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arXiv 0912.0155cond-mat.str-elcond-mat.mtrl-sci
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(La_{1-y} Pr_{y})_{0.7} Ca_{0.3} MnO_3中猝灭关联无序对相分离和磁性强影响的证据

Evidence for strong effect of quenched correlated disorder on phase separation and magnetism in (La_{1-y}Pr_{y})_{0.7}Ca_{0.3}MnO_3

V. Yu. Pomjakushin, D. V. Sheptyakov, E. V. Pomjakushina, K. Conder, A. M. Balagurov

摘要:

高分辨中子衍射结果表明,钙钛矿锰氧化物(La_{1-y} Pr_{y}){0.7} Ca_{0.3} MnO 3的铁磁(FM)和反铁磁(AFM)相的介观分离以及FM转变温度Tc强烈依赖于淬灭关联无序。不同的无序强度是通过不同的样品合成过程实现的,并通过微应变型衍射峰展宽来定量表征。随着关联无序强度的降低,体系转变为具有较小T_C的单相状态,支持了关联淬火无序是锰氧化物体系相分离的起源的观点。最终化学均匀的样品的基态是FM样的,包含约20%的AFM少数相。通过氧同位素取代降低有效载流子带宽,这种类FM态可以很容易地转变为FM相<20%的类AFM态。

英文摘要:

High resolution neutron diffraction shows that the mesoscopic separation into ferromagnetic (FM) and antiferromagnetic (AFM) phases and the FM transition temperature T_C in the perovskite manganite (La_{1-y}Pr_{y})_{0.7}Ca_{0.3}MnO_3 strongly depend on the quenched correlated disorder. The different disorder strengths are achieved by different procedures of the sample synthesis and quantitatively characterized by the micro-strain-type diffraction peak broadening. The system shifts to predominantly one phase state with smaller T_C as the correlated disorder strength is decreased supporting the viewpoint that the origin of phase separation in the indicated manganite system is the correlated quenched disorder. The ground state of an ultimately chemically homogeneous sample is FM-like containing about 20% of the AFM minority phase. This FM-like state can be readily transformed to the AFM-like one having <20% of FM-phase by the decreasing of the effective charge carrier bandwidth via oxygen isotope substitution.

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