A liquid scintillator (LS) is developed for the Taishan Antineutrino Observatory (TAO), a ton-level neutrino detector to measure the reactor antineutrino spectrum with sub-percent energy resolution by adopting Silicon Photomultipliers (SiPMs) as photosensor. To reduce the dark noise of SiPMs to an acceptable level, the LS has to work at -50 degree or lower. A customized apparatus based on a charge-coupled device (CCD) is developed to study the transparency of the liquid samples in a cryostat. We find that the water content in LS results in transparency degradation at low temperature, which can be cured by bubbling dry nitrogen to remove water. Adding 0.05% ethanol as co-solvent cures the solubility decrease problem of the fluors PPO and bis-MSB at low temperature. Finally, a Gadoliniumdoped liquid scintillator (GdLS), with 0.1% Gd by weight, 2 g/L PPO, 1 mg/L bis-MSB, and 0.05% ethanol by weight in the solvent LAB, shows good transparency at -50 degree and also good light yield.
Liquid scintillator experiments for neutrinoless double beta decay search have high sensitivity based on the ultra low background environment and high scalability. This paper describes an overview of current ongoing projects KamLAND-Zen and SNO+.
The NOvA collaboration blended and delivered 8.8 kt (2.72M gal) of liquid scintillator as the active detector medium to its near and far detectors. The composition of this scintillator was specifically developed to satisfy NOvA's performance requirements. A rigorous set of quality control procedures was put in place to verify that the incoming components and the blended scintillator met these requirements. The scintillator was blended commercially in Hammond, IN. The scintillator was shipped to the NOvA detectors using dedicated stainless steel tanker trailers cleaned to food grade.
We studied the temperature dependence of the light yield of the linear alkyl benzene (LAB)-based and mesitylene-based liquid scintillators. The light yield increases by 23% for both liquid scintillators when the temperature is lowered from $26\;^{\circ}$C to $-40\;^{\circ }$C, correcting for the temperature response of the photomultiplier tube. The measurements help to understand the energy response of the liquid scintillator detectors. Especially, the next generation reactor neutrino experiments for neutrino mass hierarchy, such as the Jiangmen Underground Neutrino Observatory (JUNO), require…
Liquid scintillator detectors are playing an increasingly important role in low-energy neutrino experiments. In this article, we describe a generic energy response model of liquid scintillator detectors that provides energy estimations of sub-percent accuracy. This model fits a minimal set of physically-motivated parameters that capture the essential characteristics of scintillator response and that can naturally account for changes in scintillator over time, helping to avoid associated biases or systematic uncertainties. The model employs a one-step calculation and look-up tables, yielding an…
We report on studies of non-toxic scintillating liquid useful for large surface detectors. Arrays of liquid scintillators offer a rather simple tool for detecting charged particles traversing a surface and tracking their path through a defined volume. Insertion of wavelength shifting fibres along the liquid scintillating containers significantly improves the light collection at the two ends of the scintillators. We have demonstrated that we can achieve timing resolution of O(1 ns) allowing good spatial resolution. Liquid scintillators with fibres read by Photo-multipliers or SiPMs provide an i…
We report on the production and characterization of liquid scintillators for the detection of electron antineutrinos by the Daya Bay Reactor Neutrino Experiment. One hundred eighty-five tons of gadolinium-loaded (0.1% by mass) liquid scintillator (Gd-LS) and two hundred tons of unloaded liquid scintillator (LS) were successfully produced from a linear-alkylbenzene (LAB) solvent in six months. The scintillator properties, the production and purification systems, and the quality assurance and control (QA/QC) procedures are described.
Environmental radioactivity is a dominant background for rare decay search experiments, and it is difficult to completely remove such an impurity from detector vessels. We propose a scintillation balloon as the active vessel of a liquid scintillator in order to identify this undesirable radioactivity. According to our feasibility studies, the scintillation balloon enables the bismuth--polonium sequential decay to be tagged with a 99.7\% efficiency, assuming a KamLAND (Kamioka Liquid scintillator AntiNeutrino Detector)-type liquid scintillator detector. This tagging of sequential decay using al…
Nonlinearity of the liquid scintillator energy response is a key to measuring the neutrino energy spectrum in reactor neutrino experiments such as Daya Bay and JUNO. We measured in laboratory the nonlinearity of the Linear Alkyl Benzene based liquid scintillator, which is used in Daya Bay and will be used in JUNO, via Compton scattering process. By tagging the scattered gamma from the liquid scintillator sample simultaneously at seven angles, the instability of the system was largely cancelled. The accurately measured nonlinearity will improve the precision of the $θ_{13}$, $Δm^2$, and reactor…
Recent developments in the field of liquid scintillator chemistry and fast-timing photosensors paved the way for a new generation of large-scale detectors capable of tackling a broad range of physics issues. Water-based Liquid Scintillator is a novel detection medium that combines the advantages of pure water, including low attenuation, accurate direction reconstruction, and low cost, and those of liquid scintillator, including high light yield and low-threshold detection. When coupled with high efficiency, fast-timing photosensors, such as Large Area Picosecond PhotoDetectors, Water-based Liq…
Pulse shape discrimination in liquid scintillator detectors is a well-established technique for the discrimination of heavy particles from light particles. Nonetheless, it is not efficient in the separation of electrons and positrons, as they give rise to indistinguishable scintillator responses. This inefficiency can be overtaken through the exploitation of the formation of ortho-Positronium (o-Ps), which alters the time profile of light pulses induced by positrons. We characterized the o-Ps properties in the most commonly used liquid scintillators, i.e. PC, PXE, LAB, OIL and PC + PPO. In add…
The construction of large-scale liquid scintillator detectors is complicated by the need to separate the scintillation region from photomultiplier tubes (PMTs) due to their intrinsic radioactivity. This is generally done using acrylic or nylon barriers, whose own activity can also lead to substantial reduction of the fiducial detection volume for a number of low energy (MeV) studies, and whose construction becomes increasingly difficult and expensive for larger detector volumes. Here we present an initial simulation study of an alternative geometric construction known as SLIPS (Stratified LIqu…
Detection of supernova relic neutrinos could provide key support for our current understanding of stellar and cosmological evolution, and precise measurements of these neutrinos could yield novel insights into the universe. In this paper, we studied the detection potential of supernova relic neutrinos using linear alkyl benzene (LAB) as a slow liquid scintillator. The linear alkyl benzene features good separation of Cherenkov and scintillation lights, thereby providing a new route for particle identification. We further addressed key issues in current experiments, including (1) the charged cur…
This paper presents measurements of the scintillation light yield and time profile for a number of concentration of water-based liquid scintillator, formulated from linear alkylbenzene (LAB) and 2,5-diphenyloxazole (PPO). We find that the scintillation light yield is linear with the concentration of liquid scintillator in water between 1 and 10% with a slope of 127.9+-17.0 ph/MeV/concentration and an intercept value of 108.3+-51.0 ph/MeV, the latter being illustrative of non-linearities with concentration at values less than 1%. This is larger than expected from a simple extrapolation of the p…
We have characterised Water-based Liquid Scintillator (WbLS) using low energy protons, UV-VIS absorbance, and fluorescence spectroscopy. We have also developed and validated a simulation model that describes the behaviour of WbLS in our detector configurations for proton beam energies of 2 GeV, 475 MeV, and 210 MeV and for two WbLS compositions. Our results have enabled us to estimate the light yield and ionisation quenching of WbLS, as well as to understand the influence of the wavelength shifting of Cerenkov light on our measurements. These results are relevant to the suitability of water-ba…
Liquid scintillator detectors are widely used in modern neutrino studies. The unique optical properties of semiconducting nanocrystals, known as quantum dots, offer intriguing possibilities for improving standard liquid scintillator, especially when combined with new photodetection technology. Quantum dots also provide a means to dope scintillator with candidate isotopes for neutrinoless double beta decay searches. In this work, the first studies of the scintillation properties of quantum-dot-doped liquid scintillator using both UV light and radioactive sources are presented.
Based on test-beam measurements, we study the response of a liquid-scintillator detector equipped with wavelength-shifting optical modules, that are proposed e.g. for the IceCube experiment and the SHiP experiment, and adiabatic light guides that are viewed either by a photomultiplier tube or by an array of silicon photomultipliers. We report on the efficiency, the time resolution and the detector response to different particle types and point out potential ways to improve the detector performance.
Quenching of light emission from an LAB based scintillator by the addition of organic amines and carboxylic acids is examined. Chemical functional groups of the quenching agents play an important role in this reduction. It is shown that "salt" formation at a 1:1 mole ratio in a mixed amine-acid system, reduces quenching by a factor of 2. Supporting NMR spectra are presented. This "quenching neutralization" has the potential to reduce the light loss incurred when metals complexed with quenching agents are loaded into organic scintillators.
We proposed a novel method for exploring the intrinsic energy resolution of a liquid scintillator (LAB + 2.5 g/L PPO + 3 mg/L bis-MSB) for approximately 1 MeV electrons. With the help of coincidence detection technology, single-energy electrons of Bi 207 were effectively selected. With careful measurement and analysis of the energy resolution of a small liquid scintillator detector, the intrinsic energy resolution to 976 keV electrons was extracted to be 1.83%. We used the wide-angle Compton coincidence (WACC) method to measure the luminescent nonlinearity of the liquid scintillator and found …
The Jiangmen Underground Neutrino Observatory (JUNO) is a multipurpose neutrino experiment with a 20 kt liquid scintillator detector designed to determine the neutrino mass hierarchy, and measure the neutrino oscillation parameters. Linear alkyl benzene (LAB) will be used as the solvent for the liquid scintillation system in the central detector of JUNO. For this purpose, we have prepared LAB samples, and have measured their light attenuation lengths, with one achieving a length of 25.8 m, comparable to the diameter of the JUNO detector.
High precision vertex and energy reconstruction is crucial for large liquid scintillator detectors such as JUNO, especially for the determination of the neutrino mass ordering by analyzing the energy spectrum of reactor neutrinos. This paper presents a data-driven method to obtain more realistic and more accurate expected PMT response of positron events in JUNO, and develops a simultaneous vertex and energy reconstruction method that combines the charge and time information of PMTs. For the JUNO detector, the impact of vertex inaccuracy on the energy resolution is about 0.6\%.
A measurement is reported for the response to charged particles of a liquid scintillator named EJ-335 doped with 0.5% gadolinium by weight. This liquid scintillator was used as the detection medium in a neutron detector. The measurement is based on the in-situ $α$-particles from the intrinsic Uranium and Thorium contamination in the scintillator. The $β$-$α$ and the $α$-$α$ cascade decays from the U/Th decay chains were used to select $α$-particles. The contamination levels of U/Th were consequently measured to be $(5.54\pm0.15)\times 10^{-11}$ g/g, $(1.45\pm0.01)\times 10^{-10}$ g/g and $(1.0…
Liquid-scintillator-based detectors are a robust technology that scales well to large volumes. For this reason, they are attractive for experiments searching for neutrinoless double-beta decay. A combination of improved photo-detection technology and novel liquid scintillators may allow for the extraction of particle direction in addition to the total energy of the particle. Such an advance would find applications beyond searches for neutrinoless double-beta decay.
Liquid scintillators are commonly used to detect low energy neutrinos from the reactors, sun, and earth. It is a challenge to reconstruct deposited energies for a large liquid scintillator detector. For detectors with multiple optical mediums such as JUNO and SNO+, the prediction of the propagation of detected photons is extremely difficult due to mixed optical processes such as Rayleigh scattering, refraction and total reflection at their boundaries. Calibration based reconstruction methods consume impractical time since a large number of calibration points are required in a giant detector. I…
Ortho-positronium (o-Ps) formation and decay can replace the annihilation process, when positron interacts in liquid scintillator media. The delay induced by the positronium decay represents either a potential signature for anti-neutrino detection, via inverse beta decay, or to identify and suppress positron background, as recently demonstrated by the Borexino experiment. The formation probability and decay time of o-Ps depend strongly on the surrounding material. In this paper, we characterize the o-Ps properties in liquid scintillators as function of concentrations of gadolinium, lithium, ne…
Scintillator detectors can be used in experiments searching for neutrinoless double beta decay. A wide variety of double beta decay candidate isotopes can be made into scintillators or can be loaded into scintillators. Experimental programs developing liquid xenon, inorganic crystals, and Nd-loaded liquid scintillator are described in this review. Experiments with 48Ca and 150Nd benefit from their high endpoint which places the neutrinoless double beta decay signal above most backgrounds from natural radioactivity.
The research of geoneutrino is a new interdisciplinary subject of particle experiments and geo-science. Potassium-40 ($^\text{40}$K) decays contribute roughly 1/3 of the radiogenic heat of the Earth, but it is still missing from the experimental observation. Solar neutrino experiments with liquid scintillators have observed uranium and thorium geoneutrinos and are the most promising in the low-background neutrino detection. In this article, we present the new concept of using liquid-scintillator Cherenkov detectors to detect the neutrino-electron elastic scattering process of $^\text{40}$K geo…
Precise vertex reconstruction is essential for large liquid scintillator detectors. A novel method based on machine learning has been successfully developed to reconstruct the event vertex in JUNO previously. In this paper, the performance of machine learning based vertex reconstruction is further improved by optimizing the input images of the neural networks. By separating the information of different types of PMTs as well as adding the information of the second hit of PMTs, the vertex resolution is improved by about 9.4 % at 1 MeV and 9.8 % at 11 MeV, respectively.
Gamma sources are routinely used to calibrate the energy scale and resolution of liquid scintillator detectors. However, non-scintillating material surrounding the source introduces energy losses, which may bias the determination of the centroid and width of the full absorption peak. In this paper, we present a general method to determine the true gamma centroid and width to a relative precision of 0.03\% and 0.50\%, respectively, using energy losses predicted by the Monte Carlo simulation. In particular, the accuracy of the assumed source geometry is readily obtained from the fit. The method …
Good optical transparency is a fundamental requirement of liquid scintillator (LS) detectors. Characterizing the transparency of a liquid scintillator to its own emitted light is a key parameter to determine the overall sensitivity of a large-volume detector. The attenuation of light in an optical-pure LS is dominated by Rayleigh scattering, which poses an intrinsic limit to the transparency of LS. This work presents a spectrometric approach of measuring the wavelength-dependent scattering length of liquids by applying the Einstein-Smoluchowski theory to a measurement of scattered light intens…
Liquid scintillators doped with metals are needed for a variety of measurements in nuclear and particle physics. Nanoparticles provide a mechanism to dope the scintillator and their unique optical properties could be used to enhance detection capabilities. We present here the first study of lead-based perovskite nanoparticles for this application. Perovskites are an attractive choice due to the versatility of their crystal structure and their ease of synthesis.
NOvA is a long-baseline neutrino oscillation experiment with two functionally identical liquid scintillator tracking detectors, i.e. the Near Detector (ND) and the Far Detector (FD). One of NOvA's physics goal is to measure neutrino oscillation parameters by studying $ν_e$ appearance and $ν_μ$ disappearance with the Neutrinos at the Main Injector (NuMI) beam at Fermi National Accelerator Laboratory. An accurate light model is a prerequisite for precise charged particle energy estimation in the detectors. Particle energy is needed in event reconstruction and classification, both of which are cr…
The liquid scintillator (LS) has been widely utilized in the past, running and future neutrino experiments, and requirement to the LS radio-purity is higher and higher. The water extraction is a powerful method to remove soluble radioactive nuclei, and a mini-extraction station has been constructed. To evaluate the extraction efficiency and optimize the operation parameters, a setup to load radioactivity to LS and a laboratory scale setup to measure radioactivity which use Bi^{212}-Po^{212}-Pb^{208} cascade decay are developed. Experiences from laboratory study will be useful to large scale wa…
We introduce a novel approach to investigate CP violation in the neutrino sector, based on the simultaneous detection of $ν_e$ and $\barν_e$ stemming from the oscillation of $ν_μ$ and $\barν_μ$ produced in the decay at rest of $π$s and $μ$s at a beam dump. This approach relies on a novel liquid scintillator detector technology expected to yield unprecedented identification of $ν_e$ and $\barν_e$ charged-current interactions, which we investigate by means of Montecarlo simulations. Here we report preliminary results concerning both the detection technique and its physics reach.
We regard the possibility of detecting the antineutrino flux producing by the $^{40}$K placing inside the Earth. Thermal flux of the Earth could be better understood with observing such a flux. Lower and upper limitations on the $^{40}$K antineutrino flux are presented.
The outer water buffer is an economic option to shield the external radiative backgrounds for liquid-scintillator neutrino detectors. However, the consequential total reflection of scintillation light at the media boundary introduces extra complexity to the detector optics. This paper develops a precise detector-response model by investigating how total reflection complicates photon propagation and degrades reconstruction. We first parameterize the detector response by regression, providing an unbiased energy and vertex reconstruction in the total reflection region while keeping the number of …
This manuscript describes measurements of water-based liquid scintillators (WbLS), demonstrating separation of the Cherenkov and scintillation components using the fast timing response of a Large Area Picosecond Photodector (LAPPD). Additionally, the time profiles of three WbLS mixtures, defined by the relative fractions of scintillating compound, are characterized, with improved sensitivity to the scintillator rise-time. The measurements were made using both an LAPPD and a conventional photomultiplier tube (PMT). All samples were measured with an effective resolution O(100 ps), which allows f…
It is challenging to achieve high precision energy resolution for large liquid scintillator detectors. Energy non-uniformity is one of the main obstacles. To surmount it, a calibration-data driven method was developed previously to reconstruct event energy in the JUNO experiment. In this paper, we investigated the choice of calibration sources thoroughly, optimized the calibration positions and corrected the residual detector azimuthal asymmetry. All these efforts lead to a reduction of the energy non-uniformity near the detector boundary, from about 0.64% to 0.38%. And within the fiducial vol…
A large-volume liquid scintillator can be used as a tracking detector to measure high-energy neutrino events, like atmospheric neutrinos and neutrino beams. The lepton flavor recognition is almost absolute above 1 GeV. The energy resolution is 2--5 %, the main uncertainties coming from nuclear physics and poorly recognized hadrons. At GeV scale antineutrinos may be statistically distinguishable from neutrinos by neutron and proton signals.
Linear alkylbenzene (LAB) based liquid scintillator is adopted as the central detector for the Jiangmen Underground Neutrino Observatory (JUNO) liquid scintillator detectors. A quenching factor measurement instrument is designed based on the Compton scattering process. Two different quenchers for the liquid scintillator have been investigated and the result shows that the scintillation light of the JUNO liquid scintillator can be quenched to a level. The emission spectrum with the absence of the quencher is also showing a desired behavior.
For the simulation of the scintillation and Cherenkov light propagation in large liquid scintillator detectors a detailed knowledge about the absorption and emission spectra of the scintillator molecules is mandatory. Furthermore reemission probabilities and quantum yields of the scintillator components influence the light propagation inside the liquid. Absorption and emission properties are presented for liquid scintillators using 2,5-Diphenyloxazole (PPO) and 4-bis-(2-Methylstyryl)benzene (bis-MSB) as primary and secondary wavelength shifter. New measurements of the quantum yields for variou…
Organic liquid scintillators have been used for decades in many neutrino physics experiments. They are particularly suited for the detection of low-energy neutrinos where energy and timing information is required. Organic liquid scintillators exhibit advantages such as high light yield, cost effectiveness, radio purity, and more. However, they also entail disadvantages, most prominently a lack of vertex resolution and particle identification. In recent years, various novel ideas have emerged to improve the performance of organic liquid scintillators. In this review, novel approaches to organic…
The electron antineutrino spectrum in the Stereo reactor experiment (ILL Grenoble) is measured via the inverse beta decay signals in an organic liquid scintillator. The six target cells of the Stereo detector are filled with about 1800 litres of Gd-loaded liquid scintillator optimised for the requirements of the experiment. These target cells are surrounded by similar cells containing liquid scintillator without the Gd-loading. The development and characteristics of these scintillators are reported. In particular, the transparency, light production and pulse shape discrimination capabilities o…
Machine-Learning based photon counting for PMT waveforms and its application to the improvement of the energy resolution in large liquid scintillator detectors
For liquid-scintillator neutrino detectors of kiloton scale, the transparency of the organic solvent is of central importance. The present paper reports on laboratory measurements of the optical scattering lengths of the organic solvents PXE, LAB, and Dodecane which are under discussion for next-generation experiments like SNO+, Hanohano, or LENA. Results comprise the wavelength range from 415 to 440nm. The contributions from Rayleigh and Mie scattering as well as from absorption/re-emission processes are discussed. Based on the present results, LAB seems to be the preferred solvent for a larg…
This study investigates the deployment of a medium-scale neutrino detector near Turkey's first nuclear power plant, the Akkuyu Nuclear Power Plant. The aim of this detector is to become a modular testbed for new technologies in the fields of new detection media and innovative photosensors. Such technologies include Water-based Liquid Scintillator (WbLS), Large Area Picosecond Photo-Detectors (LAPPDs), dichroic Winston cones, and large area silicon photomultiplier modules. The detector could be used for instantaneous monitoring of the Akkuyu Nuclear Power Plant via its antineutrino flux. In add…
Reactor neutrino experiments build large-scale detector systems to detect neutrinos. In liquid scintillator, a neutral bound state of a positron and an electron, named positronium, can be formed. The spin triplet state is called ortho-positronium (o-Ps). In this article, an experiment is designed to measure the lifetime of o-Ps, giving a result of 3.1 ns. A PSD parameter based on photon emission time distribution (PETD) was constructed to discriminate e$^+$/e$^-$. Finally, the application of e$^+$/e$^-$ discrimination in the JUNO experiment is shown. It helps suppress $^{8}$He/$^{9}$Li backgro…
Linear alkylbenzene has been recently used as the solvent of liquid scintillator by several neutrino experiments. The energy quenching effect of a linear alkylbenzene based liquid scintillator is studied in this paper with a 14 MeV D-T compact neutron generator, to improve the energy non-linearity modelling of this kind of detectors. The recoiled proton in the liquid scintillator has a kinetic energy ranging from 0.5 MeV to 13 MeV. The data is used to extract the parameters of the Birk's law, an empirical model to describe the energy quenching effect of the liquid scintillator.
Rayleigh scattering poses an intrinsic limit for the transparency of organic liquid scintillators. This work focuses on the Rayleigh scattering length of linear alkylbenzene (LAB), which will be used as the solvent of the liquid scintillator in the central detector of the Jiangmen Underground Neutrino Observatory. We investigate the anisotropy of the Rayleigh scattering in LAB, showing that the resulting Rayleigh scattering length will be significantly shorter than reported before. Given the same overall light attenuation, this will result in a more efficient transmission of photons through th…
Results are presented from a small-scale experiment to investigate the use of room temperature organic liquid scintillators as the active medium for a time projection chamber (TPC). The optical properties of liquid scintillators have long been known, but their ability to transport charge has remained, until now, largely untested. The idea of using room temperature liquids as an active medium for an ionisation chamber was first presented in \cite{EnglerTMS}. Since then the range of liquid scintillators available has been greatly developed. We present successful transport of ionization charges i…
