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arXiv 1407.5864cond-mat.mtrl-sci
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${\rm Fe}_2{\rm P}$单晶一级铁磁相变的热力学

Thermodynamics around the First-Order Ferromagnetic Phase Transition of ${\rm Fe}_2{\rm P}$ Single Crystals

M. Hudl, D. Campanini, L. Caron, V. Höglin, M. Sahlberg, P. Nordblad, A. Rydh

摘要:

实验研究了${\rm Fe}_2{\rm P}$单晶在$T_{\rm C} = 217 \,{\rm K}$的一级顺磁(PM)到铁磁(FM)相变附近的比热和热力学。相对于晶轴的磁场的大小和方向决定了推导出的H-T相图。显着不同的相位轮廓得到平行和垂直于晶体的$c$轴的字段。在平行场中,FM状态是稳定的,而在垂直场中,相变被分成两个,中间FM相位,其中没有沿$c$轴的自发磁化。零场转变显示了一阶转变的教科书示例,其在加热和冷却时具有不同的相稳定性限制。由于${\rm Fe}_2{\rm P}$是一类具有优异磁热性能的化合物的母体材料,因此这些结果具有特殊的意义。

英文摘要:

The specific heat and thermodynamics of ${\rm Fe}_2{\rm P}$ single-crystals around the first order paramagnetic (PM) to ferromagnetic (FM) phase transition at $T_{\rm C} = 217 \,{\rm K}$ are empirically investigated. The magnitude and direction of the magnetic field relative to the crystal axes govern the derived H-T phase diagram. Strikingly different phase contours are obtained for fields applied parallel and perpendicular to the $c$-axis of the crystal. In parallel fields, the FM state is stabilized, while in perpendicular fields, the phase transition is split into two, with an intermediate FM phase where there is no spontaneous magnetization along the $c$-axis. The zero-field transition displays a text-book example of a first order transition with different phase stability limits on heating and cooling. The results have special significance since ${\rm Fe}_2{\rm P}$ is the parent material to a family of compounds with outstanding magnetocaloric properties.

机构、总结、中文摘要均由AI分析而来,可能存在错误,请以论文正文为准。

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