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arXiv 2102.09275cond-mat.mes-hall
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石墨烯表面电荷转移复合物单分子膜的电子特性

Electronic Characterization of a Charge-Transfer Complex Monolayer on Graphene

Avijit Kumar, Kaustuv Banerjee, Mikko M. Ervasti, Shawulienu Kezilebieke, Marc Dvorak, Patrick Rinke, Ari Harju, Peter Liljeroth

摘要:

由强电子受体和强电子供体分子形成的有机电荷转移复合物(CTC)具有超导电性和电荷密度波等奇异效应。利用低温扫描隧道显微镜和光谱(LT-STM/STS)研究了四硫富瓦烯(TTF)和氟化四氰基醌二甲烷(F4 TCNQ)在Ir(111)上插氧外延石墨烯(G/O/Ir(111))表面的二维单层CTC。我们确认形成的电荷转移复合物的dI/dV光谱和直接成像的单占据分子轨道。高分辨率光谱揭示了在零偏置的间隙,这表明在低温下形成的相关基态。这些结果为实现和研究弱相互作用表面上电荷转移复合物单分子膜中的关联基态提供了可能。

英文摘要:

Organic charge-transfer complexes (CTCs) formed by strong electron acceptor and strong electron donor molecules are known to exhibit exotic effects such as superconductivity and charge density waves. We present a low-temperature scanning tunneling microscopy and spectroscopy (LT-STM/STS) study of a two-dimensional (2D) monolayer CTC of tetrathiafulvalene (TTF) and fluorinated tetracyanoquinodimethane (F4TCNQ), self-assembled on the surface of oxygen-intercalated epitaxial graphene on Ir(111) (G/O/Ir(111)). We confirm the formation of the charge-transfer complex by dI/dV spectroscopy and direct imaging of the singly-occupied molecular orbitals. High-resolution spectroscopy reveals a gap at zero bias, suggesting the formation of a correlated ground state at low temperatures. These results point to the possibility to realize and study correlated ground states in charge-transfer complex monolayers on weakly interacting surfaces.

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