We present a detailed study of quantum thermal machines employing quantum systems as working substances. In particular, we study two different types of two-stroke cycles where two collections of identical quantum systems with evenly spaced energy levels are initially prepared at thermal equilibrium by putting them in contact with a cold and a hot thermal bath, respectively. The two cycles differ in the absence or the presence of a mediator system, while, in both cases, non-resonant exchange Hamiltonians are exploited as particle interactions. We show that the efficiencies of these machines depend only on the energy gaps of the systems composing the collections and are equal to the efficiency of "equivalent" Otto cycles. Focusing on the cases of qubits or harmonic oscillators for both models, we maximize the engine power and analyze, in the model without the mediator, the role of the waiting time between subsequent interactions. It turns out that the case with the mediator can bring performance advantages when the interaction times are comparable with the waiting time of the correspondent cycle without the mediator. We find that in both cycles, the power peaks of qubit systems can surpass the Curzon-Ahlborn efficiency. Finally, we compare our cycle without the mediator with previous schemes of the quantum Otto cycle showing that high coupling is not required to achieve the same maximum power.
We put forth a quantum simulation of a stroboscopic two-stroke thermal engine in the IBMQ processor. The system consists of a quantum spin chain connected to two baths at their boundaries, prepared at different temperatures using the variational quantum thermalizer algorithm. The dynamics alternates between heat and work strokes, which can be separately designed using independent quantum circuits. The results show good agreement with theoretical predictions, showcasing IBMQ as a powerful tool to study thermodynamics in the quantum regime, as well as the implementation of variational quantum al…
In this work, we study the efficiency of charging a quantum battery through optical pumping. The battery consists of a qutrit and it is connected to a natural thermal reservoir and an external coherent drive in the limit where its upper energy level can be adiabatically eliminated from the dynamics. In this scenario, the drive plus spontaneous emission optically pumps the intermediate energy level of the qutrit and the battery can be understood as being charged by an effective higher temperature reservoir that takes it out of equilibrium with the natural reservoir and stores useful energy in i…
In this work, we introduce a three-stroke quantum engine with a single-qubit work-ing substance whose cycle consists of two strokes arise due to performing two distinctgeneral quantum measurements and it is completed by thermalization through contactwith a finite temperature thermal reservoir. It is demonstrated that energy is importedinto the engine by first measurement channel and work (usefulenergy) is extracted fromit, in a frictionless isentropic manner, by the second measurement channel. It is par-ticularly shown that the engine is capable to have perfect efficiency. In continuation,we e…
The precise estimation of small parameters is a challenging problem in quantum metrology. Here, we introduce a protocol for accurately measuring weak magnetic fields using a two-level magnetometer, which is coupled to two (hot and cold) thermal baths and operated as a two-stroke quantum thermal machine. Its working substance consists of a two-level system (TLS), generated by an unknown weak magnetic field acting on a qubit, and a second TLS arising due to the application of a known strong and tunable field on another qubit. Depending on this field, the machine may either act as an engine or a …
We study how a quantum heat engine based on a single trapped ion performs in finite time. The always-on thermal environment acts like the hot bath, while the motional degree of freedom of the ion plays the role of the effective cold bath. The hot isochoric stroke is implemented via the interaction of the ion with its hot environment, while a projective measurement of the internal state of the ion is performed as an equivalent to the cold isochoric stroke. The expansion and compression strokes are implemented via suitable change in applied magnetic field. We study in detail how the finite durat…
It is investigated whether non-Markovianity, i.e., the memory effects resulting from the coupling of the system to its environment, can be beneficial for the performance of quantum heat engines. Specifically, two physical models are considered. The first one is a well known single-qubit Otto engine; the non-Markovian behaviour is there implemented by replacing standard thermalization strokes with so-called extremal thermal operations which cannot be realized without the memory effects. The second one is a three-stroke engine in which the cycle consists of two extremal thermal operations and a …
We consider a finite-time quantum Otto heat engine that consists of two isochoric (thermal-contact) process, where the system is alternatively coupled to a hot squeezed and a cold thermal reservoir, and two unitary driven strokes, where the system is isolated from these two baths and its von Neumann entropy keeps constant. Both quantum inner friction and coherence are generated along the driven stroke and coherence cannot be fully erased after the finite-time hot isochore. Using full counting statistics, we present the probability distribution functions of heat injection and total work per cyc…
Refrigerators use a thermodynamic cycle to move thermal energy from a cold reservoir to a hot one. Implementing this operation principle with mesoscopic components has recently emerged as a promising strategy to control heat currents in micro and nano systems for quantum technological applications. Here, we combine concepts from stochastic and quantum thermodynamics with advanced methods of optimal control theory to develop a universal optimization scheme for such small-scale refrigerators. Covering both the classical and the quantum regime, our theoretical framework provides a rigorous proced…
We investigate the thermal entanglement of interacting two qubits. We maximize it by tuning a local Hamiltonian under a given interaction Hamiltonian. We prove that the optimizing local Hamiltonian takes a simple form which dose not depend on the temperature and that the corresponding optimized thermal entanglement decays as $1/(T log T)$ at high temperatures. We also find that at low temperatures the thermal entanglement is maximum without any local Hamiltonians and that the second derivative of the maximized thermal entanglement changes discontinuously at the boundary between the high- and l…
We study a four-stroke Otto engine whose working fluid is a quantum Ising chain. The thermodynamic cycle consists in sweeps of the transverse magnetic field occurring in thermal isolation, alternated by thermalisation strokes with reservoirs at different temperatures. The system-environment coupling is modelled in a thermodynamically consistent way by means of a nonlocal Lindblad master equation. We show that the engine may operate in four different operation modes, depending on the various parameters, in particular it can act as a heat engine and as a refrigerator. We detect an enhancement of…
We consider a quantum engine driven by repeated weak interactions with a heat bath of identical three-level atoms. This model was first introduced by Scully et al. [Science, 2003], who showed that coherence between the energy-degenerate ground states serves as a thermodynamic resource that allows operation of a thermal cycle with a coherence-dependent thermalisation temperature. We consider a similar engine out of the quasistatic limit and find that the ground-state coherence also determines the rate of thermalisation, therefore increasing the output power and the engine efficiency only when t…
Thermodynamic Performance of a Measurement-Driven Quantum Engine with a Two-Parameter $(p,q)$-Deformed Harmonic Oscillator
Khalifa University of Science and Technology（哈利法科学技术大学）；KU Research Center for Advanced Intelligent Systems (AIS), Khalifa University of Science and Technology（哈利法科学技术大学 KU 先进智能系统研究中心）
The minimal-coupling quantum heat engine is a thermal machine consisting of an explicit energy storage system, heat baths, and a working body, which alternatively couples to subsystems through discrete strokes -- energy-conserving two-body quantum operations. Within this paradigm, we present a general framework of quantum thermodynamics, where a work extraction process is fundamentally limited by a flow of non-passive energy (ergotropy), while energy dissipation is expressed through a flow of passive energy. It turns out that small dimensionality of the working body and a restriction only to t…
Experimental Demonstration of a Measurement-Feedback Quantum Information Engine
Quantum Information Institute, School of Physics and Laboratory of Zhongyuan Light, Zhengzhou University（郑州大学物理学院量子信息研究所中原光实验室）；Department of Physics, Nanchang University（南昌大学物理系）
We use fast periodic control to realize finite-time Otto cycles exhibiting quantum advantage. Such periodic modulation of the working medium - bath interaction Hamiltonian during the thermalization strokes can give rise to non-Markovian anti-Zeno dynamics, and corresponding reduction in the thermalization times. Faster thermalization can in turn significantly enhance the power output in engines, or equivalently, the rate of refrigeration in refrigerators. This improvement in performance of dynamically controlled Otto thermal machines arises due to the time-energy uncertainty relation of quantu…
We study an Otto heat machine whose working substance is a single two-level system interacting with a cold thermal reservoir and with a squeezed hot thermal reservoir. By adjusting the squeezing or the adiabaticity parameter (the probability of transition) we show that our two-level system can function as a universal heat machine, either producing net work by consuming heat or consuming work that is used to cool or heat environments. Using our model we study the performance of these machine in the finite-time regime of the isentropic strokes, which is a regime that contributes to make them use…
We analyze the performance of a quantum Otto cycle, employing time-dependent harmonic oscillator as the working fluid undergoing sudden expansion and compression strokes during the adiabatic stages, coupled to a squeezed reservoir. First, we show that the maximum efficiency that our engine can achieve is 1/2 only, which is in contrast with the earlier studies claiming unit efficiency under the effect of squeezed reservoir. Then, we obtain analytic expressions for the upper bound on the efficiency as well as on the coefficient of performance of the Otto cycle. The obtained bounds are independen…
We propose a quantum heat engine based on a quadratically coupled optomechanical system. The optical component of the system is driven periodically with an incoherent thermal drive, which induces periodic oscillations in the mechanical component. Under the action of the quadratic optomechanical interaction, the mechanical mode evolves from an initial thermal state to a thermal-squeezed steady state, as verified by calculating the Wigner functions. The dynamics of the system is identified as an effective four-stroke Otto cycle. We investigated the performance of the engine by evaluating the dis…
Ulm University（乌尔姆大学）；Institute of Theoretical Physics, Ulm University（乌尔姆大学理论物理研究所）；Center for Integrated Quantum Science and Technology (IQST)（集成量子科学与技术中心）
Real quantum heat engines lack the separation of time and length scales that is characteristic for classical engines. They must be understood as open quantum systems in non-equilibrium with time-controlled coupling to thermal reservoirs as integral part. Here, we present a systematic approach to describe a broad class of engines and protocols beyond conventional weak coupling treatments starting from a microscopic modeling. For the four stroke Otto engine the full dynamical range down to low temperatures is explored and the crucial role of the work associated with the coupling/decoupling to/fr…
We propose a quantum Stirling heat engine with an ensemble of harmonic oscillators as the working medium. We show that the efficiency of the harmonic oscillator quantum Stirling heat engine (HO-QSHE) at a given frequency can be maximized at a specific ratio of the temperatures of the thermal reservoirs. In the low temperature or equivalently high frequency limit of the harmonic oscillators, the efficiency of the HO-QSHE approaches the Carnot efficiency. Further, we analyse quantum Stirling heat engine with an ensemble of particle in box quantum systems as the working medium. Here both work and…
In this work we study the so-called quantitative complementarity quantities. We focus in the following physical situation: two qubits ($q_A$ and $q_B$) are initially in a maximally entangled state. One of them ($q_B$) interacts with a $N$-qubit system ($R$). After the interaction, projective measurements are performed in each of the qubits of $R$, in a basis that is chosen after independent optimization procedures: maximization of the visibility, the concurrence and the predictability. For a specific maximization procedure, we study in details how each of the complementary quantities behave, c…
We study the thermodynamic performance of the finite-time non-regenerative Stirling cycle used as a quantum heat engine. We consider specifically the case in which the working substance (WS) is a two-level system. The Stirling cycle is made of two isochoric transformations separated by a compression and an expansion stroke during which the working substance is in contact with a thermal reservoir. To describe these two strokes we derive a non-Markovian master equation which allows to study the dynamics of a driven open quantum system with arbitrary fast driving. We found that the finite-time dy…
A cavity optomechanical system is initiated by a radiation pressure of a cavity field onto a mirror element acting as a quantum resonator. This radiation pressure can control the thermodynamic character of the mirror to some extent, such as cooling its effective temperature. Here we show that by properly engineering the spectral density of a thermal heat bath that interacts with a quantum system, the evolution of the quantum system can be effectively turned on and off. Inside a cavity optomechanical system, when the heat bath is realized by a multi-mode oscillator modeling of the mirror, this …
The Carnot cycle combines reversible isothermal and adiabatic strokes to obtain optimal efficiency, at the expense of a vanishing power output. Quantum Carnot-analog cycles are constructed and solved, operating irreversibly at non-vanishing power. Swift thermalization is obtained in the isotherms utilizing a shortcut to equilibrium protocols and the adiabats employ frictionless unitary shortcuts. The working medium in this study is composed of a particle in a driven harmonic trap. For this system, we solve the dynamics employing a generalized canonical state. Such a description incorporates bo…
A quantum thermodynamic cycle with a chiral multiferroic working substance such as $\textrm{LiCu}_{2}\textrm{O}_{2}$ is presented. Shortcuts to adiabaticity are employed to achieve an efficient, finite time quantum thermodynamic cycle which is found to depend on the spin ordering. The emergent electric polarization associated with the chiral spin order, i.e. the magnetoelectric coupling, renders possible steering of the spin order by an external electric field and hence renders possible an electric-field control of the cycle. Due to the intrinsic coupling between of the spin and the electric p…
The study of quantum thermodynamics is key to the development of quantum thermal machines. In contrast to most of the previous proposals based on discrete strokes, here we consider a working substance that is permanently coupled to two or more baths at different temperatures and continuously driven. To this end, we investigate parametrically driven quantum harmonic oscillators coupled to heat baths via a collision model. Using a thermodynamically consistent local master equation, we derive the heat flows and power of the working device which can operate as an engine, refrigerator or accelerato…
Cross-Spectral Reservoir Correlations as a Resource for Finite-Time Quantum Otto Engines
Ramakrishna Mission Vivekananda Educational and Research Institute（拉马克里希纳使命维韦卡南达教育研究所）；TCG CREST；Academy of Scientific and Innovative Research (AcSIR)（科学与创新研究学院）
Identifying optimal thermodynamical processes has been the essence of thermodynamics since its inception. Here, we show that differentiable programming (DP), a machine learning (ML) tool, can be employed to optimize finite-time thermodynamical processes in a quantum thermal machine. We consider the paradigmatic quantum Otto engine with a time-dependent harmonic oscillator as its working fluid, and build upon shortcut-to-adiabaticity (STA) protocols. We formulate the STA driving protocol as a constrained optimization task and apply DP to find optimal driving profiles for an appropriate figure o…
We introduce unique class of cyclic quantum thermal machines (QTMs) which can maximize their performance at the finite value of cycle duration $τ$ where they are most irreversible. These QTMs are based on single-stroke thermodynamic cycles realized by the non-equilibrium steady state (NESS) of the so-called Periodically Refreshed Baths (PReB) process. We find that such QTMs can interpolate between standard collisional QTMs, which consider repeated interactions with single-site environments, and autonomous QTMs operated by simultaneous coupling to multiple macroscopic baths. We discuss the phys…
Optimal performance of thermal machines is reached by suppressing friction. Friction in quantum thermodynamics results from fast driving schemes that generate nonadiabatic excitations. The far-from-equilibrium dynamics of quantum devices can be tailored by shortcuts to adiabaticity to suppress quantum friction. We experimentally demonstrate friction-free superadiabatic strokes with a trapped unitary Fermi gas as a working substance and establish the equivalence between the superadiabatic mean work and its adiabatic value.
We study energetic exchanges and fluctuations in two-stroke quantum thermodynamic engines where the working fluid is represented by two multilevel quantum systems, i.e. qudits, the heat flow is allowed by relaxation with two thermal reservoirs at different temperatures, and the work exchange is operated by a partial-swap unitary interaction. We identify three regimes of operation (heat engine, refrigerator, and thermal accelerator), present the thermodynamic uncertainty relations between the entropy production and the signal-to-noise ratio of work and heat, and derive the full joint probabilit…
A universal scheme is introduced to speed up the dynamics of a driven open quantum system along a prescribed trajectory of interest. This framework generalizes counterdiabatic driving to open quantum processes. Shortcuts to adiabaticity designed in this fashion can be implemented in two alternative physical scenarios: one characterized by the presence of balanced gain and loss, the other involves non-Markovian dynamics with time-dependent Lindblad operators. As an illustration, we engineer superadiabatic cooling, heating, and isothermal strokes for a two-level system, and provide a protocol fo…
According to Clausius formulation of the second law of thermodynamics, for any thermal machine withdrawing heats $Q_{1,2}$ from two heat reservoirs at temperatures $T_{1,2}$, it holds $Q_1/T_1+Q_2/T_2 \leq 0$. Combined with the observation that the quantity $Q_1+Q_2$ is the work $W$ done by the system, that inequality tells that only 4 possible operation modes are possible for the thermal machine, namely heat engine [E], refrigerator [R], thermal accelerator [A] and heater [H]. We illustrate their emergence in the finite time operation of a quantum Otto engine realised with a single qubit. We …
