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arXiv 2005.03309cond-mat.mtrl-sci
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Ta对FeCrNi合金蠕变抗力显著影响的原因

Origin of the Significant Impact of Ta on the Creep Resistance of FeCrNi Alloys

D. Magne, X. Sauvage, M. Couvrat

摘要:

耐热FeCrNi合金广泛应用于石化工业,因为它们在超过900 $^\circ$ C的温度下表现出抗蠕变和抗氧化性的独特组合。它们的蠕变性能通常通过微量添加碳化物形成元素来优化。在目前的工作中,Ta微量添加剂的影响已被实验研究的铸态和老化的显微组织,以了解该元素的蠕变抗力的显着影响的起源。还进行了与thermocal软件的计算,以支持实验数据。结果表明,少量添加Ta是有益的,因为它增加了稳定的MC碳化物的体积分数。我们还表明,Ta的添加可能有显着的影响的热稳定性的微观结构。这是由于在MC/基体界面处M23 C6的平衡体积分数较小且非均相析出更明显。讨论了其对蠕变性能的影响。

英文摘要:

Heat resistant FeCrNi alloys are widely used in the petrochemical industry because they exhibit a unique combination of creep and oxidation resistance at temperatures exceeding 900$^\circ$C. Their creep properties are often optimized by micro-additions of carbide forming elements. In the present work, the influence of Ta micro-additions has been experimentally investigated both on as-cast and aged microstructures to understand the origin of the significant impact of this element on the creep resistance. Calculations with thermocal software were also carried out to support experimental data. It is shown that a small addition of Ta is beneficial as it increases the volume fraction of stable MC carbides. We demonstrate also that additions of Ta may have a dramatic effect on the thermal stability of microstructures. This is attributed to a smaller equilibrium volume fraction of M23C6 and more pronounced heterogeneous precipitation at MC/matrix interfaces. The influence on the creep properties in then discussed.

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