Spin-crossover (SCO) molecules are versatile magnetic switches with applications in molecular electronics and spintronics. Downscaling devices to the single-molecule level remains, however, a challenging task since the switching mechanism in bulk is mediated by cooperative intermolecular interactions. Here, we report on electron transport through individual Fe-SCO molecules coupled to few-layer graphene electrodes \textit{via} $π- π$ stacking. We observe a distinct bistability in the conductance of the molecule and a careful comparison with density functional theory (DFT) calculations allows to associate the bistability with a SCO-induced orbital reconfiguration of the molecule. We find long spin-state lifetimes that are caused by the specific coordination of the magnetic core and the absence of intermolecular interactions according to our calculations. In contrast with bulk samples, the SCO transition is not triggered by temperature but induced by small perturbations in the molecule at any temperature. We propose plausible mechanisms that could trigger the SCO at the single-molecule level.
The low conductance of nickel atomic junctions in the hydrogen environment is studied using the nonequilibrium Green's function theory combined with first-principles calculations. The Ni junction bridged by a $H_2$ molecule has a conductance of approximately 0.7 $G_0$. This conductance is contributed by the anti-bonding state of the $H_2$ molecule, which forms a bonding state with the $3d$ orbitals of the nearby Ni atoms. In contrast, the Ni junction bridged by the two single H atoms has a conductance of approximately 1 $G_0$, which is weakly spin-polarized. The spin-up channels were found to …
We calculate the conductance through double junctions of the type M(inf.)-Sn-Mm-Sn-M(inf.) and triple junctions of the type M(inf.)-Sn-Mm-Sn-Mm-Sn-M(inf.), where M(inf.) are semi-infinite metallic electrodes, Sn are 'n' layers of semiconductor and Mm are 'm' layers of metal (the same as the electrodes), and compare the results with the conductance through simple junctions of the type M(inf.)-Sn-M(inf.). The junctions are bi-dimensional and their parts (electrodes and 'active region') are periodic in the direction perpendicular to the transport direction. To calculate the conductance we use the…
We study the heat conductance of hybrid superconducting junctions. Our analysis involves single-channel junctions with arbitrary transmission as well as diffusive connectors and shows the influence of the superconducting gaps and phases of the contacts on the heat conductance. If the junction is diffusive, these effects are completely quenched on average, however, we find that their influence persists in weak-localization corrections and conductance fluctuations. While these statistical properties strongly deviate from the well-known analogues for the charge conductance, we demonstrate that th…
The conductance of a single metal-molecule-metal junction depends critically on the conformations of the molecule. In the simple case of a biphenyl, two phenyl rings linked together by a single C-C bond, the conductance is expected to depend on the relative twist angle between the two rings, with the planar conformation having the highest conductance. A number of different techniques have measured the conductance of metal-molecule(s)-metal junctions. However, the conductance variation from junction to junction has made it difficult to verify even the simplest predictions about how molecules sh…
We investigate quantum transport via surface states in a nanostep junction on the surface of a 3D topological insulator that involves two different side surfaces. We calculate the conductance across the junction within the scattering matrix formalism and find that as the bias voltage is increased, the conductance of the nanostep junction is suppressed by a universal factor of 1/3 compared to the conductance of a similar planar junction based on a single surface of a topological insulator. We also calculate and analyze the Fano factor of the nanostep junction and predict that the Fano factor sa…
We studied spin-dependent conductance in a normal metal (NM)/NM junction with Dresselhaus spin-orbit coupling (DSOC) and magnetization. As a reference, we also studied the spin-dependent conductance in such a junction with Rashba spin-orbit coupling (RSOC). Using a standard scattering method, we calculated the gate-voltage dependence of the spin-dependent conductances in DSOC and RSOC. In addition, we calculated the gate-voltage dependence of the conductances in a ferromagnetic metal (FM)/NM junction with spin-orbit coupling and magnetization, which we call ferromagnetic spin-orbit metal (FSOM…
We propose an objective and robust method to extract the electrical conductance of single molecules connected to metal electrodes from a set of measured conductance data. Our method roots in the physics of tunneling and is tested on octanedithiol using mechanically controllable break junctions. The single molecule conductance values can be deduced without the need for data selection.
The transport properties of Chern insulator junctions generated by bipolar junctions in quantum Hall graphene are theoretically studied in the coherent regime. Coherent transport across the junction exhibits two mesoscopic features: valley-isospin dependence of the quantum Hall conductance, and the Aharonov-Bohm (AB) effects with the interface channels. We demonstrate that the valley-isospin dependence can be measured in a graphene sample with perfect edge terminations, resulting in conductance oscillation for the smallest Chern number case. On the other hand, while conductance plateaus are fo…
Conductance $G$ of a 2DEG-Superconductor (S) device in a high magnetic field is studied: $G(ν)$ is calculated. When the cyclotron diameter in 2DEG is larger than the width of the 2DEG-S surface then $G(ν)$ becomes nonmonotonous function due to the Aharonov--Bohm type interference of quasiparticles at the surface. At certain parameters of the junction the conductance oscillates with $ν$.
We use the non-equilibrium Green function (NEGF) method in the ballistic limit to provide a quantitative description of the conductance of graphene pn junctions - an important building block for graphene electronics devices. In this paper, recent experiments on graphene junctions are explained by a ballistic transport model, but only if the finite junction transition width, Dw, is accounted for. In particular, the experimentally observed anamolous increase in the resistance asymmetry between nn and np junctions under low source/drain charge density conditions is also quantitatively captured by…
We report electronic transport measurements of single-molecule transistor devices incorporating bipyridyl-dinitro oligophenylene-ethynylene dithiol (BPDN-DT), a molecule known to exhibit conductance switching in other measurement configurations. We observe hysteretic conductance switching in 8% of devices with measurable currents, and find that dependence of the switching properties on gate voltage is rare when compared to other single-molecule transistor devices. This suggests that polaron formation is unlikely to be responsible for switching in these devices. We discuss this and alternative …
A current constrained approach is proposed to calculate negative differential conductance in molecular nano-junctions. A four-site junction is considered where a steady-state current is forced by inserting only the two central sites within the circuit. The two lateral sites (representing e.g. dangling molecular groups) do not actively participate in transport, but exchange electrons with the two main sites. These auxiliary sites allow for a variable number of electrons within the junction, while, as required by the current constrained approach, the total number of electrons in the system is ke…
We study the low-energy electronic properties of a junction made of two crossed metallic carbon nanotubes of general chiralities. We derive a tight binding tunneling matrix element that couples low-energy states on the two tubes, which allows us to calculate the contact conductance of the junction. We find that the intrinsic asymmetries of the junction cause the forward and backward hopping probabilities from one tube to another to be different. This defines a zero-field Hall conductance for the junction, which we find to scale inversely with the junction contact conductance. Through a systema…
We investigate gold-4,4'-bipyridine-gold single-molecule junctions with the mechanically controllable break junction technique at cryogenic temperature ($T=4.2\,\text{K}$). We observe bistable probabilistic conductance switching between the two molecular binding configurations, influenced both by the mechanical actuation, and the applied voltage. We demonstrate that the relative dominance of the two conductance states is tunable by the electrode displacement, whereas the voltage manipulation induces an exponential speedup of both switching times. The detailed investigation of the voltage-tunab…
We demonstrate switching behavior and quantized conductance at room temperature in percolating films of nanoparticles. Our experiments and complementary simulations show that switching and quantization result from formation of atomic scale wires in gaps between particles. These effects occur only when tunnel gaps are present in the film, close to the percolation threshold.
We calculate the linear conductance of a two-dimensional electron gas (2DEG)-based junction between a normal semiconductor section and a hybrid semiconductor-superconductor section, under perpendicular magnetic field. We consider two important terms often neglected in the literature, the magneto-orbital and transverse Rashba spin-orbit. The strong orbital effect due to the magnetic field yields topological phase transitions to nontrivial phases hosting Majorana modes in the hybrid section. The presence of a potential barrier at the junction interface reveals the Majorana phases as quantized pl…
Porphyrin molecules can form stable single molecule junctions without anchoring groups. Adding thiol end groups and pyridine axial groups yields more stable junctions with an increased spread in low-bias conductance. This is a result of different bridging geometries during breaking, the stability of which is demonstrated in time-dependent conductance measurements. This is in strong contrast with rod like molecules which show one preferential binding geometry.
We theoretically analyzed the Andreev reflection in ferromagnetic metal/nonmagnetic metal/superconductor double junctions with special attention to the electron interference effect in the nonmagnetic metal layer. We showed that the conductance oscillates as a function of the bias voltage due to the geometrical resonance. We found that the exchange field, and therefore the spin polarization of the ferromagnetic metal can be determined from the period of the conductance oscillation, which is proportional to the square root of the exchange field.
Molecular-scale components are expected to be central to nanoscale electronic devices. While molecular-scale switching has been reported in atomic quantum point contacts, single-molecule junctions provide the additional flexibility of tuning the on/off conductance states through molecular design. Thus far, switching in single-molecule junctions has been attributed to changes in the conformation or charge state of the molecule. Here, we demonstrate reversible binary switching in a single-molecule junction by mechanical control of the metal-molecule contact geometry. We show that 4,4'-bipyridine…
We theoretically examine the effect of the coupling of the transport electrons to a vibrational mode of the molecule on the ac linear-response conductance of molecular junctions. Representing the molecule by a single electronic state, we find that at very low temperatures the frequency-dependent conductance is mainly enhanced (suppressed) by the electron-vibration interaction when the chemical potential is below (above) the energy of that state. The vertex corrections of the electron-vibration interaction induce an additional peak structure in the conductance, which can be observed by tuning t…
General multi-channel SN junctions fall into two topological classes depending on whether or not there is a Majorana mode localized at the junction. This is known to lead to different behaviour of the conductance in the presence of arbitrary disorder near the junction. We discuss these topological properties from two perspectives, one based on representing the disorder by a scattering matrix in series with that of a clean SN junction and one based on low energy field theory methods. The first approach is used to discuss the effect of an Ohmic contact between a quantum wire and a three dimensio…
Graphene pn junction is the brick to build up variety of graphene nano-structures. The analytical formula of the conductance of graphene gradual pn junctions in the whole bipolar region has been absent up to now. In this paper, we analytically calculated that pn conductance with the spin-orbit coupling and stagger potential taken into account. Our analytical expression indicates that the energy gap causes the conductance to drop a constant value with respect to that without gap in a certain parameter region, and manifests that the curve of the conductance versus the stagger potential consists …
We theoretically investigate the transport properties of a normal-insulator-superconductor (NIS) junction of silicene in the thin barrier limit. Similar to graphene the tunneling conductance in such NIS structure exhibits an oscillatory behavior as a function of the strength of the barrier in the insulating region. However, unlike in graphene, the tunneling conductance in silicene can be controlled by an external electric field owing to its buckled structure. We also demonstrate the change in behavior of the tunneling conductance across the NIS junction as we change the chemical potential in t…
The interplay between groups of water molecules and single-atom contacts, as reflected in the electrical conductances and mechanical forces of copper atomic junctions, is explored by means of first-principles theory and semi-empirical calculations. We study the influence of the atomic geometries of copper electrodes with pyramidal and non-crystalline structures in the presence and absence of water on the conductance profiles as the electrodes approach each other. It is shown that the atomic arrangements of nano-contacts have crucial effects on the formation of plateaus and the conductance valu…
We study the electronic transport in a graphene-based superconductor-normal(graphene)-superconductor (SNS) junction by use of the Dirac-Bogoliubov-de Gennes equation. We consider the properties of tunneling conductance through an undoped strip of graphene with heavily doped superconducting electrodes in the dirty limit. We find that spectrum of Andreev bound states are modified in the presence of single localized defect in the bulk. The minimum tunneling conductance remains the same and this result doesn't depend on the actual location of the imperfection.
Memristive switching devices, candidates for resistive random access memory technology, have been shown to switch off through a progression of states with quantized conductance and subsequent non-integer conductance (in terms of conductance quantum $G_0$). We have performed calculations based on density functional theory to model the switching process for a Pt-HfO$_2$-Pt structure, involving the movement of one or two oxygen atoms. Oxygen atoms moving within a conductive oxygen vacancy filament act as tunneling barriers, and partition the filament into weakly coupled quantum wells. We show tha…
We report the first concurrent determination of conductance (G) and thermopower (S) of single-molecule junctions via direct measurement of electrical and thermoelectric currents using a scanning tunneling microscope-based break-junction technique. We explore several amine-Au and pyridine-Au linked molecules that are predicted to conduct through either the highest occupied molecular orbital (HOMO) or the lowest unoccupied molecular orbital (LUMO), respectively. We find that the Seebeck coefficient is negative for pyridine-Au linked LUMO-conducting junctions and positive for amine-Au linked HOMO…
In this work we theoretically consider the OPE-3 molecule bridging two metallic leads and show that because of the electron-phonon interaction and the transition of cation to triplet states, we can have a light induced negative differential conductance. Furthermore, we investigate the effects of light intensity and temperature on this phenomena.
We study the electronic transport of heterojunctions made of chiral topological superconductors (TSCs) with $N$ chiral Majorana fermion modes and quantum Hall insulators (QHIs) with integer Chern number $C$. In the weak disorder regime, we show the two-terminal conductance $σ_{12}$ of a QHI-TSC-QHI junction is generically non-quantized, but obeys a certain distribution determined by $C$ and $N$, which is induced by random SO($N$) rotations of chiral Majorana fermion mode basis on the TSC edges. Oppositely, in the strong disorder regime, $σ_{12}$ tends to be a quantized value. We conclude with …
We argue that the relative thermal conductance between interfaces with different morphologies is controlled by crystal structure through $M_{min}/M_c > 1$, the ratio between the {\it minimum mode} count on either side $M_{min}$, and the {\it conserving modes} $M_c$ that preserve phonon momentum transverse to the interface. Junctions with an added homogenous layer, "uniform", and "abrupt" junctions are limited to $M_c$ while junctions with interfacial disorder, "mixed", exploit the expansion of mode spectrum to $M_{min}$. In our studies with cubic crystals, the largest enhancement of conductanc…
When an atomic-size break junction is mechanically stretched, the total conductance of the contact remains approximately constant over a wide range of elongations, although at the same time the transmissions of the individual channels (valence orbitals of the junction atom) undergo strong variations. We propose a microscopic explanation of this phenomenon, based on Coulomb correlation effects between electrons in valence orbitals of the junction atom. The resulting approximate conductance quantization is closely related to the Friedel sum rule.
We present an \emph{ab initio} study of the role of interference effects in the thermal conductance of single-molecule junctions. To be precise, using a first-principles transport method based on density functional theory, we analyze the coherent phonon transport in single-molecule junctions based on several benzene and oligo-phenylene-ethynylene derivatives. We show that the thermal conductance of these junctions can be tuned via the inclusion of substituents, which induces destructive interference effects and results in a decrease of the thermal conductance with respect to the unmodified mol…
We experimentally investigate Andreev transport through a single junction between an s-wave indium superconductor and a thick film of a three-dimensional $Bi_2Te_3$ topological insulator. We study $Bi_2Te_3$ samples with different bulk and surface characteristics, where the presence of a topological surface state is confirmed by direct ARPES measurements. All the junctions demonstrate Andreev transport within the superconducting gap. For junctions with transparent $In-Bi_2Te_3$ interfaces we find a number of nearly periodic conductance oscillations, which are accompanied by zero-bias conductan…
Current noise in nanoscale systems provides additional information beyond the electronic conductance. We report measurements at room temperature of the nonequilibrium "excess" noise in ensembles of atomic-scale gold junctions repeatedly formed and broken between a tip and a film, as a function of bias conditions. We observe suppression of the noise near conductances associated with conductance quantization in such junctions, as expected from the finite temperature theory of shot noise in the limit of few quantum channels. In higher conductance junctions, the Fano factor of the noise approaches…
We have measured the conductance and shot-noise of superconductor-normal metal (S-N) junctions between a Niobium (Nb) film and a 2-dimensional electron gas (2DEG), formed in an InAs-based semiconductor heterostructure. Adjacent to the junction, the 2DEG is shaped into a submicrometer beam-splitter. The current shot-noise measured through one arm of the beam-splitter is found to be enhanced due to Andreev reflection. Both noise and conductance measurements indicate that the Nb-2DEG interface is of high quality with a transparency approaching approx. 60-70 %. The present device can be seen as a …
We have studied the switching behaviour of a small capacitance Josephson junction both in experiment, and by numerical simulation of a model circuit. The switching is a comples process involving the transition between two dynamical states of the non-linear circuit, arising from a frequency dependent damping of the Josephson junction. We show how a specific type of bias pulse-and-hold, can result in a fast detection of switching, even when the measurement bandwidth of the junction voltage is severely limited, and/or the level of the switching current is rather low.
We present a first-principles study on the spin denpendent conductance of five single-atom magnetic junctions consisting of a magnetic tip and an adatom adsorbed on a magnetic surface, i.e., the Co-Co/Co(001) and Ni-X/Ni(001) (X=Fe, Co, Ni, Cu) junctions. When their spin configuration changes from ferromagnetism to anti-ferromagnetism, the spin-up conductance increases while the spin-down one decreases. For the junctions with a magnetic adatom, there is nearly no spin valve effect as the decreased spin-down conductance counteracts the increased spin-up one. For the junction with a nonmagnetic …
The conductance fluctuations of a metallic wire which is interrupted by a small tunnel junction has been explored experimentally. In this system, the bias voltage V, which drops almost completely inside the tunnel barrier, is used to probe the energy dependence of conductance fluctuations due to disorder in the wire. We find that the variance of the fluctuations is directly proportional to V. The experimental data are consistently described by a theoretical model with two phenomenological parameters: the phase breaking time at low temperatures and the diffusion coefficient.
Employing an ab initio Screened Korringa-Kohn-Rostoker (SKKR) band structure method for a metal-vacuum-metal junction, we find that the tunnel conductance is different when it is calculated across the barrier and far from it. We attribute this difference to an artefact of the ballistic approach which overestimates the role of specular reflections, and its inability to pick up contributions from localized interface states. To reconcile the ballistic approach with experiment, we propose that the tunnel conductance should be calculated as if it is measured directly across the barrier. In this cas…
Thermopower measurements of molecular junctions have recently gained interest as a characterization technique that supplements the more traditional conductance measurements. Here we investigate the electronic conductance and thermopower of benzenediamine (BDA) and benzenedicarbonitrile (BDCN) connected to gold electrodes using first-principles calculations. We find excellent agreement with experiments for both molecules when exchange-correlation effects are described by the many-body GW approximation. In contrast, results from standard density functional theory (DFT) deviate from experiments b…
Using photoemission spectroscopy, we determine the relationship between electronic energy level alignment at a metal-molecule interface and single-molecule junction transport data. We measure the position of the highest occupied molecular orbital (HOMO) relative to the Au metal Fermi level for three 1,4-benzenediamine derivatives on Au(111) and Au(110) with ultraviolet and resonant x-ray photoemission spectroscopy. We compare these results to scanning tunnelling microscope based break-junction measurements of single molecule conductance and to first-principles calculations. We find that the en…
The electronic transport of graphene p-n junctions under perpendicular magnetic field is investigated in theory. Under low magnetic field, the transport is determined by the resonant tunneling of Landau levels and conductance versus magnetic field shows a Shubnikov-de Haas oscillation. At higher magnetic field, the p-n junction subjected to the quasi-classical regime and the formation of snake states results in periodical backscattering and transmission as magnetic field varies. The conductance oscillation pattern is mediated both by magnetic field and the carrier concentration on bipolar regi…
Pulsed spin-torque switching has been studied using single-shot time-resolved electrical measurements in perpendicularly magnetized magnetic tunnel junctions as a function of pulse amplitude and junction size in 50 to 100 nm diameter circular junctions. The mean switching time depends inversely on pulse amplitude for all junctions studied. However, the switching dynamics is found to be strongly dependent on junction size and pulse amplitude. In 50 nm diameter junctions the switching onset is stochastic but the switching once started, is fast; after being initiated it takes less than 2 ns to sw…
We consider conductance mapping of the snake-orbits confined along the n-p junction defined in graphene by the electrostatic doping in the quantum Hall regime. We explain the periodicity of conductance oscillations at the magnetic field and the Fermi energy scales by the properties of the n-p junction as a conducting channel. We evaluate the conductance maps for a floating gate scanning the surface of the device. In the quantum Hall conditions the currents flow near the edges of the sample and along the n-p junction. The conductance mapping resolves only the n-p junction and not the edges. The…
We consider a small p-type island defined within n-type graphene nanoribbon induced by potential of a floating electrode. In the quantum Hall conditions the island supports persistent currents localized at the $n-p$ junction. When coupled to the graphene edge the island acts as an Aharonov-Bohm interferometer. We evaluate the electrostatic potential induced by the floating gate within the ribbon near the charge neutrality point and consider equilibration of the currents at both sides of the junction. The incoherent equilibration is introduced by the virtual probes technique. We describe the ev…
The formation of quantum Hall channels inside the bulk of graphene is studied using various contact and gate geometries. p-n junctions are created along the longitudinal direction of samples, and enhanced conductance is observed in the case of bipolar doping due to new conducting channels forming in the bulk, whose position, propagating direction and, in one geometry, coupling to electrodes are determined by the gate-controlled filling factor across the device. This effect could be exploited to probe the behavior and interaction of quantum Hall channels protected against uncontrolled scatterin…
Molecular spintroinic device based on a single-molecule magnet is one of the ultimate goals of semiconductor nanofabrication technologies. It is thus necessary to understand the electron transport properties of a single-molecule magnet junction. Here we study the negative differential conductance and super-Poissonian shot noise properties of electron transport through a single-molecule magnet weakly coupled to two electrodes with either one or both of them being ferromagnetic. We predict that the negative differential conductance and super-Poissonian shot noise, which can be tuned by a gate vo…
We investigate the transport characteristics of monolayer graphene p-n junctions by means of the non-equilibrium Green's function technique. It is shown that thanks to the high interband tunneling of chiral fermions and to a finite bandgap opening when the inversion symmetry of graphene plane is broken, a strong negative-differential-conductance behavior with peak-to-valley ratio as large as a few tens can be achieved even at room temperature. The dependence of this behavior on the device parameters such as the Fermi energy, the barrier height, and the transition length is then discussed.
We study influence of image forces on conductance of ferroelectric tunnel junctions. We show that the influence of image forces is twofold: i) they enhance the electro-resistance effect due to polarization hysteresis in symmetric tunnel junctions at non-zero bias and ii) they produce the electro-resistance effect due to hysteresis of dielectric permittivity of ferroelectric barrier. We study dependence of ferroelectric tunnel junction conductance on temperature and show that image forces lead to strong conductance variation with temperature.
We present a detailed theory of transport through line junctions formed by counterpropagating single-branch fractional-quantum-Hall edge channels having different filling factors. Intriguing transport properties are exhibited when strong Coulomb interactions between electrons from the two edges are present. Such strongly correlated line junctions can be classified according to the value of an effective line-junction filling factor n that is the inverse of an even integer. Interactions turn out to affect transport most importantly for n=1/2 and n=1/4. A particularly interesting case is n=1/4 co…
Feedback-controlled electric breakdown of graphene in air or vacuum is a well-established way of fabricating tunnel junctions, nanogaps, and quantum dots. We show that the method is equally applicable to encapsulated graphene constrictions fabricated using hydrogen silsesquioxane. The silica-like layer left by hydrogen silsesquioxane resist after electron-beam exposure remains intact after electric breakdown of the graphene. We explore the conductance switching behavior that is common in graphene nanostructures fabricated via feedback-controlled breakdown, and show that it can be attributed to…
Motivated by recent experiments, we present here a systematic ab-initio study of the length dependence of the thermal conductance of single-molecule junctions. We make use of a combination of density functional theory with non-equilibrium Green's function techniques to investigate the length dependence of the phonon transport in single alkane chains, contacted with gold electrodes via both thiol and amine anchoring groups. Additionally, we study the effect of the substitution of the hydrogen atoms in the alkane chains by heavier fluorine atoms to form polytetrafluoroethylenes. Our results demo…
The electron transport through the nanotube junctions which connect the different metallic nanotubes by a pair of a pentagonal defect and a heptagonal defect is investigated by Landauer's formula and the effective mass approximation. From our previous calculations based on the tight binding model, it has been known that the conductance is determined almost only by two parameters,i.e., the energy in the unit of the onset energy of more than two channels and the ratio of the radii of the two nanotubes. The conductance is calculated again by the effective mass theory in this paper and a simple an…
A scanning tunnelling microscope has been used to determine the conductance of single molecular wires with the configuration X-bridge-X, X-bridge-Y and Y-bridge-Y (X = thiol terminus and Y = COOH). We find that for molecular wires with mixed functional groups (X-bridge-Y) the single molecule conductance decreases with respect to the comparable symmetric molecules. These differences are confirmed by theoretical computations based on a combination of density functional theory and the non-equilibrium Green functions formalism. This study demonstrates that the apparent contact resistance, as well …
The solid-state structures of organic charge transfer (CT) salts are critical in determining their mode of charge transport, and hence their unusual electrical properties, which range from semiconducting through metallic to superconducting. In contrast, using both theory and experiment, we show here that the conductance of metal | single molecule | metal junctions involving aromatic donor moieties (dialkylterthiophene, dialkylbenzene) increase by over an order of magnitude upon formation of charge transfer (CT) complexes with tetracyanoethylene (TCNE). This enhancement occurs because CT comple…
The helical state is a fundamental prerequisite for many spintronics applications and Majorana zero mode engineering in nanoscopic semiconductors. Its existence in quasi-one-dimensional nanowires was predicted to be detectable as a characteristic reentrant behavior in the conductance, which in a typical two-terminal architecture may be difficult to distinguish from other possible phenomena such as Fabry-Perot oscillations. Here we present an alternative method of helical gap detection free of the mentioned ambiguity, and based on the nonlocal conductance measurements in a three-terminal juncti…
