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arXiv 1408.3480cond-mat.mtrl-sci
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石墨炔-金属接触和石墨炔晶体管

Graphdiyne-metal contacts and graphdiyne transistors

Yuanyuan Pan, Yangyang Wang, Lu Wang, Hongxia Zhong, Ruge Quhe, Zeyuan Ni, Meng Ye, Wai-Ning Mei, Junjie Shi, Wanlin Guo, Jinbo Yang, Jing Lu

摘要:

石墨二炔是在金属表面制备的,用它制造器件也不可避免地涉及与金属的接触。采用色散修正的密度泛函理论,首次系统地研究了石墨炔与一系列金属(Al,Ag,Cu,Au,Ir,Pt,Ni,Pd)的界面性质.石墨二炔与Al、Ag和Cu处于n型欧姆或准欧姆接触,而它与Au(在源极/漏极界面处)、Pd、Pt、Ni和Ir(在源极/漏极-沟道界面处)处于肖特基接触,分别具有0.39、0.21(n型)、0.30、0.41和0.45(p型)eV的高肖特基势垒高度。用量子输运方法模拟了铝电极石墨炔场效应晶体管(FET)。该器件在10 nm沟道长度下具有高达104的开关比和1.3 × 104 mA/mm的大通态电流。这为石墨烯在高性能纳米器件中的应用开辟了新的前景。

英文摘要:

Graphdiyne is prepared on metal surface, and making devices out of it also inevitably involves contact with metals. Using density functional theory with dispersion correction, we systematically studied for the first time the interfacial properties of graphdiyne contacting with a series of metals (Al, Ag, Cu, Au, Ir, Pt, Ni, and Pd). Graphdiyne is in an n-type Ohmic or quasi-Ohmic contact with Al, Ag, and Cu, while it is in a Schottky contact with Au (at source/drain interface), Pd, Pt, Ni, and Ir (at source/drain-channel interface), with high Schottky barrier heights of 0.39, 0.21 (n-type), 0.30, 0.41, and 0.45 (p-type) eV, respectively. A graphdiyne field effect transistor (FET) with Al electrodes is simulated by using quantum transport calculations. This device exhibits an on-off ratio up to 104 and a very large on-state current of 1.3 * 104 mA/mm in a 10 nm channel length. Thus, a new prospect is opened up for graphdiyne in high performance nanoscale devices.

机构、总结、中文摘要均由AI分析而来,可能存在错误,请以论文正文为准。

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