arXivDaily arXiv每日学术速递 周一至周五更新
arXiv 1104.4080cond-mat.mes-hallcond-mat.mtrl-sci
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石墨烯能带结构对外界周期性扰动的稳定性;石墨烯上的Na

The stability of graphene band structures against an external periodic perturbation; Na on Graphene

Choongyu Hwang, Sunyoung Shin, Seon-Myeong Choi, Namdong Kim, Sanghun Uhm, Hyosang Kim, Chan-cuk Hwang, Doyoung Noh, Seung-Hoon Jhi, Jinwook Chung

摘要:

我们报告说,石墨烯的$π$带敏感地改变作为由钠引起的外部电位的函数,特别是当电位在低温下变得周期性时。我们利用同步辐射光子角分辨光电子能谱测量了6 H-SiC(0001)衬底上石墨烯层的能带结构。随着Na剂量的增加,$π$谱带在85 K下迅速扩散到背景中,而在室温下其光谱强度显著增强。一个新的抛物线带中心在$k\sim$ 1.15 $^{-1}$也形成附近的费米能与Na在85 K,而没有这样的带观察到在RT。这种变化的能带结构被发现是可逆的温度。基于第一性原理计算的分析表明,石墨烯的$π$能带的变化主要由Na诱导的电势驱动,特别是在低温下,由于结晶的Na覆盖层,电势变得周期性。新的抛物线带变成了下面的缓冲层的$π$带,部分地被来自Na吸附原子的电荷转移填充。在RT下Na吸附原子的跳跃速率增加了五个数量级,阻止了这种电荷转移,这解释了在RT下没有新带。

英文摘要:

We report that the $π$ band of graphene sensitively changes as a function of an external potential induced by Na especially when the potential becomes periodic at low temperature. We have measured the band structures from the graphene layers formed on the 6H-SiC(0001) substrate using angle-resolved photoemission spectroscopy with synchrotron photons. With increasing Na dose, the $π$ band appears to be quickly diffused into background at 85 K whereas it becomes significantly enhanced its spectral intensity at room temperature (RT). A new parabolic band centered at $k\sim$1.15 Å$^{-1}$ also forms near Fermi energy with Na at 85 K while no such a band observed at RT. Such changes in the band structure are found to be reversible with temperature. Analysis based on our first principles calculations suggests that the changes of the $π$ band of graphene be mainly driven by the Na-induced potential especially at low temperature where the potential becomes periodic due to the crystallized Na overlayer. The new parabolic band turns to be the $π$ band of the underlying buffer layer partially filled by the charge transfer from Na adatoms. The five orders of magnitude increased hopping rate of Na adatoms at RT preventing such a charge transfer explains the absence of the new band at RT.

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