We present a protocol to achieve double quantum magnetometry at large static magnetic fields. This is a regime where sensitive sample parameters, such as the chemical shift, get enhanced facilitating their characterization. In particular, our method delivers two-tone stroboscopic radiation patterns with modulated Rabi frequencies to achieve larger spectral signals. Furthermore, it does not introduce inhomogeneous broadening in the sample spectrum preventing signal misinterpretation. Moreover, our protocol is designed to work under realistic conditions such as the presence of moderate microwave power and errors on the radiation fields. Albeit we particularise to nitrogen vacancy centers, our protocol is general, thus applicable to distinct quantum sensors.
We discuss multipulse magnetometry that exploits all three magnetic sublevels of the S=1 nitrogen-vacancy center in diamond to achieve enhanced magnetic field sensitivity. Based on dual frequency microwave pulsing, the scheme works in arbitrary magnetic bias fields and is twice as sensitive to ac magnetic fields as conventional two-level magnetometry. We derive the spin evolution operator for dual frequency microwave excitation and show its effectiveness for double-quantum state swaps. Using multipulse sequences of up to 128 pulses under optimized conditions, we show enhancement of the SNR by …
Sensing static or slowly varying magnetic fields with high sensitivity and spatial resolution is critical to many applications in fundamental physics, bioimaging and materials science. Several versatile magnetometry platforms have emerged over the past decade, such as electronic spins associated with Nitrogen Vacancy (NV) centers in diamond. However, their high sensitivity to external fields also makes them poor sensors of DC fields. Indeed, the usual method of Ramsey magnetometry leaves them prone to environmental noise, limiting the allowable interrogation time to the short dephasing time T2…
We argue that it is possible in principle to reduce the uncertainty of an atomic magnetometer by double-passing a far-detuned laser field through the atomic sample as it undergoes Larmor precession. Numerical simulations of the quantum Fisher information suggest that, despite the lack of explicit multi-body coupling terms in the system's magnetic Hamiltonian, the parameter estimation uncertainty in such a physical setup scales better than the conventional Heisenberg uncertainty limit over a specified but arbitrary range of particle number N. Using the methods of quantum stochastic calculus and…
We demonstrate a magnetometry technique using nitrogen-vacancy centres in diamond which makes use of coherent two-photon transitions. We find that the sensitivity to magnetic fields can be significantly improved in isotopically purified diamond. Furthermore, the long-term stability of magnetic field measurements is significantly enhanced, thereby reducing the minimum detectable long-term field variations for both quasi-static and periodic fields. The method is useful both for sensing applications and as a spin qubit manipulation technique.
Solid-state magnetometers like the Nitrogen-Vacancy center in diamond have been of paramount importance for the development of quantum sensing with nanoscale spatial resolution. The basic protocol is a Ramsey sequence, that imprints an external static magnetic field into phase of the quantum sensor, which is subsequently readout. In this work we show that the hyperfine coupling between the Nitrogen-Vacancy and a nearby Carbon-13 can be used to set a post-selection protocol that leads to an enhancement of the sensitivity under realistic experimental conditions. We found that for an isotopically…
We report on the use of a single NV center to probe fluctuating AC magnetic fields. Using engineered currents to induce random changes in the field amplitude and phase, we show that stochastic fluctuations reduce the NV center sensitivity and, in general, make the NV response field-dependent. We also introduce two modalities to determine the field spectral composition, unknown a priori in a practical application. One strategy capitalizes on the generation of AC-field-induced coherence 'revivals', while the other approach uses the time-tagged fluorescence intensity record from successive NV obs…
Nitrogen-vacancy (NV) spin ensembles in diamond provide an advanced magnetic sensing platform, with applications in both the physical and life sciences. The development of isotopically engineered $^{15}$NV diamond offers advantages over naturally occurring $^{14}$NV for magnetometry, due to its simpler hyperfine structure. However, for sensing modalities requiring a bias magnetic field not aligned with the sensing NV axis, the absence of a quadrupole moment in the $^{15}$N nuclear spin leads to pronounced envelope modulation effects in time-dependent measurements of $^{15}$NV spin evolution. W…
We consider Bayesian estimate of static magnetic field, characterized by a prior Gaussian probability distribution, in systems of a few electron quantum dot spins interacting with infinite temperature spin environment via hyperfine interaction. Sudden transitions among optimal states and measurements are observed. Usefulness of measuring occupation levels is shown for all times of the evolution, together with the role of entanglement in the optimal scenario. For low values of magnetic field, memory effects stemming from the interaction with environment provide limited metrological advantage.
We describe the formalism for optimally estimating and controlling both the state of a spin ensemble and a scalar magnetic field with information obtained from a continuous quantum limited measurement of the spin precession due to the field. The full quantum parameter estimation model is reduced to a simplified equivalent representation to which classical estimation and control theory is applied. We consider both the tracking of static and fluctuating fields in the transient and steady state regimes. By using feedback control, the field estimation can be made robust to uncertainty about the to…
We put forward the idea of lattice quantum magnetometry, i.e. quantum sensing of magnetic fields by a charged (spinless) particle placed on a finite two-dimensional lattice. In particular, we focus on the detection of a locally static transverse magnetic field, either homogeneous or inhomogeneous, by performing ground state measurements. The system turns out to be of interest as quantum magnetometer, since it provides a non-negligible quantum Fisher information (QFI) in a large range of configurations. Moreover, the QFI shows some relevant peaks, determined by the spectral properties of the Ha…
We propose a protocol to estimate magnetic fields using a single nitrogen-vacancy (N-V) center in diamond, where the estimate precision scales inversely with time, ~1/T$, rather than the square-root of time. The method is based on converting the task of magnetometry into phase estimation, performing quantum phase estimation on a single N-V nuclear spin using either adaptive or nonadaptive feedback control, and the recently demonstrated capability to perform single-shot readout within the N-V [P. Neumann et. al., Science 329, 542 (2010)]. We present numerical simulations to show that our method…
A major challenge in quantum metrology is the generation of entangled states with macroscopic atom number. Here, we demonstrate experimentally that atomic squeezing generated via non-linear dynamics in Bose Einstein condensates, combined with suitable trap geometries, allows scaling to large ensemble sizes. We achieve a suppression of fluctuations by 5.3(5) dB for 12300 particles, which implies that similar squeezing can be achieved for more than 10$^7$ atoms. With this resource, we demonstrate quantum-enhanced magnetometry by swapping the squeezed state to magnetically sensitive hyperfine lev…
Atomic magnetometry is one of the most sensitive ways to measure magnetic fields. We present a method for converting a naturally scalar atomic magnetometer into a vector magnetometer by exploiting the polarization dependence of hyperfine transitions in rubidium atoms. First, we fully determine the polarization ellipse of an applied microwave field using a self-calibrating method, i.e. a method in which the light-atom interaction provides everything required to know the field in an orthogonal laboratory frame. We then measure the direction of an applied static field using the polarization ellip…
The sensitivity of quantum magnetometers is challenged by control errors and, especially in the solid-state, by their short coherence times. Refocusing techniques can overcome these limitations and improve the sensitivity to periodic fields, but they come at the cost of reduced bandwidth and cannot be applied to sense static (DC) or aperiodic fields. Here we experimentally demonstrate that continuous driving of the sensor spin by a composite pulse known as rotary-echo (RE) yields a flexible magnetometry scheme, mitigating both driving power imperfections and decoherence. A suitable choice of R…
Halbach magnets are a source of homogeneous magnetic field in an enclosed volume while keeping stray fields at a minimum. Here, we present the design, construction, and characterization for a 10 cm inner diameter double Halbach ring providing a homogeneous (<100 ppm over 1 x 1 x 0.5 cm3) magnetic field of around 105 mT, which will be used for a diamond based microwave-free widefield imaging setup. The final characterization is performed with a novel fiberized diamond-based sensor on a 3D translation stage documenting the high homogeneity of the constructed Halbach array and its suitability for…
New magnetometry techniques based on Nitrogen-Vacancy (NV) defects in diamond allow for the imaging of static (DC) and oscillatory (AC) nanoscopic magnetic systems. However, these techniques require accurate knowledge and control of the sample dynamics, and are thus limited in their ability to image fields arising from rapidly fluctuating (FC) environments. We show here that FC fields place restrictions on the DC field sensitivity of an NV qubit magnetometer, and that by probing the dephasing rate of the qubit in a magnetic FC environment, we are able to measure fluctuation rates and RMS field…
We consider the phase-coherent transport of electrons passing through an Aharonov-Bohm ring while interacting with a tunnel charge in a double quantum dot (representing a charge qubit) which couples symmetrically to both arms of the ring. For Aharonov-Bohm flux Phi_AB=h/2e we find that electrons can only be transmitted when they flip the charge qubit's pseudospin parity an odd number of times. The perfect correlations of the dynamics of the pseudospin and individual electronic transmission and reflection events can be used to entangle the charge qubit with an individual passing electron.
We study the sensitive detection of a weak static magnetic field via Faraday rotation induced by an ensemble of spins in a bimodal degenerate microwave cavity. We determine the limit of the resolution for the sensitivity of the magnetometry achieved using either single-photon or multiphoton inputs. For the case of a microwave cavity containing an ensemble of Nitrogen-vacancy defects in diamond, we obtain a magnetometry sensitivity exceeding $0.5~\text{\nano\tesla}/\sqrt{\text{\hertz}}$, utilizing a single photon probe field, while for a multiphoton input we achieve a sensitivity about $1 \text…
Continuous-wave AC magnetometry up to hundreds of megahertz using nitrogen-vacancy centers under a strong transverse magnetic field
School of Fundamental Science and Technology, Keio University（庆应义塾大学基础科学与技术学院）；Center for Spintronics Research Network, Keio University（庆应义塾大学自旋电子学研究网络中心）；Department of Electrical, Electronic, and Communication Engineering, Faculty of Advanced Science and Engineering, Chuo University（中央大学理工学部电气·电子·通信工程系）；Advanced Research Center for Diamond Science and Technology, Kanazawa University（金泽大学金刚石科学技术高级研究中心）
Magnetometry is an important tool prevalent in many applications such as fundamental research, material characterization and biological imaging. Atomic magnetometry conventionally makes use of two quantum states, the energy difference of which depends linearly on the magnetic field due to the Zeeman effect. The magnetic field is evaluated from repeated measurements of the accumulated dynamic phase between the two Zeeman states in a superposition. Here we propose a magnetometry method that employs a superposition of clock states with energies that do not depend, to first-order, on the magnetic …
We investigate the electron spin resonance of an ensemble of Nitrogen-Vacancy (NV) color centers in a bulk diamond crystal. The four possible orientations of the NV-center in the lattice lead to different dependences on the magnitude and the orientation of an external static magnetic field. Experimental results obtained with a continuous microwave excitation are in good agreement with simulations. In addition, we observe that the average radiative lifetime of the NV color center is also modified when the external magnetic field is applied. This variation is explained by the mixing between mS =…
Precision magnetometry is fundamental to the development of novel magnetic materials and devices. Recently, the nitrogen-vacancy (NV) center in diamond has emerged as a promising probe for static magnetism in 2D van der Waals materials, capable of quantitative imaging with nanoscale spatial resolution. However, the dynamic character of magnetism, crucial for understanding the magnetic phase transition and achieving technological applications, has rarely been experimentally accessible in single 2D crystals. Here, we coherently control the NV center's spin precession to achieve ultra-sensitive, …
Single-Spin Nitrogen-Vacancy Hybrid Magnetometer with Enhanced Static Field Sensitivity
University of Calgary（卡尔加里大学）；Max Planck Institute for Biophysical Chemistry（马克斯·普朗克生物物理化学研究所）；Sichuan University of Science and Engineering（四川理工学院）；QNeura；VinUniversity（越南大学）；XeedQ GmbH（XeedQ有限公司）
We theoretically investigate the robustness of cluster states in charge qubit system based on quantum dot (QD) and double quantum point contact (DQPC). Trap state is modeled by an island structure in DQPC and represents a dynamical fluctuation. We found that the dynamical fluctuations affect the cluster states more than static fluctuation caused by QD size fluctuation.
We analyze the Wannier-Stark spectrum of a quantum particle in tilted two-dimensional lattices with the Bloch spectrum consisting of two subbands, which could be either separated by a finite gap or connected at the Dirac points. For rational orientations of the static field given by an arbitrary superposition of the translation vectors the spectrum is a ladder of energy bands. We obtain asymptotic expressions for the energy bands in the limit of large and weak static fields and study them numerically for intermediate field strength. We show that the structure of energy bands determines the rat…
Intrinsic Vectorial Gradiometry via Quantum Control of a Spin-based Sensor
University of the Basque Country UPV/EHU（巴斯克大学）；EHU Quantum Center, University of the Basque Country UPV/EHU（巴斯克大学量子中心）；IKERBASQUE, Basque Foundation for Science（伊卡巴斯基奎，巴斯克科学基金会）
This dissertation explores the topics of parameter estimation and model reduction in the context of quantum filtering. Chapters 2 and 3 provide a review of classical and quantum probability theory, stochastic calculus and filtering. Chapter 4 studies the problem of quantum parameter estimation and introduces the quantum particle filter as a practical computational method for parameter estimation via continuous measurement. Chapter 5 applies these techniques in magnetometry and studies the estimator's uncertainty scalings in a double-pass atomic magnetometer. Chapter 6 presents an efficient fee…
We study theoretically an optical cavity and a parity-time ($\mathcal{PT}$)-symmetric pair of mechanical resonators, where all oscillators are pairwise coupled, forming an optomechanical system with a closed-contour interaction. Due to the presence of both gain and feedback, we explore its stability and the root loci over a wide coupling range. Under the red-sideband pumping and for the so-called $\mathcal{PT}$-unbroken phase it displays a double optomechanically induced transparency (OMIT) for an experimentally realizable parameter set. We show that both the transmission amplitude and the gro…
We study the effect of a DC magnetic field on the phase sensitivity of a double-lambda system coupled by two laser fields, a probe and a pump. It is demonstrated that the gain and the refractive index of the probe can be controlled by either the magnetic field or the relative phase between the two laser fields. More interestingly, when the system reduces to a single-lambda system, turning on the magnetic field transforms the system from a phase-insensitive process to a phase-sensitive one. In the pulsed-probe regime, we observed switching between slow and fast light when the magnetic field or …
Quantum tunneling through an almost classical potential barrier can be strongly enhanced by a nonstationary field so that the penetration through the barrier becomes not exponentially small. This constitutes an extremely unusual phenomenon of quantum physics called Euclidean resonance. A certain nonstationary barrier is proposed with a very low WKB tunneling rate. The quantum dynamics of this barrier is mapped on resonant tunneling across a static double barrier with a resonant level inside. The real penetration through the dynamical barrier is not exponentially small providing an example of E…
Absolute knowledge about the magnetic field orientation plays a crucial role in single spin-based quantum magnetometry and the application toward spin-based quantum computation. In this paper, we reconstruct the 3D orientation of an arbitrary static magnetic field with individual nitrogen vacancy (NV) centers in diamond. We determine the polar and the azimuthal angle of the magnetic field orientation relative to the diamond lattice. Therefore, we use information from the photoluminescence anisotropy of the NV, together with a simple pulsed Optically Detected Magnetic Resonance (ODMR) experimen…
We analyze the Wannier-Stark spectrum of a quantum particle in generic one-dimensional double-periodic lattices. In the limit of weak static field the spectrum is shown to be a superposition of two Wannier-Stark ladders originated from two Bloch subbands. As the strength of the field is increased, the spectrum rearranges itself into a single Wannier-Stark ladder. We derive analytical expressions which describe the rearrangement employing the analogy between the Wannier-Stark problem and the driven two-level system in the strong-coupling regime.
