This brief review discusses electronic properties of mesoscopic graphene-based structures. These allow controlling the confinement and transport of charge and spin; thus, they are of interest not only for fundamental research, but also for applications. The graphene-related topics covered here are: edges, nanoribbons, quantum dots, $pn$-junctions, $pnp$-structures, and quantum barriers and waveguides. This review is partly intended as a short introduction to graphene mesoscopics.
In graphene, the valleys represent spin-like quantities and can act as a physical resource in valley-based electronics to novel quantum computation schemes. Here we demonstrate a direct route to tune and read the valley quantum states of disordered graphene by measuring the mesoscopic conductance fluctuations. We show that the conductance fluctuations in graphene at low temperatures are reduced by a factor of four when valley triplet states are gapped in the presence of short range potential scatterers at high carrier densities. We also show that this implies a gate tunable universal symmetry …
We show a dramatic deviation from ergodicity for the conductance fluctuations in graphene. In marked contrast to the ergodicity of dirty metals, fluctuations generated by varying magnetic field are shown to be much smaller than those obtained when sweeping Fermi energy. They also exhibit a strongly anisotropic response to the symmetry-breaking effects of a magnetic field, when applied perpendicular or parallel to the graphene plane. These results reveal a complex picture of quantum interference in graphene, whose description appears more challenging than for conventional mesoscopic systems.
We measured the conductance fluctuation of bi- and trilayer graphene devices prepared on mechanical exfoliated graphene by an all-dry, lithography-free process using an ultrathin quartz filament as a shadow mask. Reproducible fluctuations in conductance as a function of applied gate voltage or magnetic field were found. As the gate voltage was tuned so that the graphene device was pushed to the charge neutral point, the amplitude of the conductance fluctuation was found to be suppressed quickly from a value consistent with universal conductance fluctuation when the devices were still well with…
Ballistic transport through an impurity-free section of the Corbino disk in graphene is investigated by means of the Landauer-Büttiker formalism in the mesoscopic limit. In the linear-responce regime the conductance is quantized in steps close to integer multiples of $4e^{2}/h$, yet Fabry-Perot oscillations are strongly suppressed. The quantization arises for small opening angles $θ\lesssimπ/3$ and large radii ratios $R_2/R_1\gtrsim{}10$. We find that the condition for emergence of the $n$-th conductance step can be written as $\sqrt{n}θ/π\ll{}1$. A brief comparison with the conductance spectr…
We numerically investigate the electronic transport properties between two mesoscopic graphene disks with a twist by employing the density functional theory coupled with non-equilibrium Green's function technique. By attaching two graphene leads to upper and lower graphene layers separately, we explore systematically the dependence of electronic transport on the twist angle, Fermi energy, system size, layer stacking order and twist axis. When choose different twist axes for either AA- or AB-stacked bilayer graphene, we find that the dependence of conductance on twist angle displays qualitative…
Mesoscopic conductance fluctuations are a ubiquitous signature of phase-coherent transport in small conductors, exhibiting universal character independent of system details. In this work, however, we demonstrate a pronounced breakdown of this universality, due to the interplay of local and remote phenomena in transport. Our experiments are performed in a graphene-based interaction-detection geometry, in which an artificial magnetic texture is induced in the graphene layer by covering a portion of it with a micromagnet. When probing conduction at some distance from this region, the strong influ…
Using a generalized Landauer approach we study the non-linear transport in mesoscopic graphene with zig-zag and armchair edges. We find that for clean systems, the low-bias low-temperature conductance, G, of an armchair edge system in quantized as G/t=4 n e^2/h, whereas for a zig-zag edge the quantization changes to G/t t=4(n+1/2)e^2/h, where t is the transmission probability and n is an integer. We also study the effects of a non-zero bias, temperature, and magnetic field on the conductance. The magnetic field dependence of the quantization plateaus in these systems is somewhat different from…
Van der Waals heterostructures based on two-dimensional materials have recently become a very active topic of research in spintronics, both aiming at a fundamental description of spin dephasing processes in nanostructures and as a potential element in spin-based information processing schemes. Here, we theoretically investigate the magnetoconductance of mesoscopic devices built from graphene proximity-coupled to a high spin-orbit coupling material. Through numerically exact tight-binding simulations, we show that the interfacial breaking of inversion symmetry generates robust weak antilocaliza…
We present scanning tunneling microscopy (STM) images of single-layer graphene crystals examined under ultrahigh vacuum conditions. The samples, with lateral dimensions on the micron scale, were prepared on a silicon dioxide surface by direct exfoliation of single crystal graphite. The single-layer films were identified using Raman spectroscopy. Topographic images of single-layer samples display the honeycomb structure expected for the full hexagonal symmetry of an isolated graphene monolayer. The absence of observable defects in the STM images is indicative of the high quality of these films.…
The Corbino geometry allows one to investigate the propagation of electric current along a p-n interface in ballistic graphene in the absence of edge states appearing for the familiar Hall-bar geometry. Using the transfer matrix in the angular-momentum space we find that for sufficiently strong magnetic fields the current propagates only in one direction, determined by the magnetic field direction and the interface orientation, and the two valleys, K and K', are equally occupied. Spatially-anisotropic effective mass may suppress one of the valley currents, selected by the external electric fie…
We investigate the 1/f noise properties of epitaxial graphene devices at low temperatures as a function of temperature, current and magnetic flux density. At low currents, an exponential decay of the 1/f noise power spectral density with increasing temperature is observed that indicates mesoscopic conductance fluctuations as the origin of 1/f noise at temperatures below 50 K. At higher currents, deviations from the typical quadratic current dependence and the exponential temperature dependence occur as a result of nonequilibrium conditions due to current heating. By applying the theory of Kuba…
Magic-angle twisted bilayer graphene exhibits quasi-flat low-energy bands with Van Hove singularities close to the Fermi level. These singularities play an important role in the exotic phenomena observed in this material, such as superconductivity and magnetism, by amplifying electronic correlation effects. In this work, we study the correspondence of four-terminal conductance and the Fermi surface topology as a function of the twist angle, pressure, and energy in mesoscopic, ballistic samples of small-angle twisted bilayer graphene. We establish a correspondence between features in the wide-j…
In this article we discuss confinement of electrons in graphene via smooth magnetic fields which are finite everywhere on the plane. We shall consider two types of magnetic fields leading to systems which are conditionally exactly solvable and quasi exactly solvable. The bound state energies and wave functions in both cases have been found exactly.
Long coherence lifetimes of electron spins transported using moving potential dots are shown to result from the mesoscopic confinement of the spin vector. The confinement dimensions required for spin control are governed by the characteristic spin-orbit length of the electron spins, which must be larger than the dimensions of the dot potential. We show that the coherence lifetime of the electron spins is independent of the local carrier densities within each potential dot and that the precession frequency, which is determined by the Dresselhaus contribution to the spin-orbit coupling, can be m…
Due to Klein tunneling, electrostatic potentials are unable to confine Dirac electrons. We show that it is possible to confine massless Dirac fermions in a monolayer graphene sheet by inhomogeneous magnetic fields. This allows one to design mesoscopic structures in graphene by magnetic barriers, e.g. quantum dots or quantum point contacts.
The ground state of a two-dimensional, harmonically confined mesoscopic assembly of up to thirty polar molecules is studied by computer simulations. As the strength of the confining trap is increased, clusters evolve from superfluid, to supersolid, to insulating crystals. For strong confinement, the crystalline structure can be predicted based on classical energetics. However, clusters of specific numbers of particles (i.e., N=12 and N=19) display a {\it non-classical crystalline structure}, stabilized by quantum effects, in an intermediate range of confinement strength. In these cases, coexis…
We report on flux confinement effects in superconducting submicron line, loop and dot structures. The main idea of our study was to vary the boundary conditions for confinement of the superconducting condensate by taking samples of different topology and, through that, modifying the lowest Landau level E_{LLL}(H). Since the critical temperature versus applied magnetic field T_{c}(H) is, in fact, E_{LLL}(H) measured in temperature units, it is varied as well when the sample topology is changed. We demonstrate that in all studied submicron structures the shape of the T_{c}(H) phase boundary is d…
We theoretically analyze the possibility to confine electrons in single-layer graphene with the help of metallic gates, via the evaluation of the density of states of such a gate-defined quantum dot in the presence of a ring-shaped metallic contact. The possibility to electrostatically confine electrons in a gate-defined ``quantum dot'' with finite-carrier density, surrounded by an undoped graphene sheet, strongly depends on the integrability of the electron dynamics in the quantum dot. With the present calculations we can quantitatively compare confinement in dots with integrable and chaotic …
Because of the peculiar coupling of spatial and spin degrees of freedom effected by the Rashba spin-orbit interaction, lateral confinement of a two dimensional electronic system leads to a finite transverse spin polarization near the longitudinal edges of a current carrying quantum wire. The sign of this component of the polarization is opposite at the two edges and can be reversed upon inversion of the current. Interestingly for small spin orbit coupling this is the largest contribution to the total polarization, its magnitude being of second order in the coupling constant. As a consequence t…
We study a new type of one-dimensional chiral states that can be created in bilayer graphene (BLG) by electrostatic lateral confinement. These states appear on the domain walls separating insulating regions experiencing the opposite gating polarity. While the states are similar to conventional solitonic zero-modes, their properties are defined by the unusual chiral BLG quasiparticles, from which they derive. The number of zero-mode branches is fixed by the topological vacuum charge of the insulating BLG state. We discuss how these chiral states can manifest experimentally, and emphasize their …
We combine electrostatic and magnetic confinement to define a quantum dot in bilayer graphene. The employed geometry couples $n$-doped reservoirs to a $p$-doped dot. At magnetic field values around $B = 2~$T, Coulomb blockade is observed. This demonstrates that the coupling of the co-propagating modes at the $p$-$n$ interface is weak enough to form a tunnel barrier, facilitating transport of single charge carriers onto the dot. This result may be of use for quantum Hall interferometry experiments.
Quantum confinement of graphene Dirac-like electrons in artificially crafted nanometer structures is a long sought goal that would provide a strategy to selectively tune the electronic properties of graphene, including bandgap opening or quantization of energy levels However, creating confining structures with nanometer precision in shape, size and location, remains as an experimental challenge, both for top-down and bottom-up approaches. Moreover, Klein tunneling, offering an escape route to graphene electrons, limits the efficiency of electrostatic confinement. Here, a scanning tunneling mic…
We theoretically analyse the possibility to electrostatically confine electrons in circular quantum dot arrays, impressed on contacted graphene nanoribbons by top gates. Utilising exact numerical techniques, we compute the scattering efficiency of a single dot and demonstrate that for small-sized scatterers the cross-sections are dominated by quantum effects, where resonant scattering leads to a series of quasi-bound dot states. Calculating the conductance and the local density of states for quantum dot superlattices we show that the resonant carrier transport through such graphene-based nanos…
We demonstrate the existence of localized electron and hole states in a ring-shaped potential kink in biased bilayer graphene. Within the continuum description, we show that for sharp potential steps the Dirac equation describing carrier states close to the K (or K') point of the first Brillouin zone can be solved analytically for a circular kink/anti-kink dot. The solutions exhibit interfacial states which exhibit Aharonov-Bohm oscillations as functions of the height of the potential step and/or the radius of the ring.
We report on the fabrication and measurement of nanoscale devices based on bilayer graphene sandwiched between hexagonal boron nitride bottom and top gate dielectrics. The top gates are patterned such that constrictions and islands can be electrostatically induced by applying appropriate voltages to the gates. The high quality of the devices becomes apparent from conductance quantization in the constrictions at low temperature. The islands exhibit clear Coulomb blockade and single-electron transport.
Coulomb blockade is observed in a graphene nanoribbon device with a top gate. When two pn junctions are formed via the back gate and the local top gate, electrons are confined between the pn junctions which act as the barriers. When no pn junctions are induced by the gate voltages, electrons are still confined, as a result of strong disorder, but in a larger area. Measurements on five other devices with different dimensions yield consistent results.
Quantum confined devices that manipulate single electrons in graphene are emerging as attractive candidates for nanoelectronics applications. Previous experiments have employed etched graphene nanostructures, but edge and substrate disorder severely limit device functionality. Here we present a technique that builds quantum confined structures in suspended bilayer graphene with tunnel barriers defined by external electric fields that break layer inversion symmetry, thereby eliminating both edge and substrate disorder. We report clean quantum dot formation in two regimes: at zero magnetic field…
The coupling of geometrical and electronic properties is a promising venue to engineer conduction properties in graphene. Confinement added to strain allows for interplay of different transport mechanisms with potential device applications. To investigate strain signatures on transport in confined geometries, we focus on graphene nanoribbons (GNR) with circularly symmetric deformations. In particular, we study GNR with an inhomogeneous, out of plane Gaussian deformation, connected to reservoirs. We observe an enhancement of the density of states in the deformed region, accompanied with a decre…
We study fluctuations of the conductance of micron-sized graphene devices as a function of the Fermi energy and magnetic field. The fluctuations are studied in combination with analysis of weak localization which is determined by the same scattering mechanisms. It is shown that the variance of conductance fluctuations depends not only on inelastic scattering that controls dephasing but also on elastic scattering. In particular, contrary to its effect on weak localization, strong intervalley scattering suppresses conductance fluctuations in graphene. The correlation energy, however, is independ…
Using low-temperature scanning tunneling spectroscopy, we map the local density of states (LDOS) of graphene quantum dots supported on Ir(111). Due to a band gap in the projected Ir band structure around the graphene K point, the electronic properties of the QDs are dominantly graphene-like. Indeed, we compare the results favorably with tight binding calculations on the honeycomb lattice based on parameters derived from density functional theory. We find that the interaction with the substrate near the edge of the island gradually opens a gap in the Dirac cone, which implies soft-wall confinem…
We compare the conductance of an undoped graphene sheet with a small region subject to an electrostatic gate potential for the cases that the dynamics in the gated region is regular (disc-shaped region) and classically chaotic (stadium). For the disc, we find sharp resonances that narrow upon reducing the area fraction of the gated region. We relate this observation to the existence of confined electronic states. For the stadium, the conductance looses its dependence on the gate voltage upon reducing the area fraction of the gated region, which signals the lack of confinement of Dirac quasipar…
Magic angle twisted bilayer graphene has emerged as a powerful platform for studying strongly correlated electron physics, owing to its almost dispersionless low-energy bands and the ability to tune the band filling by electrostatic gating. Techniques to control the twist angle between graphene layers have led to rapid experimental progress but improving sample quality is essential for separating the delicate correlated-electron physics from disorder effects. Owing to the 2D nature of the system and the relatively low carrier density, the samples are highly susceptible to small doping inhomoge…
Mesoscopic conductance fluctuations in graphene samples at energies not very close to the Dirac point are studied analytically. We demonstrate that the conductance variance $<[δG]^2>$ is very sensitive to the elastic scattering breaking the valley symmetry. In the absence of such scattering (disorder potential smooth at atomic scales, trigonal warping negligible), the variance $<[δG]^2 > = 4 < [δG]^2 >_\text{metal}$ is four times greater than that in conventional metals, which is due to the two-fold valley degeneracy. In the absence of intervalley scattering, but for strong intravalley scatter…
We investigate mesoscopic Josephson junction arrays created by patterning superconducting disks on monolayer graphene, concentrating on the high-$T/T_c$ regime of these devices and the phenomena which contribute to the superconducting glass state in diffusive arrays. We observe features in the magnetoconductance at rational fractions of flux quanta per array unit cell, which we attribute to the formation of flux-quantized vortices. The applied fields at which the features occur are well described by Ginzburg-Landau simulations that take into account the number of unit cells in the array. We fi…
We consider the orbital magnetic properties of non-interacting charge carriers in graphene-based nanostructures in the low-energy regime. The magnetic response of such systems results both, frombulk contributions and from confinement effects that can be particularly strong in ballistic quantum dots. First we provide a comprehensive study of the magnetic susceptibility $χ$ of bulk graphene in a magnetic field for the different regimes arising from the relative magnitudes of the energy scales involved, i.e. temperature, Landau level spacing and chemical potential. We show that for finite tempera…
Atomic collapse in graphene nanoribbons behaves in a fundamentally different way as compared to monolayer graphene, due to the presence of multiple energy bands and the effect of edges. For armchair nanoribbons we find that bound states gradually transform into atomic collapse states with increasing impurity charge. This is very different in zig-zag nanoribbons where multiple quasi-one-dimensional \emph{bound states} are found that originates from the zero energy zig-zag edge states. They are a consequence of the flat band and the electron distribution of these bound states exhibits two peaks.…
We investigate the impact of strained nanobubbles on the conductance characteristics of graphene nanoribbons using a combined molecular dynamics - tight-binding simulation scheme. We describe in detail how the conductance, density of states, and current density of zigzag or armchair graphene nanoribbons are modified by the presence of a nanobubble. In particular, we establish that low-energy electrons can be confined in the vicinity or within the nanobubbles by the delicate interplay between the pseudomagnetic field pattern created by the shape of the bubble, mode mixing, and substrate interac…
In graphene moiré superlattices, electronic interactions between layers are mostly hidden as band structures get crowded because of folding, making their interpretation cumbersome. Here, the evolution of the electronic band structure as a function of the interlayer rotation angle is studied using Density Functional Theory followed by unfolding bands and then comparing them to their corresponding individual components. We observe interactions at regions not theoretically elucidated so far, where for small interlayer angles, gaps turn into discrete-like states that are evenly spaced in energy. W…
We study the electronic properties of the confined honeycomb lattice in the presence of the intrinsic spin-orbit (ISO) interaction and perpendicular magnetic field, and report on uncommon aspects of the quantum spin Hall conductance corroborated by peculiar properties of the edge states. The ISO interaction induces two specific gaps in the Hofstadter spectrum, namely the 'weak' topological gap defined by Beugeling et al [Phys. Rev. B 86, 075118 (2012)], and spin-imbalanced gaps in the relativistic range of the energy spectrum. We analyze the evolution of the helical states with the magnetic fi…
An atomic force microscope is used to structure a film of multilayer graphene. The resistance of the sample was measured in-situ during nanomachining narrow trenches. We found a reversible behavior in the electrical resistance which we attribute to the movement of dislocations. After several attempts also permanent changes are observed.
The motion of massless Dirac-electrons in graphene mimics the propagation of photons. This makes it possible to control the charge-carriers with components based on geometrical-optics and has led to proposals for an all-graphene electron-optics platform. An open question arising from the possibility of reducing the component-size to the nanometer-scale is how to access and understand the transition from optical-transport to quantum-confinement. Here we report on the realization of a circular p-n junction that can be continuously tuned from the nanometer-scale, where quantum effects are dominan…
We report an approach to confine the carriers in single-layer graphene, which leads to quantum devices with field-induced quantum confinement. We demonstrated that the Coulomb-blockade effect evolves under a uniform magnetic field perpendicular to the graphene device. Our experimental results show that field-induced quantum dots are realized in graphene, and a quantum confinement-deconfinement transition is switched by the magnetic field.
We report the electronic properties of two-dimensional systems made of graphene nanoribbons which are patterned with ad-atoms in two separated regions. Due to the extra electronic confinement induced by the presence of the impurities, we find resonant levels, quasi-bound and impurity-induced localized states, which determine the transport properties of the system. Regardless of the ad-atom distribution in the system, we apply band-folding procedures to simple models and predict the energies and the spatial distribution of those impurity-induced states. We take into account two different scenar…
Massless Dirac particles cannot be confined by an electrostatic potential. This is a problem for making graphene quantum dots but confinement can be achieved with a magnetic field and here, general conditions for confined and deconfined states are derived. There is a class of potentials for which the character of the state can be controlled at will. Then a confinement-deconfinement transition occurs which allows the Klein paradox to be probed experimentally in graphene dots.
We have studied quantization and confinement effects in nanostructured superconductors. Three different types of nanostructured samples were investigated: individual structures (line, loop, dot), 1-dimensional (1D) clusters of loops and 2D clusters of antidots, and finally large lattices of antidots. Hereby, a crossover from individual elementary "plaquettes", via clusters, to huge arrays of these elements, is realized. The main idea of our study was to vary the boundary conditions for confinement of the superconducting condensate by taking samples of different topology and, through that, modi…
We investigate conductance fluctuations as a function of carrier density $n$ and magnetic field in diffusive mesoscopic samples made from monolayer and bilayer graphene. We show that the fluctuations' correlation energy and field, which are functions of the diffusion coefficient, have fundamentally different variations with $n$, illustrating the contrast between massive and massless carriers. The field dependent fluctuations are nearly independent of $n$, but the $n$-dependent fluctuations are not universal and are largest at the charge neutrality point. We also measure the second order conduc…
Quantum confinement of graphene carriers is an effective way to engineer its properties. It is commonly realized through physical edges that are associated with the deterioration of mobility and strong suppression of plasmon resonances. Here, we demonstrate a simple, large-area, edge-free nanostructuring technique, based on amplifying random nanoscale structural corrugations to a level where they efficiently confine carriers, without inducing significant inter-valley scattering. This soft confinement, allows the low-loss lateral ultra-confinement of graphene plasmons, scaling up their resonanc…
A continuum, post-deposition mesoscopic model of a Moiré-regulated self-assembly of metal nanoclusters on a twisted bilayer graphene is presented. Quasi-two-dimensional nanocluster-like steady states at a low adsorbate coverage are analytically determined for Pt, Ni, and Pb adsorbates, pointing that nanoclusters self-assemble at the Moiré cells centers. This is followed by the computations of nanoclusters self-assembly dynamics. Differences in the self-assembly efficiency for three chosen metals are highlighted across three typical values of an initial submonolayer coverage and for three tempe…
In mesoscopic physics, interference effects play a central role on the transport properties of conduction electrons, giving rise to exotic phenomena such as weak localization, Aharonov-Bohm effect, and universal conduction fluctuations. Mesoscopic objects have a size on the order of the {\em phase-breaking length} $L_ϕ$, the length conduction electrons travel while keeping phase coherence. In this letter, we use vibrational spectroscopy in combination with a novel optical defocusing method to measure $L_ϕ$ of photo-excited electrons in graphene which undergo inelastic scattering by optical pho…
Isolating the natural edges of bilayer graphene in gate-defined mesoscopic devices
University of Basel（巴塞尔大学）；Advanced Materials Laboratory, National Institute for Materials Science（国家材料科学研究所先进材料实验室）；Solid State Physics Laboratory, ETH Zürich（苏黎世联邦理工学院固体物理实验室）；Swiss Nanoscience Institute（瑞士纳米科学研究所）
We consider a straight one-dimensional potential step created across a graphene flake. Charge and spin transport through such a potential step are studied in the presence of both intrinsic and extrinsic (Rashba) spin-orbit coupling (SOC). At normal incidence electrons are completely reflected when the Rashba interaction (with strength $λ_R$) is dominant whereas they are perfectly transmitted if the two types of SOC are exactly balanced. At normal incidence, the transmission probability of the step is thus controlled continuously from 0 to 1 by tuning the ratio of the two types of SOC. Besides …
We study mesoscopic spin Hall effect on the surface of topological insulator with a step-function potential. The giant spin polarization induced by a transverse electric current is derived analytically by using McMillan method in the ballistic transport limit, which oscillates across the potential boundary with no confinement from the potential barrier due to the Klein paradox, and should be observable in spin resolved scanning tunneling microscope.
We study Josephson effect in a ballistic graphene strip of length $L$ smaller than the superconducting coherence length and arbitrary width $W$. We find that the dependence of the critical supercurrent $I_{c}$ on $W$ is drastically different for different types of the edges. For \textit{smooth} and \textit{armchair} edges at low concentration of the carriers $I_{c}$ decreases monotonically with decreasing $W/L$ and tends to a constant minimum for a narrow strip $W/L\lesssim1$. The minimum supercurrent is zero for smooth edges but has a finite value $eΔ_{0}/\hbar$ for the armchair edges. At hig…
