Current and near term quantum computers (i.e. NISQ devices) are limited in their computational power in part due to qubit decoherence. Here we seek to take advantage of qubit decoherence as a resource in simulating the behavior of real world quantum systems, which are always subject to decoherence, with no additional computational overhead. As a first step toward this goal we simulate the thermal relaxation of quantum beats in radical ion pairs (RPs) on a quantum computer as a proof of concept of the method. We present three methods for implementing the thermal relaxation, one which explicitly applies the relaxation Kraus operators, one which combines results from two separate circuits in a classical post-processing step, and one which relies on leveraging the inherent decoherence of the qubits themselves. We use our methods to simulate two real world systems and find excellent agreement between our results, experimental data, and the theoretical prediction.
In previous works, we introduced a geometric route to define our Ehrenfest Statistical Dynamics (ESD) and we proved that, for a simple toy-model, the resulting ESD does not preserve purity. We now take a step further: we investigate decoherence and pointer basis in the ESD model by considering some uncertainty in the degrees of freedom of a simple but realistic molecular model, consisting of two classical cores and one quantum electron. The Ehrenfest model is sometimes discarded as a valid approximation to non-adiabatic coupled quantum-classical dynamics because it does not describe the decohe…
Contrary to the usual picture that decoherence destroys quantum properties and causes the quantum-to-classical transition, we argue that decoherence can also play a constructive role in driving quantum dynamics and amplifying its results to macroscopic scales. We support this perspective by presenting an example system from spin chemistry, which is also of importance for biological systems, e.g. in avian magnetoreception.
We show that it is possible to explain the quantum measurement process within the framework of quantum mechanics without any additional postulates. The key concept of the theory is decoherence, which appears as an inherent characteristic of quantum mechanics and results from the uncertainty relation. In contrast to environment-induced decoherence, this decoherence exists prior to a measurement being made. To clarify our idea, we examine three elemental experiments: a Stern-Gerlach-like experiment, the Einstein-Podolsky-Rosen-Bohm (EPR-Bohm) experiment, and the double-slit experiment. By consid…
A complete theoretical treatment in many problems relevant to physics, chemistry, and biology requires considering the action of the environment over the system of interest. Usually the environment involves a relatively large number of degrees of freedom, this making the problem numerically intractable from a purely quantum-mechanical point of view. To overcome this drawback, a new class of quantum trajectories is proposed. These trajectories, based on the same grounds as Bohmian ones, are solely associated to the system reduced density matrix, since the evolution of the environment degrees of…
This introductory review discusses the main problems facing the attempt to build quantum information processing systems (like quantum computers) from spin-based qubits. We emphasize 'bottom-up' attempts using methods from chemistry. The essentials of quantum computing are explained, along with a description of the qubits and their interactions in terms of physical spin qubits. The main problem to be overcome is decoherence - how this works is described, along with ways to suppress contributions from spin bath and oscillator bath environments, and from dipolar interactions. Finally we discuss v…
The study and prediction of chemical reactivity is one of the most important application areas of molecular quantum chemistry. Large-scale, fully error-tolerant quantum computers could provide exact or near-exact solutions to the underlying electronic structure problem with exponentially less effort than a classical computer thus enabling highly accurate predictions for comparably large molecular systems. In the nearer future, however, only "noisy" devices with a limited number of qubits that are subject to decoherence will be available. For such near-term quantum computers the hybrid quantum-…
Qubit realizations based on Majorana bound states have been considered promising candidates for quantum information processing which is inherently inert to decoherence. We put the underlying general arguments leading to this conjecture to the test from an open quantum system perspective. It turns out that, from a fundamental point of view, the Majorana qubit is as susceptible to decoherence as any local paradigm of a qubit.
A scheme to implement a quantum computer subjected to decoherence and governed by an untunable qubit-qubit interaction is presented. By concatenating dynamical decoupling through bang-bang (BB) pulse with decoherence-free subspaces (DFSs) encoding, we protect the quantum computer from environment-induced decoherence that results in quantum information dissipating into the environment. For the inherent qubit-qubit interaction that is untunable in the quantum system, BB control plus DFSs encoding will eliminate its undesired effect which spoils quantum information in qubits. We show how this qua…
A simplified Bogoliubov transform reduces a fully-interacting many-fermion spin-1/2 system-plus-environment to a more tractable many-to-one variant. The transform additionally yields exact solutions for bosonic multi-particle interactions sans the approximation introduced by using discrete time steps to deal with quantum parallelism. The decohering effect of relatively general finite environments is therewith modeled and compared to the decohering effect of an infinite environmental "bath." The anti-symmetric singlet state formed by two maximally-entangled two-state particles is shown to be in…
Large scale quantum information processing requires stable and long-lived quantum memories. Here, using atom-photon entanglement, we propose an experimentally feasible scheme to realize decoherence-free quantum memory with atomic ensembles, and show one of its applications, remote transfer of unknown quantum state, based on laser manipulation of atomic ensembles, photonic state operation through optical elements, and single-photon detection with moderate efficiency. The scheme, with inherent fault-tolerance to the practical noise and imperfections, allows one to retrieve the information in the…
We study the intrinsic decoherence of coupled harmonic oscillators. The Milburn master equation is solved exactly, and the dynamics of virtual ground state excitations are investigated. The interaction of quantum correlations and virtual excitation was then studied. The following is a summary of our major findings. (i) The damped oscillatory profile of all three quantities is the same. (ii) Ultra-strong coupling combined with huge anisotropy values results in the reemergence of entanglement and steering. (iii) To sustain entanglement and steering, virtual excitations are required. (iv) The qua…
We study the decoherence of a quantum computer in an environment which is inherently correlated in time and space. We first derive the nonunitary time evolution of the computer and environment in the presence of a stabilizer error correction code, providing a general way to quantify decoherence for a quantum computer. The general theory is then applied to the spin-boson model. Our results demonstrate that effects of long-range correlations can be systematically reduced by small changes in the error correction codes.
This course aims to introduce the student to random matrix models for decoherence and fidelity decay. They present a very powerful alternate approach, that emphasizes the disordered character of many environments and uncontrollable perturbations/couplings. The inherent integrability of such models makes analytic studies possible. We limit our considerations to linear response treatment, as high fidelity and small decoherence are the backbone of quantum information processes. For fidelity decay, where experimental results are available, a comparison with experiments shows excellent agreement wi…
The distribution and processing of quantum entanglement form the basis of quantum communication and quantum computing. The realization of the two is difficult because quantum information inherently has a high susceptibility to decoherence, i.e. to uncontrollable information loss to the environment. For entanglement distribution, a proposed solution to this problem is capable of fully eliminating decoherence; namely iterative entanglement distillation. This approach builds on a large number of distillation steps each of which extracts a number of weakly decohered entangled states from a larger …
Decoherence and gate errors severely limit the capabilities of state-of-the-art quantum computers. This work introduces a strategy for reference-state error mitigation (REM) of quantum chemistry that can be straightforwardly implemented on current and near-term devices. REM can be applied alongside existing mitigation procedures, while requiring minimal post-processing and only one or no additional measurements. The approach is agnostic to the underlying quantum mechanical ansatz and is designed for the variational quantum eigensolver (VQE). Two orders-of-magnitude improvement in the computati…
HQS Quantum Simulations GmbH（HQS量子模拟有限公司）；Institute for Quantum Electronics, ETH Zürich（苏黎世联邦理工学院量子电子研究所）；Quantum Center, ETH Zürich（苏黎世联邦理工学院量子中心）；Fraunhofer Institute for Applied Solid State Physics IAF（弗劳恩霍夫应用固体物理研究所）
Quantum annealing devices have been subject to various analyses in order to classify their usefulness for practical applications. While it has been successfully proven that such systems can in general be used for solving combinatorial optimization problems, they have not been used to solve chemistry applications. In this paper we apply a mapping, put forward by Xia et al. (The Journal of Physical Chemistry B 122.13 (2017): 3384-3395.), from a quantum chemistry Hamiltonian to an Ising spin glass formulation and find the ground state energy with a quantum annealer. Additionally we investigate th…
It is well known that the interaction of quantum systems with the environment reduces the inherent quantum correlations. Under special circumstances the effect of decoherence can be reversed, for example, the interaction modeled by an amplitude damping channel can boost the teleportation fidelity from the classical to the quantum region for a bipartite quantum state. Here, we first show that this phenomena fails in the case of a quantum key distribution protocol. We further show that the technique of weak measurement can be used to slow down the process of decoherence, thereby helping to prese…
Simulation of interacting electron systems is one of the great challenges of modern quantum chemistry and solid state physics. Controllable quantum systems offer the opportunity to create artificial structures which mimic the system of interest. An interesting quantity to extract from these quantum simulations is the spectral function. We map a noisy quantum simulator onto a fermionic system and investigate the influence of decoherence on the simulation of the spectral density using a diagrammatic approach on Keldysh contour. We show that features stronger than the single-qubit decoherence rat…
Quantum superpositions can be used for parallel information processing, but only if protected against decoherence. A two-particle four-state system may have two-dimensional subspaces that are partially or completely decoherence-free, e.g., the symmetric triplet state as an example of the former, the anti-symmetric singlet state of the latter. By extension, a multiparticle system that in the laboratory basis is plagued by decoherence may in some other basis exhibit the symmetries that yield such decoherence-free subspaces (DFS's). Fully-interacting many-fermion spin 1/2 networks may be mathemat…
The physics of low-energy quantum systems is usually studied without explicit consideration of the background spacetime. Phenomena inherent to quantum theory on curved space-time, such as Hawking radiation, are typically assumed to be only relevant at extreme physical conditions: at high energies and in strong gravitational fields. Here we consider low-energy quantum mechanics in the presence of gravitational time dilation and show that the latter leads to decoherence of quantum superpositions. Time dilation induces a universal coupling between internal degrees of freedom and the centre-of-mas…
We study the open system dynamics of a circuit QED model operating in the ultrastrong coupling regime. If the resonator is pumped periodically in time the underlying classical system is chaotic. Indeed, the periodically driven Jaynes-Cummings model in the Born-Oppenheimer approximation resembles a Duffing oscillator which in the classical limit is a well-known example of a chaotic system. Detection of the field quadrature of the output field acts as an effective position measurement of the oscillator. We address how such detection affects the quantum chaotic evolution in this bipartite system.…
We study the stability of superpositions of macroscopically distinct quantum states under decoherence. We introduce a class of quantum states with entanglement features similar to Greenberger-Horne-Zeilinger (GHZ) states, but with an inherent stability against noise and decoherence. We show that in contrast to GHZ states, these so-called concatenated GHZ states remain multipartite entangled even for macroscopic numbers of particles and can be used for quantum metrology in noisy environments. We also propose a scalable experimental realization of these states using existing ion-trap set-ups.
The inherent difficulty in talking about quantum decoherence in the context of quantum cosmology is that decoherence requires subsystems, and cosmology is the study of the whole Universe. Consistent histories gave a possible answer to this conundrum, by phrasing decoherence as loss of interference between alternative histories of closed systems. When one can apply Boolean logic to a set of histories, it is deemed 'consistent'. However, the vast majority of the sets of histories that are merely consistent are blatantly nonclassical in other respects, and further constraints than just consistenc…
There are several important solid-state systems, such as defects in solids, superconducting circuits and molecular qubits, for attractive candidates of quantum computations. Molecular qubits, which benefit from the power of chemistry for the tailored and inexpensive synthesis of new systems, face the challenge from decoherence effect. The decoherence effect is due to the molecular qubits' inevitable interactions to their environment. Strategies to overcome decoherence effect have been developed, such as designing a nuclear spin free environment and working at atomic clock transitions. These ch…
Reliable processing of quantum information for developing quantum technologies requires precise control of out-of-equilibrium many-bodysystems. This is a highly challenging task as the fragility of quantum states to external perturbations increases with the system-size. Here, we report on a series of experimental quantum simulations that quantify the sensitivity of a controlled Hamiltonian evolution to perturbations that drive the system away from the targeted evolution. Based on out-of-time ordered correlations, we demonstrate that the decay-rate of the process fidelity increases with the eff…
We propose a physically realizable machine which can either generate multiparticle W-like states, or implement high fidelity $1 \to M$ ($M=1,2,... \infty$) anti-cloning of an arbitrary qubit state, in a single step. Moreover this universal machine acts as a catalyst in that it is unchanged after either procedure, effectively resetting itself for its next operation. It also possesses an inherent {\em immunity} to decoherence. Most importantly in terms of practical multi-party quantum communication, the machine's robustness in the presence of decoherence actually {\em increases} as the number of…
The uncertainty principle is an inherent characteristic of quantum mechanics. This principle can be formulated in various form. Fundamentally, this principle can be expressed in terms of the standard deviation of the measured observables. In quantum information theory the preferred mathematical quantity to express the entropic uncertainty relation is the Shannon's entropy. In this work, we consider the generalized entropic uncertainty relation in which there is an additional particle as a quantum memory. Alice measures on her particle $A$ and Bob, with memory particle $B$, predicts the Alice's…
Path-Degenerate Quantum Interferometry for Loss Resilience in Gravitational-Wave Detectors
Universität Hamburg（汉堡大学）；Russian Quantum Center, Skolkovo IC（俄罗斯量子中心，斯科尔科沃创新中心）；Faculty of Physics, M V Lomonosov Moscow State University（莫斯科国立大学物理学院）
Recently, there has been increasing interest in designing schemes for quantum computations that are robust against errors. Although considerable research has been devoted to developing quantum error correction schemes, much less attention has been paid to optimizing the speed it takes to perform a quantum computation and developing computation models that act on decoherence-free subspaces. Speeding up a quantum computation is important, because fewer errors are likely to result. Encoding quantum information in a decoherence-free subspace is also important, because errors would be inherently su…
The intention of this work is twofold, first to present a most simple system capable of simulating the intrinsic bosonic Josephson effect with photons, and second to study various outcomes deriving from inherent or external decoherence. A qubit induces an effective coupling between two externally pumped cavity modes. Without cavity losses and in the dispersive regime, intrinsic Josephson oscillations of photons between the two modes occurs. In this case, contrary to regular Markovian decoherence, the qubit purity shows a Gaussian decay and recurrence of its coherence. Due to intrinsic non-line…
In quantum chemistry, the price paid by all known efficient model chemistries is either the truncation of the Hilbert space or uncontrolled approximations. Theoretical computer science suggests that these restrictions are not mere shortcomings of the algorithm designers and programmers but could stem from the inherent difficulty of simulating quantum systems. Extensions of computer science and information processing exploiting quantum mechanics has led to new ways of understanding the ultimate limitations of computational power. Interestingly, this perspective helps us understand widely used m…
Nuclear magnetic resonance spectroscopy is one of the few remaining areas of physical chemistry for which polynomially scaling simulation methods have not so far been available. Here, we report such a method and illustrate its performance by simulating common 2D and 3D liquid state NMR experiments (including accurate description of spin relaxation processes) on isotopically enriched human ubiquitin - a protein containing over a thousand nuclear spins forming an irregular polycyclic three-dimensional coupling lattice. The algorithm uses careful tailoring of the density operator space to only in…
InstaDeep（英斯塔迪普）；University of Oxford（牛津大学）；Russian Quantum Center（俄罗斯量子中心）
In recent years, neural network quantum states (NNQS) have emerged as powerful tools for the study of quantum many-body systems. Electronic structure calculations are one such canonical many-body problem that have attracted significant research efforts spanning multiple decades, whilst only recently being attempted with NNQS. However, the complex non-local interactions and high sample complexity are significant challenges that call for bespoke solutions. Here, we parameterise the electronic wavefunction with a novel autoregressive neural network (ARN) that permits highly efficient and scalable…
Chemically induced dynamic nuclear polarization is a signature of spin order appearing in many photosynthetic reaction centers. Such polarization, significantly enhanced above thermal equilibrium, is known to result from the nuclear spin sorting inherent in the radical pair mechanism underlying long-lived charge-separated states in photosynthetic reaction centers. We will here show that the recently understood fundamental quantum dynamics of radical-ion-pair reactions open up a new and completely unexpected venue towards obtaining CIDNP signals. The fundamental decoherence mechanism inherent i…
With the growing efforts in isolating solid-state qubits from external decoherence sources, the origins of noise inherent to the material start to play a relevant role. One representative example are charged impurities in the device material or substrate, which typically produce telegraph noise and can hence be modelled as bistable fluctuators. In order to demonstrate the possibility of the active suppression of the disturbance from a {\em single} fluctuator, we theoretically implement an elementary bang-bang control protocol. We numerically simulate the random walk of the qubit state on the B…
Radical-ion-pair reactions were recently shown to represent a rich biophysical laboratory for the application of quantum measurement theory methods and concepts. We here propose a concrete experimental test that can clearly discriminate among the fundamental master equations currently attempting to describe the quantum dynamics of these reactions. The proposed measurement based on photon statistics of fluorescing radical pairs is shown to be model-independent and capable of elucidating the singlet-triplet decoherence inherent in the radical-ion-pair recombination process.
In this work, we present an efficient rank-compression approach for the classical simulation of Kraus decoherence channels in noisy quantum circuits. The approximation is achieved through iterative compression of the density matrix based on its leading eigenbasis during each simulation step without the need to store, manipulate, or diagonalize the full matrix. We implement this algorithm in an in-house simulator, and show that the low rank algorithm speeds up simulations by more than two orders of magnitude over an existing implementation of full rank simulator, and with negligible error in th…
In spite of the macroscopic character of the fluctuation amplitudes, we show that the standard inflationary distribution of primordial density fluctuations still exhibits inherently quantum mechanical correlations (which cannot be mimicked by any classical stochastic ensemble). To this end, we propose a Gedanken experiment for which certain Bell inequalities are violated. We also compute the effect of decoherence and show that the violation persists provided that the decoherence lies below a certain non-vanishing threshold. Moreover, there exists a higher threshold above which no violation of …
The analysis of traps, i.e., locally but not globally optimal controls, for quantum control systems has attracted a great interest in recent years. The central problem that has been remained open is to demonstrate for a given system either existence or absence of traps. We prove the absence of traps and hence completely solve this problem for the important tasks of unconstrained manipulation of the transition probability and unitary gate generation in the Landau-Zener system---a system with a wide range of applications across physics, chemistry and biochemistry. This finding provides the first…
Cluster-configurational study of G-center in Silicon
Virginia Tech（弗吉尼亚理工大学）；Virginia Tech Center for Quantum Information Science and Engineering（弗吉尼亚理工学院量子信息与工程中心）；Virginia Tech National Security Institute（弗吉尼亚理工学院国家安全研究所）
