light output of four types of organic scintillator were characterized before and after neutron and gamma-ray irradiation. The main go…
New experimental research programs in the field of neutrino physics are calling for new detectors with large masses, high energy resolution and good background rejection capabilities. This paper presents a novel hybrid organic/inorganic scintillator, which is able to improve on all three aspects simultaneously. This scintillator consists of microscopic grains of inorganic crystals suspended in an organic scintillating carrier medium. Due to multiple scattering off the crystals, this scintillator appears opaque over longer distances and is intended for use in specialized detectors. Thanks to th…
The fluorescence decay-time constants have been measured for several scintillator mixtures based on phenyl-o-xylylethane (PXE) and linear alkylbenzene (LAB) solvents. The resulting values are of relevance for the physics performance of the proposed large-volume liquid scintillator detector LENA (Low Energy Neutrino Astronomy). In particular, the impact of the measured values to the search for proton decay via p -> K+ antineutrino is evaluated in this work.
It is shown that a large volume liquid organic scintillator detector with an energy resolution of 10 keV at 200 keV 1 sigma will be sensitive to solar pp-neutrino, if operated at the target radiopurity levels for the Borexino detector, or the solar neutrino project of KamLAND.
Recent progress in the development of novel organic scintillators necessitates modern characterization capabilities. As the primary means of energy deposition by neutrons in these materials is n-p elastic scattering, knowledge of the proton light yield is paramount. This work establishes a new model-independent method to continuously measure proton light yield in organic scintillators over a broad energy range. Using a deuteron breakup neutron source at the 88-Inch Cyclotron at Lawrence Berkeley National Laboratory and an array of organic scintillators, the proton light yield of EJ-301 and EJ-…
Emission spectra of several organic liquid-scintillator mixtures which are relevant for the proposed LENA detector have been measured by exciting the medium with electrons of ~10keV. The results are compared with spectra resulting from ultraviolet light excitation. Good agreement between spectra measured by both methods has been found.
A comparative study of the neutron-$γ$ Pulse Shape Discrimination (PSD) with seven organic scintillators is performed using an identical setup and digital electronics. The scintillators include plastics (EJ-299-33 and a plastic prototype), single crystals (stilbene and the recent doped $p$-terphenyl) and liquids (BC501A, NE213 and the deuterated liquid BC537). First, the overall PSD performance of the different scintillators is compared and threshold neutron energies for a given discrimination quality are determined. Then, using statistical arguments, two intrinsic contributions to the PSD cap…
A novel formulation to dope organic liquid scintillators (OLS) with indium at concentrations up to 10% is presented: it is based on specific indium carboxylate compounds adequately synthesized. The produced In-OLS has been characterized: it has light yield 8500 ph/MeV at indium concentration 5.5% and light attenuation length of 2,5 m at wavelength of 430 nm. The scintillator properties were stable during all time of investigation (~ 1 years). The produced In-OLS is compared to other In-OLS formulations and shows superior performances. The developed methodic to metal dope OLS can be easily exte…
In this manuscript we report on the scintillation properties and pulse shape discrimination (PSD) performance of new organic glass scintillator. Two cylindrical samples with dimensions of 2x2 inches were tested. Additionally, this two samples were used in stack configuration in order to measure the PSD characteristics of a sample with a size of 2x4 inches. The study covers the measurements of neutron/gamma discrimination capability, emission spectra, photoelectron yield and analysis of the light pulse shapes originating from events related to gamma-rays and fast neutrons. The results were comp…
In this work we report the performances and the chemical and physical properties of a (2 x 1.2) ton organic liquid scintillator target doped with Gd up to ~0.1%, and the results of a 2 year long stability survey. In particular we have monitored the amount of both Gd and primary fluor actually in solution, the optical and fluorescent properties of the Gd-doped liquid scintillator (GdLS) and its performances as a neutron detector, namely neutron capture efficiency and average capture time. The experimental survey is ongoing, the target being continuously monitored. After two years from the dopin…
In this work, Rossi-alpha measurements were simultaneously performed with a $^3$He-based detection system and an organic scintillator-based detection system. The assembly is 15 kg of plutonium (93 wt$\%$ $^{239}$Pu) reflected by copper and moderated by lead. The goal of Rossi-alpha measurements is to estimate the prompt neutron decay constant, alpha. Simulations estimate $k_\text{eff}$ = 0.624 and $α$ = 52.3 $\pm$ 2.5 ns for the measured assembly. The organic scintillator system estimated $α$ = 47.4 $\pm$ 2.0 ns, having a 9.37$\%$ error (though the 1.09 standard deviation confidence intervals …
Thallium-doped sodium iodide (NaI(Tl)) crystals are widely used in radiation detection applications, from gamma-ray spectroscopy to particle dark matter searches. However, if the crystal is exposed to relative humidity of even a few percent, its light emission degrades, making the crystal impractical as a detector. Surrounding the crystal with organic scintillators not only protects the surface of the crystal from humid air but also offers a new capability to tag backgrounds such as external gamma rays and surface contaminations. We developed a detector that is constructed by fully encasing a …
Scintillating NaI(Tl) crystals are used for various rare decay experiments, such as dark matter searches. The hygroscopicity of NaI(Tl) crystal makes the construction of crystal detectors in these experiments challenging and requires a tight encapsulation to prevent from air contact. More importantly, in a low radioactivity measurement, identification of external radiations and surface contamination is crucial to characterize the origin of total crystal radioactivities. Studies for NaI(Tl) crystal encapsulation with active organic scintillator vetoes have been performed to mitigate the above-m…
The characterization of a liquid scintillator incorporating an aqueous solution of enriched lithium chloride to produce a scintillator with 0.40% Li-6 is presented, including the performance of the scintillator in terms of its optical properties and neutron response. The scintillator was incorporated into a fast neutron spectrometer, and the light output spectra from 2.5 MeV, 14.1 MeV, and Cf-252 neutrons were measured using capture-gated coincidence techniques. The spectrometer was operated without coincidence to perform thermal neutron measurements. Possible improvements in spectrometer perf…
The NUCLEUS experiment aims at measuring the coherent elastic scattering of nuclear reactor antineutrinos off nuclei using cryogenic calorimeters. Operating at an overburden of 3m.w.e., muon-induced backgrounds are expected to be dominant. It is therefore essential to develop an efficient muon veto, with a detection efficiency of more than 99%. This will be realized in NUCLEUS through a compact cube assembly of plastic scintillator panels. In order to prevent a large unshielded area where the cryostat intersects the shielding arrangement without unnecessarily increasing the induced detector de…
Organic liquid scintillators are used in a wide variety of applications in experimental nuclear and particle physics. Boron-loaded scintillators are particularly useful for detecting neutron captures, due to the high thermal neutron capture cross section of $^{10}$B. These scintillators are commonly used in neutron detectors, including the DarkSide-50 neutron veto, where the neutron may produce a signal when it scatters off protons in the scintillator or when it captures on $^{10}$B. Reconstructing the energy of these recoils is complicated by scintillation quenching. Understanding how nuclear…
We propose a hierarchical Bayesian model and state-of-art Monte Carlo sampling method to solve the unfolding problem, i.e., to estimate the spectrum of an unknown neutron source from the data detected by an organic scintillator. Inferring neutron spectra is important for several applications, including nonproliferation and nuclear security, as it allows the discrimination of fission sources in special nuclear material (SNM) from other types of neutron sources based on the differences of the emitted neutron spectra. Organic scintillators interact with neutrons mostly via elastic scattering on h…
In this contribution we present a new concept of the large acceptance detector systems based on organic scintillators which may allow for simultaneous diagnostic of large fraction of the human body. Novelty of the concept lies in employing large blocks of polymer scintillators instead of crystals as detectors of annihilation quanta, and in using predominantly the timing of signals instead of their amplitudes.
The electron antineutrino spectrum in the Stereo reactor experiment (ILL Grenoble) is measured via the inverse beta decay signals in an organic liquid scintillator. The six target cells of the Stereo detector are filled with about 1800 litres of Gd-loaded liquid scintillator optimised for the requirements of the experiment. These target cells are surrounded by similar cells containing liquid scintillator without the Gd-loading. The development and characteristics of these scintillators are reported. In particular, the transparency, light production and pulse shape discrimination capabilities o…
An organic glass scintillator developed by Sandia National Laboratories was characterized in terms of its light output and pulse shape discrimination (PSD) properties and compared to commercial liquid (EJ-309) and plastic (EJ-276) organic scintillators. The electron light output was determined through relative comparison of the $^{137}$Cs Compton edge location. The proton light yield was measured using a double time-of-flight technique at the 88-Inch Cyclotron at Lawrence Berkeley National Laboratory. Using a tunable broad-spectrum neutron source and an array of pulse-shape-discriminating obse…
The purpose of nondestructive assay in the context of nuclear safeguards is to precisely verify the declared mass of a sample of nuclear material in a noninhibitive amount of time. 237Np is a proliferation concern, and the capacity to efficiently assay samples of it is a missing piece in the verification and safeguards toolbox. The material is subject to the same safeguards as 235U, is reportable in gram quantities, and is classified as "other nuclear material" according to the United States Department of Energy. Given that 3000 kg of 237Np is annually produced in the US and the bare sphere cr…
Fast-neutron/gamma-ray pulse-shape discrimination has been performed for the organic liquid scintillators NE 213A and EJ 305 using a time-of-flight based neutron-tagging technique and waveform digitization on an event-by-event basis. Gamma-ray sources and a Geant4-based simulation were used to calibrate the scintillation-light yield. The difference in pulse shape for the neutron and gamma-ray events was analysed by integrating selected portions of the digitized waveform to produce a figure-of-merit for neutron/gamma-ray separation. This figure-of-merit has been mapped as a function of detector…
The detectors based on the liquid scintillator (LS) monitored by an array of photo-multiplier tubes (PMT) are often used in low energy experiments such as neutrino oscillation studies and search for dark matter. Detectors of this kind operate in an energy range spanning from hundreds of keV to a few GeV providing a few percent resolution at energies above 1 MeV and allowing to observe fine spectral features. This article gives a brief overview of relevant physical processes and introduces a new universal simulation tool LSMC (Liquid Scintillator Monte Carlo) for simulation of LS-based detector…
We report on the study of a new liquid scintillator target for neutrino interactions in the framework of the research and development program of the BOREXINO solar neutrino experiment. The scintillator consists of 1,2-dimethyl-4-(1-phenylethyl)-benzene (phenyl-o-xylylethane, PXE) as solvent and 1,4-diphenylbenzene (para-Terphenyl, p-Tp) as primary and 1,4-bis(2-methylstyryl)benzene (bis-MSB) as secondary solute. The density close to that of water and the high flash point makes it an attractive option for large scintillation detectors in general. The study focused on optical properties, radioac…
A 3-D position sensitive neutron detector is being developed based on a plastic scintillator array. A double side SiPM readout is used to determine the depth of interaction (DOI) in each scintillator unit. In the preliminary test, the DOI in a 254 x 6 x 6 mm3 SP101 plastic scintillator is measured at different positions using a collimated Co-60 source. The SiPM (KETEK PM6660) signals are recorded by a 2.5 GS/s digital oscilloscope. The DOI results are calculated using both the amplitude and the temporal information. Position resolutions (FWHM) of 2.5 cm and 6.6 cm are realized, respectively. A…
We report on the energy, timing, and pulse-shape discrimination performance of cylindrical 5 cm diameter x 5 cm thick and 7 cm diameter x 7 cm thick {\it trans}-stilbene crystals read out with the passively summed output of three different commercial silicon photo-multiplier arrays. Our results indicate that using the summed output of an 8x8 array of SiPMs provides performance competitive with photo-multiplier tubes for many neutron imaging and correlated particle measurements: for the 5x5 cm crystal read out with SensL's ArrayJ-60035\_64P-PCB, which had the best overall properties, we measure…
Electron anti-neutrinos are commonly detected in liquid scintillator experiments via inverse beta decay, by looking at the coincidence between the reaction products, neutron and positron. Prior to positron annihilation, an electron-positron pair may form an orthopositronium (o-Ps) state, with a mean life of a few ns. Even if the o-Ps decay is speeded up by spin flip or pick off effects, it may introduce distortions in the photon emission time distribution, crucial for position reconstruction and pulse shape discrimination algorithms in anti-neutrino experiments. Reversing the problem, the o-Ps…
Localised response of a sensitive light detector, such as Hamamatsu H9500 multi anode photomultiplier tube (MAPMT), is of vital importance for coded-aperture imaging systems. When coupled with a suitable sensitive detector (e.g. EJ-299-34 plastic scintillator), output signals of the MAPMT can be retrieved to infer the interaction location in the pixelated scintillator. Given the number of anodes in H9500 (256), significant processing power would be necessary to handle each pulse individually. Therefore, a readout electronics system was developed, based on resistive network approach, which redu…
Results are presented from a small-scale experiment to investigate the use of room temperature organic liquid scintillators as the active medium for a time projection chamber (TPC). The optical properties of liquid scintillators have long been known, but their ability to transport charge has remained, until now, largely untested. The idea of using room temperature liquids as an active medium for an ionisation chamber was first presented in \cite{EnglerTMS}. Since then the range of liquid scintillators available has been greatly developed. We present successful transport of ionization charges i…
A light-yield calibration of an NE 213A organic liquid scintillator detector has been performed using both monoenergetic and polyenergetic gamma-ray sources. Scintillation light was detected in a photomultiplier tube, and the corresponding pulses were subjected to waveform digitization on an event-by-event basis. The resulting Compton edges have been analyzed using a Geant4 simulation of the detector which models both the interactions of the ionizing radiation as well as the transport of scintillation photons. The simulation is calibrated and also compared to well-established prescriptions use…
The scintillation anisotropy effect for proton recoil events has been investigated in five pure organic crystalline materials: anthracene, trans-stilbene, p-terphenyl, bibenzyl, and diphenylacetylene. These measurements include characterization of the scintillation response for one hemisphere of proton recoil directions in each crystal. In addition to standard measurements of the total light output and pulse shape at each angle, the prompt and delayed light anisotropies are analyzed, allowing for investigation of the singlet and triplet molecular excitation behaviors independently. This work p…
Quenching of light emission from an LAB based scintillator by the addition of organic amines and carboxylic acids is examined. Chemical functional groups of the quenching agents play an important role in this reduction. It is shown that "salt" formation at a 1:1 mole ratio in a mixed amine-acid system, reduces quenching by a factor of 2. Supporting NMR spectra are presented. This "quenching neutralization" has the potential to reduce the light loss incurred when metals complexed with quenching agents are loaded into organic scintillators.
The CHErenkov / Scintillation Separation experiment (CHESS) has been used to demonstrate the separation of Cherenkov and scintillation light in both linear alkylbenzene (LAB) and LAB with 2g/L of PPO as a fluor (LAB/PPO). This is the first such demonstration for the more challenging LAB/PPO cocktail and improves on previous results for LAB. A time resolution of 338 +/- 12 ps FWHM results in an efficiency for identifying Cherenkov photons in LAB/PPO of 70 +/- 3% and 63 +/- 8% for time- and charge-based separation, respectively, with scintillation contamination of 36 +/- 5% and 38 +/- 4%. LAB/PP…
The proton light yield of organic scintillators has been measured extensively in recent years using fast waveform digitizers and large discrepancies exist in the values reported by different authors. In this letter, we address principles of digital signal processing that must be considered when conducting scintillator light yield measurements. Digitized waveform pulse height values are only proportional to the amount of scintillation light if the temporal shape of the scintillation pulse is independent of the amount of energy deposited. This is not the case for scintillation pulses resulting f…
We report on the position, timing, and energy resolution of a range of plastic scintillator bars and reflector treatments using dual-ended silicon photomultiplier readout. These measurements are motivated by the upcoming construction of an optically segmented single-volume neutron scatter camera, in which neutron elastic scattering off of hydrogen is used to kinematically reconstruct the source direction and energy of an incoming neutron. For this application, interaction position resolutions of about 10 mm and timing resolutions of about 1 ns are necessary to achieve the desired efficiency fo…
A comparison of the neutron detection efficiency and response characteristics of two pixelated PSD-capable organic scintillator detectors with different photo-detection readout methods
The removal of radioactivity from liquid scintillator has been studied in preparation of a low background phase of KamLAND. This paper describes the methods and techniques developed to measure and efficiently extract radon decay products from liquid scintillator. We report the radio-isotope reduction factors obtained when applying various extraction methods. During this study, distillation was identified as the most efficient method for removing radon daughters from liquid scintillator.
Compact neutron imagers using double-scatter kinematic reconstruction are being designed for localization and characterization of special nuclear material. These neutron imaging systems rely on scintillators with a rapid prompt temporal response as the detection medium. As n-p elastic scattering is the primary mechanism for light generation by fast neutron interactions in organic scintillators, proton light yield data are needed for accurate assessment of scintillator performance. The proton light yield of a series of commercial fast plastic organic scintillators---EJ-200, EJ-204, and EJ-208--…
Organic scintillators doped with capture agents provide a detectable signal for neutrons over a broad energy range. This work characterizes the fast and slow neutron response of EJ-254, an organic plastic scintillator with 5% natural boron loading by weight. For fast neutrons, the primary mechanism for light generation in organic scintillators is n-p elastic scattering. To study the fast neutron response, the proton light yield of EJ-254 was measured at the 88-Inch Cyclotron at Lawrence Berkeley National Laboratory. Using a broad-spectrum neutron source and a double time-of-flight technique, t…
We study the response of EJ-301 liquid scintillator to monochromatic 244.6 $\pm$ 8.4 keV neutrons, targeting the 10-100 keV proton recoil energy interval. Limited experimental information exists for proton light yield in this range, for this or any other organic scintillator. Our results confirm the adequacy of a modified Birks' model, common to all organic scintillator formulations, predicting a marked increase in quenching factor as proton energy approaches the few keV regime. The relevance of this behavior within the context of searches for low-mass particle dark matter is mentioned.
For liquid-scintillator neutrino detectors of kiloton scale, the transparency of the organic solvent is of central importance. The present paper reports on laboratory measurements of the optical scattering lengths of the organic solvents PXE, LAB, and Dodecane which are under discussion for next-generation experiments like SNO+, Hanohano, or LENA. Results comprise the wavelength range from 415 to 440nm. The contributions from Rayleigh and Mie scattering as well as from absorption/re-emission processes are discussed. Based on the present results, LAB seems to be the preferred solvent for a larg…
Plastic organic scintillators have been tailored in composition to achieve ultra-fast temporal response, thereby enabling the design and development of fast neutron detection systems with high timing resolution. Eljen Technology's plastic organic scintillators -- EJ-230, EJ-232, and EJ-232Q -- are prospective candidates for use in emerging neutron imaging systems, where fast timing is paramount. To support the neutron response characterization of these materials, the relative proton light yields of EJ-230, EJ-232, and EJ-232Q were measured at the 88-Inch Cyclotron at Lawrence Berkeley National…
Electron antineutrinos are detected in organic liquid scintillator based neutrino experiments by means of the inverse beta decay, producing both a positron and a neutron. The positron may form a bound state together with an electron, called positronium (Ps). The longer-lived spin state of Ps, orthopositronium (o-Ps) has a lifetime of about $3\,\mathrm{ns}$ in organic liquid scintillators (LS). Its formation changes the time distribution of photon emission, which affects positron reconstruction algorithms and allows the application of pulse shape discrimination (PSD) to distinguish electron fro…
The organic liquid scintillator used in the LVD experiment (INFN Gran Sasso National Laboratory) has been exposed to an Am-Be neutron source to measure the light response function for neutron energies in the region from about 4 to 11 MeV. A full Monte Carlo simulation, incorporating the detector response, is used to generate neutron scattering spectra which are matched to the observed ones to determine the quenching factors. The obtained light output response is well described by the semi-empirical Birks model. The results, consistent with those obtained by other authors using similar hydrocar…
