Laser decoherence limits the stability of optical clocks by broadening the observable resonance linewidths and adding noise during the dead time between clock probes. Correlation spectroscopy avoids these limitations by measuring correlated atomic transitions between two ensembles, which provides a frequency difference measurement independent of laser noise. Here, we apply this technique to perform stability measurements between two independent clocks based on the $^1S_0\leftrightarrow{}^3P_0$ transition in $^{27}$Al$^+$. By stabilizing the dominant sources of differential phase noise between the two clocks, we observe coherence between them during synchronous Ramsey interrogations as long as 8 s at a frequency of $1.12\times10^{15}$ Hz. The observed contrast in the correlation spectroscopy signal is consistent with the 20.6 s $^3P_0$ state lifetime and supports a measurement instability of $(1.8\pm0.5)\times 10^{-16}/\sqrt{τ/\textrm{s}}$ for averaging periods longer than the probe duration when deadtime is negligible.
A caesium fountain clock is operated utilizing a microwave oscillator that derives its frequency stability from a stable laser by means of a fiber-laser femtosecond frequency comb. This oscillator is based on the technology developed for optical clocks and replaces the quartz based microwave oscillator commonly used in fountain clocks. As a result, a significant decrease of the frequency instability of the fountain clock is obtained, reaching 0.74E-14 at 100 s averaging time. We could demonstrate that for a significant range of detected atom numbers the instability is limited by quantum projec…
We describe an optical frequency stabilization scheme of a microwave oscillator that is used for the interrogation of primary caesium fountain clocks. Because of its superior phase noise properties, this scheme, which is based on an ultrastable laser and a femtosecond laser frequency comb, overcomes the frequency instability limitations of fountain clocks given by the previously utilized quartz-oscillator-based frequency synthesis. The presented scheme combines the transfer of the short-term frequency instability of an optical cavity and the long-term frequency instability of a hydrogen maser …
Optical clock interrogation protocols, based on laser-pulse spectroscopy, are suffering from probe-induced frequency shifts and their variations induced by laser power. Original Hyper-Ramsey probing scheme, which was proposed to alleviate those issues, does not fully eliminate the shift, especially when decoherence and relaxation by spontaneous emission or collisions are present. We propose to solve the fundamental problem of frequency shifts induced by laser probe by deriving the exact canonical form of a multi-pulse generalized Hyper-Ramsey (GHR) resonance, including decoherence and relaxati…
The mid-term fractional frequency stability of miniaturized atomic clocks can be limited by light-shift effects. In this Letter, we demonstrate the implementation of a symmetric Auto-Balanced Ramsey (SABR) interrogation sequence in a microcell-based atomic clock based on coherent population trapping (CPT). Using this advanced protocol, the sensitivity of the clock frequency to laser power, microwave power and laser frequency variations is reduced, at least by one order of magnitude, in comparison with continuous-wave (CW) or Ramsey interrogation schemes. Light-shift mitigation obtained with th…
The frequency stability achieved by an optical atomic clock ultimately depends on the coherence of its local oscillator. Even the best ultrastable lasers only allow interrogation times of a few seconds, at present. Here we present a universal measurement protocol that overcomes this limitation. Engineered dynamic decoupling of laser phase noise allows any optical atomic clock with high signal-to-noise ratio in a single interrogation to reconstruct the laser's phase well beyond its coherence limit. A compound clock is then formed in combination with another optical clock of any type, allowing t…
Quantum-logic-based ${}^{27}\textrm{Al}^+$ optical clock has been demonstrated in several schemes as there are different choices of the auxiliary ion species. In this paper, we present the first detailed evaluation of the systematic shift and the total uncertainty of an ${}^{27}\textrm{Al}^+$ optical clock sympathetically cooled by a ${}^{40}\textrm{Ca}^+$ ion. The total systematic uncertainty of the ${}^{40}\textrm{Ca}^+ - {}^{27}\textrm{Al}^+$ quantum logic clock has been estimated to be $7.9 \times 10^{-18}$, which was mainly limited by the uncertainty of the quadratic Zeeman shift. By comp…
We stabilise a microwave oscillator at 9.6 GHz to an optical clock laser at 344 THz by using a fibre-based femtosecond laser frequency comb as a transfer oscillator. With a second frequency comb we measure independently the instability of the microwave source with respect to another optical clock laser frequency at 456 THz. The total fractional frequency instability of this optic-to-microwave and microwave-to-optic conversion resulted in an Allan deviation sigma_y, of sigma_y=1.2E-14 at 1 s averaging time (band width 50 kHz). The residual phase noise density is -97 dBc/Hz at 10 Hz offset from …
Electrometry is performed using Rydberg states to evaluate the quadratic Stark shift of the $5s^2$ $^1\textrm{S}_0-5s5p$ $^3\textrm{P}_0$ clock transition in strontium. By measuring the Stark shift of the highly excited $5s75d\;^1\textrm{D}_2$ state using electromagnetically induced transparency, we characterize the electric field with sufficient precision to provide tight constraints on the systematic shift to the clock transition. Using the theoretically derived, and experimentally verified, polarizability for this Rydberg state we can measure the residual field with an uncertainty well belo…
We report on the setup and characterization of a 698 nm master-slave diode laser system to probe the 1S0-3P0 clock transition of strontium atoms confined in a one-dimensional optical lattice. A linewidth in the order of around 100 Hz of the laser system has been measured with respect to an ultrastable 657 nm diode laser with 1 Hz linewidth using a femtosecond fiber comb as transfer oscillator. The laser has been used to measure the magnetically induced 1S0-3P0 clock transition in 88Sr where a linewidth of 165 Hz has been observed. The transfer oscillator method provides a virtual beat signal b…
We have developed an ultra-stable source in the deep ultraviolet, suitable to fulfill the interrogation requirements of a future fully-operational lattice clock based on neutral mercury. At the core of the system is a Fabry-Pérot cavity which is highly impervious to temperature and vibrational perturbations. The mirror substrate is made of fused silica in order to exploit the comparatively low thermal noise limits associated with this material. By stabilizing the frequency of a 1062.6 nm Yb-doped fiber laser to the cavity, and including an additional link to LNE-SYRTE's fountain primary freque…
We present a new scheme of compact Rubidium cold-atom clock which performs the diffuse light cooling, the microwave interrogation and the detection of the clock signal in a cylindrical microwave cavity. The diffuse light is produced by the reflection of the laser light at the inner surface of the microwave cavity. The pattern of injected laser beams is specially designed to make most of the cold atoms accumulate in the center of the microwave cavity. The microwave interrogation of cold atoms in the cavity leads to Ramsey fringes whose line-width is 24.5 Hz and the contrast of 95.6% when the fr…
Light-induced frequency shifts can be a key limiting contribution to the mid and long-term frequency instability in atomic clocks. In this letter, we demonstrate the experimental implementation of the combined error signal interrogation protocol to a cold-atom clock based on coherent population trapping (CPT) and Ramsey spectroscopy. The method uses a single error signal that results from the normalized combination of two error signals extracted from two Ramsey sequences of different dark periods. The single combined error signal is used to stabilize the atomic clock frequency. Compared to the…
Atomic clocks based on optical transitions are the most stable, and therefore precise, timekeepers available. These clocks operate by alternating intervals of atomic interrogation with dead time required for quantum state preparation and readout. This non-continuous interrogation of the atom system results in the Dick effect, an aliasing of frequency noise of the laser interrogating the atomic transition. Despite recent advances in optical clock stability achieved by improving laser coherence, the Dick effect has continually limited optical clock performance. Here we implement a robust solutio…
Bayesian Frequency Metrology with Optimal Ramsey Interferometry in Optical Atomic Clocks
Institute for Theoretical Physics and Institute for Gravitational Physics (Albert-Einstein-Institute), Leibniz University Hannover（汉诺威莱布尼茨大学理论物理研究所与引力物理研究所（爱因斯坦研究所））
We show that the light shift in atomic clocks can be suppressed using time variation of the interrogation field intensity. By measuring the clock output at two intensity levels, error signals can be generated that simultaneously stabilize a local oscillator to an atomic transition and correct for the shift of this transition caused by the interrogating optical field. These methods are suitable for optical clocks using one- and two-photon transitions, as well as for microwave clocks based on coherent population trapping or direct interrogation. The proposed methods can be widely used both for h…
Credible-interval-based adaptive Bayesian quantum frequency estimation for entanglement-enhanced atomic clocks
Sun Yat-Sen University (Zhuhai Campus)（中山大学（珠海校区））；Shenzhen University（深圳大学）；Quantum Science Center of Guangdong-Hong Kong-Macao Greater Bay Area (Guangdong)（粤港澳大湾区量子科学中心（广东））
Portable laser-cooled ytterbium beam clock based on an ultra-narrow optical transition
Institute for Photonics and Advanced Sensing (IPAS) and School of Physics, Chemistry and Earth Sciences, University of Adelaide（阿德莱德大学光子学与先进传感研究所及物理、化学与地球科学学院）；School of Mathematics and Physics, University of Queensland（昆士兰大学数学与物理学院）
We devise a perturbation-immune version of Ramsey's method of separated oscillatory fields. Spectroscopy of an atomic clock transition without compromising the clock's accuracy is accomplished by actively balancing the spectroscopic responses from phase-congruent Ramsey probe cycles of unequal durations. Our simple and universal approach eliminates a wide variety of interrogation-induced line shifts often encountered in high precision spectroscopy, among them, in particular, light shifts, phase chirps, and transient Zeeman shifts. We experimentally demonstrate auto-balanced Ramsey spectroscopy…
The 7.8 eV nuclear isomer transition in 229 Thorium has been suggested as an etalon transition in a new type of optical frequency standard. Here we discuss the construction of a "solid-state nuclear clock" from Thorium nuclei implanted into single crystals transparent in the vacuum ultraviolet range. We investigate crystal-induced line shifts and broadening effects for the specific system of Calcium fluoride. At liquid Nitrogen temperatures, the clock performance will be limited by decoherence due to magnetic coupling of the Thorium nucleus to neighboring nuclear moments, ruling out the common…
Sophisticated Ramsey-based interrogation protocols using composite laser pulse sequences have been recently proposed to provide next-generation high-precision atomic clocks with a near perfect elimination of frequency shifts induced during the atom-probing field interaction. We propose here a simple alternative approach to the auto-balanced Ramsey (ABR) interrogation protocol and demonstrate its application to a cold-atom microwave clock based on coherent population trapping. The main originality of the method, based on two consecutive Ramsey sequences with different dark periods, is to sample…
Stringent conditions on the phase relation of multiple photons are a prerequisite for novel protocols of high-resolution coherent spectroscopy. In a recent experiment we have implemented an interrogation process of a Ca$^+$-ion cloud based on three-photon coherent population trapping, with the potential to serve as a frequency reference in the THz-range. This high-resolution interrogation has been made possible by phase-locking both laser sources for cooling and repumping of the trapped ions to a clock laser at 729~nm by means of an optical frequency comb. The clock laser, a titanium-sapphire …
Vapor cell atomic clocks exhibit reduced frequency stability for averaging time between about one hundred and a few thousand seconds. Here we report a study on the impact of the main parameters on the mid-to-long term instability of a buffer-gas vapor cell Cs clock, based on coherent population trapping (CPT). The CPT signal is observed on the Cs D1 line transmission, using a double $Λ$ scheme and a Ramsey interrogation technique. The effects on the clock frequency of the magnetic field, the cell temperature, and the laser intensities are reported. We show in particular that the laser intensit…
We present and implement a non-destructive detection scheme for the transition probability readout of an optical lattice clock. The scheme relies on a differential heterodyne measurement of the dispersive properties of lattice-trapped atoms enhanced by a high finesse cavity. By design, this scheme offers a 1st order rejection of the technical noise sources, an enhanced signal-to-noise ratio, and an homogeneous atom-cavity coupling. We theoretically show that this scheme is optimal with respect to the photon shot noise limit. We experimentally realize this detection scheme in an operational str…
We have developed a universal method to form the reference signal for the stabilization of arbitrary atomic clocks based on Ramsey spectroscopy. Our approach uses an interrogation scheme of the atomic system with two different Ramsey periods and a specially constructed combined error signal (CES) computed by subtracting two error signals with the appropriate calibration factor. CES spectroscopy allows for perfect elimination of probe-induced light shifts and does not suffer from the effects of relaxation, time-dependent pulse fluctuations and phase-jump modulation errors and other imperfection…
We present a new interrogation scheme for the next generation of quantum clocks to suppress frequency-shifts induced by laser probing fields themselves based on Generalized Hyper-Ramsey resonances. Sequences of composite laser pulses with specific selection of phases, frequency detunings and durations are combined to generate a very efficient and robust frequency locking signal with almost a perfect elimination of the light-shift from off resonant states and to decouple the unperturbed frequency measurement from the laser's intensity. The frequency lock point generated from synthesized error s…
We present an analysis of the different types of noise from the detection and interrogation laser in our strontium lattice clock. We develop a noise model showing that in our setup quantum projection noise--limited detection is possible if more than 130~atoms are interrogated. Adding information about the noise spectrum of our clock laser with sub-$10^{-16}$ fractional frequency instability allows to infer the clock stability for different modes of operation. Excellent agreement with experimental observations for the instability of the difference between two interleaved stabilizations is found…
Quantum projection noise will soon limit the best achievable precision of optical atomic clocks based on lattice-confined neutral atoms. Squeezing the collective atomic pseudo-spin via measurement of the clock state populations during Ramsey interrogation suppresses the projection noise. We show here that the lattice laser field can be used to perform ideal quantum non-demolition measurements without clock shifts or decoherence and explore the feasibility of such an approach in theory with the lattice field confined in a ring-resonator. Detection of the motional sideband due to the atomic vibr…
Light-shifts are known to be an important limitation to the mid- and long-term fractional frequency stability of different types of atomic clocks. In this article, we demonstrate the experimental implementation of an advanced anti-light shift interrogation protocol onto a continuous-wave (CW) microcell atomic clock based on coherent population trapping (CPT). The method, inspired by the Auto-Balanced Ramsey (ABR) spectroscopy technique demonstrated in pulsed atomic clocks, consists in the extraction of atomic-based information from two successive light-shifted clock frequencies obtained at two…
The next generation of atomic frequency standards based on an ensemble of neutral atoms or a single-ion will provide very stringent tests in metrology, applied and fundamental physics requiring a new step in very precise control of external systematic corrections. In the proceedings of the 8th Symposium on Frequency Standards and Metrology, we present a generalization of the recent Hyper-Ramsey spectroscopy with separated oscillating fields using composites pulses in order to suppress field frequency shifts induced by the interrogation laser itself. Sequences of laser pulses including specific…
We investigate the leading systematic effects in ro-vibrational spectroscopy of the molecular hydrogen ions H2+ and HD+, in order to assess their potential for the realization of optical clocks that would be sensitive to possible variations of the proton-to-electron mass ratio. Both two-photon (2E1) and quadrupole (E2) transitions are considered. In view of the weakness of these transitions, most attention is devoted to the light shift induced by the probe laser, which we express as a function of the transition amplitude, differential dynamic polarizability and clock interrogation times. Trans…
We develop an abstract model of atomic clocks that fully describes the dynamics of repeated synchronization between a classical oscillator and a quantum reference. We prove existence of a stationary state of the model and study its dependence on the control scheme, the interrogation time and the stability of the oscillator. For unbiased atomic clocks, we derive a fundamental bound on atomic clocks long time stability for a given local oscillator noise. In particular, we show that for a local oscillator noise with integrated frequency variance scaling as $T^α$ for short times $T$, the optimal c…
A two-photon transition in laser-cooled and trapped calcium atoms is proposed as the atomic reference in an optical frequency standard. An efficient scheme for interrogation of the frequency standard is described, and the sensitivity of the clock transition to systematic effects is estimated. Frequency standards based on this transition could lead to compact and portable devices that are capable of rapidly averaging down to $< 10^{-16}$.
We have investigated the benefits of spin squeezed states for clocks operated with typical Brownian frequency noise-limited laser sources. Based on an analytic model of the closed servo-loop of an optical atomic clock, we can give quantitative predictions on the optimal clock stability for a given dead time and laser noise. Our analytic predictions are in very good agreement with numerical simulations of the closed servo-loop. We find that for usual cyclic Ramsey interrogation of single atomic ensembles with dead time, even with the current most stable lasers spin squeezing can only improve th…
We demonstrate precision measurement and control of inhomogeneous broadening in a multi-ion clock consisting of three $^{176}$Lu$^+$ ions. Microwave spectroscopy between hyperfine states in the $^3D_1$ level is used to characterise differential systematic shifts between ions, most notably those associated with the electric quadrupole moment. By appropriate alignment of the magnetic field, we demonstrate suppression of these effects to the $\sim 10^{-17}$ level relative to the $^1S_0\leftrightarrow{}^3D_1$ optical transition frequency. Correlation spectroscopy on the optical transition demonstr…
Deep laser cooling of atoms, ions, and molecules facilitates the study of fundamental physics as well as applied research. In this work, we report on the narrow-line laser cooling of thulium atoms at the wavelength of $506.2\,\textrm{nm}$ with the natural linewidth of $7.8\,\textrm{kHz}$, which widens the limits of atomic cloud parameters control. Temperatures of about $400\,\textrm{nK}$, phase-space density of up to $3.5\times10^{-4}$ and $2\times10^6$ number of trapped atoms were achieved. We have also demonstrated formation of double cloud structure in an optical lattice by adjusting parame…
Comparisons of high-accuracy optical atomic clocks \cite{Ludlow2015} are essential for precision tests of fundamental physics \cite{Safronova2018}, relativistic geodesy \cite{McGrew2018, Grotti2018, Delva2019}, and the anticipated redefinition of the SI second \cite{Riehle2018}. The scientific reach of these applications is restricted by the statistical precision of interspecies comparison measurements. The instability of individual clocks is limited by the finite coherence time of the optical local oscillator (OLO), which bounds the maximum atomic interrogation time. In this letter, we experi…
We propose a compact atomic clock based on ultracold Rb atoms that are magnetically trapped near the surface of an atom microchip. An interrogation scheme that combines electromagnetically-induced transparency (EIT) with Ramsey's method of separated oscillatory fields can achieve atomic shot-noise level performance of 10^{-13}/sqrt(tau) for 10^6 atoms. The EIT signal can be detected with a heterodyne technique that provides noiseless gain; with this technique the optical phase shift of a 100 pW probe beam can be detected at the photon shot-noise level. Numerical calculations of the density mat…
The Dick effect can be a limitation of the achievable frequency stability of a passive atomic frequency standard when the ancillary frequency source is only periodically sampled. Here we analyze the Dick effect for a pulsed vapor cell clock using coherent population trapping (CPT). Due to its specific interrogation process without atomic preparation nor detection outside of the Ramsey pulses, it exhibits an original shape of the sensitivity function to phase noise of the oscillator. Numerical calculations using a three-level atom model are successfully compared with measurements; an approximat…
We propose a new frequency standard based on a $4f^{14} 6s6p~ ^3\!P_0 - 4f^{13} 6s^2 5d ~(J=2)$ transition in neutral Yb. This transition has a potential for high stability and accuracy and the advantage of the highest sensitivity among atomic clocks to variation of the fine-structure constant $α$. We find its dimensionless $α$-variation enhancement factor to be $K=-15$, in comparison to the most sensitive current clock (Yb$^+$ E3, $K=-6$), and it is 18 times larger than in any neutral-atomic clocks (Hg, $K=0.8$). Combined with the unprecedented stability of an optical lattice clock for neutra…
We observe two-body loss of ${}^3P_0$ ${}^{87}$Sr atoms trapped in a one-dimensional optical lattice. We measure loss rate coefficients for atomic samples between 1 and 6 $μ$K that are prepared either in a single nuclear-spin-sublevel or with equal populations in two sublevels. The measured temperature and nuclear spin preparation dependence of rate coefficients agree well with calculations and reveal that rate coefficients for distinguishable atoms are only slightly enhanced over those of indistinguishable atoms. We further observe a suppression of excitation and losses during interrogation o…
Active optical frequency standards provide interesting alternatives to their passive counterparts. Particularly, such a clock alone continuously generates highly-stable narrow-line laser radiation. Thus a local oscillator is not required to keep the optical phase during a dead time between interrogations as in passive clocks, but only to boost the active clock's low output power to practically usable levels with the current state of technology. Here we investigate the spectral properties and the stability of active clocks, including homogeneous and inhomogeneous broadening effects. We find tha…
We propose a method of joint interrogation in a single atom interferometer which overcomes the dead time between consecutive measurements in standard cold atomic fountains. The joint operation enables for a faster averaging of the Dick effect associated with the local oscillator noise in clocks and with vibration noise in cold atom inertial sensors. Such an operation allows achieving the lowest stability limit due to atom shot noise. We demonstrate a multiple joint operation in which up to five clouds of atoms are interrogated simultaneously in a single setup. The essential feature of multiple…
We develop an universal method to significantly suppress probe-induced shifts in any types of atomic clocks using the Ramsey spectroscopy. Our approach is based on adaptation of the synthetic frequency concept [V. I. Yudin, et al., Phys. Rev. Lett. 107, 030801 (2011)] (previously developed for BBR shift suppression) to the Ramsey spectroscopy with the use of interrogations for different dark time intervals. Universality of the method consists in arbitrariness of the possible Ramsey schemes. However, most extremal results are obtained in combination with so-called hyper-Ramsey spectroscopy [V. …
We report on an ultrastable molecular clock based on the interrogation of the 3ν rotational-vibrational combination band at 1563nm of carbon monoxide 12C16O. The laser stabilization scheme is based on frequency modulation (FM) saturation spectroscopy in a high-finesse ultra-low expansion (ULE) glass optical cavity using CO as the molecular reference for longterm stabilization of the cavity resonance. The NICEOHMS FM modulation method is employed to maintain a high signal-to-noise ratio and avoid conversion of laser frequency noise into amplitude noise by the high finesse cavity. We report an A…
