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arXiv 1102.5602astro-ph.EP
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正则解模型在原行星尘埃凝聚中的作用

The effect of the regular solution model in the condensation of protoplanetary dust

Francesco C. Pignatale, Sarah T. Maddison, Vianney Taquet, Geoffrey Brooks, Kurt Liffman

摘要:

我们利用化学平衡代码,以研究冷凝过程中发生在原行星盘形成的第一个固体。该模型特别侧重于固体物质的热力学行为,假设规则的溶液模型。对于每一种解决方案,我们建立的物种,组成和温度使用文献中的实验数据的活性之间的关系。然后,我们应用吉布斯自由能最小化方法和研究所产生的冷凝序列的温度和压力范围内的原行星盘。我们的研究结果表明,使用正规溶液模型表明,晶粒凝聚在一个大的温度范围内,因此在整个大部分的光盘。在高温区(T > 1400 K),Ca-Al化合物占主导地位,Ca-Al化合物的形成对压力敏感。中温区主要由Fe(s)和硅酸盐如Mg 2SiO 4和MgSiO 3组成。镁橄榄石和顽火辉石的化学成分是严格相关的,我们的模拟显示了一个序列的镁橄榄石顽火辉石镁橄榄石随着温度的降低。在低温区(T < 600 K),形成一系列铁化合物和硫化物。我们还运行模拟使用理想的解决方案模型,并看到明显的差异,在所产生的冷凝序列与不同的解决方案模型,特别是,我们发现,转折点,其中镁橄榄石取代顽火辉石在低温区域是敏感的解决方案模型。我们的研究结果表明,理想的解决方案模型往往是一个贫穷的近似实验数据在大多数温度下重要的原行星盘。我们发现一些重要的差异时,使用正规溶液模型的冷凝序列,并建议该模型应提供一个更现实的冷凝序列。

英文摘要:

We utilize a chemical equilibrium code in order to study the condensation process which occurs in protoplanetary discs during the formation of the first solids. The model specifically focuses on the thermodynamic behaviour on the solid species assuming the regular solution model. For each solution, we establish the relationship between the activity of the species, the composition and the temperature using experimental data from the literature. We then apply the Gibbs free energy minimization method and study the resulting condensation sequence for a range of temperatures and pressures within a protoplanetary disc. Our results using the regular solution model show that grains condense over a large temperature range and therefore throughout a large portion of the disc. In the high temperature region (T > 1400 K) Ca-Al compounds dominate and the formation of corundum is sensitive to the pressure. The mid-temperature region is dominated by Fe(s) and silicates such as Mg2SiO4 and MgSiO3 . The chemistry of forsterite and enstatite are strictly related, and our simulations show a sequence of forsterite-enstatite-forsterite with decreasing temperature. In the low temperature regions (T < 600 K) a range of iron compounds and sulfides form. We also run simulations using the ideal solution model and see clear differences in the resulting condensation sequences with changing solution model In particular, we find that the turning point in which forsterite replaces enstatite in the low temperature region is sensitive to the solution model. Our results show that the ideal solution model is often a poor approximation to experimental data at most temperatures important in protoplanetary discs. We find some important differences in the resulting condensation sequences when using the regular solution model, and suggest that this model should provide a more realistic condensation sequence.

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