We report a novel pressure-induced spin-density-wave transition in the superconductor Mo3Sb7 figured our by measurements of the electrical resistivity and magnetization under hydrostatic pressure. The critical temperature of superconducting Mo3Sb7 is found to increase with increasing pressure, from 2.15 K at 0.2 kbar up to 2.37 K at 22 kbar. Above 4.5 kbar, superconductivity exists in parallel with a pressure-induced spin-density wave state, revealed by a sharp jump in the electrical resistivity and a maximum in the magnetization at the phase transition temperature T_SDW. The application of pressure shifts T_SDW to lower temperatures, from 6.6 K at 4.5 kbar down to 6.15 K at 22 kbar. A strong magnetic field dependence of T_SDW and a maximum seen in the magnetization indicate an antiferromagnetic character of T_SDW. The pressure dependence of T_c and T_SDW suggests a competition of the SDW and the superconducting states in this system.
We revealed that the superconducting transition temperature Tc of the multi-component superconductor Sr2RuO4 is enhanced to 3.3 K under in-plane uniaxial pressure that reduces the tetragonal crystal symmetry. This result suggests that new superconducting phases with a one-component order parameter are induced. We have also clarified the inplane pressure direction dependence of the emergence of this higher-Tc superconducting phase: pressure along the [100] direction is more favorable than pressure along the [110] direction. This result is probably closely related to the direct shortening of the…
Electrical-resistivity and magnetic-susceptibility measurements under hydrostatic pressure up to p = 2.75 GPa have been performed on superconducting LiFeP. A broad superconducting (SC) region exists in the temperature - pressure (T-p) phase diagram. No indications for a spin-density-wave transition have been found, but an enhanced resistivity coefficient at low pressures hints at the presence of magnetic fluctuations. Our results show that the superconducting state in LiFeP is more robust than in the isostructural and isoelectronic LiFeAs. We suggest that this finding is related to the nearly …
In the present work, we measure the temperature dependent electrical resistivity from 300K down to 2K under applied hydrostatic pressure of upto 2.5GPa for SrFBiS2, which is the parent compound for the BiS2 based superconductors. Though the normal state resistivity of the compound decreases with pressure, the same is not superconducting down to 2K under applied pressure of up to 2.5Gpa.
We report high pressure magnetic susceptibility and electrical resistivity measurements on Ca_{3}Ir_{4}Sn_{13} single crystals up to 60 kbar. These measurements allow us to follow the evolution of the superconducting critical temperature T_c, the resistivity anomaly temperature T*, the superconducting coherence length and the Fermi velocity under pressure. The pressure-temperature phase diagram constructed for Ca_{3}Ir_{4}Sn_{13} shows a dome-shaped pressure dependence of T_c. The initial rise in T_c, which is accompanied by a decrease in T*, is consistent with a reduction in the partial gappi…
We report the pressure dependence of the superconducting transition temperature, $T_c$, in TlNi$_2$Se$_{2-x}$S$_x$ detected via the AC susceptibility method. The pressure-temperature phase diagram constructed for TlNi$_{2}$Se$_{2}$, TlNi$_{2}$S$_{2}$ and TlNi$_{2}$SeS exhibits two unexpected features: (a) a sudden collapse of the superconducting state at moderate pressure for all three compositions and (b) a dome-shaped pressure dependence of $T_c$ for TlNi$_{2}$SeS. These results point to the nontrivial role of S substitution and its subtle interplay with applied pressure, as well as novel su…
We measure the electrical resistance of o-TaS3 between 1K and 300K under pressures up to 20GPa. We observe a gradual decrease of the charge density wave transition temperature with increasing pressure P following a mean-field quantum fluctuation power law with a quantum critical point at a pressure Pc = 11.5GPa. Around the quantum critical point we observe a superconducting dome with a maximum superconducting transition temperature Tc = 3.1K. Such dome is similar to superconducting domes around other types of order suggesting that the QCP is directly responsible for the enhancement of supercon…
Recent observation of pressure induced second superconducting phase in AyFe2-xSe2 [A=K, (Tl,Rb)] calls for the models of superconductivity that are rich enough to allow for multiple superconducting phases. We propose the model where pressure induced changes in Fermi surface topology lead to appearance of the hole pocket at $Γ$ point at high pressure. We develop low-energy effective model, derived from first-principles band-structure calculation, to suggest the phase assignment where low pressure superconducting state with no hole pocket at $Γ$ point is a nodeless d-wave state. It evolves into …
Magnetic field and pressure effects on charge density wave, superconducting, and magnetic states in Lu$_5$Ir$_4$Si$_{10}$ and Er$_5$Ir$_4$Si$_{10}$
研究了超导Lu $_5$ Ir $_4$ Si $_{10}$和反铁磁Er $_5$ Ir $_4$ Si $_{10}$的电荷密度波（CDW）态随温度、磁场和流体静压的变化.对于Lu $_5$ Ir $_4$ Si $_{10}$，施加压力强烈抑制CDW相，但微弱地增强超导相。对于Er-$_5$-Ir-$_4$-Si $_{10}$，无公度CDW态与压力无关，公度CDW态与压力有很强的依赖关系，而压力对反铁磁有序有轻微的抑制作用.此外，Er $_5$ Ir $_4$ Si $_{10}$在低温下显示负磁阻，而Lu $_5$ Ir $_4$ Si $_{10}$显示正磁阻。
Magnetic measurements on optimally doped single crystals of BaFe$_2$(As$_{1-x}$P$_{x}$)$_2$ ($x\approx0.35$) with magnetic fields applied along different crystallographic axes were performed under pressure, enabling the pressure evolution of coherence lengths and the anisotropy factor to be followed. Despite a decrease in the superconducting critical temperature, our studies reveal that the superconducting properties become more anisotropic under pressure. With appropriate scaling, we directly compare these properties with the values obtained for BaFe$_2$(As$_{1-x}$P$_{x}$)$_2$ as a function o…
We report electrical resistivity measurements on a high-quality Ba$_{1-x}$K$_{x}$Fe$_{2}$As$_{2}$ thin film ($x=0.4$) under pressure. The superconducting transition temperature (=39.95 K) of the optimally-doped thin film shows a dome shape with pressure, reaching a maximal value 40.8 K at 11.8 kbar. The unusually high superconducting transition temperature and its anomalous pressure dependence are ascribed to a lattice mismatch between the LaAlO$_3$ substrate and the thin film. The local temperature exponent of the resistivity ($n=d\text{ln}Δρ/d\text{ln}T$) shows a funnel shape around the opti…
Quantitative thermodynamic study of superconducting and normal states in UTe2 under pressure
Univ. Grenoble Alpes（格勒诺布尔阿尔卑斯大学）；CEA（法国原子能和替代能源委员会）；Grenoble INP（格勒诺布尔国立理工学院）；IRIG（辐射与集成研究研究所）；PHELIQS（物理化学与量子科学实验室）；Institute for Quantum Materials and Technologies, Karlsruhe Institute of Technology（卡尔斯鲁厄理工学院量子材料与技术研究所）；Max Planck Institute for Chemical Physics of Solids（马克斯·普朗克固体化学物理学研究所）；Institute for Solid State and Materials Physics, TU Dresden University of Technology（德累斯顿工业大学固态与材料物理研究所）；CNRS, Institut Néel（法国国家科学研究中心内耳研究所）
We performed $^{185/187}$Re nuclear quadrupole resonance (NQR) measurements under pressure to investigate the superconducting properties of noncentrosymmetric superconductor Cd$_{2}$Re$_{2}$O$_{7}$ under various crystal structures. The pressure dependence of superconducting transition temperature $T_{\rm c}$ determined through ac susceptibility measurements is consistent with the results of previous resistivity measurements [T. C. Kobayashi $et al$., J. Phys. Soc. Jpn. 80, 023715 (2011).]. Below 2.2 GPa, in the nuclear spin-lattice relaxation rate $1/T_{1}$, a clear coherence peak was observed…
Low-temperature (T) heat-capacity measurements under hydrostatic pressure of up to p=2.1 GPa have been performed on single-crystalline CeCu2Si2. A broad superconducting (SC) region exists in the T-p phase diagram. In the low-pressure region antiferromagnetic spin fluctuations and in the high-pressure region valence fluctuations had previously been proposed to mediate Cooper pairing. We could identify these two distinct SC regions. We found different thermodynamic properties of the SC phase in both regions, supporting the proposal that different mechanisms might be implied in the formation of s…
We report Cu nuclear-quadrupole-resonance results under pressure on a homogeneous CeCu2Si2 (Tc = 0.65 K) that revealed critical magnetic fluctuations at the border to an antiferromagnetic phase. This exotic superconducting phase evolves into the typical heavy-fermion superconducting phase at minute pressures exceeding Pc ~ 0.2 GPa. The nuclear spin-lattice relaxation data in a pressure range 0.85 - 2.58 GPa are shown to be accountable by the SCR theory based on the nearly antiferromagnetic Fermi-liquid model. In 0 < P < Pc ~ 0.2 GPa, by contrast, we conclude that the exotic superconducting pha…
We report measurements of the pressure dependence of the superconducting transition temperature T_c in single crystal samples of the rare-earth doped superconductor Ca$_{0.73}$La$_{0.27}$Fe$_2$As$_2$. We track T_c with two techniques, via in-plane resistivity measurements and with a resonant tunnel diode oscillator circuit which is sensitive to the skin depth. We show that initially T_c rises steeply with pressure, forming a superconducting dome with a maximum T_c of ~44 K at 20 kbar. We discuss this observation in the context of other electron-doped iron pnictide superconductors, and conclude…
The pressure dependence of superconducting transition temperature $T_{\rm c}$ has been investigated through the DC magnetic measurements for FeSe$_{0.8}$ and FeSe$_{1.0}$. For both samples, with increasing pressure $P$, the $T_{\rm c}$$-$$P$ curve exhibits a two-step increase, showing a local maximum of $\sim$11 K at $P$$\sim$1.0 GPa and a rapid increase with an extremely large pressure coefficient for $P$$>$1.5 GPa. $T_{\rm c}$ saturates at $\sim$25 K (21 K) in FeSe$_{1.0}$ (FeSe$_{0.8}$) for $P$$>$3 GPa. A rapid decrease in superconducting volume fraction is observed with an increase in $T_{…
We present measurements of the superconducting critical temperature Tc and upper critical field Hc2 as a function of pressure in the transition metal dichalcogenide 2H-NbS2 up to 20 GPa. We observe that Tc increases smoothly from 6K at ambient pressure to about 8.9K at 20GPa. This range of increase is comparable to the one found previously in 2H-NbSe2. The temperature dependence of the upper critical field Hc2(T) of 2H-NbS2 varies considerably when increasing the pressure. At low pressures, Hc2(0) decreases, and at higher pressures both Tc and Hc2(0) increase simultaneously. This points out th…
We predict that simple metals and early transition metals that become superconducting under high pressures will show a change in sign of their Hall coefficient from negative to positive under pressure. If verified, this will strongly suggest that hole carriers play a fundamental role in `conventional' superconductivity, as predicted by the theory of hole superconductivity.
Charge density wave (CDW) instability is often found in phase diagrams of superconductors such as cuprates and certain transition-metal dichalcogenides. This proximity to superconductivity triggers the question on whether CDW instability is responsible for the pairing of electrons in these superconductors. However, this issue remains unclear and new systems are desired to provide a better picture. Here, we report the temperature-pressure phase diagram of a recently discovered BiS$_2$ superconductor La$_2$O$_2$Bi$_3$AgS$_6$, which shows a possible CDW transition at $T^*\sim$155 K and a supercon…
The antiferromagnet CaFe$_2$As$_2$ does not become superconducting when subject to ideal hydrostatic pressure conditions, where crystallographic and magnetic states also are well defined. By measuring electrical resistivity and magnetic susceptibility under quasi-hydrostatic pressure, however, we find that a substantial volume fraction of the sample is superconducting in a narrow pressure range where collapsed tetragonal and orthorhombic structures coexist. At higher pressures, the collapsed tetragonal structure is stabilized, with the boundary between this structure and the phase of coexistin…
We report muon spin rotation ($μ$SR) and magnetization measurements under pressure on Fe$_{1+δ}$Se$_\mathrm{1\text{-}x}$S$_\mathrm{x}$ with x $\approx 0.11$.Above $p\approx0.6$ GPa we find microscopic coexistence of superconductivity with an extended dome of long range magnetic order that spans a pressure range between previously reported separated magnetic phases. The magnetism initially competes on an atomic scale with the coexisting superconductivity leading to a local maximum and minimum of the superconducting $T_\mathrm{c}(p)$. The maximum of $T_\mathrm{c}$ corresponds to the onset of mag…
Angle-resolved photoemission spectroscopy is used to study the band-structure of superconducting electrochemically intercalated Cu$_x$Bi$_2$Se$_3$. We find that in these samples the band-gap at the $Γ$ point is much larger than in pristine Bi$_2$Se$_3$. Comparison to the results of band-structure calculations indicates that the origin of this large gap is internal stress caused by disorder created by the Cu intercalation. We suggest that the internal pressure may be necessary for superconductivity in Cu$_x$Bi$_2$Se$_3$.
A new NMR anvil cell design is used for measuring the influence of high pressure on the electronic properties of the high-temperature superconductor YBa$_2$Cu$_4$O$_8$ above the superconducting transition temperature $T_{\rm c}$. It is found that pressure increases the spin shift at all temperatures in such a way that the pseudo-gap feature has almost disappeared at 63 kbar. This change of the temperature dependent spin susceptibility can be explained by a pressure induced proportional decrease (factor of two) of a temperature dependent component, and an increase (factor of 9) of a temperature…
We use heat capacity measurements as a function of field rotation to identify the nodal gap structure of CeIrIn5 at pressures to 2.05 GPa, deep inside its superconducting dome. A four-fold oscillation in the heat capacity at 0.3 K is observed for all pressures but with its sign reversed between 1.50 and 0.90 GPa. On the basis of recent theoretical models for the field-angle dependent specific heat, all data, including the sign reversal, imply a d{x^2-y^2} order parameter with nodes along [110], which constrains theoretical models of the pairing mechanism in CeIrIn5.
We report on the synthesis of superconducting single crystals of FeSe, and their characterization by X-ray diffraction, magnetization and resistivity. We have performed ac susceptibility measurements under high pressure in a hydrostatic liquid argon medium up to 14 GPa and we find that TC increases up to 33-36 K in all samples, but with slightly different pressure dependences on different samples. Above 12 GPa no traces of superconductivity are found in any sample. We have also performed a room temperature high pressure X-ray diffraction study up to 12 GPa on a powder sample, and we find that …
Recent Scanning Tunneling Spectra(STS) measurement on underdoped cuprate discovers the increase of the maximum superconducting transition temperature $T_c$ when the size of charge transfer gap (CTG) is reduced. Applying pressure is another well known method to increase maximum $T_c$. However, these pressure experiments also found another puzzle that $T_c$ is enhanced in underdoped and optimal doped samples but suppressed in overdoped. Here we present a possible mechanism based on the charge fluctuation to explain both these two effects simultaneously. Starting from 3-band Hubbard model, we ret…
We report measurements of ac magnetic susceptibility $χ_{ac}$ and de Haas-van Alphen (dHvA) oscillations in KFe$_2$As$_2$ under high pressure up to 24.7 kbar. The pressure dependence of the superconducting transition temperature $T_c$ changes from negative to positive across $P_c \sim 18$ kbar as previously reported. The ratio of the upper critical field to $T_c$, i.e, $B_{c2} / T_c$, is enhanced above $P_c$, and the shape of $χ_{ac}$ vs field curves qualitatively changes across $P_c$. DHvA oscillations smoothly evolve across $P_c$ and indicate no drastic change in the Fermi surface up to 24.7…
Hidden magnetic order within the pressure induced superconducting dome of UTe2
New Cornerstone Science Laboratory, Center for Correlated Matter and School of Physics, Zhejiang University（浙江大学相关物质研究中心新Cornerstone科学实验室）；National Key Laboratory of Surface Physics and Chemistry（表面物理与化学国家重点实验室）；Nanhu Laser Laboratory（南湖激光实验室）；Max Planck Inst（马克斯·普朗克研究所）
Multiple superconducting order parameters are extremely rare. Here we show that a very small pressure can induce this phenomenon in the recently discovered heavy fermion superconductor UTe2. This nearly ferromagnetic system shows several intriguing phenomena, including an extraordinary reinforcement of superconductivity in very strong magnetic fields. We find that pressure can tune the system to a more correlated state and probable magnetic order. The superconducting critical temperature is strongly enhanced, reaching almost 3K, a new record for Ce- and U-based heavy fermion superconductors. M…
We report a novel superconducting (SC) and antiferromagnetic (AF) hybrid state in SrFe2As2 revealed by 75As nuclear magnetic resonance (NMR) experiments on a single crystal under highly hydrostatic pressure up to 7 GPa. The NMR spectra at 5.4 GPa indicate simultaneous development of the SC and AF orders below 30 K. The nuclear spin-lattice relaxation rate in the SC domains shows a substantial residual density of states, suggesting proximity effects due to spontaneous formation of a nano-scale SC/AF hybrid structure. This entangled behavior is a remarkable example of a self-organized heterogene…
We report the pressure dependences of the superconducting transition temperature (T_c) in several perovskite-type Fe-based superconductors through the resistivity measurements up to ~4 GPa. In Ca_4(Mg,Ti)_3Fe_2As_2O_y with the highest T_c of 47 K in the present study, the T_c keeps almost constant up to ~1 GPa, and starts to decrease above it. From the comparison among several systems, we obtained a tendency that low T_c with the longer a-axis length at ambient pressure increases under pressure, but high T_c with the shorter a-axis length at ambient pressure hardly increases. We also report th…
The pressure evolution of the Raman active electronic excitations of the transition metal dichalcogenides 2H-TaS$_2$ is followed through the pressure phase diagram embedding incommensurate charge-density-wave and superconducting states. At high pressure, the charge-density-wave is found to collapse at 8.5~GPa. In the coexisting charge-density-wave and superconducting orders, we unravel a strong in-gap superconducting mode, attributed to a Higgs mode, coexisting with the expected incoherent Cooper-pair breaking signature. The latter remains in the pure superconducting state reached above 8.5~GP…
We performed AC calorimetry and magnetoresistance measurements under pressure for H || a-axis (easy-magnetization axis) in the novel heavy-fermion superconductor UTe2. Thanks to the thermodynamic information, multiple superconducting phases have been revealed under pressure and magnetic field. The (H,T) phase diagram of superconductivity under pressure displays an abrupt increase of the upper critical field (Hc2) at low temperature and in the high field region, and a strong convex curvature of Hc2 at high temperature. This behavior of Hc2 and the multiple superconducting phases require a state…
Two single crystalline samples with the same nominal composition of Rb0.8Fe2Se2 prepared via slightly different precursor routes under the same thermal processing conditions were investigated at ambient and high pressures. One sample was found superconducting with a Tc of ~31 K without the previously reported resistivity-hump and the other was unexpectedly found to be a narrow-gap semiconductor. While the high pressure data can be understood in terms of pressure-induced variation in doping, the detailed doping effect on superconductivity is yet to be determined.
We have measured the temperature dependence of resistivity in single-crystalline CeNiGe$_{3}$ under hydrostatic pressure in order to establish the characteristic pressure-temperature phase diagram. The transition temperature to AFM-I phase $T_{\rm N1}$ = 5.5 K at ambient pressure initially increases with increasing pressure and has a maximum at $\sim$ 3.0 GPa. Above 2.3 GPa, a clear zero-resistivity is observed (SC-I phase) and this superconducting (SC) state coexists with AFM-I phase. The SC-I phase suddenly disappears at 3.7 GPa simultaneously with the appearance of an additional kink anomal…
We report on measurements of the magnetic susceptibility and electrical resistance under He-gas pressure on single crystals of Ca(Fe$_{1-x}$Co$_{x}$)$_{2}$As$_{2}$. We find that for properly heat-treated crystals with modest Co-concentration, $x$ = 0.028, the salient ground states associated with iron-arsenide superconductors, i.e., orthorhombic/antiferromagnetic (o/afm), superconducting, and nonmagnetic collapsed-tetragonal (cT) states can be accessed all in one sample with reasonably small and truly hydrostatic pressure. This is possible owing to the extreme sensitivity of the o/afm (for $T …
This work reports studies performed in the superconducting compound FeSe0:5Te0:5 under high pressure. Changes were observed in the transition temperature, superconducting critical fields,anomalous variations in the Meissner fraction, and in Ginzburg Landau parameters. The superconducting properties were calculated and compared using the Werthamer-Helfand-Hohenber approximation and Ginzburg-Landau theory. Hydrostatic pressure was produced from atmospheric to 823 MPa, the increment in the critical temperature was from 14.45 to 20.5 K at a rate of change about 0.0069 K/MPa.
UTe$_2$ is a recently discovered unconventional superconductor that has attracted much interest due to its many intriguing properties - a large residual density-of-states in the superconducting state, re-entrant superconductivity in high magnetic fields, and potentially spin-triplet topological superconductivity. Our ac calorimetry, electrical resistivity, and x-ray absorption study of UTe$_2$ under applied pressure reveals key new insights on the superconducting and magnetic states surrounding pressure-induced quantum criticality at P$_{c1}$ = 1.3 GPa. First, our specific heat data at low pre…
As the simplest iron-based superconductor, FeSe forms a tetragonal structure with transition temperature Tc ~ 8 K. With assistance of pressure, or other techniques, Tc can be greatly enhanced, even to above liquid nitrogen temperature. The newly discovered superconducting tetragonal FeS (Tc ~ 4.5 K), a sulfide counterpart of FeSe, promotes us on its high pressure investigation. The transport and structure evolution of FeS with pressure have been studied. A rapid suppression of Tc and vanishing of superconductivity at 4.0 GPa are observed, followed by a second superconducting dome with a 30% en…
We present the structural, electronic and superconducting properties of Li2B2 under pressure within the framework of the density functional theory. The structural parameters, electronic band structure, phonon frequency of the E2g phonon mode and superconducting critical temperature Tc were calculated for pressures up to 20 GPa. We predicted that the superconducting critical temperature of Li2B2 is about 11 K and this decreases as pressure increases. We found that even though the lattice dynamics of the E2g phonon mode is similar to MgB2, the reduction of the σ-band density of states at Fermi l…
The pressure dependence, up to 11.3 kbar, of basic parameters of the superconducting state, such as the critical temperature (Tc), the lower and the upper critical fields, the coherence length, the penetration depth, and their anisotropy, was determined from magnetic measurements performed for two singlecrystalline samples of FeTe0.5Se0.5. We have found pressure-induced enhancement of all of the superconducting state properties, which entails a growth of the density of superconducting carriers. However, we noticed more pronounced increase in superconducting carrier density under pressure than …
Resistivity and magnetic susceptibility measurements under external pressure were performed on single-crystals NaFe1-xCoxAs (x=0, 0.01, 0.028, 0.075, 0.109). The maximum Tc enhanced by pressure in both underdoped and optimally doped NaFe1-xCoxAs is the same, as high as 31 K. The overdoped sample with x = 0.075 also shows a positive pressure effect on Tc, and an enhancement of Tc by 13 K is achieved under pressure of 2.3 GPa. All the superconducting samples show large positive pressure coefficient on superconductivity, being different from Ba(Fe1-xCox)2As2. However, the superconductivity cannot…
Candidates for new thermoelectric and superconducting materials, which have narrow band gap and flat bands near band edges, were searched by the high-throughput first-principles calculation from an inorganic materials database. The synthesized SnBi$_2$Se$_4$ among the target compounds showed a narrow band gap of 354 meV, and a thermal conductivity of 1 W/Km at ambient pressure. The sample SnBi$_2$Se$_4$ showed a metal-insulator transition at 11.1 GPa, as predicted by a theoretical estimation. Furthermore, the two pressure-induced superconducting transitions were discovered at under 20.2 GPa an…
