We investigate the velocity dependence of kinetic friction with a model which makes minimal assumptions on the actual mechanism of friction so that it can be applied at many scales provided the system involves multi-contact friction. Using a recently developed master equation approach we investigate the influence of two concurrent processes. First, at a nonzero temperature thermal fluctuations allow an activated breaking of contacts which are still below the threshold. As a result, the friction force monotonically increases with velocity. Second, the aging of contacts leads to a decrease of the friction force with velocity. Aging effects include two aspects: the delay in contact formation and aging of a contact itself, i.e., the change of its characteristics with the duration of stationary contact. All these processes are considered simultaneously with the master equation approach, giving a complete dependence of the kinetic friction force on the driving velocity and system temperature, provided the interface parameters are known.
The earthquake-like model with a continuous distribution of static thresholds is used to describe the properties of solid friction. The evolution of the model is reduced to a master equation which can be solved analytically. This approach naturally describes stick-slip and smooth sliding regimes of tribological systems within a framework which separates the calculation of the friction force from the studies of the properties of the contacts.
At the mesoscale friction occurs through the breaking and formation of local contacts. This is often described by the earthquake-like model which requires numerical studies. We show that this phenomenon can also be described by a master equation, which can be solved analytically in some cases and provides an efficient numerical solution for more general cases. We examine the effect of temperature and aging of the contacts and discuss the statistical properties of the contacts for different situations of friction and their implications, particularly regarding the existence of stick-slip.
The contribution of sliding-induced, atomic-scale instabilities to the kinetic friction force is investigated by molecular dynamics. For this purpose, we derive a relationship between the kinetic friction force $F_{\rm k}$ and the non-equilibrium velocity distribution $P(v)$ of the lubricant particles. $P(v)$ typically shows exponential tails, which cannot be described in terms of an effective temperature. It is investigated which parameters control the existence of instabilities and how they affect $P(v)$ and hence $F_{\rm k}$. The effects of the interfaces' dimensionality, lubricant coverage…
Within the framework of a Boltzmann-Lorentz equation, we analyze the dynamics of a granular rotor immersed in a bath of thermalized particles in the presence of a frictional torque on the axis. In numerical simulations of the equation, we observe two scaling regimes at low and high bath temperatures. In the large friction limit, we obtain the exact solution of a model corresponding to asymptotic behavior of the Boltzmann-Lorentz equation. In the limit of large rotor mass and small friction, we derive a Fokker-Planck equation for which the exact solution is also obtained.
We extend quantum kinetic theory to deal with a strongly Bose-condensed atomic vapor in a trap. The method assumes that the majority of the vapor is not condensed, and acts as a bath of heat and atoms for the condensate. The condensate is described by the particle number conserving Bogoliubov method developed by one of the authors. We derive equations which describe the fluctuations of particle number and phase, and the growth of the Bose-Einstein condensate. The equilibrium state of the condensate is a mixture of states with different numbers of particles and quasiparticles. It is not a quant…
Master equations define the dynamics that govern the time evolution of various physical processes on lattices. In the continuum limit, master equations lead to Fokker-Planck partial differential equations that represent the dynamics of physical systems in continuous spaces. Over the last few decades, nonlinear Fokker-Planck equations have become very popular in condensed matter physics and in statistical physics. Numerical solutions of these equations require the use of discretization schemes. However, the discrete evolution equation obtained by the discretization of a Fokker-Planck partial di…
We investigate a mechanism of the appearance of kinetic friction in granular materials. We consider a small number of intervening inelastic particles between two rough surfaces as one of the simplest dynamical models to study granular friction. The resistance force applied to the upper surface is numerically calculated. We find that the resistance force F(t) is scaled as F'(vt) for a small pulling velocity v. The time average F_0=<F(t)> in the limit v->0 is not zero owing to the mutual collisions between the intervening particles. The nonzero F_0 implies the appearance of kinetic friction in t…
We present first elements of kinetic theory appropriate to the inhomogeneous phase of the HMF model. In particular, we investigate the case of strongly inhomogeneous distributions for $T\to 0$ and exhibit curious behaviour of the force auto-correlation function and friction coefficient. The temporal correlation function of the force has an oscillatory behaviour which averages to zero over a period. By contrast, the effects of friction accumulate with time and the friction coefficient does not satisfy the Einstein relation. On the contrary, it presents the peculiarity to increase linearly with …
The path integral approach offers not only an exact expression for the non- equilibrium dynamics of dissipative quantum systems, but is also a convenient starting point for perturbative treatments. An alternative way to explore the influence of friction in the quantum realm is based on master equations which require, however, in one or the other aspect approximations. Here it is discussed under which conditions and limitations Markovian master equations can be derived from exact path integrals thus providing a firm basis for their applicability.
We perform large-scale molecular dynamics simulations to study heated granular fluids in three dimensions. Granular particles dissipate their kinetic energy due to solid frictional interaction with other particles. The velocity of each particle is perturbed by a uniformly-distributed random noise, which mimics the heating. At the early stage of evolution, the kinetic energy of the system decays with time and reaches a steady state at a later stage. The velocity distribution in the steady state shows a non-Gaussian distribution. This has been characterized by using the Sonine polynomial expansi…
The melting of ultrathin lubricant film is studied by friction between atomically flat surfaces. The fluctuations of lubricant temperature are taken into account defined by Ornstein-Uhlenbeck process. The phase diagrams and portraits are calculated for the cases of second-order and first-order transitions -- the melting of amorphous and crystalline lubricants. It is shown that in the first case the stick-slip friction domain appears, dividing the regions of dry and sliding friction. In the second case the three stick-slip friction domains arise characterized by transitions between dry, metasta…
We investigate how the time evolution of different kinetic Ising models depends on the initial conditions of the dynamics. To this end we consider the simultaneous evolution of two identical systems subjected to the same thermal noise. We derive a master equation for the time evolution of a joint probability distribution of the two systems. This equation is then solved within an effective-field approach. By analyzing the fixed points of the master equation and their stability we identify regular and chaotic phases.
We review and complete the existing literature on the kinetic theory of spatially homogeneous systems with long-range interactions taking collective effects into account. The evolution of the system as a whole is described by the Lenard-Balescu equation which is valid in a weak coupling approximation. When collective effects are neglected it reduces to the Landau equation and when collisions (correlations) are neglected it reduces to the Vlasov equation. The relaxation of a test particle in a bath is described by a Fokker-Planck equation involving a diffusion term and a friction term. For a th…
In the framework of a field theoretic model obtained by second quantization of Doi-type master equation, we investigate the effects of random sources and sinks on the reaction kinetics in the master-equation description. We show that random sources and sinks significantly affect the asymptotic behavior of the model and identify two universality classes when describing them using scaling analysis. We compare the results with the Langevin-equation description of the same process.
Based on the trajectories of the separation between water molecule pairs from MD simulations, we investigate the bond breakage dynamics in bulk water. From the spectrum of mean first-passage times, the Fokker-Planck equation allows us to derive the diffusivity profile along the separation coordinate and thus to unambiguously disentangle the effects of free-energy and local friction on the separation kinetics. For tightly coordinated water the friction is six times higher than in bulk, which can be interpreted in terms of a dominant reaction path that involves additional orthogonal coordinates.
The master equation for 12-monomer lattice heteropolymers is solved numerically and the time evolution of the occupancy of the native state is determined. At low temperatures, the median folding time follows the Arrhenius law and is governed by the longest relaxation time. For good folders, significant kinetic traps appear in the folding funnel whereas for bad folders, the traps also occur in non-native energy valleys.
A covariant Fokker-Planck type equation for a simple gas and an equation for the Brownian motion are derived from a relativistic kinetic theory based on the Boltzmann equation. For the simple gas the dynamic friction four-vector and the diffusion tensor are identified and written in terms of integrals which take into account the collision processes. In the case of Brownian motion, the Brownian particles are considered as non-relativistic whereas the background gas behaves as a relativistic gas. A general expression for the semi-relativistic viscous friction coefficient is obtained and the part…
A deterministic theory describing the behavior of an ultrathin lubricant film between two atomically-smooth solid surfaces is proposed. For the description of lubricant state the parameter of excess volume arising due to chaotization of solid medium structure in the course of melting is introduced. Thermodynamic and shear melting is described consistently. Dependences of friction force on temperature of lubricant, shear velocity of rubbing surfaces, and pressure upon surfaces are analyzed. Within the framework of a simple tribological model the stick-slip mode of friction, when the lubricant p…
Quantum Brownian motion in the strong friction limit is studied based on the exact path integral formulation of dissipative systems. In this limit the time-nonlocal reduced dynamics can be cast into an effective equation of motion, the quantum Smoluchowski equation. For strongly condensed phase environments it plays a similar role as master equations in the weak coupling range. Applications for chemical, mesoscopic, and soft matter systems are discussed and reveal the substantial role of quantum fluctuations.
We analyze an ideal gas like model of a trading market with quenched random saving factors for its agents and show that the steady state income ($m$) distribution $P(m)$ in the model has a power law tail with Pareto index $ν$ exactly equal to unity, confirming the earlier numerical studies on this model. The analysis starts with the development of a master equation for the time development of $P(m)$. Precise solutions are then obtained in some special cases.
In this paper the conditions are investigated for the occurrence of the so-called macroscopic irreversibility property and the related phenomenon of decay to kinetic equilibrium which may characterize the $1-$body probability density function (PDF) associated with hard-sphere systems. The problem is set in the framework of the axiomatic "ab initio" approach to classical statistical mechanics recently developed [Tessarotto \textit{et al}., 2013-2017] and the related establishment of an exact kinetic equation realized by Master equation for the same kinetic PDF. As shown in the paper the task in…
We propose a general stochastic formalism for describing the evolution of chemical reactions involving a finite number of molecules. This approach is consistent with the statistical analysis based on the Chemical Master Equation, and provides the formal setting for the existing algorithmic approaches (Gillespie algorithm). Some practical advantages of this formulation are addressed, and several examples are discussed pointing out the connection with quantum transitions (radiative interactions).
We present a kinetic theory for Bose-Einstein condensation of a weakly interacting atomic gas in a trap. Starting from first principles, we establish a Markovian kinetic description for the evolution towards equilibrium. In particular, we obtain a set of self-consistent master equations for mean fields, normal densities, and anomalous fluctuations. These kinetic equations generalize the Gross-Pitaevskii mean-field equations, and merge them consistently with a quantum-Boltzmann equation approach.
A nonlinear master equation is derived, reflecting properly the entropy of open quantum systems. In contrast to linear alternatives, its equilibrium solution is exactly the canonical Gibbs density matrix. The corresponding nonlinear equation for the Wigner function accounts rigorously for the thermo-quantum entropy. It reduces at large friction to the Smoluchowski-Bohm equation in the coordinate subspace, which reflects the stochastic Langevin-Bohm dynamics. The previously derived Maxwell-Heisenberg relation for the nonequilibrium momentum dispersion of quantum Brownian particles is confirmed …
We present a general method to produce well-conditioned continuum reaction-drift-diffusion equations directly from master equations on a discrete, periodic state space. We assume the underlying data to be kinetic Monte Carlo models (i.e., continuous-time Markov chains) produced from atomic sampling of point defects in locally periodic environments, such as perfect lattices, ordered surface structures or dislocation cores, possibly under the influence of a slowly varying external field. Our approach also applies to any discrete, periodic Markov chain. The analysis identifies a previously omitte…
The conditions for the occurrence of the so-called macroscopic irreversibility property and the related phenomenon of decay to kinetic equilibrium which may characterize the 1-body probability density function (PDF) associated with hard-sphere systems are investigated. The problem is set in the framework of the axiomatic "ab initio" theory of classical statistical mechanics developed recently and the related establishment of an exact kinetic equation realized by the Master equation for the same kinetic PDF. As shown in the paper the task involves the introduction of a suitable functional of th…
The Boltzmann kinetic equation is obtained from an integro-differential master equation that describes a stochastic dynamics in phase space of an isolated thermodynamic system. The stochastic evolution yields a generation of entropy, leading to an increase of Gibbs entropy, in contrast to a Hamiltonian dynamics, described by the Liouville equation, for which the entropy is constant in time. By considering transition rates corresponding to collisions of two particles, the Boltzmann equation is attained. When the angle of the scattering produced by collisions is small, the master equation is sho…
A tribological system consisting of two contacting blocks has been considered. One of them is arranged between two springs, the other is driven periodically. The kinetics of the system has been studied in the boundary friction mode, when an ultrathin lubricant film is contained between the atomically smooth surfaces. In order to describe the film state, the expression for the free energy density is used in the form of an expansion in a power series in the order parameter, the latter being reduced to the shear modulus of a lubricant. The stick-slip mode is shown to be realized in a wide range o…
We present a detailed study of the kinetic cluster growth process during gelation of weakly attractive colloidal particles by means of experiments on critical Casimir attractive colloidal systems, simulations and analytical theory. In the experiments and simulations, we follow the mean coordination number of the particles during the growth of clusters to identify an attractive-strength independent cluster evolution as a function of mean coordination number. We relate this cluster evolution to the kinetic attachment and detachment rates of particles and particle clusters. We find that single-pa…
A dilute gas of particles with short range interactions is considered in a shearing stationary state. A Gaussian thermostat keeps the total kinetic energy constant. For infinitely many particles it is shown that the thermostat becomes a friction force with constant friction coefficient. For finite number of particles N, the fluctuations around this constant are of order one over the square root of N, and distributed approximately Gaussian with deviations for large fluctuations. These deviations prohibit a derivation of fluctuation-dissipation relations far from equilibrium, based on the Fluctu…
A self-consistent and universal description of friction and diffusion for Brownian particles (grains) in different systems, as a gas with Boltzmann collisions, dusty plasma with ion absorption by grains, and for active particles (e.g., cells in biological systems) is suggested on the basis of the appropriate Fokker-Planck equation. Restrictions for application of the Fokker-Planck equation to the problem of velocity-dependent friction and diffusion coefficients are found. General description for this coefficient is formulated on the basis of master equation. Relation of the diffusion coefficie…
The two-body stochastic dealer model is revisited to provide an exact solution to the average order-book profile using the kinetic approach. The dealer model is a microscopic financial model where individual traders make decisions on limit-order prices stochastically and then reach agreements on transactions. In the literature, this model was solved for several cases: an exact solution for two-body traders $N=2$ and a mean-field solution for many traders $N\gg 1$. Remarkably, while kinetic theory plays a significant role in the mean-field analysis for $N\gg 1$, its role is still elusive for th…
A master equation with a Lindblad structure is derived, which describes the interaction of a test particle with a macroscopic system and is expressed in terms of the operator valued dynamic structure factor of the system. In the case of a free Fermi or Bose gas the result is evaluated in the Brownian limit, thus obtaining a single generator master equation for the description of quantum Brownian motion in which the correction due to quantum statistics is explicitly calculated. The friction coefficients for Boltzmann and Bose or Fermi statistics are compared.
The dynamics of two 12-monomer heteropolymers on the square lattice is studied exactly within the master equation approach. The time evolution of the occupancy of the native state is determined. At low temperatures, the median folding time follows the Arrhenius law and is governed by the longest relaxation time. For good folders, significant kinetic traps appear in the folding funnel whereas for bad folders, the traps also occur in non-native energy valleys.
The model of inelastic Maxwell particles (IMP) allows one to derive some exact results which show the strong influence of inelasticity on the nonequilibrium properties of a granular gas. The aim of this work is to propose a simple model kinetic equation that preserves the most relevant properties of the Boltzmann equation (BE) for IMP and reduces to the BGK kinetic model in the elastic limit. In the proposed kinetic model the collision operator is replaced by a relaxation-time term toward a reference Maxwellian distribution plus a term representing the action of a friction force. It contains t…
We show that the fragility $m$, the steepness of the viscosity and relaxation time close to the vitrification, increases with the degree of elastic softening, i.e. the decrease of the elastic modulus with increasing temperature, in universal way. This provides a novel connection between the thermodynamics, via the modulus, and the kinetics. The finding is evidenced by numerical simulations and comparison with the experimental data of glassformers with widely different fragilities ($33 \le m \le 115$), leading to a fragility-independent elastic master curve extending over eighteen decades in vi…
