We investigate the superconducting gap function of topological superconductor PbTaSe$_2$. Temperature, magnetic field, and three-dimensional (3D) field-angle dependences of the specific heat prove that the superconductivity of PbTaSe$_2$ is fully-gapped, with two isotropic $s$-wave gaps. The pair-breaking effect is probed by systematically increasing non-magnetic disorders through H$^+$-irradiations. The superconducting transition temperature, $T_{\rm{c}}$, is found to be robust against disorders, which suggests that the pairing should be sign-preserved rather than sign-reversed.
The search for topological superconductors (TSCs) is one of the most urgent contemporary problems in condensed matter systems. TSCs are characterized by a full superconducting gap in the bulk and topologically protected gapless surface (or edge) states. Within each vortex core of TSCs, there exist the zero energy Majorana bound states, which are predicted to exhibit non-Abelian statistics and to form the basis of the fault-tolerant quantum computation. So far, no stoichiometric bulk material exhibits the required topological surface states (TSSs) at Fermi level combined with fully gapped bulk …
We report the $^{207}$Pb nuclear magnetic resonance (NMR) measurements on polycrystalline sample of PbTaSe$_2$ with noncentrosymmetric crystal structure and topological electronic band. The nuclear spin-lattice relaxation rate $1/T_1$ shows a suppressed coherence peak below the superconducting transition temperature $T_{\rm c}$ = 4.05 K and decreases as an exponential function of temperature. The penetration depth derived from the NMR spectrum is almost temperature independent below $T$ = 0.7 $T_{\rm c}$. The Knight shift $K$ decreases below $T_{\rm c}$. These results suggest spin-singlet supe…
We present muon spin rotation ($μ$SR) measurements on the noncentrosymmetric superconductor PbTaSe$_2$. From measurements in an applied transverse field between $H_{c1}$ and $H_{c2}$, we extract the superfluid density as a function of temperature in the vortex state. This data can be fit with a fully gapped two-band model, consistent with previous evidence from ARPES, thermal conductivity, and resistivity. Furthermore, zero field measurements show no evidence for a time reversal symmetry breaking field greater than 0.05~G in the superconducting state. This makes exotic fully gapped spin-triple…
Spontaneous symmetry breaking has been a paradigm to describe the phase transitions in condensed matter physics. In addition to the continuous electromagnetic gauge symmetry, an unconventional superconductor can break discrete symmetries simultaneously, such as time reversal and lattice rotational symmetry. In this work we report a characteristic in-plane 2-fold behaviour of the resistive upper critical field and point-contact spectra on the superconducting semimetal PbTaSe2 with topological nodal-rings, despite its hexagonal lattice symmetry (or D_3h in bulk while C_3v on surface, to be preci…
Topological superconductivity is an exotic phenomenon due to the symmetry-protected topological surface state, in which a quantum system has an energy gap in the bulk but supports gapless excitations confined to its boundary. Symmetries including central and time-reversal (TRS), along with their relations with topology, are crucial for topological superconductivity. We report muon spin relaxation/rotation ($μ$SR) experiments on a topological noncentrosymmetric superconductor PbTaSe$_2$ to study its TRS and gap symmetry. Zero-field $μ$SR experiments indicate the absence of internal magnetic fie…
Low-temperature thermal conductivity measurements were performed on single crystal of PbTaSe$_2$, a noncentrosymmetric superconductor with topological bulk nodal lines in the electronic band structure. It is found that the residual linear term $κ_0/T$ is negligible in zero magnetic field. Furthermore, the field dependence of $κ_0/T$ exhibits a clear "$S$"-shape curve. These results suggest that PbTaSe$_2$ has multiple nodeless superconducting gaps. Therefore, the spin-triplet state with gap nodes does not play an important role in this noncentrosymmetric superconductor with strong spin-orbital…
We report an investigation of the superconducting order parameter of the noncentrosymmetric compound PbTaSe$_2$, which is believed to have a topologically nontrivial band structure. Precise measurements of the London penetration depth $Δλ(T)$ obtained using a tunnel diode oscillator (TDO) based method show an exponential temperature dependence at $T\ll T_c$, suggesting a nodeless superconducting gap structure. A single band s-wave model well describes the corresponding normalized superfluid density, with a gap magnitude of $Δ(0)=1.85T_c$. This is very close to the value of $1.76T_c$ for weak-c…
Layered, non-centrosymmetric, heavy element PbTaSe2 is found to be superconducting. We report its electronic properties accompanied by electronic structure calculations. Specific heat, electrical resistivity and magnetic susceptibility measurements indicate that PbTaSe2 is a moderately coupled, type-II BCS superconductor (Tc = 3.72 K, Ginzburg-Landau parameter Kappa = 14) with an electronphonon coupling constant of Lambda_ep = 0.74. Electronic structure calculations reveal a single bulk 3D Dirac cone at the K point of the Brillouin Zone derived exclusively from its hexagonal Pb layer; it is si…
We report on a pure $^{181}$Ta-nuclear quadrupole resonance (NQR) measurement of PbTaSe$_2$ at zero magnetic field, which has the advantage of directly probing the intrinsic superconducting phase and electronic states of the TaSe$_2$ layer. We observed the $^{181}$Ta-NQR spectrum of the intrinsic structure with space group $P6$-$m2$, which agrees well with density functional theory (DFT) calculations. The nuclear spin relaxation rate ($1/T_1$) shows an exponential decrease well below $T_{\rm_c}$, indicating that the superconducting state is fully gapped in the framework of Bardeen-Cooper-Schri…
Recently the superconductor and topological semimetal PbTaSe$_2$ was experimentally found to exhibit surface-only lattice rotational symmetry breaking below $T_c$. We exploit the Ginzburg-Landau free energy and propose a microscopic two-channel model to study possible superconducting states on the surface of PbTaSe$_2$. We identify two types of topological superconducting states. One is time-reversal invariant and preserves the lattice hexagonal symmetry while the other breaks both symmetries. We find that such time-reversal symmetry breaking is unavoidable for a superconducting state in a two…
Nonreciprocal or nonlinear responses in symmetry-broken systems are powerful probes of emergent properties in quantum materials, including superconductors, magnets, and topological materials. Recently, vortex matter has been recognized as a key ingredient of giant nonlinear responses in superconductors with broken inversion symmetry. However, nonlinear effects have been probed as excess voltage only under broken time-reversal symmetry. In this study, we report intrinsic rectification and nonlinear anomalous Hall effect under time-reversal symmetry in the noncentrosymmetric trigonal superconduc…
We solve the Bogoliubov-de Gennes equations self-consistently for d-wave superconductors with [110] surfaces. We find spontaneous breaking of time-reversal symmetry (TRS) caused by the spontaneous occurrence of a complex order parameter with an extended s-wave symmetry along the [110] surfaces. In the TRS-breaking phase, the d-wave order parameter itself becomes complex. We also show that vortex-antivortex pairs can appear along the [110] surfaces of nanoribbons. These pairs are detectable with surface sensitive probes.
We analyze the possible interaction-induced superconducting instabilities in noncentrosymmetric systems based on symmetries of the normal state. It is proven that pure electron-phonon coupling will always lead to a fully gapped superconductor that does not break time-reversal symmetry and is topologically trivial. We show that topologically nontrivial behavior can be induced by magnetic doping without gapping out the resulting Kramers pair of Majorana edge modes. In case of superconductivity arising from the particle-hole fluctuations associated with a competing instability, the properties of …
The noncentrosymmetric superconductor Re$_6$Zr has attracted much interest due to the observation of broken time-reversal symmetry in the superconducting state. Here we report an investigation of the superconducting gap structure of Re$_6$Zr single crystals by measuring the magnetic penetration depth shift $Δλ(T)$ and electronic specific heat $C_e(T)$. $Δλ(T)$ exhibits an exponential temperature dependence behavior for $T~\ll~T_c$, which indicates a fully-open superconducting gap. Our analysis shows that a single gap $s$-wave model is sufficient to describe both the superfluid density $ρ_s(T)$…
To understand the impurity effect on Tc in FeAs superconductors, we analyze a simple two-band BCS model with repulsive interband interaction. The realized fully-gapped superconducting state with sign reversal, which is predicted by spin fluctuation theories in this compound, is suppressed by impurities due to the interband hopping of Cooper pairs, if the interband impurity scattering $I'$ is equal to the intraband one $I$. When $|I'/I| < 1$, in highly contrast, Tc is almost unchanged by strong impurity scattering since the interband scattering is almost prohibited by the multiple scattering ef…
We solve the Bogoliubov-de Gennes equations self-consistently for the $d$-wave order parameter in nanoscale $d$-wave systems with [110] surfaces and show that spontaneous time-reversal symmetry (TRS) breaking occurs at low temperatures due to a spontaneously induced complex order parameter of extended $s$-wave symmetry. The Andreev surface bound states, which are protected by a one-dimensional (1D) topological invariant in the presence of TRS, are gapped by the emergence of this new order parameter. The extended $s$-wave order parameter is localized within a narrow region near the surfaces, wh…
We report an investigation of the superconducting properties of the hexagonal noncentrosymmetric compound LaPdIn. Electrical resistivity, specific heat and ac susceptibility measurements demonstrate the presence of bulk superconductivity below $T_c$ = 1.6 K. The specific heat, together with the penetration depth measured using transverse-field muon spin rotation and the tunnel diode oscillator based method, are well described by single gap $s$-wave superconductivity, with a gap magnitude of 1.8$k_BT_c$. From zero-field muon spin relaxation results no evidence is found for the spontaneous emerg…
By employing a series of experimental techniques, we provide clear evidence that CaPtAs represents a rare example of a noncentrosymmetric superconductor which simultaneously exhibits nodes in the superconducting gap and broken time-reversal symmetry (TRS) in its superconducting state (below $T_c$ $\approx$ 1.5 K). Unlike in fully-gapped superconductors, the magnetic penetration depth $λ(T)$ does not saturate at low temperatures, but instead it shows a $T^2$-dependence, characteristic of gap nodes. Both the superfluid density and the electronic specific heat are best described by a two-gap mode…
We study the superconducting state in newly discovered high-Tc superconductor K$_x$Fe$_2$Se$_2$ based on the ten-orbital Hubbard-Holstein model without hole-pockets. When the Coulomb interaction is large, spin-fluctuation mediated d-wave state appears due to the nesting between electron-pockets. Interestingly, the symmetry of the body-centered tetragonal structure in K$_x$Fe$_2$Se$_2$ requires the existence of nodes in the d-wave gap, although fully-gapped d-wave state is realized in the case of simple tetragonal structure. In the presence of moderate electron-phonon interaction due to Fe-ion …
Charge-$4e$ superconductivity as a novel phase of matter remains elusive so far. Here we show that charge-$4e$ phase can arise as a vestigial order above the nematic superconducting transition temperature in time-reversal-invariant nematic superconductors. On the one hand, the nontrivial topological defect -- nematic vortex -- is energetically favored over the superconducting phase vortex when the nematic stiffness is less than the superfluid stiffness; consequently the charge-$4e$ phase emerges by proliferation of nematic vortices upon increasing temperatures. On the other hand, the Ginzburg-…
Recently, the niobium (Nb)-doped topological insulator Bi_2Se_3, in which the finite magnetic moments of the Nb atoms are intercalated in the van der Waals gap between the Bi_2Se_3 layers, has been shown to exhibit both superconductivity with T_c = 3 K and topological surface states. Here we report on muon spin rotation experiments probing the temperature-dependent of effective magnetic penetration depth Lambda_eff(T) in the layered topological superconductor candidate Nb_0.25Bi_2Se_3. The exponential temperature dependence of lambda_(eff)^(-2)(T) at low temperatures suggests a fully gapped su…
The topological invariants of gapped time reversal invariant lattice superconductors are studied by mapping the superconducting mean field Hamiltonian to a Bloch Hamiltonian. There is a single $Z_2 $ invariant in two dimensions and four such invariants in three dimensions. We briefly discuss the properties of states with non-trivial topological invariants.
Despite rapid progress in understanding gapped topological states, much less is known about gapless topological phases of matter, especially in strongly correlated electrons. In this work we discuss a large class of robust gapless quantum spin liquids in frustrated magnets made of half-integer spins, which are described by gapless fermionic spinons coupled to dynamical $Z_2$ gauge fields. Requiring $U(1)$ spin conservation, time reversal and certain space group symmetries, we show that certain spinon symmetry fractionalization class necessarily leads to a gapless spectrum. These gapless excita…
We show that a layered superconductor, described by a two-component order parameter, has a gapped state above the ground state, topologically protected from decay, containing flow and counter flow in the absence of an applied magnetic field. This state is made of skyrmions, breaks time reversal symmetry and produces a weak local magnetic field below the present threshold of detection by $μ$SR and NMR/NQR. We estimate the density of carriers that condense into the pseudogap.
We report the discovery of Zr$_3$Ir as a new type of unconventional noncentrosymmetric superconductor (with $T_c = 2.3$ K), here investigated mostly via muon-spin rotation/relaxation ($μ$SR) techniques. Its superconductivity was characterized using magnetic susceptibility, electrical resistivity, and heat capacity measurements. The low-temperature superfluid density, determined via transverse-field $μ$SR and electronic specific heat, suggests a fully-gapped superconducting state. The spontaneous magnetic fields, revealed by zero-field $μ$SR below $T_c$, indicate the breaking of time-reversal s…
We report a comprehensive study of the noncentrosymmetric NbReSi superconductor by means of muon-spin rotation and relaxation ($μ$SR) and nuclear magnetic resonance (NMR) techniques. NbReSi is a bulk superconductor with $T_c = 6.5$ K, characterized by a large upper critical field, which exceeds the Pauli limit. Both the superfluid density $ρ_\mathrm{sc}(T)$ (determined via transverse-field $μ$SR) and the spin-lattice relaxation rate $T_1^{-1}(T)$ (determined via NMR) suggest a nodeless superconductivity (SC) in NbReSi. We also find signatures of multigap SC, here evidenced by the field-depende…
Gapped excitation spectra of Andreev states are studied in one- and two-dimensional (1D and 2D) normal systems in superconducting contacts subject to a parallel magnetic field. In the ballistic regime, a specific interplay between magnetic field spin splitting and the effect of a screening supercurrent is found to preserve time-reversal symmetry for certain groups of Andreev states remaining gapped despite the presense of the magnetic field. In 1D wires such states can lead to a fractional thermal magnetoconductance equal to half of the thermal conductance quantum. In 2D systems the thermal ma…
It is well known that the 3D electronic topological insulator (TI) with charge-conservation and time-reversal symmetry cannot have a trivial insulating surface that preserves symmetry. It is often implicitly assumed that if the TI surface preserves both symmetries then it must be gapless. Here we show that it is possible for the TI surface to be both gapped and symmetry-preserving, at the expense of having surface-topological order. In contrast to analogous bosonic topological insulators, this symmetric surface topological order is intrinsically non-Abelian. We show that the surface-topologica…
A topological superconductor is a fully gapped superconductor that exhibits exotic zero-energy Andreev surface states at interfaces with a normal metal. In this paper we investigate the properties of a three-dimensional time reversal invariant topological superconductor by means of a two-band model with unconventional pairing in both the inter- and intraband channels. Due to the bulk-boundary correspondence the presence of Andreev surface states in this system is directly related to the topological structure of the bulk wavefunctions, which is characterized by a winding number. Using quasiclas…
The interplay between bulk spin-orbit coupling and electron-electron interactions produces umklapp scattering in the helical edge states of a two-dimensional topological insulator. If the chemical potential is at the Dirac point, umklapp scattering can open a gap in the edge state spectrum even if the system is time-reversal invariant. We determine the zero-energy bound states at the interfaces between a section of a helical liquid which is gapped out by the superconducting proximity effect and a section gapped out by umklapp scattering. We show that these interfaces pin charges which are mult…
To gain insight into the unconventional superconductivity of Fe-pnictides with no electron pockets, we measure the thermal conductivity $κ$ and penetration depth $λ$ in the heavily hole-doped regime of Ba$_{1-x}$K$_x$Fe$_2$As$_2$. The residual thermal conductivity $(κ/T)_{T \rightarrow 0\,{\rm K}}$ and $T$-dependence of $λ$ consistently indicate the fully gapped superconductivity at $x=0.76$ and the (line) nodal superconductivity at higher hole concentrations. The magnitudes of $\fracκ{T}\cdot T_c|_{T \rightarrow 0\,{\rm K}}$ and $\frac{dλ}{d(T/T_c)}$ at low temperatures, both of which are det…
Many clever routes to Majorana fermions have been discovered by exploiting the interplay between superconductivity and band topology in metals and insulators. However, realizations in semimetals remain less explored. We ask, ``under what conditions do superconductor vortices in time-reversal symmetric Weyl semimetals -- three-dimensional semimetals with only time-reversal symmetry -- trap Majorana fermions on the surface?'' If each constant-$k_{z}$ plane, where $z$ is the vortex axis, contains equal numbers of Weyl nodes of each chirality, we predict a generically gapped vortex and derive a to…
The robustness against local perturbations, as long as the symmetry of the system is preserved, is a distinctive feature of topological quantum states. Magnetic impurities and defects break time-reversal invariance and, consequently, time-reversal invariant (TRI) topological superconductors are fragile against this type of disorder. Non-magnetic impurities, however, preserve time-reversal symmetry and one naively expects a TRI topological superconductor to persist in the presence of non-magnetic impurities. In this work, we study the effect of non-magnetic disorder on a TRI topological superco…
In search of the origin of superconductivity in diluted rhenium superconductors and their significantly enhanced $T_c$ compared to pure Be (0.026 K), we investigated the intermetallic ReBe$_{22}$ compound, mostly by means of muon-spin rotation/relaxation ($μ$SR). At a macroscopic level, its bulk superconductivity (with $T_c=9.4$ K) was studied via electrical resistivity, magnetization, and heat-capacity measurements. The superfluid density, as determined from transverse-field $μ$SR and electronic specific-heat measurements, suggest that ReBe$_{22}$ is a fully-gapped superconductor with some mu…
In heavy-fermion superconductors, it is widely believed that the superconducting gap function has sign-reversal due to the strong electron correlation. However, recently discovered fully-gapped s-wave superconductivity in CeCu2Si2 has clarified that strong attractive pairing interaction can appear even in heavy-fermion systems. To understand the origin of attractive force, we develop the multipole fluctuation theory by focusing on the inter-multipole many-body interaction called the vertex corrections. By analyzing the periodic Anderson model for CeCu2Si2, we find that hexadecapole fluctuation…
Majorana vortex phases in time-reversal invariant higher-order topological insulators and topologically trivial insulators
Anhui Province Key Laboratory of Low-Energy Quantum Materials and Devices, High Magnetic Field Laboratory, HFIPS, Chinese Academy of Sciences（中国科学院合肥物质科学研究院高磁场实验室安徽省低能量子材料与器件重点实验室）；Department of Physics, Hong Kong University of Science and Technology（香港科技大学物理系）；School of Physics and Optoelectronic Engineering, Anhui University（安徽大学物理与光电工程学院）
The superconducting gap structures in the transition-metal-based kagome metal AV$_3$Sb$_5$ (A=K,Rb,Cs), the first family of quasi-two-dimensional kagome superconductors, remain elusive as there is strong experimental evidence for both nodal and nodaless gap structures. Here we show that the dichotomy can be resolved because of the coexistence of time-reversal symmetry breaking with a conventional fully gapped superconductivity. The symmetry protects the edge states which arise on the domains of the lattice symmetry breaking order to remain gapless in proximity to a conventional pairing. We dem…
Topological superconductors are gapped superconductors with protected Majorana surface/edge states on the boundary. In this paper, we study the Josephson coupling between time-reversal invariant topological superconductors and s-wave superconductors. The Majorana edge/surface states of time-reversal invariant topological superconductors in all physical dimensions 1, 2, 3 have a generic topological property which we named as time-reversal anomaly. Due to the time-reversal anomaly, the Josephson coupling prefers a nonzero phase difference between topological and trivial superconductors. The nont…
Symmetry protected topological (SPT) phases are gapped quantum phases with a certain symmetry, which can all be smoothly connected to the same trivial product state if we break the symmetry. For non-interacting fermion systems with time reversal (T), charge conjugation (C), and/or U(1) (N) symmetries, the total symmetry group can depend on the relations between those symmetry operations, such as T N T^{-1}= N or T N T^{-1}= -N. As a result, the SPT phases of those fermion systems with different symmetry groups have different classifications. In this paper, we use Kitaev's K-theory approach to …
We establish the topology of the spin-singlet superconducting states in the bare hyperhoneycomb lattice and derive analytically the full phase diagram using only symmetry and topology in combination with simple energy arguments. The phase diagram is dominated by two states preserving time-reversal symmetry. We find that the line-nodal state dominating at low doping levels is topologically nontrivial and exhibits surface Majorana flat bands, which we show perfectly match the bulk-boundary correspondence using Berry phase approach. At higher doping levels we find a fully gapped state with trivia…
We consider manifestations of topological order in time-reversal-symmetric fractional topological liquids (TRS-FTLs), defined on planar surfaces with holes. We derive a formula for the topological ground state degeneracy of such a TRS-FTL, which applies to cases where the edge modes on each boundary are fully gapped by appropriate backscattering terms. The degeneracy is exact in the limit of infinite system size, and is given by $q^{N^{\,}_{\mathrm{h}}}$, where $N^{\,}_{\mathrm{h}}$ is the number of holes and $q$ is an integer that is determined by the topological field theory. When the degene…
We report a comprehensive study of the Zr$_5$Pt$_3$C$_x$ superconductors, with interstitial carbon comprised between 0 and 0.3. At a macroscopic level, their superconductivity, with $T_c$ ranging from 4.5 to 6.3 K, was investigated via electrical-resistivity-, magnetic-susceptibility-, and specific-heat measurements. The upper critical fields $μ_0H_\mathrm{c2}$ $\sim$ 7 T were determined mostly from measurements of the electrical resistivity in applied magnetic fields. The microscopic electronic properties were investigated by means of muon-spin rotation and relaxation ($μ$SR) and nuclear magn…
Superconductors with broken time-reversal symmetry represent arguably one of the most promising venues for realizing highly sought-after topological superconductivity that is vital to fault-tolerant quantum computation. Here, by using extensive muon-spin relaxation and rotation measurements, we report that the isostructural silicide superconductors (Ta, Nb)OsSi spontaneously break time-reversal symmetry at the superconducting transition while surprisingly showing a fully-gapped superconductivity characteristic of conventional superconductors. The first-principles calculations show that (Ta, Nb…
We report theoretical predictions on the pairing symmetry of the newly discovered superconducting nickelate Nd$_{1-x}$Sr$_{x}$NiO$_{2}$ based on the renormalized mean-field theory for a generalized model Hamiltonian proposed in [Phys. Rev. B \textbf{101}, 020501(R)]. For practical values of the key parameters, we find a transition between a gapped ($d+is$)-wave pairing state in the small doping region to a gapless $d$-wave pairing state in the large doping region, accompanied by an abrupt Fermi surface change at the critical doping. Our overall phase diagram also shows the possibility of a ($d…
It is shown that the patches of complex d_{xy} component are generated around magnetic impurity in the presence of the coupling between orbital moment of the condensate and impurity spin S. Locally induced d_{xy} gap leads to the fully gapped quasiparticle spectrum near impurity. The phase of the induced i d_{xy} component is determined by impurity spin and averages to zero at high temperatures. It is suggested that at low temperature the well defined patches of d_{xy} are formed and they can undergo a phase transition into phase locked state via Josephson effect. Violation of time-reversal sy…
The single helical Fermi surface on the surface state of three-dimensional topological insulator Bi2Se3 is constrained by the time-reversal invariant bulk topology to possess a spin-singlet superconducting pairing symmetry. In fact, the Cu-doped, and pressure-tuned superconducting Bi2Se3 show no evidence of the time reversal symmetry breaking. We report on the detection of the time reversal symmetry (TRS) breaking in the topological superconductor Sr0.1Bi2Se3 , probed by zero-field (ZF) μSR measurements. The TRS breaking provides strong evidence for the existence of spin-triplet pairing state.…
Nonunitary superconductivity is a rare and striking phenomenon in which spin up and spin down electrons segregate into two different quantum condensates. Because they support topological excitations, such superconductors are being seriously considered for potential quantum information applications. We report the discovery of nonunitary spin-triplet superconductivity in UTe2, featuring the high transition temperature of 1.6 K and a remarkably large and anisotropic upper critical field exceeding 40 T. In this unusual superconducting state, electrons with parallel spins pair, yet only half of the…
Strain-Induced Helical Superconductivity and the Zero-Field Diode Effect
Institute for Theory of Condensed Matter, Karlsruhe Institute of Technology（卡尔斯鲁厄理工学院凝聚态理论研究所）；Institute for Quantum Materials and Technologies, Karlsruhe Institute of Technology（卡尔斯鲁厄理工学院量子材料与技术研究所）
Epitaxial bilayer films of Bi(110) and Ni host a time-reversal symmetry (TRS) breaking superconducting order with an unexpectedly high transition temperature $T_c = 4.1$ K. Using time-domain THz spectroscopy, we measure the low energy electrodynamic response of a Bi/Ni bilayer thin film from $0.2$ THz to $2$ THz as a function of temperature and magnetic field. We analyze the data in the context of a BCS-like superconductor with a finite normal-state scattering rate. In zero magnetic field, all states in the film become fully gapped, providing important constraints into possible pairing symmetr…
It is commonly believed that in the absence of disorder or an external magnetic field, there are three possible types of superconducting excitation gaps: the gap is nodeless, it has point nodes, or it has line nodes. Here, we show that for an even-parity nodal superconducting state which spontaneously breaks time-reversal symmetry, the low-energy excitation spectrum generally does not belong to any of these categories, instead it has extended Bogoliubov Fermi surfaces. These Fermi surfaces can be visualized as two-dimensional surfaces generated by "inflating" point or line nodes into spheroids…
We report a comprehensive study of the noncentrosymmetric superconductor Mo$_3$P. Its bulk superconductivity, with $T_c = 5.5$ K, was characterized via electrical resistivity, magnetization, and heat-capacity measurements, while its microscopic electronic properties were investigated by means of muon-spin rotation/relaxation ($μ$SR) and nuclear magnetic resonance (NMR) techniques. In the normal state, NMR relaxation data indicate an almost ideal metallic behavior, confirmed by band-structure calculations, which suggest a relatively high electron density of states, dominated by the Mo $4d$-orbi…
