We consider the problem of keeping an arbitrary state $ρ_s$ out of thermal equilibrium. We find that counter-acting thermalisation using only a resource system which is in a stationary state at the initial time and a system-resource interaction that preserves the global energy is possible if and only if the target state $ρ_s$ is block-diagonal in the eigenbasis of the system's Hamiltonian $H_s.$ As a consequence, we compute the extra work the operator must provide by tuning the resource-system interaction to overcome this constraint. This quantity, which is interpreted as the work needed to preserve the coherences in the state, can be expressed in terms of the target state $ρ_s$ and the thermal equilibrium state $ρ_β,$ and it is proportional to the symmetrized relative entropy between $ρ_s$ and $ρ_β.$
Interaction between a quantum system and its environment can induce stationary coherences -- off-diagonal elements in the reduced system density matrix -- even at equilibrium. This work investigates the ``quantumness'' of such phenomena by examining the ability of classical and semiclassical models to describe equilibrium stationary coherence in the multi-level spin boson (MLSB) model, a common model for light-harvesting systems. A well justified classical harmonic oscillator model is found to fail to capture equilibrium coherence. This failure is attributed to the effective weakness of classi…
We study the steady state of two coupled two-level atoms interacting with a non-equilibrium environment that consists of two heat baths at different temperatures. Specifically, we analyze four cases with respect to the configuration about the interactions between atoms and heat baths. Using secular approximation, the conventional master equation usually neglects steady-state coherence, even when the system is coupled with a non-equilibrium environment. When employing the master equation with no secular approximation, we find that the system coherence in our model, denoted by the off-diagonal t…
We study the steady state of a three-level system in contact with a non-equilibrium environment, which is composed of two independent heat baths at different temperatures. We derive a master equation to describe the non-equilibrium process of the system. For the three level systems with two dipole transitions, i.e., the $Λ$-type and V-type, we find that the interferences of two transitions in a non-equilibrium environment can give rise to non-vanishing steady quantum coherence, namely, there exist non-zero off-diagonal terms in the steady state density matrix (in the energy representation). Mo…
Thermodynamic irreversibility is well characterized by the entropy production arising from non-equilibrium quantum processes. We show that the entropy production of a quantum system undergoing open-system dynamics can be formally split into a term that only depends on population unbalances, and one that is underpinned by quantum coherences. The population unbalances are found to contribute to both an entropy flux and an entropy production rate. The decoherence, on the other hand, contributes only to the entropy production rate. This allows us to identify a genuine quantum contribution to the e…
Heat exchanges are the essence of Thermodynamics. In order to investigate non-equilibrium effects like quantum coherence and correlations in heat flows we introduce the concept of apparent temperature. Its definition is based on the expression of the heat flow between out-of-equilibrium quantum systems. Such apparent temperatures contain crucial information on the role and impact of correlations and coherence in heat exchanges. In particular, both behave as populations, affecting dramatically the population balance and therefore the apparent temperatures and the heat flows. We show how seminal…
We investigate analytically and numerically the steady-state entanglement and coherence of two coupled qubits each interacting with a local boson or fermion reservoir, based on the Bloch-Redfield master equation beyond the secular approximation. We find that there is non-vanishing steady-state coherence in the nonequilibrium scenario, which grows monotonically with the nonequilibrium condition quantified by the temperature difference or chemical potential difference of the two baths. The steady-state entanglement in general is a non-monotonic function of the nonequilibrium condition as well as…
Exploiting the relative entropy of coherence, we isolate the coherent contribution in the energetics of a driven non-equilibrium quantum system. We prove that a division of the irreversible work can be made into a coherent and incoherent part, which provides an operational criterion for quantifying the coherent contribution in a generic non-equilibrium transformation on a closed quantum system. We then study such a contribution in two physical models of a driven qubit and kicked rotor. In addition, we also show that coherence generation is connected to the non-adiabaticity of a processes, for …
The interplay between steering and quantum coherence is studied in a scenario, where two atoms move through an external massless scalar field. We show that just like entanglement, the steering induced coherence of the equilibrium state may increase or decrease with acceleration depending on the initial condition of the state. We also investigate the condition for coherence steerability - as opposed to simple state steerability. Interestingly, we find that the quantum coherence of the equilibrium state cannot be steered, even when the steering induced coherence is non-zero. We argue that under …
The Two Point Measurement scheme for computing the thermodynamic work performed on a system requires it to be initially in equilibrium. The Margenau-Hill scheme, among others, extends the previous approach to allow for a non-equilibrium initial state. We establish a quantitative comparison between both schemes in terms of the amount of coherence present in the initial state of the system, as quantified by the $l_1$-coherence measure. We show that the difference between the two first moments of work, the variances of work and the average entropy production obtained in both schemes can be cast i…
We propose a new dynamical method to connect equilibrium quantum phase transitions and quantum coherence using out-of-time-order correlations (OTOCs). Adopting the iconic Lipkin-Meshkov-Glick and transverse-field Ising models as illustrative examples, we show that an abrupt change in coherence and entanglement of the ground state across a quantum phase transition is observable in the spectrum of multiple quantum coherence (MQC) intensities, which are a special type of OTOC. We also develop a robust protocol to obtain the relevant OTOCs using quasi-adiabatic quenches through the ground state ph…
Coherence arises from the superposition principle, where it plays a central role in quantum mechanics. In [Phys.Rev.Lett.114,210401(2015)], it has been shown that the freezing phenomenon of quantum correlations beyond entanglement, is intimately related to the freezing of quantum coherence (QC). In this paper, we compare the behaviour of entanglement and quantum discord with quantum coherence in two di erent subsystems (optical and mechanical). We use respectively the en-tanglement of formation (EoF) and the Gaussian quantum discord (GQD) to quantify entanglement and quantum discord. Under the…
Non-locality is a fundamental trait of quantum many-body systems, both at the level of pure states, as well as at the level of mixed states. Due to non-locality, mixed states of any two subsystems are correlated in a stronger way than what can be accounted for by considering correlated probabilities of occupying some microstates. In the case of equilibrium mixed states, we explicitly build two-point quantum correlation functions, which capture the specific, superior correlations of quantum systems at finite temperature, and which are directly { accessible to experiments when correlating measur…
The entropy produced when a quantum system is driven away from equilibrium can be decomposed in two parts, one related with populations and the other with quantum coherences. The latter is usually based on the so-called relative entropy of coherence, a widely used quantifier in quantum resource theories. In this paper we argue that, despite satisfying fluctuation theorems and having a clear resource-theoretic interpretation, this splitting has shortcomings. First, it predicts that at low temperatures the entropy production will always be dominated by the classical term, irrespective of the qua…
Recent studies have pointed out the intrinsic dependence of figures of merit of thermodynamic relevance -- such as work, heat and entropy production -- on the amount of quantum coherences that is made available to a system. However, whether coherences hinder or enhance the value taken by such quantifiers of thermodynamic performance is yet to be ascertained. We show that, when considering entropy production generated in a process taking a finite-size bipartite quantum system out of equilibrium through local non-unitary channels, no general monotonicity relationship exists between the entropy p…
Coherent control of self-contained quantum systems offers the possibility to fabricate smallest thermal transistors. The steady coherence created by the delocalization of electronic excited states arouses nonlinear heat transports in non-equilibrium environment. Applying this result to a three-level quantum system, we show that quantum coherence gives rise to negative differential thermal resistances, making the thermal transistor suitable for thermal amplification. The results show that quantum coherence facilitates efficient thermal signal processing and can open a new field in the applicati…
We investigate the behavior in time of the energy current between a quantum spin chain and its surrounding non-Markovian, finite temperature baths, together with its relationship to the coherence dynamics of the system. To be specific, both the system and the baths are assumed to be initially in thermal equilibrium at temperature $T_s$ and $T_b$, respectively. This model plays a fundamental role for the study of quantum system evolution towards thermal equilibrium in an open system. The non-Markovian quantum state diffusion (NMQSD) equation approach is used to calculate the dynamics of the spi…
We established a theoretical framework in terms of the curl flux, population landscape, and coherence for non-equilibrium quantum systems at steady state, through exploring the energy and charge transport in molecular processes. The curl quantum flux plays the key role in determining transport properties and the system reaches equilibrium when flux vanishes. The novel curl quantum flux reflects the degree of non-equilibriumness and the time-irreversibility. We found an analytical expression for the quantum flux and its relationship to the environmental pumping (non-equilibriumness quantified b…
We develop an approach based on stochastic quantum trajectories for an incoherently pumped system of interacting bosons relaxing their energy in a thermal reservoir. Our approach enables the study of the versatile coherence properties of the system. We apply the model to exciton polaritons in a semiconductor microcavity. Our results demonstrate the onset of macroscopic occupation in the lowest-energy mode accompanied by the establishment of both temporal and spatial coherence. We show that temporal coherence exhibits a transition from a thermal to coherent statistics and the spatial coherence …
Coherence is a defining feature of quantum condensates. These condensates are inherently multimode phenomena and in the macroscopic limit it becomes extremely difficult to resolve populations of individual modes and the coherence between them. In this work we demonstrate non-equilibrium Bose-Einstein condensation (BEC) of photons in a sculpted dye-filled microcavity, where threshold is found for $8\pm 2$ photons. With this nanocondensate we are able to measure occupancies and coherences of individual energy levels of the bosonic field. Coherence of individual modes generally increases with inc…
We study the non-equilibrium dynamics of two coupled mechanical oscillators with general linear couplings to two uncorrelated thermal baths at temperatures $T_1$ and $T_2$, respectively. We obtain the complete solution of the Heisenberg-Langevin equations, which reveal a coherent mixing among the normal modes of the oscillators as a consequence of their off-diagonal couplings to the baths. Unique renormalization aspects resulting from this mixing are discussed. Diagonal and off-diagonal (coherence) correlation functions are obtained analytically in the case of strictly Ohmic baths with differe…
Quantum resource manipulation may include an ancillary state called a catalyst, which aids the transformation while restoring its original form at the end, and characterizing the enhancement enabled by catalysts is essential to reveal the ultimate manipulability of the precious resource quantity of interest. Here, we show that allowing correlation among multiple catalysts can offer arbitrary power in the manipulation of quantum coherence. We prove that any state transformation can be accomplished with an arbitrarily small error by covariant operations with catalysts that may create a correlati…
We address open quantum systems out-of-equilibrium as effective quantum probes for the characterisation of their environment. We discuss estimation schemes for parameters driving a de-phasing evolution of the probe and then focus on qubits, establishing a relationship between the quantum Fisher information and the residual coherence of the probe. Finally, we apply our results to the characterisation of the ohmicity parameter of a bosonic environment.
Non-equilibrium physics is a particularly fascinating field of current research. Generically, driven systems are gradually heated up so that quantum effects die out. In contrast, we show that a driven central spin model including controlled dissipation in a highly excited state allows us to distill quantum coherent states, indicated by a substantial reduction of entropy. The model is experimentally accessible in quantum dots or molecules with unpaired electrons. The potential of preparing and manipulating coherent states by designed driving potentials is pointed out.
We explore the properties of steady-state Fano coherences generated in a three-level V-system continuously pumped by polarized incoherent light in the absence of coherent driving. The ratio of the stationary coherences to excited-state populations $\mathcal{C} = (1+\frac{Δ^2}{γ(r+γ)} )^{-1}$ is maximized when the excited-state splitting $Δ$ is small compared to either the spontaneous decay rate $γ$ or the incoherent pumping rate $r$. We demonstrate that an intriguing regime exists where the $\mathcal{C}$ ratio displays a maximum as a function of the dephasing rate $γ_d$. We attribute the surpr…
Single-qubit thermometry presents the simplest tool to measure the temperature of thermal baths with reduced invasivity. At thermal equilibrium, the temperature uncertainty is linked to the heat capacity of the qubit, however the best precision is achieved outside equilibrium condition. Here, we discuss a way to generalize this relation in a non-equilibrium regime, taking into account purely quantum effects such as coherence. We support our findings with an experimental photonic simulation.
The theoretical description of non-equilibrium Bose--Einstein condensate (BEC) is one of the main challenges in modern statistical physics and kinetics. The non-equilibrium nature of BEC makes it impossible to employ the well-established formalism of statistical mechanics. We develop a framework for the analytical description of a non-equilibrium phase transition to BEC that, in contrast to previously developed approaches, takes into account the infinite number of continuously distributed states. We consider the limit of fast thermalization and obtain an analytical expression for the full dens…
Thermal operations are an operational model of non-equilibrium quantum thermodynamics. In the absence of coherence between energy levels, exact state transition conditions under thermal operations are known in terms of a mathematical relation called thermo-majorization. But incorporating coherence has turned out to be challenging, even under the relatively tractable model wherein all Gibbs state-preserving quantum channels are included. Here we find a mathematical generalization of thermal operations at low temperatures, "cooling maps", for which we derive the necessary and sufficient state tr…
Standard thermometry employs the thermalisation of a probe with the system of interest. This approach can be extended by incorporating the possibility of using the non-equilibrium states of the probe, and the presence of coherence. Here, we illustrate how these concepts apply to the single-qubit thermometer introduced by Jevtic et al. by performing a simulation of the qubit-environment interaction in a linear-optical device. We discuss the role of the coherence, and how this affects the usefulness of non-equilibrium conditions. The origin of the observed behaviour is traced back to the propens…
Synchronisation is a collective phenomenon widely investigated in classical oscillators and, more recently, in quantum systems. However, it remains unclear what features distinguish synchronous behaviour in these two scenarios. Recent works have shown that investigating the dynamics of synchronisation in open quantum systems can give insight into this issue. Here we study transient synchronisation in a bio-inspired vibronic dimer, where the dynamics of electronic excitation is mediated by coherent interactions with intramolecular vibrational modes. We show that the synchronisation dynamics of …
Dynamics of Steered Quantum Coherence and Magic Resource under Sudden Quench
Buein Zahra Technical University（布因扎赫拉理工大学）；Ruhr-Universität Bochum（波鸿鲁尔大学）；Beijing Institute of Mathematical Sciences and Applications (BIMSA)（北京数学科学应用研究所）；Institute for Advanced Studies in Basic Sciences (IASBS)（基础科学高等研究院）；Institute for Research in Fundamental Sciences (IPM)（基本科学研究院）；University of Gothenburg（哥德堡大学）
We study the role of the initial quantum coherence in coherent processes generated by an external control of some parameters by looking on the thermodynamic work done. We start by taking in exam an active state and we isolate the contribution to the ergotropy coming from the quantum coherence among the energy eigenstates. It is shown to be related to the quantum relative entropy of coherence through an inequality which involves the completely passive state connected to the initial state. Finally, we extend the analysis to a general out-of-equilibrium process and we show how to take in account …
We present a model for an autonomous quantum thermal machine comprised of two qubits capable of manipulating and even amplifying the local coherence in a non-degenerate external system. The machine uses only thermal resources, namely, contact with two heat baths at different temperatures, and the external system has a non-zero initial amount of coherence. The method we propose allows for an interconversion between energy, both work and heat, and coherence in an autonomous configuration working in out-of-equilibrium conditions. This model raises interesting questions about the role of fundament…
Impact of quantum coherence on the dynamics and thermodynamics of quenched free fermions coupled to a localized defect
Istituto Nazionale di Ottica del Consiglio Nazionale delle Ricerche (CNR-INO)（意大利国家光学研究所）；European Laboratory for Non-linear Spectroscopy（欧洲非线性光谱学实验室）；Università di Firenze（佛罗伦萨大学）；Física Teòrica: Informació i Fenòmens Quàntics, Departament de Física, Universitat Autònoma de Barcelona（巴塞罗那自治大学物理系理论物理、信息与量子现象部门）；Centre for Quantum Materials and Technology, School of Mathematics and Physics, Queen’s University Belfast（贝尔法斯特女王大学数学与物理学院量子材料与技术中心）；Department of Physics, University of Trieste（的里雅斯特大学物理系）
Quantum coherences are paramount resources for applications, such as quantum-enhanced light-harvesting or quantum computing, which are fragile against environmental noise. We here derive generalized quantum master equations using perturbation theory in order to describe the effective ensemble-averaged time-evolution of finite-size quantum systems subject to static noise on all time scales. We then analyse the time-evolution of the coherences under energy broadening noise in a variety of systems characterized by both short and long-range interactions, by strongly correlated and fully uncorrelat…
We introduce and study a class of models of free fermions hopping between neighbouring sites with random Brownian amplitudes. These simple models describe stochastic, diffusive, quantum, unitary dynamics. We focus on periodic boundary conditions and derive the complete stationary distribution of the system. It is proven that the generating function of the latter is provided by the Harish-Chandra-Itzykson-Zuber integral which allows us to access all fluctuations of the system state. The steady state is characterized by non trivial correlations which have a topological nature. Diagrammatic tools…
