The timing and spectral characteristics of four highly efficient, slow fluors are presented for liquid scintillator solutions using linear alkylbenzene (LAB) as the primary solvent. The mixtures exhibit high light yields, but with rise times of several ns or more and decay times on the order of tens of ns. Consequently, such liquid scintillator mixtures can be used for effective separation of Cherenkov and scintillation components based on timing in large scale liquid scintillation detectors. Such a separation, showing high light yield and directional information, is demonstrated here on a bench-top scale for electrons with energies extending below 1 MeV. This could have significant consequences for the future development of such detectors for measurements of solar neutrinos and neutrinoless double beta decay as well as providing good directional information for elastic scattering events from supernovae neutrinos and reactor anti-neutrinos, amongst others.
The CHErenkov / Scintillation Separation experiment (CHESS) has been used to demonstrate the separation of Cherenkov and scintillation light in both linear alkylbenzene (LAB) and LAB with 2g/L of PPO as a fluor (LAB/PPO). This is the first such demonstration for the more challenging LAB/PPO cocktail and improves on previous results for LAB. A time resolution of 338 +/- 12 ps FWHM results in an efficiency for identifying Cherenkov photons in LAB/PPO of 70 +/- 3% and 63 +/- 8% for time- and charge-based separation, respectively, with scintillation contamination of 36 +/- 5% and 38 +/- 4%. LAB/PP…
This manuscript describes measurements of water-based liquid scintillators (WbLS), demonstrating separation of the Cherenkov and scintillation components using the fast timing response of a Large Area Picosecond Photodector (LAPPD). Additionally, the time profiles of three WbLS mixtures, defined by the relative fractions of scintillating compound, are characterized, with improved sensitivity to the scintillator rise-time. The measurements were made using both an LAPPD and a conventional photomultiplier tube (PMT). All samples were measured with an effective resolution O(100 ps), which allows f…
NOvA is a long-baseline neutrino oscillation experiment with two functionally identical liquid scintillator tracking detectors, i.e. the Near Detector (ND) and the Far Detector (FD). One of NOvA's physics goal is to measure neutrino oscillation parameters by studying $ν_e$ appearance and $ν_μ$ disappearance with the Neutrinos at the Main Injector (NuMI) beam at Fermi National Accelerator Laboratory. An accurate light model is a prerequisite for precise charged particle energy estimation in the detectors. Particle energy is needed in event reconstruction and classification, both of which are cr…
The research of geoneutrino is a new interdisciplinary subject of particle experiments and geo-science. Potassium-40 ($^\text{40}$K) decays contribute roughly 1/3 of the radiogenic heat of the Earth, but it is still missing from the experimental observation. Solar neutrino experiments with liquid scintillators have observed uranium and thorium geoneutrinos and are the most promising in the low-background neutrino detection. In this article, we present the new concept of using liquid-scintillator Cherenkov detectors to detect the neutrino-electron elastic scattering process of $^\text{40}$K geo…
This paper presents measurements of the scintillation light yield and time profile for a number of concentration of water-based liquid scintillator, formulated from linear alkylbenzene (LAB) and 2,5-diphenyloxazole (PPO). We find that the scintillation light yield is linear with the concentration of liquid scintillator in water between 1 and 10% with a slope of 127.9+-17.0 ph/MeV/concentration and an intercept value of 108.3+-51.0 ph/MeV, the latter being illustrative of non-linearities with concentration at values less than 1%. This is larger than expected from a simple extrapolation of the p…
Linear alkyl benzene (LAB) has in recent years been used as a solvent for PPO in large-scale scintillation detectors, like Daya Bay and SNO+. The combination has several nice properties, including high light yield, good materials compatibility, and excellent pulse shape discrimination. As charged particles move through the LAB+PPO, both Cherenkov and scintillation light are created. Separating Cherenkov from scintillation light would allow a broad range of physics in future large-scale detectors like THEIA, by allowing direction reconstruction with Cherenkov light while retaining the high ligh…
Detection of supernova relic neutrinos could provide key support for our current understanding of stellar and cosmological evolution, and precise measurements of these neutrinos could yield novel insights into the universe. In this paper, we studied the detection potential of supernova relic neutrinos using linear alkyl benzene (LAB) as a slow liquid scintillator. The linear alkyl benzene features good separation of Cherenkov and scintillation lights, thereby providing a new route for particle identification. We further addressed key issues in current experiments, including (1) the charged cur…
Linear alkylbenzene (LAB) based liquid scintillator is adopted as the central detector for the Jiangmen Underground Neutrino Observatory (JUNO) liquid scintillator detectors. A quenching factor measurement instrument is designed based on the Compton scattering process. Two different quenchers for the liquid scintillator have been investigated and the result shows that the scintillation light of the JUNO liquid scintillator can be quenched to a level. The emission spectrum with the absence of the quencher is also showing a desired behavior.
The fluorescence decay-time constants have been measured for several scintillator mixtures based on phenyl-o-xylylethane (PXE) and linear alkylbenzene (LAB) solvents. The resulting values are of relevance for the physics performance of the proposed large-volume liquid scintillator detector LENA (Low Energy Neutrino Astronomy). In particular, the impact of the measured values to the search for proton decay via p -> K+ antineutrino is evaluated in this work.
We describe here measurements with a new device, the "dichroicon," a Winston-style light concentrator built out of dichroic reflectors, which could allow large-scale neutrino detectors to sort photons by wavelength with small overall light loss. Photon sorting would benefit large-scale water or ice Cherenkov detectors such as Hyper-Kamiokande or ICECUBE by providing a measure of dispersion, which in turn could allow improved position reconstruction and timing. For scintillator detectors like JUNO, upgrades to SNO+ or KamLAND-ZEN, or to water-based liquid scintillator detectors like Theia, dich…
For the simulation of the scintillation and Cherenkov light propagation in large liquid scintillator detectors a detailed knowledge about the absorption and emission spectra of the scintillator molecules is mandatory. Furthermore reemission probabilities and quantum yields of the scintillator components influence the light propagation inside the liquid. Absorption and emission properties are presented for liquid scintillators using 2,5-Diphenyloxazole (PPO) and 4-bis-(2-Methylstyryl)benzene (bis-MSB) as primary and secondary wavelength shifter. New measurements of the quantum yields for variou…
The scope of this article is to understand the role of radiative losses in detector energy scale at energies of 5-100 MeV and to estimate the non-linear effect they produce in large liquid scintillator and Cherenkov detectors. For this purpose the generalized energy scale detector model was constructed and the detector response was simulated by means of toy Monte Carlo simulations. It was found that the non-linearity grows proportionally to a relative fraction of the Cherenkov light into the total light yield achieving the maximum for pure water Cherenkov detectors. The effect generally increa…
This paper presents studies of the performance of water-based liquid scintillator in both 1-kt and 50-kt detectors. Performance is evaluated in comparison to both pure water Cherenkov detectors and a nominal model for pure scintillator detectors. Performance metrics include energy, vertex, and angular resolution, along with a metric for ability to separate the Cherenkov from the scintillation signal, as being representative of various particle identification capabilities that depend on the Cherenkov / scintillation ratio. We also modify the time profile of scintillation light to study the same…
Semiconductor nanoparticles (quantum dots) were studied in the context of liquid scintillator development for upcoming neutrino experiments. The unique optical and chemical properties of quantum dots are particularly promising for the use in neutrinoless double beta decay experiments. Liquid scintillators for large scale neutrino detectors have to meet specific requirements which are reviewed, highlighting the peculiarities of quantum-dot-doping. In this paper, we report results on laboratory-scale measurements of the attenuation length and the fluorescence properties of three commercial quant…
The fluorescence quantum yield of bis-MSB, a widely used liquid scintillator wavelength shifter, was measured to study the photon absorption and re-emission processes in liquid scintillator. The re-emission process affects the photoelectron yield and distribution, especially in a large liquid scintillator detector, thus must be understood to optimize the liquid scintillator for good energy resolution and to precisely simulate the detector with Monte Carlo. In this study, solutions of different bis-MSB concentration were prepared for absorption and fluorescence emission measurements to cover a …
The potential for using slow-fluor liquid scintillators to study low energy solar neutrinos and neutrinoless double beta decay (0nbb) is explored through a series of simulations. The fluorescence model assumed for the primary fluor has characteristics similar to acenaphthene, recently used to demonstrate Cherenkov separation at energies around 1 MeV. Results here indicate notably better directional reconstruction in large-scale detectors than has previously been suggested by other approaches, allowing better identification of low energy solar neutrinos. These studies indicate that a detector w…
Emission spectra of several organic liquid-scintillator mixtures which are relevant for the proposed LENA detector have been measured by exciting the medium with electrons of ~10keV. The results are compared with spectra resulting from ultraviolet light excitation. Good agreement between spectra measured by both methods has been found.
We present a technique for separating double beta-decay from $^8$B solar neutrino interactions in a liquid scintillator detector. The technique uses position and time of photo-electrons (PEs) to separate directional Cherenkov light from isotropic sintillation light in the reconstruction of the kinematics of candidate events. Here we introduce a Cherenkov-scintillation space time boundary defined as the light cone in the 2-dimensional space of the arrival time and the polar angle of each PE with respect to the axis from the center of the detector to the vertex. The PEs located near the boundary…
An experimental test of the electron energy scale linearities of SNO+ and EJ-301 scintillators was carried out using a Compton spectrometer with electrons in the energy range 0.09-3 MeV. The linearity of the apparatus was explicitly demonstrated. It was found that the response of both types of scintillators with respect to electrons becomes non-linear below ~0.4 MeV. An explanation is given in terms of Cherenkov light absorption and re-emission by the scintillators.
Large liquid-scintillator-based detectors have proven to be exceptionally effective for low energy neutrino measurements due to their good energy resolution and scalability to large volumes. The addition of directional information using Cherenkov light and fast timing would enhance the scientific reach of these detectors, especially for searches for neutrino-less double-beta decay. In this paper, we develop a technique for extracting particle direction using the difference in arrival times for Cherenkov and scintillation light, and evaluate several detector advances in timing, photodetector sp…
Slow liquid scintillator Cherenkov detectors have been proposed as part of several future neutrino experiments because they can provide both directionality and energy measurements. This feature is expected to enhance the sensitivities for MeV-scale neutrino physics, including solar physics, the search for supernova relic neutrino, and the study of geo-sciences. In this study, the characteristics of a slow liquid scintillator were investigated, along with the light yields and decay time constants for various combinations of linear alkylbenzene (LAB), 2,5-diphenyloxazole (PPO), and 1,4-bis (2-me…
To separate scintillation and Cherenkov lights in water-based liquid scintillator detectors is a desired feature for future neutrino and proton decay researches. Linear alkyl benzene (LAB) is one important ingredient of a water-based liquid scintillator being developed. In this paper we observed a good separation of scintillation and Cherenkov lights in an LAB sample. The rising and decay times of the scintillation light of the LAB were measured to be $(7.7\pm3.0)\ \rm{ns}$ and $(36.6\pm2.4)\ \rm{ns}$, respectively, while the full width [-3$σ$, 3$σ$] of the Cherenkov light was 12 ns dominated …
We present a technique for separating nuclear double beta decay ($ββ$-decay) events from background neutrino interactions due to $^{8}$B decays in the sun. This background becomes dominant in a kiloton-scale liquid-scintillator detector deep underground and is usually considered as irreducible due to an overlap in deposited energy with the signal. However, electrons from 0$νββ$-decay often exceed the Cherenkov threshold in liquid scintillator, producing photons that are prompt and correlated in direction with the initial electron direction. The use of large-area fast photodetectors allows some…
The ability to separately identify the Cherenkov and scintillation light components produced in scintillating mediums holds the potential for a major breakthrough in neutrino detection technology, allowing development of a large, low-threshold, directional detector with a broad physics program. The CHESS (CHErenkov / Scintillation Separation) experiment employs an innovative detector design with an array of small, fast photomultiplier tubes and state-of-the-art electronics to demonstrate the reconstruction of a Cherenkov ring in a scintillating medium based on photon hit time and detected phot…
The FlatDot detector has been used to demonstrate the separation of Cherenkov and scintillation light for 1 to 2MeV electrons in linear alkylbenzene (LAB). With an average PMT transit time spread (TTS) of 200ps, the early light in each event is clearly dominated by the Cherenkov signal, which on average comprises $86^{+2}_{-3}\%$ of the light collected in the first 4.1ns of each event. The spatial distributions of the Cherenkov and scintillation light are found to match those predicted in Monte Carlo simulations. This is a key step towards demonstrating direction reconstruction of $β$ decays, …
We report on the optical and structural properties of plastic scintillators irradiated with neutron beams produced by the IBR-2 reactor of the Frank Laboratory of Neutron Physics in JINR, Dubna. Blue UPS-923A and green plastic scintillators were irradiated with neutron fluence ranging from 10$^{13}$ to 10$^{17}$ n/cm$^2$. Discolouring in the plastic scintillators was observed after irradiation. The effects of radiation damage on the optical and structural properties of the samples were characterized by conducting light yield, light transmission, light fluorescence and Raman spectroscopy studie…
Measurement of Light Yield Response of Gd-compatible Water-based Liquid Scintillator with the Brookhaven 1-ton testbed
Chung-Ang University（中央大学）；University of California at Berkeley（加州大学伯克利分校）；Lawrence Berkeley National Laboratory（劳伦斯伯克利国家实验室）；Brookhaven National Laboratory（布鲁克海文国家实验室）；The Pennsylvania State University（宾夕法尼亚州立大学）；Bronx Community College（布朗克斯社区学院）；University of Alabama（阿拉巴马大学）；Stony Brook University（石溪大学）
In this work we report the performances and the chemical and physical properties of a (2 x 1.2) ton organic liquid scintillator target doped with Gd up to ~0.1%, and the results of a 2 year long stability survey. In particular we have monitored the amount of both Gd and primary fluor actually in solution, the optical and fluorescent properties of the Gd-doped liquid scintillator (GdLS) and its performances as a neutron detector, namely neutron capture efficiency and average capture time. The experimental survey is ongoing, the target being continuously monitored. After two years from the dopin…
We have characterised Water-based Liquid Scintillator (WbLS) using low energy protons, UV-VIS absorbance, and fluorescence spectroscopy. We have also developed and validated a simulation model that describes the behaviour of WbLS in our detector configurations for proton beam energies of 2 GeV, 475 MeV, and 210 MeV and for two WbLS compositions. Our results have enabled us to estimate the light yield and ionisation quenching of WbLS, as well as to understand the influence of the wavelength shifting of Cerenkov light on our measurements. These results are relevant to the suitability of water-ba…
The possibility of measuring the 85Kr activity with a liquid scintillation spectrometer (LSS) by registering the scintillations in krypton was investigated. It was found that at partial pressure of krypton less than atmospheric, the conversion efficiency of krypton scintillators amounts to 3 keV/photon and is 20 times lower than the conversion efficiency of liquid scintillators. The amplitude of the pulses due to scintillations in krypton is approximately equal to the amplitude of the pulses from Cherenkov radiation which occurs in the walls of the vial under the influence of 85Kr beta particl…
The Accelerator Neutrino Neutron Interaction Experiment (ANNIE) is designed to serve as a test bed for new detector technologies in future water and liquid scintillator based neutrino experiments. Located on the Booster Neutrino Beam at Fermilab, ANNIE will be the first gadolinium-loaded water Cherenkov detector on a neutrino beam and will provide high statistics measurements of neutron yields from neutrino interactions in water. It is also the first particle physics application of the new photosensor technology: Large Area Picosecond Photodetectors (LAPPDs). With single photon time resolution…
The polystyrene dopped with 2,5-diphenyloxazole as a primary fluor and 2-(4-styrylphenyl)benzoxazole as a wavelength shifter, prepared as a plastic scintillator was investigated using positronium probe in wide range of temperatures from 123 to 423 K. Three structural transitions at 260 K, 283 K and 370 K were found in the material. In the o-Ps intensity dependence on temperature, the significant hysteresis is observed. Heated to 370 K, the material exhibits the o-Ps intensity variations in time.
A liquid scintillator (LS) is developed for the Taishan Antineutrino Observatory (TAO), a ton-level neutrino detector to measure the reactor antineutrino spectrum with sub-percent energy resolution by adopting Silicon Photomultipliers (SiPMs) as photosensor. To reduce the dark noise of SiPMs to an acceptable level, the LS has to work at -50 degree or lower. A customized apparatus based on a charge-coupled device (CCD) is developed to study the transparency of the liquid samples in a cryostat. We find that the water content in LS results in transparency degradation at low temperature, which can…
Water-based liquid scintillators (WbLS) present an attractive target medium for large-scale detectors with the ability to enhance the separation of Cherenkov and scintillation signals from a single target. This work characterizes the scintillation properties of WbLS samples based on LAB/PPO liquid scintillator (LS). X-ray luminescence spectra, decay profiles, and relative light yields are measured for WbLS of varying LS concentration as well as for pure LS with a range of PPO concentrations up to 90 g/L. The scintillation properties of the WbLS are related to the precursor LAB/PPO: starting fr…
Liquid scintillator (LS) will be adopted as the detector material in JUNO (Jiangmen Underground Neutrino Observatory). The energy resolution requirement of JUNO is 3%, which has never previously been reached. To achieve this energy resolution, the light yield of liquid scintillator is an important factor. PPO (the fluor) and bis-MSB (the wavelength shifter) are the two main materials dissolved in LAB. To study the influence of these two materials on the transmission of scintillation photons in LS, 25 and 12 cm-long quartz vessels were used in a light yield experiment. LS samples with different…
For future MeV-scale neutrino experiments, a Cherenkov scintillation detector, CSD, is of particular interest for its capability to reconstruct both energy and direction for charged particles. A type of new target material, slow liquid scintillator, SlowLS, which can be used to separate Cherenkov and scintillation lights, is one of the options for the neutrino detectors. A multi-hundred ton spherical CSD is simulated using a Geant4-based Monte Carlo software, which handles the detailed the micro processes of MeV particles and optical photons and the functions for photomultiplier, PMT, and read…
Electron anti-neutrinos are commonly detected in liquid scintillator experiments via inverse beta decay, by looking at the coincidence between the reaction products, neutron and positron. Prior to positron annihilation, an electron-positron pair may form an orthopositronium (o-Ps) state, with a mean life of a few ns. Even if the o-Ps decay is speeded up by spin flip or pick off effects, it may introduce distortions in the photon emission time distribution, crucial for position reconstruction and pulse shape discrimination algorithms in anti-neutrino experiments. Reversing the problem, the o-Ps…
Liquid scintillator detectors play a central role in the detection of neutrinos from various sources. In particular, it is the only technique used so far for the precision spectroscopy of sub-MeV solar neutrinos, as demonstrated by the Borexino experiment at the Gran Sasso National Laboratory in Italy. The benefit of a high light yield, and thus a low energy threshold and a good energy resolution, comes at the cost of the directional information featured by water Cherenkov detectors, measuring $^8$B solar neutrinos above a few MeV. In this paper we provide the first directionality measurement …
This article describes the physics and nonproliferation goals of WATCHMAN, the WAter Cherenkov Monitor for ANtineutrinos. The baseline WATCHMAN design is a kiloton scale gadolinium-doped (Gd) light water Cherenkov detector, placed 13 kilometers from a civil nuclear reactor in the United States. In its first deployment phase, WATCHMAN will be used to remotely detect a change in the operational status of the reactor, providing a first- ever demonstration of the potential of large Gd-doped water detectors for remote reactor monitoring for future international nuclear nonproliferation applications…
The Jiangmen Underground Neutrino Observatory (JUNO), a multi-purpose neutrino experiment, will use 20 kt liquid scintillator (LS). To achieve the physics goal of determining the neutrino mass ordering, 3$\%$ energy resolution at 1 MeV is required. This puts strict requirements on the LS light yield and the transparency. Four LS purification steps have been designed and mid-scale plants have been built at Daya Bay. To examine the performance of the purified LS and find the optimized LS composition, the purified LS was injected to the antineutrino detector 1 in the experimental hall 1 (EH1-AD1)…
