We theoretically study NQR and NMR spectra in the presence of odd-parity multipoles originating from staggered antiferromagnetic and antiferroquadrupole orderings. For the $f$-electron metal, CeCoSi, which is a candidate hosting odd-parity multipoles, we derive an effective hyperfine field acting on Co nucleus generated from electronic origin multipole moments at Ce ion under zero and nonzero magnetic fields. We elucidate that emergent odd-parity multipoles give rise to sublattice-dependent spectral splittings in NQR and NMR through the effective hyperfine coupling in the absence of the global inversion symmetry. We mainly examine behaviors of the NQR and NMR spectra in three odd-parity multipole ordered states: a $y$-type magnetic toroidal dipole order with a staggered $x$-type antiferromagnetic structure, an $xy$-type electric toroidal quadrupole order with a staggered $x^2-y^2$-type antiferroquadrupole structure, and a $z$-type electric dipole order with a staggered $3z^2-r^2$-type antiferroquadrupole structure. We show that different odd-parity multipole orders lead to different field-dependent spectral splittings in NMR, while only the $xy$-type electric toroidal quadrupole order exhibits the NQR spectral splitting. We also present possible sublattice-dependent spectral splittings for all the odd-parity multipole orders potentially activated in low-energy crystal-field levels, which will be useful to identify odd-parity order parameters in CeCoSi by NQR and NMR measurements.
We performed $^{59}$Co nuclear magnetic and quadrupole resonance (NMR and NQR) measurements under pressure on a single-crystalline CeCoSi, which undergoes an unresolved phase transition at $T_0$. The NQR spectra clearly showed that the phase transition at $T_0$ is nonmagnetic, but any symmetry lowering at the Co site was not seen irrespective of the feature of second-order phase transition. By contrast, the NMR spectra were split by the induced magnetic field perpendicular to the external magnetic field. These results show that the phase below $T_0$ is not a simple paramagnetic state but is mo…
The quantum antiferromagnet Cu2Te2O5Br2 was investigated by NMR and NQR. The 125Te NMR investigation showed that there is a magnetic transition around 10.5K at 9T, in agreement with previous studies. From the divergence of the spin-lattice relaxation rate, we ruled out the possibility that the transition could be governed by a one-dimensional divergence of the spin-spin correlation function. The observed anisotropy of the 125Te shift was shown to be due to a spin polarization of the 5s2 "E" doublet of the [TeO3E] tetrahedra, highlighting the importance of tellurium in the exchange paths. In th…
We report 209Bi NMR and NQR measurements on a single crystal of the Kondo insulator U3Bi4Ni3. The 209Bi nuclear spin-lattice relaxation rate ($T_1^{-1}$) shows activated behavior and is well-fit by a spin gap of 220 K. The 209Bi Knight shift (K) exhibits a strong temperature dependence arising from 5f electrons, in which K is negative at high temperatures and increases as the temperature is lowered. Below 50 K, K shows a broad maximum and decreases slightly upon further cooling. Our data provide insight into the evolution of the hyperfine fields in a fully gapped Kondo insulator based on 5f el…
We report a 139La NMR investigation of low-doped insulating manganite samples (LaMnO(3+y) and La(1-x)Ca(x)MnO(3+y)) as a function of temperature. A volume fraction with fast nuclear relaxations was revealed by the inhomogeneous loss of the NMR signal over a broad temperature interval. Comparison with muSR data demonstrates that the wipe out of the 139La signal is mainly due to slowly fluctuating electric field gradients. This provides strong evidence for the slow diffusion of lattice excitations, identified with Jahn-Teller small polarons.
We report $^{105}$Pd NMR and NQR measurements on a single crystal of Ce$_3$Pd$_{20}$Si$_6$, where antiferroquadrupolar and antiferromagnetic orders develop at low temperature. From the analysis of NQR and NMR spectra, we have determined the electric field gradient (EFG) tensors and the anisotropic Knight shift ($K$) components for both inequivalent Pd sites - Pd($32f$) and Pd($48h$). The observed EFG values are in excellent agreement with our state-of-the-art DFT calculations. The principal values of the quadrupolar coupling are $(20.37 \pm 0.02)$ MHz and $(5.45 \pm 0.02)$ MHz, for the Pd($32f…
We have performed $^{69,71}$Ga nuclear magnetic resonance (NMR) and nuclear quadrupole resonance (NQR) and muon spin rotation/resonance on the quasi two-dimensional antiferromagnet (AFM) NiGa$_2$S$_4$, in order to investigate its spin dynamics and magnetic state at low temperatures. Although there exists only one crystallographic site for Ga in NiGa$_2$S$_4$, we found two distinct Ga signals by NMR and NQR. The origin of the two Ga signals is not fully understood, but possibly due to stacking faults along the c axis which induce additional broad Ga NMR and NQR signals with different local symm…
We report experimental results of nuclear magnetic resonance (NMR) at the La site and nuclear quadrupole resonance (NQR) at the Sb site in the filled skutterudite LaOs$_4$Sb$_{12}$. We found that the nuclear spin-lattice relaxation rate divided by temperature $1/T_1T$ at the La site exhibits a different temperature dependence from that at the Sb site. Although $1/T_1T$ at the Sb site is explained by the Korringa mechanism, $1/T_1T$ at the La site exhibits a broad maximum around 50 K, showing the presence of an additional contribution at the La site. The additional low-lying excitations observe…
We present high-field magnetization and $^{79}$Br nuclear quadrupole resonance (NQR) and $^{125}$Te nuclear magnetic resonance (NMR) studies in the weakly coupled Cu$^{2+}$ ($S=1/2$) tetrahedral system Cu$_2$Te$_2$O$_5$Br$_2$. The field-induced level crossing effects were observed by the magnetization measurements in a long-ranged magnetically ordered state which was confirmed by a strong divergence of the spin-lattice relaxation rate 1/T1 at T0=13.5 K. In the paramagnetic state, 1/T1 reveals an effective singlet-triplet spin gap much larger than that observed by static bulk measurements. Our …
Some of recent advances in the NMR and NQR studies of high-Tc superconductors YBa2Cu3O7-d and YBa2Cu4O8 are presented. The topics concerned are the understanding of magnetic phase diagram, impurity substitution effects and vortex core states in the mixed states.
We report on Cu nuclear quadrupole resonance (NQR) and NMR studies of an optimally hole-doped superconductor Ca2-xNaxCuO2Cl2 (Tc ~ 28 K for x ~ 0.2). In spite of robust oxygen composition, we observed a multiple broad NQR frequency spectrum and nonexponential Cu nuclear spin-lattice relaxation, being similar to those of La2-xSrxCuO4-d.
$^{75}$As nuclear magnetic resonance (NMR) and nuclear quadrupole resonance (NQR) measurements have been carried out to investigate the magnetic and electronic properties of the filled skutterudite metallic compound SrFe$_4$As$_{12}$. The temperature dependence of Knight shift $K$ determined by the NQR spectrum under a small magnetic field ($\le$ 0.5 T) shows the similar temperature dependence of the magnetic susceptibility $χ$ which exhibits a broad maximum at $T^\ast$ $\sim$ 50 K. The nuclear spin-lattice relaxation rate divided by temperature, 1/$T_1T$, increases with decreasing temperature…
Sb-NMR/NQR study has revealed a formation of a pseudogap at the Fermi level in the density of states in a valence fluctuating compound CeIrSb. The nuclear spin-lattice relaxation rate divided by temperature, 1/T_1T has a maximum around 300 K and decreases significantly as 1/T_1T ~ T^2, followed by a 1/T_1T = const. relation at low temperature. This temperature dependence of 1/T_1T is well reproduced by assuming a V-shaped energy gap with a residual density of states at the Fermi level. The size of energy gap for CeIrSb is estimated to be about 350 K, which is by one order of magnitude larger t…
Filled skutterudite compound EuFe$_4$As$_{12}$ shows the highest magnetic ordering temperature of $T_{\rm C}$ = 154 K among Eu-based skutterudite compounds, but its magnetic ground state has not been determined yet. Here, we performed $^{153}$Eu nuclear magnetic resonance (NMR) and $^{75}$As nuclear quadrupole resonance (NQR) measurements on EuFe$_4$As$_{12}$ to reveal its magnetic ground state as well as the physical properties from a microscopic point of view. From the temperature and magnetic field dependence of $^{153}$Eu NMR spectrum in the magnetically ordered state, we found that the Eu…
We report Cd NMR and Re NQR studies on Cd2Re2O7, the first superconductor among pyrochlore oxides Tc=1 K. Re NQR spectrum at zero magnetic field below 100 K rules out any magnetic or charge order. The spin-lattice relaxation rate below Tc exhibits a pronounced coherence peak and behaves within the weak-coupling BCS theory with nearly isotropic energy gap. Cd NMR results point to moderate ferromagnetic enhancement at high temperatures followed by rapid decrease of the density of states below the structural transition temperature of 200 K.
$^{75}$As and $^{139}$La NMR and nuclear quadrupole resonance (NQR) studies on Zn-substituted LaFeAsO$_{0.85}$ have been performed to investigate the Zn-impurity effects microscopically. Although superconductivity in LaFeAsO$_{0.85}$ disappears by 3% Zn substitution, we found that NMR/NQR spectra and NMR physical quantities in the normal state are hardly changed, indicating that the crystal structure and electronic states are not modified by Zn substitution. Our results suggest that the suppression of superconductivity by Zn substitution is not due to the change of the normal-state properties,…
In order to investigate the relationship between superconductivity and magnetism in bilayer-hydrate cobaltate Na_x(H_3O)_zCoO_2 \cdot yH_2O, Co nuclear magnetic resonance (NMR) and nuclear quadrupole resonance (NQR) measurements were performed on three different samples, which demonstrate various ground states at low temperatures. The appearance of small internal fields is observed in the NQR spectra below approximately 6 K on one of the samples that possesses the largest c-axis length and the highest NQR frequency. The other two samples exhibit superconducting transition in zero magnetic fiel…
We report $^{121/123}$Sb nuclear quadrupole resonance (NQR) and $^{51}$V nuclear magnetic resonance (NMR) measurements on kagome metal CsV$_3$Sb$_5$ with $T_{\rm c}=2.5$ K. Both $^{51}$V NMR spectra and $^{121/123}$Sb NQR spectra split after a charge density wave (CDW) transition, which demonstrates a commensurate CDW state. The coexistence of the high temperature phase and the CDW phase between $91$ K and $94$ K manifests that it is a first order phase transition. At low temperature, electric-field-gradient fluctuations diminish and magnetic fluctuations become dominant. Superconductivity eme…
We present $^{75}$As Nuclear Magnetic and Quadrupole Resonance results (NMR, NQR) on a new set of LaFeAsO$_{1-x}$F$_x$ polycrystalline samples. Improved synthesis conditions led to more homogenized samples with better control of the fluorine content. The structural$\equiv$nematic, magnetic, and superconducting transition temperatures have been determined by NMR spin-lattice relaxation rate and AC susceptibility measurements. The so-determined phase diagram deviates from the published one especially for low F-doping concentrations. However, if the doping level is determined from the NQR spectra…
We report magnetization, specific heat, and NMR investigations on YFe2Al10 over a wide range in temperature and magnetic field and zero field (NQR) measurements. Magnetic susceptibility, specific heat and spin-lattice relaxation rate divided by T (1/T1T) follow a weak power law (T^-0.4) temperature dependence, which is a signature of critical fluctuations of Fe moments. The value of the Sommerfeld-Wilson ratio and linear relation between 1/T1T and chi(T) suggest the existence of ferromagnetic correlations in this system. No magnetic ordering down to 50 mK in Cp(T) and the unusual temperature a…
We report 139La, 57Fe and 75As nuclear magnetic resonance (NMR) and nuclear quadrupole resonance (NQR) measurements on powders of the new LaO1-xFxFeAs superconductor for x = 0 and x = 0.1 at temperatures up to 480 K, and compare our measured NQR spectra with local density approximation (LDA) calculations. For all three nuclei in the x = 0.1 material, it is found that the local Knight shift increases monotonically with an increase in temperature, and scales with the macroscopic susceptibility, suggesting a single magnetic degree of freedom. Surprisingly, the spin lattice relaxation rates for al…
Magnetization and 63Cu NMR-NQR relaxation measurements are used to study the superconducting fluctuations in YBa2Cu3O6+x (YBCO) oriented powders. In optimally doped YBCO the fluctuating negative magnetization M_{fl}(H,T) is rather well described by an anisotropic Ginzburg-Landau (GL) functional and the curves M_{fl}/sqrt{H} cross at Tc. In underdoped YBCO, instead, over a wide temperature range an anomalous diamagnetism is observed, stronger than in the optimally doped compound by about an order of magnitude. The field and temperature dependences of M_{fl} cannot be described either by an anis…
We report 73Ge-NMR and NQR results for ferromagnetic (FM) superconductor URhGe. The magnitude and direction of the internal field, H_int, and parameters of the electric field gradient at the Ge site were determined experimentally. Using powdered polycrystalline samples oriented by different methods, the field dependences of NMR shift and nuclear spin relaxation rates for H_0 // c (easy axis) and H_0 // b were obtained. From the NMR shifts for H_0 // b, we confirmed a gradual suppression of the Curie temperature and observed a phase separation near the spin reorientation. The observation of the…
We report systematic 57Fe-NMR and 75As-NMR/NQR studies on an underdoped sample (T_c=20 K), an optimally doped sample (T_c=28 K), and an overdoped sample (T_c=22 K) of oxygen-deficient iron (Fe)-based oxypnictide superconductor LaFeAsO_{1-y}$. A microscopic phase separation between superconducting domains and magnetic domains is shown to take place in the underdoped sample, indicating a local inhomogeneity in association with the density distribution of oxygen deficiencies. As a result, 1/T_1T in the normal state of the superconducting domain decreases significantly upon cooling at both the Fe …
Motivated by the recent observation of ferromagnetic spin correlations in the filled skutterudite SrFe$_4$As$_{12}$ [Ding et al., Phys. Rev. B 98, 155149 (2018)], we have carried out $^{75}$As nuclear magnetic resonance (NMR) and nuclear quadrupole resonance (NQR) measurements to investigate the role of magnetic fluctuations in a newly discovered isostructural superconductor SrOs$_4$As$_{12}$ with a superconducting transition temperature of $T_{\rm c}$ $\sim$ 4.8 K. Knight shift $K$ determined by the NQR spectrum under a small magnetic field ($\le$ 0.5 T) is nearly independent of temperature, …
We report 75As-NQR/NMR studies on the oxygen-deficient iron(Fe)-based oxypnictide superconductors LaFeAsO_{0.6} (T_c=28 K) along with the results on LaFeAsO, LaFeAsO_{0.75}(T_c=20 K) and NdFeAsO_{0.6}(T_c=53 K). Nuclear spin-lattice relaxation rate 1/T_1 of 75As NQR at zero field on LaFeAsO_{0.6} has revealed a T^3 dependence below T_c upon cooling without the coherence peak just below T_c, evidencing the unconventional superconducting state with the line-node gap. We have found an intimate relationship between the nuclear quadrupole frequencyof 75As and T_c for four samples used in this study…
We discuss the novel superconducting characteristics and unusual normal-state properties of iron (Fe)-based pnictide superconductors REFeAsO$_{1-y}$ (RE=La,Pr,Nd) and Ba$_{0.6}$K$_{0.4}$Fe$_2$As$_2$($T_{c}=$ 38 K) by means of $^{57}$Fe-NMR and $^{75}$As-NQR/NMR. In the superconducting state of LaFeAsO$_{0.7}$ ($T_{c}=$ 28 K), the spin component of the $^{57}$Fe-Knight shift decreases to almost zero at low temperatures, which provide firm evidence of the superconducting state formed by spin-singlet Cooper pairing. The nuclear spin-lattice relaxation rates $(1/T_{1})$ in LaFeAsO$_{0.7}$ and Ba$_…
We report magnetization, nuclear magnetic resonance (NMR), nuclear quadrupole resonance (NQR), and transmission electron microscopy (TEM) studies on the quasi-two-dimensional spin-gap system (CuCl)LaNb2O7, a possible candidate for the J1-J2 model on a square lattice. A sharp single NQR line is observed at the Cu and Cl sites, indicating that both Cu and Cl atoms occupy a unique site. However, the electric field gradient tensors at the Cu, Cl, and La sites do not have axial symmetry. This is incompatible with the reported crystal structure. Thus the J1-J2 model has to be modified. We propose al…
We present the results of $^{75}$As nuclear magnetic resonance (NMR), nuclear quadrupole resonance (NQR), and resistivity measurements in KFe$_2$As$_2$ under pressure ($p$). The temperature dependence of the NMR shift, nuclear spin-lattice relaxation time ($T_1$) and resistivity show a crossover between a high-temperature incoherent, local-moment behavior and a low-temperature coherent behavior at a crossover temperature ($T^*$). $T^*$ is found to increase monotonically with pressure, consistent with increasing hybridization between localized $3d$ orbital-derived bands with the itinerant elect…
Co nuclear magnetic resonance (NMR) and nuclear quadrupole resonance (NQR) studies were performed in the recently discovered UCoGe, in which the ferromagnetic and superconducting (SC) transitions were reported to occur at $T_{\rm Curie} \sim 3$ K and $T_S \sim 0.8$ K (N. T. Huy {\it et al.}, Phys. Rev. Lett. {\bf 99} (2007) 067006), in order to investigate the coexistence of ferromagnetism and superconductivity as well as the normal-state and SC properties from a microscopic point of view. From the nuclear spin-lattice relaxation rate $1/T_1$ and Knight-shift measurements, we confirmed that fe…
We present our NMR studies of double-layer hydrated cobalt oxides NaxCoO2-yH2O (x ~ 0.35, y ~ 1.3) with various Tc = 0 - 4.8 K and magnetic transition temperatures. High-resolution $^{1}$H NMR spectrum served as an evidence for the existence of H$_{3}$O$^{+}$ oxonium ions. $^{23}$Na nuclear spin-lattice relaxation rates served to detect local field fluctuations sensitive to Tc. $^{59}$Co nuclear quadrupole resonance (NQR) spectra served to classify the various Tc samples. From the classification by $^{59}$Co NQR frequency, the double-layer hydrated compounds were found to have two superconduct…
$^{73}$Ge and $^{59}$Co nuclear magnetic resonance (NMR) and nuclear quadrupole resonance (NQR) measurements have been performed on a $^{73}$Ge-enriched single-crystalline sample of the ferromagnetic superconductor UCoGe in the paramagnetic state. The $^{73}$Ge NQR parameters deduced from NQR and NMR are close to those of another isostructural ferromagnetic superconductor URhGe. The Knight shifts of the Ge and Co sites are well scaled to each other when the magnetic field is parallel to the $b$ or $c$ axis. The hyperfine coupling constants of Ge are estimated to be close to those of Co. The la…
We report In-NQR and Co-NMR experiments of CeCoIn$_5$ that undergoes a superconducting transition with a record high $T_{\rm c}$ = 2.3 K to date among heavy-fermion superconductors. At zero magnetic field, an anomalous temperature ($T$) dependence of nuclear spin-lattice relaxation rate $1/T_1$ of $^{115}$In is explained by the relation $1/T_1\propto T\cdotχ_Q(T)^{3/4}$ based on the anisotropic spin-fluctuations model in case of the proximity to an antiferromagnetic (AFM) quantum critical point (QCP). The novel behavior of $1/T_1\sim T^{1/4}$ over a wide $T$ range of $T_{\rm c} < T < 40$ K ari…
We report $^{125}$Te nuclear magnetic resonance and $^{181}$Ta nuclear quadrupole resonance studies on single-crystal Ta$_{4}$Pd$_{3}$Te$_{16}$, which has a quasi-one-dimensional structure and superconducts below $T_{\rm c}=4.3$ K. $^{181}$Ta with spin $I=7/2$ is sensitive to quadrupole interactions, while $^{125}$Te with spin $I=1/2$ can only relax by magnetic interactions. By comparing the spin-lattice relaxation rate ( $1/T_{1}$) of $^{181}$Ta and $^{125}$Te, we found that electric-field-gradient (EFG) fluctuations develop below $80$ K. The EFG fluctuations are enhanced with decreasing temp…
The electronic and superconducting properties associated with the topologically non-trivial bands in Weyl semimetals have recently attracted much attention. We report the microscopic properties of the type-I Weyl semimetal TaAs measured by $^{75}$As nuclear magnetic (quadrupole) resonance under zero and elevated magnetic fields over a wide temperature range up to 500 K. The magnetic susceptibility measured by the Knight shift $K$ is found to be negative at low magnetic fields and have a strong field ($B$) dependence as ln$B$ at $T$ = 1.56 K. Such nonlinear field-dependent magnetization can be …
We report the $^{121/123}$Sb-NMR/nuclear quadrupole resonance (NQR) measurements on the newly-discovered superconductor BaTi$_2$Sb$_2$O with a two-dimensional Ti$_2$O square-net layer formed with Ti$^{3+}$ (3$d^1$). NQR measurements revealed that the in-plane four-fold symmetry is broken at the Sb site below $T_{\rm A} \sim$ 40 K, without an internal field appearing at the Sb site. These exclude a spin-density wave (SDW)/ charge density wave (CDW) ordering with incommensurate correlations, but can be understood with the commensurate CDW ordering at $T_{\rm A}$. The spin-lattice relaxation rate…
Temperature- and field- dependent $^1$H-, $^{19}$F-, and $^{79,81}$Br- NMR measurements together with zero - field $^{79,81}$Br-NQR measurements on polycrystalline samples of barlowite, Cu$_4$(OH)$_6$FBr are conducted to study the magnetism and possible structural distortions on a microscopic level. The temperature dependence of the $^{79,81}$Br- NMR spin-lattice relaxation rates 1/$T_1$ indicate a phase transition at $T_{\rm N}\simeq$15 K which is of magnetic origin, but with an unusually weak slowing down of fluctuations below $T_{\rm N}$. Moreover, 1/$T_1T$ scales linear with the bulk susce…
We report on 139La and 63Ccu NMR/NQR measurements in the high-Tc superconductor La1.90Sr0.10CuO4 with Tc=26.5 K. Spin fluctuations probed by 139La spin-lattice relaxation (T1), continuously slow down on cooling through Tc. We argue that spin-freezing and superconductivity are bulk effects in this sample. Thus, both phenomena have to coexist microscopically. The distribution of 139La T1 values at low temperature reveals a wide spread of spin fluctuation frequencies in CuO2 planes. A simple estimate shows that Cu nuclei at sites where electronic fluctuations are the slowest are not observable be…
In this Rapid Communication, a set of $^{209}$Bi-nuclear magnetic resonance (NMR)/nuclear quadrupole resonance (NQR) measurements has been performed to investigate the physical properties of superconducting (SC) BaTi$_2$Bi$_2$O from a microscopic point of view. The NMR and NQR spectra at 5~K can be reproduced with a non-zero in-plane anisotropic parameter $η$, indicating the breaking of the in-plane four-fold symmetry at the Bi site without any magnetic order, i.e., `the electronic nematic state'. In the SC state, the nuclear spin-lattice relaxation rate divided by temperature, $1/T_1T$, does …
A 63Cu and 139La NMR/NQR study of superconducting (Tc=7 K) La1.94Sr0.06CuO4 single crystal is reported. Coexistence of spin-glass and superconducting phases is found below ~5 K from 139La NMR relaxation. 63Cu and 139La NMR spectra show that, upon cooling, CuO2 planes progressively separate into two magnetic phases, one of them having enhanced antiferromagnetic correlations. These results establish the AF-cluster nature of the spin-glass. We discuss how this phase can be related to the microsegregation of mobile holes and to the possible pinning of charge-stripes.
The low-temperature magnetic properties of LaCoGe with the tetragonal CeFeSi-type structure were investigated by ^{59}Co- and ^{139}La-nuclear magnetic resonance (NMR) and nuclear quadrupole resonance (NQR) measurements. The nuclear spin-lattice relaxation rate divided by the temperature, 1/(T_1 T), gradually increases with decreasing temperature and shows a kink at approximately 18 K, below which an inhomogeneous internal field appears at the Co nuclear site. These results indicate that antiferromagnetic ordering occurs below T_N ~ 18 K. However, an internal field was not observed at the La n…
Incommensurate modulation with $Q=0$ A-type Antiferromagnetic Order in CeRh$_2$As$_2$ revealed by NQR studies
Kyoto University（京都大学）；Max Planck Institute for Chemical Physics of Solids（马克斯·普朗克固体化学物理研究所）；Institute for Quantum Materials and Technology, Karlsruhe Institute of Technology（卡尔斯鲁厄理工学院量子材料与技术研究所）；Technical University Dresden, Institute for Solid State and Materials Physics（德累斯顿工业大学固体与材料物理研究所）
We report a complete set of $^{59}$Co NMR data taken on the $x=2/3$ phase of sodium cobaltates Na$_{x}$CoO$_{2}$, for which we have formerly established the in plane Na ordering and its three dimensional stacking from a combination of symmetry arguments taken from Na and Co NQR/NMR data. Here we resolve all the parameters of the Zeeman and quadrupolar Hamiltonians for all cobalt sites in the unit cell and report the temperature dependencies of the NMR shift and spin lattice relaxation $T_{1}$ data for these sites. We confirm that three non-magnetic Co$^{3+}$ (Co1) are in axially symmetric posi…
We use single crystal $^{63}$Cu NMR techniques to revisit the early $^{63}$Cu NQR signature of charge order observed for La$_{1.875}$Ba$_{0.125}$CuO$_{4}$ ($T_{\text{c}} =4$~K) [A. W. Hunt et al., Phys. Rev. Lett. {\bf 82}, 4300 (1999)]. We show that the growth of spin correlations is accelerated below $\sim 80$~K, where the inverse Laplace transform (ILT) T$_{1}$ analysis of the $^{139}$La NMR spin-lattice relaxation curve recently uncovered emergence of the slow components in the lattice and/or charge fluctuations [P. M. Singer et al., {\bf 101}, 174508 (2020)]. From the accurate measurement…
The NMR and NQR spectra of $^{63}$Cu in the CuO$_2$ plane of YBa$_2$Cu$_3$O$_7$ in the superconducting state are discussed in terms of the phenomenological theory of Ginzburg-Landau type extended to lower temperatures. We show that the observed spectra, Kumagai {\em et al.}, PRB {\bf 63}, 144502 (2001), can be explained by a standard theory of the Bernoulli potential with the charge transfer between CuO$_2$ planes and CuO chains assumed.
We present a new type of quantum critical material YbCo$_2$Ge$_4$, having the largest quantum-critical pseudospin size ever. The YbCo$_2$Ge$_4$-type structure is new, forms in the orthorhombic $Cmcm$ system, and is related to the well-known ThCr$_2$Si$_2$ structure. Heavy rare earth (Tm,Yb,Lu, or Y) members are also possible to be grown. YbCo$_2$Ge$_4$ possesses the Ising-type ground-state doublet, namely the simplest ones of uniaxially up or down, $|\pm \sim 7/2\rangle$. It is clearly manifested through comprehensive resistivity, magnetization, specific heat, and NQR/NMR experiments. Large ps…
NMR evidence for a loop-current state with broken $C_6$ symmetry in the charge-ordered CsV$_3$Sb$_5$
Institute of Physics, Chinese Academy of Sciences（中国科学院物理研究所）；Beijing National Laboratory for Condensed Matter Physics（北京凝聚态物理国家研究中心）；School of Physical Sciences, University of Chinese Academy of Sciences（中国科学院大学物理科学学院）
We use 89Y NMR in $YBa_{2}Cu_{3}O_{6+y}$ in order to evaluate with high sensitivity the distribution of hole content p in the CuO2 planes. For y=1 and y=0.6, this hole doping distribution is found narrow with a full width at half maximum smaller than Delta p=0.025. This rules out any large static phase separation between underdoped and optimally doped regions in contrast with the one observed by STM in Bi2212 and by NQR in LaSrCuO. This establishes that static electronic phase separation is not a generic feature of the cuprates.
