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arXiv 1608.04486cond-mat.str-el
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Co掺杂CuO中偶极有序的缺失

Absence of dipolar ordering in Co doped CuO

N Vijay Prakash Chaudhary, J. Krishna Murthy, A. Venimadhav

摘要:

采用流动氧气固相法制备了Co掺杂的CuO多晶样品,并对其结构和多铁性进行了研究。结构研究证实了所有样品的单相单斜晶体结构,然而,在Co掺杂的样品中,随着单斜畸变的增加,发现体积减小。对于原始样品,温度相关的磁化强度证实了在213 K和230 K处的两个反铁磁(AFM)转变和频率无关的介电峰,这些AFM转变表明铁电性质。Co掺杂样品的磁化强度显示出高温AFM转变的有序温度的边际增加和低温AFM有序温度的降低。此外,掺杂样品显示出巨大的介电常数,没有铁电性的特征。X射线光电光谱研究揭示了多个价态的Co和Cu的掺杂样品,同时解释了巨大的介电常数和铁电秩序的抑制。

英文摘要:

Polycrystalline CuO samples with Co doping were prepared by solid state method with flowing oxygen condition and examined their structural and multiferroic properties. Structural studies have confirmed single phase monoclinic crystal structure of all samples, however, in Co doped samples a decrease in volume with an increase in monoclinic distortion is found. For pristine sample, temperature dependent magnetization has confirmed two antiferromagnetic (AFM) transitions at 213 K and 230 K and frequency independent dielectric peaks at these AFM transitions suggesting the ferroelectric nature. Magnetization of the Co doped samples has showed a marginal increase in ordering temperature of the high-temperature AFM transition and decrease in low temperature AFM ordering temperature. Further, doped samples have shown giant dielectric constant with no signature of ferroelectricity. The x-ray photoelectric spectroscopy study has revealed multiple valance states for both Co and Cu in the doped samples that simultaneously explain the giant dielectric constant and suppression of ferroelectric order.

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