A radio frequency um-jet plasma source is studied using He/O2 mixture. This um-jet can be used for different applications as a source of chemical active species e.g. oxygen atoms, molecular metastables and ozone. Using absolutely-calibrated optical emission spectroscopy and numerical simulation, the gas temperature in active plasma region and plasma parameters (electron density and electron distribution function) are determined. Concentrations of oxygen atoms and ozone in the plasma channel and in the effluent of the plasma source are measured using emission and absorption spectroscopy. To interpret the measured spatial distributions, the steady-state species' concentrations are calculated using determined plasma parameters and gas temperature. At that the influence of the surface processes and gas flow regime on the loss of the active species in the plasma source are discussed. The measured spatial distributions of oxygen atom and ozone densities are compared with the simulated ones.
Plasma jets belong to the category remote plasma. This means that the discharge conditions and the chemical effect on samples can be tuned separately, this being a big advantage compared to standard low-pressure reactors. The inductive coupling brings the advantage of a pure and dense plasma. The microwave excitation allows furthermore miniaturization and generation of low temperature plasmas. The present paper shows the state of the art of the research on such sources, demonstrating their work up to atmospheric pressure.
We performed self-consistent modeling of the atmospheric-pressure plasmas produced by arc discharges. Special numerical procedure for coupling of the plasma current, emission current, ion current, sheath voltage drop, heat fluxes at plasma-electrode interfaces was developed and implemented into the ANSYS CFX code. Validation of the simulation results is performed through comparison of simulation results with the previously available experimental data obtained by a range of various plasma diagnostics.
Molecular dynamics simulations are used to model ion and neutral temperature evolution in partially-ionized atmospheric pressure plasma at different ionization fractions. Results show that ion-ion interactions are strongly coupled at ionization fractions as low as 10^-5 and that the temperature evolution is influenced by effects associated with the strong coupling. Specifically, disorder-induced heating is found to rapidly heat ions on a timescale of the ion plasma period (~10s ps) after an ionization pulse. This is followed by the collisional relaxation of ions and neutrals, which cools ions …
Inactivation of microorganisms on sensitive surfaces by cold atmospheric plasma (CAP) is one major application in the field of plasma medicine because it provides a simple and effective way to sterilize heat-sensitive materials. Therefore, one has to know whether plasma treatment affects the treated surfaces, and thus causes long-term surface modifications. In this contribution, the effect of cold atmospheric Surface Micro-Discharge (SMD) plasma on different materials and its sporicidal behavior was investigated. Hence, different material samples (stainless steel, different polymers and glass)…
This work investigates the influence of pulse modulation frequency ranging from 50 Hz- 10 kHz on the helium RF atmospheric pressure plasma jet's fundamental characteristics. The impact of modulation frequency on plasma jet discharge behavior, geometrical variation, reactive species emission, and plasma parameters (gas temperature Tg, electron excitation temperature Texc, and electron density (ne) are studied using various diagnostics such as optical imaging, emission spectra, and thermal diagnostics. From the experiments, it is observed that operating the plasma jet at low pulse modulation fre…
Optical diagnostics and mass spectrometry on the afterglow of an atmospheric pressure Ar/O$_2$ radiofrequency plasma used for polymer surface treatment
A microwave discharge of atmospheric pressure, maintained by focused CW radiation of a 24-GHz gyrotron in an argon flow in an external air atmosphere, was investigated. The electron temperature was determined by the current-voltage curve of a dual Langmuir probe placed in a plasma torch. The electron temperature was also estimated from plasma emission spectra within the framework of a coronal plasma model. The obtained values of the electron temperature coincide within the measurement accuracy. Also, the electron temperature is many times higher than the gas temperature. This fact allows us to…
Atmospheric pressure plasmas are effective sources for reactive species, making them applicable for industrial and biomedical applications. We quantify ground-state densities of key species, atomic oxygen (O) and hydrogen (H), produced from admixtures of water vapour (up to 0.5%) to the helium feed gas in a radio-frequency-driven plasma at atmospheric pressure. Absolute density measurements, using two-photon absorption laser induced fluorescence, require accurate effective excited state lifetimes. For atmospheric pressure plasmas, picosecond resolution is needed due to the rapid collisional de…
The article reports the excitation of a helical argon atmospheric pressure plasma jet using a pulse modulated 13.56 MHz radiofrequency (RF) power source. This helical structure is observed in open ambient air which is far different from the conventional conical shape. This helical structure originates due to the periodic pressure variation in the discharge region caused by pulse modulated RF (2 kHz modulation frequency (fp)) and propagates downstream into the ambient air. The geometrical characteristics of the observed structure are explored using optical imaging. Moreover, the influence of va…
The energy balance of a plasma holds fundamental information not only about basic plasma physics, but it is also important for tailoring plasmas to specific applications. Especially RF-driven atmospheric pressure plasma jets (APPJs) operated in helium with oxygen admixture have high application potential in industry and medicine. Many types of plasma jets have been studied up to now, leading to the challenge how to compare results from various sources. We have developed a method for measuring the power deposited in the plasma as the parameter to compare different sources and gas mixtures with …
In order to optimize the parameters of the plasma plume for atmospheric pressure plasma applications such as biological and industrial applications, it is highly necessary to thoroughly understand its characteristics. In this paper, various diagnostic techniques are discussed to characterize the atmospheric pressure plasma plume. The major emphasis of this work is to utilize possibly simple methods, low complexity in post data analysis and obtain in-situ information. The parameters of the plasma plume such as spatial variation of gas temperature, electron excitation temperature, plume velocity…
Nanoparticles grown in a plasma are used to visualize the process of film deposition in a pulsed radio-frequency (rf) atmospheric pressure glow discharge. Modulating the plasma makes it possible to successfully prepare porous TiO2 films. We study the trapping of the particles in the sheath during the plasma-on phase and compare it with numerical simulations. During the plasma-off phase, the particles are driven to the substrate by the electric field generated by residual ions, leading to the formation of porous TiO2 film. Using video microscopy, the collective dynamics of particles in the whol…
Hydrogen is largely produced via natural gas reforming or electrochemical water-splitting, leaving organic solid feedstocks under-utilized. Plasma technology powered by renewable electricity can lead to the sustainable upcycling of plastic waste and production of green hydrogen. In this work, low-temperature atmospheric pressure plasma reactors based on transferred arc (transarc) and gliding arc (glidarc) discharges are designed, built, and characterized to produce hydrogen from low-density polyethylene (LDPE) as a model plastic waste. Experimental results show that hydrogen production rate an…
A two-dimensional fluid model is used to investigate the electron heating dynamics and the production of neutral species in a capacitively coupled radio-frequency micro atmospheric pressure helium plasma jet -- specifically the COST jet -- with a small oxygen admixture. Electron heating mode transitions are found to be induced by varying the driving voltage amplitude and the O$_2$ concentration numerically and experimentally. The helium metastable density, and the charged species densities are highly relevant to the electron heating dynamics. By analyzing the creation and destruction mechanism…
Understanding the formation and long-timescale evolution of atmospheric plasmas produced by ultrashort, long wavelength IR (LWIR) pulses is an important but partially understood problem. Of particular interest are plasmas produced in air with a peak laser intensity $\sim$10$^{12}$ W/cm$^2$, the so-called clamping intensity observed in LWIR atmospheric guiding experiments where tunneling and multi-photon ionization operative at near-IR or shorter wavelengths are inoperative. We find that avalanche breakdown on the surface of aerosol (dust) particles can act to seed the breakdown of air observed…
This paper studies a continuous atmospheric-pressure discharge maintained by focused subterahertz radiation of a 263 GHz gyrotron. A plasma torch propagating towards microwave radiation was sustained on an argon flow exiting a metal gas tube in the surrounding atmosphere of air. Using a high-speed camera, the spatial structure of the torch was studied and the temporal dynamics on timescales of the order of 20 ns was examined. The emission spectra of the optical wavelength range were used to estimate the excitation temperature of argon atoms and electron density. It was shown that a discharge o…
In-depth diffusion of oxygen into LDPE exposed to an Ar--O2 atmospheric post-discharge: a complementary approach between AR-XPS and Tof-SIMS techniques
Space-resolved characterization of high frequency atmospheric-pressure plasma in nitrogen applying optical emission spectroscopy and numerical simulation
The characteristics of atmospheric-pressure microdischarges excited by nanosecond high-voltage pulses are investigated in helium-nitrogen mixtures, as a function of the parameters of the excitation voltage pulses. In particular, cases of single-pulse excitation, unipolar and bipolar double-pulse excitation are studied, at different pulse durations, voltage amplitudes, and delay times (for the case of double-pulse excitation). Our investigations are carried out with a particle-simulation code that also comprises the treatment of the VUV resonance radiation in the plasma. The simulations allow g…
Radio-frequency-driven atmospheric pressure plasma jets (RF APPJs) play an essential role in many technological applications. This work studies the characteristics of these discharges in the so-called non-neutral regime where the conventional structure of a quasi-neutral bulk and an electron depleted sheath does not develop, and the electrons are instead organized in a drift-soliton-like structure that never reaches quasi-neutrality. A hybrid particle-in-cell/Monte Carlo collisions (PIC/MCC) simulation is set up, which combines a fully kinetic electron model via the PIC/MCC algorithm with a dr…
