The Casimir force between arbitrary objects in equilibrium is related to scattering from individual bodies. We extend this approach to heat transfer and Casimir forces in non-equilibrium cases where each body, and the environment, is at a different temperature. The formalism tracks the radiation from each body and its scatterings by the other objects. We discuss the radiation from a cylinder, emphasizing its polarized nature, and obtain the heat transfer between a sphere and a plate, demonstrating the validity of proximity transfer approximation at close separations and arbitrary temperatures.
In this work, we establish an exact relation which connects the heat exchange between two systems initialized in their thermodynamic equilibrium states at different temperatures and the Rényi divergences between the initial thermodynamic equilibrium state and the final non-equilibrium state of the total system. The relation tells us that the various moments of the heat statistics are determined by the Renyi divergences between the initial equilibrium state and the final non-equilibrium state of the global system. In particular the average heat exchange is quantified by the relative entropy bet…
Using information entropy formalism, we consider a one-dimensional system with heat flux and extend the meaning of equilibrium variables to non equilibrium scenarios when classical local equilibrium approach is not applicable; this is particularly important for the performance evaluation of modern thermal systems and microdevices, which usually operate in extreme situations. The extended non equilibrium entropy, temperature, thermal conductivity and heat capacity have been analyzed as functions of the local energy density (kinetic temperature) and heat flux.
The non-equilibrium state of two oscillators with a mutual interaction and coupled to separate heat baths is discussed. Bosonic baths are considered, and an exact spectral representation for the elements of the covariance matrix is provided analytically. A wide class of spectral densities for the relevant bath modes is allowed for. The validity of the fluctuation-dissipation theorem is established for global equilibrium (both baths at the same temperature) in the stationary state. Spectral measures of entanglement are suggested by comparing to the equilibrium spectrum of zero-point fluctuation…
The study of quantum heat transport in superconducting circuits is significant for further understanding the connection between quantum mechanics and thermodynamics, and for possible applications for quantum information. The first experimental realisations of devices demonstrating photonic heat transport mediated by a qubit have already been designed and measured. Motivated by the analysis of such experimental results, and for future experimental designs, we numerically evaluate the photonic heat transport of qubit-resonator devices in the linear circuit regime through electromagnetic simulati…
Real quantum heat engines lack the separation of time and length scales that is characteristic for classical engines. They must be understood as open quantum systems in non-equilibrium with time-controlled coupling to thermal reservoirs as integral part. Here, we present a systematic approach to describe a broad class of engines and protocols beyond conventional weak coupling treatments starting from a microscopic modeling. For the four stroke Otto engine the full dynamical range down to low temperatures is explored and the crucial role of the work associated with the coupling/decoupling to/fr…
This study is related to the fluctuation theory of electromagnetic fields, charges and currents. The three-dimensional system under consideration is a semi-infinite conductor, modeled by the jellium, in vacuum. In previous theoretical studies it was found that the correlation functions of the surface charge density on the conductor decay as the inverse cube of the distance at asymptotically large distances. The prefactor to this asymptotic decay was obtained in the classical limit and in the quantum case without retardation effects. To describe the retarded regime, we study a more general prob…
We present a detailed derivation of heat radiation, heat transfer and (Casimir) interactions for N arbitrary objects in the framework of fluctuational electrodynamics in thermal non-equilibrium. The results can be expressed as basis-independent trace formulae in terms of the scattering operators of the individual objects. We prove that heat radiation of a single object is positive, and that heat transfer (for two arbitrary passive objects) is from the hotter to a colder body. The heat transferred is also symmetric, exactly reversed if the two temperatures are exchanged. Introducing partial wav…
We obtain lower and upper bounds on the heat kernel and Green functions of the Schroedinger operator in a random Gaussian magnetic field and a fixed scalar potential. We apply stochastic Feynman-Kac representation, diamagnetic upper bounds and the Jensen inequality for the lower bound. We show that if the covariance of the electromagnetic (vector) potential is increasing at large distances then the lower bound is decreasing exponentially fast for large distances and a large time.
Standard heat machines (engine, heat pump, refrigerator) are composed of a system ("working fluid") coupled to at least two equilibrium baths at different temperatures and periodically driven by an external device (piston or rotor) called sometimes work reservoir. The aim of this paper is to go beyond this scheme by considering environments which are stationary but cannot be decomposed into few baths at thermal equilibrium. Such situations are important, for example in solar cells, chemical machines in biology, various realizations of laser cooling or nanoscopic machines driven by laser radiat…
We continue studying long-ranged quantum correlations of surface charge densities on the interface between two media of distinct dielectric functions which are in thermal equilibrium with the radiated electromagnetic field. Two regimes are considered: the non-retarded one with the speed of light $c$ taken to be infinitely large and the retarded one with finite value of $c$. The analysis is based on results obtained by using fluctuational electrodynamics in [L. Šamaj and B. Jancovici, Phys. Rev. E {\bf 78}, 051119 (2008)]. Using an integration method in the complex plane and the general analyti…
Results of a previous article with the same title are retrieved by a different method. A one-component plasma is bounded by a plane surface. The plasma is fully coupled to the electromagnetic field, therefore the charge correlations are retarded. The quantum correlation function of the surface charge densities, at times different by $t$, at asymptotical large distances $R$, at inverse temperature $β$, decays as $-1/(8π^2βR^3)$, a surprisingly simple result: the decay is independent of Planck's constant $\hbar$ and of the time difference $t$. The present paper is based on the analysis of the co…
It has very recently been suggested that asymmetric coupling of electromagnetic fields to thermal reservoirs under nonequilibrium conditions can produce unexpected oscillatory behavior in the local photon statistics in layered structures. Better understanding of the predicted phenomena could enable useful applications related to thermometry, noise filtering, and enhancing optical interactions. In this work we briefly review the field quantization and study the local steady state temperature distributions in optical cavities formed of lossless and lossy media to show that also local field tempe…
The time evolution of occupation number is studied for fermionic or bosonic oscillator linearly fully coupled to several fermionic and bosonic heat baths. The influence of characteristics of thermal reservoirs of different statistics on the non-stationary population probability is analyzed at large times. Applications of the absence of equilibrium in such systems for creating a dynamic (nonstationary) memory storage are discussed.
We study the radiative heat transfer and the Casimir-Lifshitz force occurring between two bodies in a system out of thermal equilibrium. We consider bodies of arbitrary shape and dielectric properties, held at two different temperatures, and immersed in a environmental radiation at a third different temperature. We derive explicit closed-form analytic expressions for the correlations of the electromagnetic field, and for the heat transfer and Casimir-Lifshitz force, in terms of the bodies scattering matrices. We then consider some particular cases which we investigate in detail: the atom-surfa…
For the first time, based on the fluctuation-electromagnetic theory, we have calculated the drug force, the radiation heat flux and the frictional torque on a small rotating particle moving at a relativistic velocity through the equilibrium background radiation (photon gas). The particle and background radiation are characterized by different temperatures corresponding to the local thermodynamic equilibrium in their own reference frames.
We develop an exact method for computing Casimir forces and the power of radiative heat transfer between two arbitrary nanostructured surfaces out of thermal equilibrium. The method is based on a generalization of the scattering approach recently used in investigations on the Casimir effect. Analogously to the equilibrium case, we find that also out of thermal equilibrium the shape and composition of the surfaces enter only through their scattering matrices. The expressions derived provide exact results in terms of the scattering matrices of the intervening surfaces.
We study the fluctuation electromagnetic interaction in a system of two rotating electrically neutral nonmagnetic particles with allowance for relativistic retardation effect. The particles are assumed to have different temperatures being embedded into a heated vacuum background (photon gas). Closed expressions for the free energy, frictional torque and the rate of heat transfer are derived and compared to the known static results and those in the electrostatic limit without retardation.
Probing Non-equilibrium baths: Frequency-Resolved Thermometry and Quantum Heat Current Turnover
Institute for Theoretical Physics, Department of Quantum and Classical Dynamics, Johannes Kepler Universität Linz（林茨约翰·开普勒大学理论物理系量子与经典动力学部）；Schulich Faculty of Chemistry and Helen Diller Quantum Center, Technion-Israel Institute of Technology（以色列理工学院舒利希化学学院及海伦·迪勒量子中心）
A theory of thermal and nonthermal radiation in a vacuum background of arbitrary temperature generated by relativistic polarizable particle with spin is proposed. When the particle rotates, radiation is produced by vacuum fluctuations even in the case of zero temperature of the system. In the ultrarelativistic case, the spectral-angular intensity of radiation is concentrated along the velocity of the particle. At finite temperatures of particle and vacuum, the particle temperature (in its rest frame) rather quickly acquires an equilibrium magnitude depending on the velocities of rotation and u…
When a quantum system is subject to a thermal gradient it may sustain a steady non-equilibrium heat current, by entering into a so-called non equilibrium steady state (NESS). Here we show that NESS constitute a thermodynamic resource that can be exploited to fuel a quantum heat engine. This adds to the list of recently reported sources available at the nano-scale, such as coherence, entanglement and quantum measurements. We elucidate this concept by showing analytic and numerical studies of a two-qubits quantum battery that is alternatively charged by a thermal gradient and discharged by appli…
We study the Casimir-Lifshitz force and the radiative heat transfer in a system consisting of three bodies held at three independent temperatures and immersed in a thermal environment, the whole system being in a stationary configuration out of thermal equilibrium. The theory we develop is valid for arbitrary bodies, i.e. for any set of temperatures, dielectric and geometrical properties, and describes each body by means of its scattering operators. For the three-body system we provide a closed-form unified expression of the radiative heat transfer and of the Casimir-Lifshitz force (both in an…
In this work we analyze the incidence of the plates' thickness on the Casimir force and radiative heat transfer for a configuration of parallel plates in a non-equilibrium scenario, relating to Lifshitz's and Landauer's formulas. From a first-principles canonical quantization scheme for the study of the matter-field interaction, we give closed-form expressions for the non-equilibrium Casimir force and the heat transfer between plates of thickness $d_{\rm L},d_{\rm R}$. We distinguish three different contributions to the Casimir force and to the heat transfer in the general non-equilibrium situ…
Considering an entropy-based division of energy transferred into heat and work, we develop an alternative theoretical framework for the thermodynamic analysis of two-level systems. When comparing these results with those obtained under the standard definitions of these quantities, we observe the appearance of a new term of work, which represents the energy cost of rotating the Bloch vector in presence of the external field that defines the local Hamiltonian. Additionally, we obtain explicit expressions for the temperature, the heat capacity and the internal entropy production of the system in …
Temperature uncertainty of a quantum system in canonical ensemble is inversely determined by its energy fluctuation, which is known as the temperature-energy uncertainty relation. No such uncertainty relation was discovered for a non-equilibrium open quantum system. In this article, we derive a universal temperature uncertainty relation for general non-equilibrium processes. We find that it is the fluctuation of heat, which is defined as the change in bath energy, determines the temperature uncertainty in non-equilibrium case. Specifically, the heat is divided into trajectory heat and backacti…
Heat exchanges are the essence of Thermodynamics. In order to investigate non-equilibrium effects like quantum coherence and correlations in heat flows we introduce the concept of apparent temperature. Its definition is based on the expression of the heat flow between out-of-equilibrium quantum systems. Such apparent temperatures contain crucial information on the role and impact of correlations and coherence in heat exchanges. In particular, both behave as populations, affecting dramatically the population balance and therefore the apparent temperatures and the heat flows. We show how seminal…
Quantum and thermal fluctuations of electromagnetic waves are the cornerstone of quantum and statistical physics, and inherent to such phenomena as thermal radiation and van der Waals forces. While the basic principles are the material of elementary texts, recent experimental and technological advances have made it necessary to come to terms with counterintuitive consequences of electromagnetic fluctuations at short scales -- in the so called {\it near-field} regime. We focus on three manifestations of such behavior: {\bf (i)} The Stefan--Boltzmann law describes thermal radiation from macrosco…
In this paper, we investigate the thermodynamic properties of a set of neutral Dirac particles in the presence of an electromagnetic field in contact with a heat bath for the relativistic and non-relativistic cases. In order to perform the calculations, the high-temperature limit is considered and the Euler-MacLaurin formula is taking into account. Next, we explicitly determine the behavior of the main thermodynamic functions of the canonical ensemble: the Helmholtz free energy, the mean energy, the entropy, and the heat capacity. As a result, we verified that the mean energy and the heat capa…
In this paper, we investigate the strong coupling quantum thermodynamics of the hybrid quantum system far away from equilibrium. The strong coupling hybrid system consists of a cavity and a spin ensemble of the NV centers in diamond under external driving that has been realized experimentally. We apply the renormalization theory of quantum thermodynamics we developed recently to study the transient quantum heat and work in this hybrid system. We find that the dissipation and fluctuation dynamics of the system induce the transient quantum heat current which involve the significant non-Markovian…
We study the Casimir-Lifshitz force and the radiative heat transfer occurring between two arbitrary bodies, each one held at a given temperature, surrounded by environmental radiation at a third temperature. The system, in stationary configuration out of thermal equilibrium, is characterized by a force and a heat transfer depending on the three temperatures, and explicitly expressed in terms of the scattering operators of each body. We find a closed-form analytic expression valid for bodies of any geometry and dielectric properties. As an example, the force between two parallel slabs of finite…
We report on numerical simulations of the dynamics of a test particle coupled to competing Boltzmann heat baths of finite size. After discussing some features of the single bath case, we show that the presence of two heat baths further constraints the conditions necessary for the test particle to thermalize with the heat baths. We find that thermalization is a spectral property in which the oscillators of the bath with frequencies in the range of the test particle characteristic frequency determine its degree of thermalization. We also find an unexpected frequency shift of the test particle re…
Heat engines, which cyclically transform heat into work, are ubiquitous in technology. Lasers and masers, which generate a coherent electromagnetic field, may be viewed as heat engines that rely on population inversion or coherence in the active medium. Here we put forward an unconventional paradigm of a remarkably simple electromagnetic heat-powered engine that bears basic differences to any known maser or laser: it does not rely on population inversion or coherence in its two-level working medium. Nor does it require any coherent driving or pump aside from two (hot and cold) baths. Strikingl…
We report a theoretical study of the electromagnetic waves (EWs) propagation through an array of superconducting qubits, i.e. coherent two-level systems, embedded in a low-dissipative transmission line. We focus on the near-resonant case as the frequency of EWs $ω\simeq ω_q$, where $ω_q$ is the qubit frequency. In this limit we derive the effective dynamic nonlinear wave equation allowing one to obtain the frequency dependent transmission coefficient of EWs, $D(ω)$. In the linear regime and a relatively wide frequency region we obtain a strong resonant suppression of $D(ω)$ in both cases of a …
For the first time, using nonrelativistic approach we have calculated the attraction force, friction torque and the rate of radiation heat exchange in the system of two sprerical rotating particles located at a distance between one another.
A general theory of photon-mediated energy and momentum transfer in N-body planar systems out of thermal equilibrium is introduced. It is based on the combination of the scattering theory and the fluctuational-electrodynamics approach in many-body systems. By making a Landauer-like formulation of the heat transfer problem, explicit formulas for the energy transmission coefficients between two distinct slabs as well as the self-coupling coefficients are derived and expressed in terms of the reflection and transmission coefficients of the single bodies. We also show how to calculate local equili…
