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arXiv 1003.0273cond-mat.supr-concond-mat.str-el
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一步合成NdFeAsO0. 80 F. 20块体50 K超导体的物理性能表征

Physical property characterization of single step synthesized NdFeAsO0.80F0.20 bulk 50K superconductor

V. P. S. Awana, R. S. Meena, Anand Pal, Arpita Vajpayee, K. V. R. Rao, H. Kishan

摘要:

本文报道了一种简单的一步合成方法,合成了具有50 K以下体超导性的NdFeAsO_(0.80)F_(0.20)超导体。标题化合物是通过在真空(10-3托)石英管中封装经由固态反应路线合成的。粉末X射线衍射数据的Rietveld分析表明,化合物为四方晶系结构,空间群为P4/nmm。R(T)H测量显示出超导性,Tc(R=0)在48 K和一个非常高的上临界场(Hc 2)高达345特斯拉。磁性测量显示,在低于50 K的抗磁开始体超导性。在5 K时,低临界场(Hc 1)约为1000 Oe。在正常状态下,高于60 K时,该化合物表现出纯顺磁性行为,因此排除了基质中任何有序FeOx杂质的存在。在比热测量中,由于系统中Nd+3离子的原子力显微镜有序性,在超导转变(Tc)附近观察到跳跃,并在T=4 K以下观察到上升。热电功率(TEP)在Tc以下为负值,表明NdFeAsO_(0.80)F_(0.20)超导体中的主要载流子为n型。本文研究了大块超导NdFeAsO_(0.8)F_(0.2)样品的粒度,并通过观察外加交流驱动磁场的不同振幅和频率,研究了晶粒内和晶粒间的贡献。

英文摘要:

We report an easy single step synthesis route of title compound NdFeAsO0.80F0.20 superconductor having bulk superconductivity below 50 K. The title compound is synthesized via solid-state reaction route by encapsulation in an evacuated (10-3 Torr) quartz tube. Rietveld analysis of powder X-ray diffraction data shows that compound crystallized in tetragonal structure with space group P4/nmm. R(T)H measurements showed superconductivity with Tc (R=0) at 48 K and a very high upper critical field (Hc2) of up to 345 Tesla. Magnetic measurements exhibited bulk superconductivity in terms of diamagnetic onset below 50 K. The lower critical field (Hc1) is around 1000 Oe at 5 K. In normal state i.e., above 60 K, the compound exhibited purely paramagnetic behavior and thus ruling out the presence of any ordered FeOx impurity in the matrix. In specific heat measurements a jump is observed in the vicinity of superconducting transition (Tc) along with an upturn at below T=4 K due to the AFM ordering of Nd+3 ions in the system. The Thermo-electric power (TEP) is negative down to Tc, thus indicating dominant carriers to be of n-type in NdFeAsO0.80F0.20 superconductor. The granularity of the bulk superconducting NdFeAsO0.8F0.2 sample is investigated and the intra and inter grain contributions have been individuated by looking at various amplitude and frequencies of the applied AC drive magnetic field.

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