V. V. Andreev
To describe a relativistic hydrogen atom we used the Poincare-covariant model of a two particle system with gauge invariant potential. The kernel of the radial integral equation is obtained which describes a system of two fermions with electromagnetic interaction.
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Beyond Poincaré Stresses: A Modern Quantum Field Theory Take on Hydrogen's Electromagnetic Mass
该研究从现代量子场论视角重新审视电磁质量问题，通过分析两分离氢原子系统的能量-动量张量，发现有效电磁质量偏离传统关系，差异源于电磁场非定域性，且指出需非微扰处理树图级作用量以捕捉束缚态动力学。
Paper I of this series introduced a nonlinear version of quantum mechanics that blocks cats, and paper II postulated a random part of the wavefunction to explain outcomes in experiments such as Stern-Gerlach or EPRB. However, an ad hoc extra parameter was assumed for the randomness. Here I provide some analytic and simulation evidence that the nonlinear theory exhibits sensitive dependence on initial conditions in measurement scenarios, perhaps implying that the magnitude of randomness required is determined by structural features of the model, and does not require a free parameter.
We discuss the process to obtain Poisson brackets among the phase-space variables of a system of a charged particle on a Poincaré hyperboloid in the presence of a uniform magnetic field. We show that after quantization the Dirac bracket algebra becomes the algebra of ISO(1,2). The representation of this algebra is explicitly analyzed and the Hamiltonian of this system has been derived.
Quantum manifestations of the dynamics around resonant tori in perturbed Hamiltonian systems, dictated by the Poincaré--Birkhoff theorem, are shown to exist. They are embedded in the interactions involving states which differ in a number of quanta equal to the order of the classical resonance. Moreover, the associated classical phase space structures are mimicked in the quasiprobability density functions and their zeros.
We give a unitary irreducible representation of the proper Poincaré group that leads to an operational version of the classical relativistic dynamics of a massive spinless particle. Unlike quantum mechanics, in this operational theory there is no uncertainty principle between position and momentum. It will be shown that the theory contains the Koopman-von Neumann formalism as a particular case, and a explicit connection with relativistic Hamiltonian mechanics will be given.
We first compare the mathematical structure of quantum and classical mechanics when both are formulated in a C*-algebraic framework. By using finite von Neumann algebras, a quantum mechanical analogue of Liouville's theorem is then proposed. We proceed to study Poincare recurrence in C*-algebras by mimicking the measure theoretic setting. The results are interpreted as recurrence in quantum mechanics, similar to Poincare recurrence in classical mechanics.
This comment identifies a mistake in a paper by P. Bowman that claims that the total angular momentum of the ground state of atomic hydrogen is 1.
The hydrogen atom is investigated, within a pseudo-complex extension of the coordinates and momenta, which introduces a minimal length scale (l) and results into a non-commutative Quantum Mechanics. After resuming the pseudo-complex extension of Quantum Mechanics, the modified energies of the hydrogen atom are deduced, producing corrections of the order of the square of the minimal length scale. Using the Lamb Shift, we obtain an upper boundary for the minimal length scale l, orders of magnitude more restrictive than former estimations.
The standard momentum operator $-i \nabla$ can not be accepted as observable in relativistic quantum mechanics of the Majorana particle. Instead, one can use axial momentum operator recently proposed in Phys. Lett. A {\bf383}, 1242 (2019). In the present paper we report several new results related to the axial momentum which elucidate its usability. First, a new motivation for the axial momentum is given, and the Heisenberg uncertainty relation checked. Next, we show that the general solution of time evolution equation in the axial momentum basis has a connection with quaternions. Single trave…
The Schroedinger equation is solved exactly within the Born-Oppenheimer approximation for a simulacrum of the $H_3^{++}$-ion. The ion is assumed to form an isosceles triangle and the ground state energy is obtained over its geometrical parameter space. No multi-center molecular integrations are required. We indicate how the approximation to the actual molecule can be improved systematically.
The Poincaré-Snyder relativity was introduced in an earlier paper of ours as an extended form of Einstein relativity obtained by appropriate limiting setting of the full Quantum Relativity. The latter, with fundamental constants $\hbar$ and $G$ built into the symmetry, is supposed to be the relativity of quantum space-time. Studying the mechanics of Poincaré-Snyder relativity is an important means to get to confront the great challenge of constructing the dynamics of Quantum Relativity. The mechanics will also be of interest on its own, plausibly yielding prediction accessible to experiments. …
The behavior of a classical charged point particle under the influence of only a Coulombic binding potential and classical electromagnetic zero-point radiation, is shown to yield agreement with the probability density distribution of Schroedinger's wave equation for the ground state of hydrogen. These results, obtained without any fitting parameters, again raise the possibility that the main tenets of stochastic electrodynamics (SED) are correct, thereby potentially providing a more fundamental basis of quantum mechanics. The present methods should help propel yet deeper investigations into SE…
The construction of quantum mechanics from electromagnetism. Part II: the Hydrogen atom
本文将带电单一实体的量子力学描述推广至氢原子，提出一种不依赖类比或特设推导的系统构建以取代传统量子力学，并探讨薛定谔时间演化的孤立概念与测量悖论及其认识论基础。
Stochastic Electrodynamics (SED) has had success modeling black body radiation, the harmonic oscillator, the Casimir effect, van der Waals forces, diamagnetism, and uniform acceleration of electrodynamic systems using the stochastic zero-point fluctuations of the electromagnetic field with classical mechanics. However the hydrogen atom, with its 1/r potential remains a critical challenge. Cole and Zou in 2003 and Nieuwenhuizen and Liska in 2015 found that the SED field prevented the electron orbit from collapsing into the proton but eventually the atom became ionized. We look at the issues of …
Is it possible that two different transitions in the non-relativistic quantum mechanical model of the hydrogen atom give the same frequency? That is, can different energy level transitions in a hydrogen atom have the same photon radiation frequency? This question, which was asked during a Ph.D. oral exam in 1997 at the University of Colorado Boulder, is well-known among physics graduate students. We show a general solution to this question, in which all equifrequency transition pairs can be obtained from the set of solutions of a Diophantine equation. This fun puzzle is a simple yet concrete e…
An exact analogue of the method of averaging in classical mechanics is constructed for self--adjoint operators. It is shown to be completely equivalent to the usual Rayleigh--Schrödinger perturbation theory but gives the sums over intermediate states in closed form expressions. The anharmonic oscillator and the Henon--Heiles system are treated as examples to illustrate the quantum averaging method.
The hydrogen atom is a system amenable to an exact treatment within Schroedinger's formulation of quantum mechanics according to coordinates in four systems -- spherical polar, paraboloidal, ellipsoidal and spheroconical coordinates; the latter solution is reported for the first time. Applications of these solutions include angular momenta, a quantitative calculation of the absorption spectrum and accurate plots of surfaces of amplitude functions. The shape of an amplitude function, and even the quantum numbers in a particular set to specify such an individual function, depend on the coordinat…
This paper summarizes and generalizes a recently proposed mathematical framework that unifies the standard formalisms of special relativity and quantum mechanics. The framework is based on Hilbert spaces H of functions of four space-time variables x,t, furnished with an additional indefinite inner product invariant under Poincaré transformations, and isomorphisms of these spaces that preserve the indefinite metric. The indefinite metric is responsible for breaking the symmetry between space and time variables and for selecting a family of Hilbert subspaces that are preserved under Galileo tran…
The purpose of this work is to retrace the steps that were made by scientists of XX century, like Bohr, Schrodinger, Heisenberg, Pauli, Dirac, for the formulation of what today represents the modern quantum mechanics and that, within two decades, put in question the classical physics. In this context, the study of the electronic structure of hydrogen atom has been the main starting point for the formulation of the theory and, till now, remains the only real case for which the quantum equation of motion can be solved exactly. The results obtained by each theory will be discussed critically, hig…
A general technique is presented for constructing a quantum theory of a finite number of interacting particles satisfying Poincaré invariance, cluster separability, and the spectral condition. Irreducible representations and Clebsch-Gordan coefficients of the Poincaré group are the central elements of the construction. A different realization of the dynamics is obtained for each basis of an irreducible representation of the Poincaré group. Unitary operators that relate the different realizations of the dynamis are constructed. This technique is distinguished from other solutions of this proble…
$SO(4)$ Symmetry in Hydrogen Atom with Spin
本研究将量子Runge-Lenz矢量推广为自旋依赖形式，基于$SO(4)$对称性推导含自旋氢原子的新哈密顿量并确定其能谱，拓展了氢原子研究基础，可为相关复杂模型提供参考。
We consider general theoretical models of water and in particular the nature of the motions of the hydrogen nuclei. If the motion of hydrogen nuclei is classical, then the thermodynamic pressure equation of state for heavy water wherein the hydrogen nuclei are deuterons is identical to the pressure equation of state for light water wherein the hydrogen nuclei are protons. Since the experimental thermodynamic phase diagram for light water is clearly measurably different from the experimental thermodynamic phase diagram for heavy water, one may deduce that the motions of hydrogen nuclei are quan…
The construction of quantum mechanics from electromagnetism. Theory and hydrogen atom
本文基于电磁学重构量子力学，以哈密顿最小作用量原理为统一原则，构建带电单实体量子力学并系统描述氢原子，从而消除传统测量悖论并批评工具主义。
Oganesson versus Uranium Hydrogen-like Ions and Beyond (from the Viewpoint of Old Quantum Mechanics)
本文在旧量子力学框架下比较铀与假想超重元素类氢离子，借助 Mathematica 证明强库仑场中自相交轨道，并提出用绕数对超重元素库仑场强度进行拓扑分类。
The notion of phase plays an esential role in both classical and quantum mechanics.But what is a phase? We show that if we define the notion of phase in phase (!) space one can very easily and naturally recover the Heisenberg-Weyl formalism; this is achieved using the properties of the Poincare-Cartan invariant, and without making any quantum assumption.
In 1926, Erwin Schrodinger wrote a series of papers that invented wave mechanics and set the foundation for much of the single-particle quantum mechanics that we teach today. In his first paper, he solved the Schrodinger equation using the Laplace method, which is a technique that is quite powerful, but rarely taught. This is unfortunate, because it opens the door to examining quantum mechanics from a complex-analysis perspective. Gaining this experience with complex analysis is a useful notion to consider when teaching quantum mechanics, as these techniques can be widely used outside of quant…
Quantum mechanics is considered to arise from an underlying classical structure (``hidden variable theory'', ``sub-quantum mechanics''), where quantum fluctuations follow from a physical noise mechanism. The stability of the hydrogen ground state can then arise from a balance between Lorentz damping and energy absorption from the noise. Since the damping is weak, the ground state phase space density should predominantly be a function of the conserved quantities, energy and angular momentum. A candidate for this phase space density is constructed for ground state of the relativistic hydrogen pr…
In this note we shall construct, in the framework of relativistic quantum mechanics, the Poincare-invariant motion equations with realistic mass spectra. These equations describe a system with mass spectra of the form $m^2=a^2+b^2 s(s+1)$, where a and b are arbitrary parameters. Such equations are obtained by a reduction of the motion equation for two particles to a one-particle equation which describes the particle in various mass and spin states. It we impose a certain condition on the wave function of the derived equation, such an equation describes the free motion of a fixed-mass particle …
Quantum Filtering of Hydrogen Isotopes through Graphene
本研究提出利用石墨烯层进行量子过滤，实现高效且经济可行的氢同位素分离，通过计算隧穿和粘附概率，证明该方法可有效富集氘。
Simulating and comparing the quantum and classical mechanical motion of two hydrogen atoms
本研究采用修正的Tavis-Cummings-Hubbard模型模拟中性氢分子的缔合与解离，比较量子隧穿与经典涨落下的核运动，发现经典运动达到相同终态所需时间短一个数量级，并识别出两个单重态暗态改变产物分支比。
Curved spacetimes from quantum mechanics
本文推广了 Penrose 自旋几何定理，证明仅利用抽象 Poincaré 不变量子力学系统的可观测量，即可在经典极限下恢复弯曲 Lorentzian 4-流形的局部度规与曲率结构。
A great number of problems of relativistic position in quantum mechanics are due to the use of coordinates which are not inherent objects of spacetime, cause unnecessary complications and can lead to misconceptions. We apply a coordinate-free approach to rule out such problems. Thus it will be clear, for example, that the Lorentz covariance of position, required usually on the analogy of Lorentz covariance of spacetime coordinates, is not well posed and we show that in a right setting the Newton--Wigner position is Poincaré covariant, in contradiction with the usual assertions.
The fractional operators together with exponential quantum in coordinate and momentum space corresponding to the power of observables are introduced. Based on an exponential relation between energy and momentum, the fractional Schrödinger equations for the free particle and the one in potential fields in heterogeneous complex media are found. The fractional equation of motion and the fractional virial theorem for anomalous quantum mechanics are then developed. Applying the fractional virial theorem, we derive an anomalous hydrogen atom whose transition energy values are much higher than that o…
Algebra of quantum mechanics via classical phonons. II: Klein-Gordon dynamics, the Heisenberg formalism, the Dirac canonical commutation rule and the Poincare algebra through the continuous Poisson bracket formalism
研究如何从经典声子模型出发，通过经典哈密顿形式主义恢复单无自旋粒子相对论量子力学特征，定义连续泊松括号，建立与量子力学形式的联系并恢复庞加莱群变换及代数。
The nonrelativistic limit of the centrally extended Poincaré group is considered and their consequences in the modal Hamiltonian interpretation of quantum mechanics are discussed [ O. Lombardi and M. Castagnino, Stud. Hist. Philos. Mod. Phys 39, 380 (2008) ; J. Phys, Conf. Ser. 128, 012014 (2008) ]. Through the assumption that in quantum field theory the Casimir operators of the Poincaré group actualize, the nonrelativistic limit of the latter group yields to the actualization of the Casimir operators of the Galilei group, which is in agreement with the actualization rule of previous versions …
Formulations of magnetic monopoles in a Hilbert-space formulation of quantum mechanics require Dirac's quantization condition of magnetic charge, which implies a large value that can easily be ruled out for elementary particles by standard atomic spectroscopy. However, an algebraic formulation of non-associative quantum mechanics is mathematically consistent with fractional magnetic charges of small values. Here, spectral properties in non-associative quantum mechanics are derived, applied to the ground state of hydrogen with a magnetically charged nucleus. The resulting energy leads to new st…
Recently a new formulation of quantum mechanics has been suggested which is based on the concept of signed particles, that is, classical objects provided with a position, a momentum and a sign simultaneously. In this paper, we comment on the plausibility of simulating atomic systems beyond the Born-Oppenheimer approximation by means of the signed particle formulation of quantum mechanics. First, in order to show the new perspective offered by this new formalism, we provide an example studying quantum tunnelling through a simple Gaussian barrier in terms of the signed particle formulation. Then…
We study the Hydrogen atom as a quantum mechanical system with a Coulomb like potential, with a semiclassical approach based on an effective description of quantum mechanics. This treatment allows us to describe the quantum state of the system as a system of infinite many classical equations for expectation values of configuration variables, their moments and quantum dispersions. It also provides a semiclassical description of the orbits and the evolution of observables and spreadings and their back-reaction on the evolution.
Inspired by Bohr's dictum that "physical phenomena are observed relative to different experimental setups", this article investigates the notion of relativity in Bohr's sense, starting from a set of binary elements. The most general form of information coding within such sets requires a description by four-component states. By using Bohr's dictum as a guideline a quantum mechanical description of the set is obtained in the form of a SO(3,2) based spin network. For large (macroscopic) sub-networks a flat-space approximation of SO(3,2) leads to a Poincare symmetrical Hilbert space. The concept o…
Our familiar Newton's laws allow determination of both position and velocity of any object precisely. Early nineteenth century saw the birth of quantum mechanics where all measurements must obey Heisenberg's uncertainty principle. Basically, we cannot simultaneously measure with precision, both position and momentum of particles in the microscopic atomic world. A natural extension will be to assume that space becomes fuzzy as we approach the study of early universe. That is, all the components of position cannot be simultaneously measured with precision. Such a space is called non-commutative …
An Abelian gerbe is constructed over classical phase space. The 2-cocycles defining the gerbe are given by Feynman path integrals whose integrands contain the exponential of the Poincare-Cartan form. The U(1) gauge group on the gerbe has a natural interpretation as the invariance group of the Schroedinger equation on phase space.
Based on an exposition of the underlying physics and applied mathematics in arXiv:1603.00899, this paper in five separate parts presents a description of the properties of the amplitude functions of the hydrogen atom according to wave mechanics in the coordinate representation in all four systems of coordinates in which Schroedinger's equations are separable, explicitly I spherical polar coordinates, II paraboloidal coordinates, III ellipsoidal coordinates and IV spheroconical coordinates; part V discusses the implications of these multiple systems in which these atomic orbitals can be directl…
Based on a linear realization formulation of a quantum relativity -- the proposed relativity for quantum `space-time', we introduce the Poincaré-Snyder relativity and Snyder relativity as relativities in between the latter and the well known Galilean and Einstein cases. We discuss how the Poincaré-Snyder relativity may provide a stronger framework for the description of the usual (Einstein) relativistic quantum mechanics and beyond. In particular, we discuss a geometric quantization picture through the U(1) central extension of the relativity group, which had been establish to work well for th…
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