时效对BiS₂基化合物超导性能的影响:首个12年重研究
Aging Effects on Superconducting Properties of BiS2-Based Compounds: First-12-Year Restudy
AI总结:
本研究针对2012年首次合成的两种BiS₂基超导体开展12年时效影响研究,发现Bi₄O₄S₃超导转变温度仅微降0.2K仍保持体超导,高压合成的LaO₀.₅F₀.₅BiS₂转变温度明显下降,揭示时效与高压应变的关联。
摘要:
超导体的分解有时在研究其基本物理性质时至关重要。例如,铜氧化物超导体YBa₂Cu₃O₇₋d经长时间空气暴露会发生分解。本研究中,我们探究了时效对两种均于2012年首次合成的BiS₂基超导体Bi₄O₄S₃和LaO₀.₅F₀.₅BiS₂超导性能的影响,实验采用数年前合成的多晶样品。我们发现,存放12年的Bi₄O₄S₃样品仍表现出体超导性,其超导转变温度(Tc)仅轻微下降0.2 K。对于高压合成的LaO₀.₅F₀.₅BiS₂样品,观测到Tc明显下降,表明高压应变随时效作用有所降低。
英文摘要:
Decomposition of superconductors sometimes becomes crucial when studying essential physical properties of the superconductors. For example, the cuprate superconductor YBa2Cu3O7-d decomposes by long-time air exposure. In this study, we investigate the aging effects on superconducting properties of BiS2-based superconductors Bi4O4S3 and LaO0.5F0.5BiS2, both were first synthesized in 2012, using their polycrystalline samples synthesized several years ago. We find that 12-year-old Bi4O4S3 samples exhibit bulk superconductivity with a slight degradation of the superconducting transition temperature (Tc) of 0.2 K. For a high-pressure-synthesized LaO0.5F0.5BiS2 sample, clear decrease in Tc is observed, which suggests that high-pressure strain is reduced by aging.
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