Variation in Superconducting Symmetry against Pressure on Noncentrosymmetric Superconductor Cd$_2$Re$_2$O$_7$ Revealed by $^{185/187}$Re Nuclear Quadrupole Resonance
We performed $^{185/187}$Re nuclear quadrupole resonance (NQR) measurements under pressure to investigate the superconducting properties of noncentrosymmetric superconductor Cd$_{2}$Re$_{2}$O$_{7}$ under various crystal structures. The pressure dependence of superconducting transition temperature $T_{\rm c}$ determined through ac susceptibility measurements is consistent with the results of previous resistivity measurements [T. C. Kobayashi $et al$., J. Phys. Soc. Jpn. 80, 023715 (2011).]. Below 2.2 GPa, in the nuclear spin-lattice relaxation rate $1/T_{1}$, a clear coherence peak was observed just below $T_{\rm c}$, indicating conventional $s$-wave superconductivity. In contrast, the coherence peak disappears at 3.1 GPa, suggesting a change in superconducting symmetry to the $p$-wave dominant state against pressure.
We present synthesis and $^{75}$As-nuclear quadrupole resonance (NQR) measurements for the noncentrosymmetric superconductor CaPtAs with a superconducting transition temperature $T_c$ of $\sim 1.5$ K. We discovered two different forms of CaPtAs during synthesis; one is a high-temperature tetragonal form that was previously reported, and the other is a low-temperature form consistent with the orthorhombic structure of CaPtP. According to the $^{75}$As-NQR measurement for superconducting tetragonal CaPtAs, the nuclear spin-lattice relaxation rate $1/T_1$ has an obvious coherence peak below $T_c$…
We report normal and superconducting properties of the Rashba-type noncentrosymmetric com- pound CaIrSi3, using single crystalline samples with nearly 100% superconducting volume fraction. The electronic density of states revealed by the hard x-ray photoemission spectroscopy can be well explained by the relativistic first-principle band calculation. This indicates that strong spin-orbit interaction indeed affects the electronic states of this compound. The obtained H - T phase diagram exhibits only approximately 10% anisotropy, indicating that the superconducting properties are almost three di…
We report the longitudinal resistivity and Hall effect measurements on the noncentrosymmetric superconducting Mg$_{12-δ}$Ir$_{19}$B$_{16}$ samples with different critical transition temperatures. A strong temperature dependence of the Hall coefficient $R_H$ and nonlinear magnetic field dependence of the Hall resistivity $ρ_{xy}$ in wide temperature region are observed, suggesting a strong multi-band effect in this system. Moreover, a large magnetoresistance up to 20% is found at the field of 9 T. We also observe the violation of the Kohler's rule from our magnetoresistance data, further confir…
RhGe synthesized at high pressure is crystallized in noncentrosymmetric cubic structure of the B20 type. Measurements of the electrical resistivity and magnetization demonstrate a superconducting state below T$_c$ ~ 4.5 K and a weak ferromagnetism below T$_m$ ~ 140 K. Specific heat data confirm the bulk nature of superconductivity in this ferromagnetic superconductor. The superconducting region forms a dome on the P-T diagram with a maximum of T$_c$ near 4 GPa. Ab initio simulations suggest that the observed weak magnetization emerges from the pronounced spin polarization with magnetic quadrup…
We report a $^{71}$Ga nuclear-quadrupole-resonance (NQR) study on the characteristics of superconductivity in noncentrosymmetric Ir$_2$Ga$_9$ at zero field (H=0). The $^{71}$Ga-NQR measurements have revealed that $1/T_1$ has the clear coherence peak just below $T_{\rm c}$, and decreases exponentially upon further cooling in Ir$_2$Ga$_9$. From these results, Ir$_2$Ga$_9$ is concluded to be the conventional s-wave superconductor. Despite the lack of spatial centrosymmetry, there are no evidence for unconventional superconducting state ascribed to ASOC in Ir$_2$Ga$_9$.
We report the discovery of Zr$_3$Ir as a new type of unconventional noncentrosymmetric superconductor (with $T_c = 2.3$ K), here investigated mostly via muon-spin rotation/relaxation ($μ$SR) techniques. Its superconductivity was characterized using magnetic susceptibility, electrical resistivity, and heat capacity measurements. The low-temperature superfluid density, determined via transverse-field $μ$SR and electronic specific heat, suggests a fully-gapped superconducting state. The spontaneous magnetic fields, revealed by zero-field $μ$SR below $T_c$, indicate the breaking of time-reversal s…
We report 29Si-NMR study on a single crystal of the heavy-fermion superconductor CeIrSi3 without an inversion symmetry along the c-axis. The 29Si-Knight shift measurements under pressure have revealed that the spin susceptibility for the ab-plane decreases slightly below Tc, whereas along the c-axis it does not change at all. The result can be accounted for by the spin susceptibility in the superconducting state being dominated by the strong antisymmetric (Rashba-type) spin-orbit interaction that originates from the absence of an inversion center along the c-axis and it being much larger than …
We report a systematic study by 75As nuclear-quadrupole resonance in LaFeAsO1-xFx. The antiferromagnetic spin fluctuation (AFSF) found above the magnetic ordering temperature TN = 58 K for x = 0.03 persists in the regime 0.04 < x < 0.08 where superconductivity sets in. A dome-shaped x-dependence of the superconducting transition temperature Tc is found, with the highest Tc = 27 K at x = 0.06 which is realized under significant AFSF. With increasing x further, the AFSF decreases, and so does Tc. These features resemble closely the cuprates La2-xSrxCuO4. In x = 0.06, the spin-lattice relaxation …
Noncentrosymmetric superconductors have sparked significant research interests due to their exciting properties, such as the admixture of spin-singlet and spin-triplet Cooper pairs. Here we report $μ$SR and thermodynamic measurements on the noncentrosymmetric superconductor La7Rh3 which indicate a fully established superconducting gap and spontaneous time-reversal-symmetry breaking at the onset of superconductivity. We show that our results pose severe constraints on any microscopic theory of superconductivity in the system. A symmetry analysis identifies ground states compatible with time-rev…
We report the $^{121/123}$Sb-NMR/nuclear quadrupole resonance (NQR) measurements on the newly-discovered superconductor BaTi$_2$Sb$_2$O with a two-dimensional Ti$_2$O square-net layer formed with Ti$^{3+}$ (3$d^1$). NQR measurements revealed that the in-plane four-fold symmetry is broken at the Sb site below $T_{\rm A} \sim$ 40 K, without an internal field appearing at the Sb site. These exclude a spin-density wave (SDW)/ charge density wave (CDW) ordering with incommensurate correlations, but can be understood with the commensurate CDW ordering at $T_{\rm A}$. The spin-lattice relaxation rate…
We report $^{75}$As nuclear quadrupole resonance (NQR) studies on superconducting oxypnictide LaFeAsO$_{0.92}$F$_{0.08}$ ($T_{\rm c}$ = 23 K). The temperature dependence of the spin lattice relaxation rate (1/$T_1$) decreases below $T_{\rm c}$ without a coherence (Hebel-Slichter) peak and shows a temperature dependence that is not simple power-law nor exponential. We show that the result can be understood in terms of two superconducting gaps of either $d$- or ${\pm}s$-wave symmetry, with the larger gap $Δ_1\sim 4 k_{\rm B}T_{\rm c}$ and the smaller one $Δ_2 \sim 1.5 k_{\rm B}T_{\rm c}$. Our re…
The noncentrosymmetric superconductor Re$_{24}$Ti$_{5}$, a time-reversal symmetry (TRS) breaking candidate with $T_c = 6$\,K, was studied by means of muon-spin rotation/relaxation ($μ$SR) and tunnel-diode oscillator (TDO) techniques. At a macroscopic level, its bulk superconductivity was investigated via electrical resistivity, magnetic susceptibility, and heat capacity measurements. The low-temperature penetration depth, superfluid density and electronic heat capacity all evidence an $s$-wave coupling with an enhanced superconducting gap. The spontaneous magnetic fields revealed by zero-field…
We present here the mathematical background of our approach, presented in Phys. Rev. B 86, 134526 (2012) regarding the gap function and symmetry for the noncentrosymmetric (NCS) superconductor $Li_2Pt_3B$. As revealed by the experiment, this NCS superconductor gives rise to line nodes in the superconducting order parameter, which is responsible for many of its experimental behaviors. Owing to the enhanced d-character of the relevant bands that cross the Fermi level,the system gets weakly correlated. The nature and symmetry of this nodal behavior is explained from a microscopic viewpoint. In th…
Co nuclear-quadrupole-resonance (NQR) measurements were performed on various bilayered hydrate cobaltate Na_x(H_3O)_zCoO_2\cdot yH_2O with different values of the superconducting and magnetic-ordering temperatures, T_c and T_M, respectively. From measurements of the temperature and sample dependence of the NQR frequency, it was revealed that the NQR frequency is changed by the change of the electric field gradient (EFG) along the c axis ν_{zz} rather than the asymmetry of EFG within the ab-plane. In addition, it is considered that the change of ν_{zz} is gaverned mainly by the trigonal distort…
In this Rapid Communication, a set of $^{209}$Bi-nuclear magnetic resonance (NMR)/nuclear quadrupole resonance (NQR) measurements has been performed to investigate the physical properties of superconducting (SC) BaTi$_2$Bi$_2$O from a microscopic point of view. The NMR and NQR spectra at 5~K can be reproduced with a non-zero in-plane anisotropic parameter $η$, indicating the breaking of the in-plane four-fold symmetry at the Bi site without any magnetic order, i.e., `the electronic nematic state'. In the SC state, the nuclear spin-lattice relaxation rate divided by temperature, $1/T_1T$, does …
We report $^{125}$Te nuclear magnetic resonance and $^{181}$Ta nuclear quadrupole resonance studies on single-crystal Ta$_{4}$Pd$_{3}$Te$_{16}$, which has a quasi-one-dimensional structure and superconducts below $T_{\rm c}=4.3$ K. $^{181}$Ta with spin $I=7/2$ is sensitive to quadrupole interactions, while $^{125}$Te with spin $I=1/2$ can only relax by magnetic interactions. By comparing the spin-lattice relaxation rate ( $1/T_{1}$) of $^{181}$Ta and $^{125}$Te, we found that electric-field-gradient (EFG) fluctuations develop below $80$ K. The EFG fluctuations are enhanced with decreasing temp…
We report a $^{73}$Ge nuclear-quadrupole-resonance (NQR) study on novel evolution of unconventional superconductivity in antiferromagnetic (AFM) CeNiGe$_3$. The measurements of the $^{73}$Ge-NQR spectrum and the nuclear spin-lattice relaxation rate ($1/T_1$) have revealed that the unconventional superconductivity evolves inside a commensurate AFM phase around the pressure ($P$) where Néel temperature $T_{\rm N}$ exhibits its maximum at 8.5 K. The superconducting transition temperature $T_{\rm SC}$ has been found to be enhanced with increasing $T_{\rm N}$, before reaching the quantum critical p…
We report $^{115}$In nuclear quadrupolar resonance (NQR) measurements on the heavy-fermion superconductor PuCoIn$_5$, in the temperature range $0.29{\rm K}\leq T\leq 75{\rm K}$. The NQR parameters for the two crystallographically inequivalent In sites are determined, and their temperature dependence is investigated. A linear shift of the quadrupolar frequency with lowering temperature below the critical value $T_c$ is revealed, in agreement with the prediction for composite pairing. The nuclear spin-lattice relaxation rate $T_1^{-1}(T)$ clearly signals a superconducting (SC) phase transition a…
Pressure evolution of the normal- and superconducting-state properties of the line-nodal material CaSb$_2$ revealed by $^{123}$Sb nuclear quadrupole resonance
We report detailed 17O, 139La, and 63Cu Nuclear Magnetic Resonance (NMR) and Nuclear Quadrupole Resonance (NQR) measurements in a stripe ordered La1.875Ba0.125CuO4 single crystal and in oriented powder samples of La1.8-xEu0.2SrxCuO4. We observe a partial wipeout of the 17O NMR intensity and a simultaneous drop of the 17O electric field gradient (EFG) at low temperatures where the spin stripe order sets in. In contrast, the 63Cu intensity is completely wiped out at the same temperature. The drop of the 17O quadrupole frequency is compatible with a charge stripe order. The 17O spin lattice relax…
We discuss superconductivity in a model on a cubic lattice for a $Γ_3$ non-Kramers system. In previous studies, it is revealed that $d$-wave superconductivity with $E_g$ symmetry occurs in a wide parameter range in a $Γ_3$ system. Such anisotropic superconductivity can break the cubic symmetry of the lattice. In a $Γ_3$ system, the quadrupole degrees of freedom are active and the effect of the cubic symmetry breaking should be important. Here, we investigate the coexisting states of the $d$-wave superconductivity and quadrupole order by a mean-field theory. In particular, we discuss possible c…
To trace the origin of time-reversal symmetry breaking (TRSB) in Re-based superconductors, we performed comparative muon-spin rotation/relaxation ($μ$SR) studies of superconducting noncentrosymmetric Re$_{0.82}$Nb$_{0.18}$ ($T_c = 8.8$ K) and centrosymmetric Re ($T_c = 2.7$ K). In Re$_{0.82}$Nb$_{0.18}$, the low temperature superfluid density and the electronic specific heat evidence a fully-gapped superconducting state, whose enhanced gap magnitude and specific-heat discontinuity suggest a moderately strong electron-phonon coupling. In both Re$_{0.82}$Nb$_{0.18}$ and pure Re, the spontaneous …
We report $^{121/123}$Sb nuclear quadrupole resonance (NQR) and $^{51}$V nuclear magnetic resonance (NMR) measurements on kagome metal CsV$_3$Sb$_5$ with $T_{\rm c}=2.5$ K. Both $^{51}$V NMR spectra and $^{121/123}$Sb NQR spectra split after a charge density wave (CDW) transition, which demonstrates a commensurate CDW state. The coexistence of the high temperature phase and the CDW phase between $91$ K and $94$ K manifests that it is a first order phase transition. At low temperature, electric-field-gradient fluctuations diminish and magnetic fluctuations become dominant. Superconductivity eme…
Signatures of time-reversal-symmetry breaking in multiband 2H-TaS2 revealed by zero-field Josephson nonreciprocity
CIC nanoGUNE BRTA（纳米科学中心）；Centro de Física de Materiales – Materials Physics Center (CFM-MPC) CSIC-EHU（材料物理中心）；Istituto di Struttura della Materia, Consiglio Nazionale delle Ricerche（意大利国家研究理事会材料结构研究所）
We measure the nuclear quadrupole resonance (NQR) signal on the Zn site in nearly optimally doped YBa$_2$Cu$_3$O$_{6.92}$, when Cu is substituted by 3\% of isotopically pure $^{67}$Zn. We observe that Zn creates large insulating islands, confirming two earlier conjectures: that doping provokes an orbital transition in the CuO$_2$ plane, which is locally reversed by Zn substitution, and that the islands are antiferromagnetic. Also, we find that the Zn impurity locally induces a breaking of the D$_4$ symmetry. Cluster and DFT calculations show that the D$_4$ symmetry breaking is due to the same …
$^{73}$Ge and $^{59}$Co nuclear magnetic resonance (NMR) and nuclear quadrupole resonance (NQR) measurements have been performed on a $^{73}$Ge-enriched single-crystalline sample of the ferromagnetic superconductor UCoGe in the paramagnetic state. The $^{73}$Ge NQR parameters deduced from NQR and NMR are close to those of another isostructural ferromagnetic superconductor URhGe. The Knight shifts of the Ge and Co sites are well scaled to each other when the magnetic field is parallel to the $b$ or $c$ axis. The hyperfine coupling constants of Ge are estimated to be close to those of Co. The la…
We report an 75As-nuclear quadrupole resonance (NQR) study on heavily electron-doped LaFeAsO_1-xF_x(La1111) with Tc=5 K. Nuclear spin relaxation rate (1/T1) measurement has revealed that a Hebel-Slichter (HS) peak partially recovers in heavily electron-overdoped regimes where the nesting condition of hole and electron Fermi surfaces(FSs) becomes significantly worse. This is in contrast to previous results reported in optimally doped La1111 with Tc=28 K where a lack of the HS peak was reported. It indicates that the interband scattering between the hole and electron FSs is strongly suppressed b…
We report $^{75}$As nuclear magnetic resonance (NMR) and nuclear quadrupole resonance (NQR) studies on the superconductor Rb$_{2}$Cr$_{3}$As$_{3}$ with a quasi one-dimensional crystal structure. Below $T\sim$ 100 K, the spin-lattice relaxation rate (1/$T_{1}$) divided by temperature, 1/$T_{1}T$, increases upon cooling down to $T_{\rm c}$ = 4.8 K, showing a Curie-Weiss-like temperature dependence. The Knight shift also increases with decreasing temperature. These results suggest ferromagnetic spin fluctuation. In the superconducting state, 1/$T_{1}$ decreases rapidly below $T_{\text{c}}$ withou…
Motivated by the recent observation of ferromagnetic spin correlations in the filled skutterudite SrFe$_4$As$_{12}$ [Ding et al., Phys. Rev. B 98, 155149 (2018)], we have carried out $^{75}$As nuclear magnetic resonance (NMR) and nuclear quadrupole resonance (NQR) measurements to investigate the role of magnetic fluctuations in a newly discovered isostructural superconductor SrOs$_4$As$_{12}$ with a superconducting transition temperature of $T_{\rm c}$ $\sim$ 4.8 K. Knight shift $K$ determined by the NQR spectrum under a small magnetic field ($\le$ 0.5 T) is nearly independent of temperature, …
Co nuclear magnetic resonance (NMR) and nuclear quadrupole resonance (NQR) studies were performed in the recently discovered UCoGe, in which the ferromagnetic and superconducting (SC) transitions were reported to occur at $T_{\rm Curie} \sim 3$ K and $T_S \sim 0.8$ K (N. T. Huy {\it et al.}, Phys. Rev. Lett. {\bf 99} (2007) 067006), in order to investigate the coexistence of ferromagnetism and superconductivity as well as the normal-state and SC properties from a microscopic point of view. From the nuclear spin-lattice relaxation rate $1/T_1$ and Knight-shift measurements, we confirmed that fe…
Incommensurate modulation with $Q=0$ A-type Antiferromagnetic Order in CeRh$_2$As$_2$ revealed by NQR studies
Kyoto University（京都大学）；Max Planck Institute for Chemical Physics of Solids（马克斯·普朗克固体化学物理研究所）；Institute for Quantum Materials and Technology, Karlsruhe Institute of Technology（卡尔斯鲁厄理工学院量子材料与技术研究所）；Technical University Dresden, Institute for Solid State and Materials Physics（德累斯顿工业大学固体与材料物理研究所）
The relationship between charge density wave (CDW) orders and superconductivity in arsenide superconductor SrPt$_2$As$_2$ with $T_c$ = 5.2 K which crystallizes in the CaBe$_2$Ge$_2$-type structure was studied by $^{75}$As nuclear magnetic resonance (NMR) measurements up to 520 K, and $^{75}$As nuclear quadrupole resonance (NQR) and $^{195}$Pt-NMR measurements down to 1.5 K. At high temperature, $^{75}$As-NMR spectrum and nuclear spin relaxation rate ($1/T_1$) have revealed two distinct CDW orders, one realized in the As-Pt-As layer below $T_{\rm CDW}^{\rm As(1)}$ $=$ 410 K and the other in the…
We report $^{75}$As nuclear magnetic resonance (NMR) studies on a new iron-based superconductor CaKFe$_4$As$_4$ with $T_{\rm c}$ = 35 K. $^{75}$As NMR spectra show two distinct lines corresponding to the As(1) and As(2) sites close to the K and Ca layers, respectively, revealing that K and Ca layers are well ordered without site inversions. We found that nuclear quadrupole frequencies $ν_{\rm Q}$ of the As(1) and As(2) sites show an opposite temperature ($T$) dependence. Nearly $T$ independent behavior of the Knight shifts $K$ are observed in the normal state, and a sudden decrease in $K$ in t…
We report that a novel type of superconducting order parameter has been realized in the ferromagnetic states in UGe$_2$ via $^{73}$Ge nuclear-quadrupole-resonance (NQR) experiments performed under pressure ($P$). Measurements of the nuclear spin-lattice relaxation rate $(1/T_1)$ have revealed an unconventional nature of superconductivity such that the up-spin band is gapped with line nodes, but the down-spin band remains gapless at the Fermi level. This result is consistent with that of a ferromagnetic spin-pairing model in which Cooper pairs are formed among ferromagnetically polarized electr…
We report Cu nuclear-quadrupole-resonance results under pressure on a homogeneous CeCu2Si2 (Tc = 0.65 K) that revealed critical magnetic fluctuations at the border to an antiferromagnetic phase. This exotic superconducting phase evolves into the typical heavy-fermion superconducting phase at minute pressures exceeding Pc ~ 0.2 GPa. The nuclear spin-lattice relaxation data in a pressure range 0.85 - 2.58 GPa are shown to be accountable by the SCR theory based on the nearly antiferromagnetic Fermi-liquid model. In 0 < P < Pc ~ 0.2 GPa, by contrast, we conclude that the exotic superconducting pha…
The phase separation of the ferromagnetic (FM) and paramagnetic (PM) phases in the superconducting (SC) state of UCoGe at the FM critical region was investigated using $^{59}$Co nuclear quadrupole resonance (NQR) technique by taking advantage of its site-selective feature. The NQR measurements revealed that the first-order quantum phase transition occurs between the FM and the PM states. The nuclear spin-lattice relaxation rate $1/T_1$ exhibited a clear drop at the SC state in the PM phase, whereas it was not detected in the FM phase, which indicates that the superconductivity in the FM phase …
Intertwined Charge and Spin Density Waves in Trilayer Nickelate La$_4$Ni$_3$O$_{10}$ Revealed by $^{139}$La NQR
Institute of Physics, Chinese Academy of Sciences（中国科学院物理研究所）；Beijing National Laboratory for Condensed Matter Physics（北京凝聚态物理国家研究中心）；School of Physical Sciences, University of Chinese Academy of Sciences（中国科学院大学物理科学学院）；State Key Laboratory of Crystal Materials, Institute of Crystal Materials, Shandong University（山东大学晶体材料研究所晶体材料国家重点实验室）；State Key Laboratory of Quantum Functional Materials, School of Physical Science and Technology, ShanghaiTech University（上海科技大学物质科学与技术学院量子功能材料国家重点实验室）；School of Physics and Astronomy, Beijing Normal University（北京师范大学物理与天文学院）；Key Laboratory of Multiscale Spin Physics, Ministry of Education, Beijing Normal University（北京师范大学多尺度自旋物理教育部重点实验室）
We report systematic measurements of ac-susceptibility, nuclear-quadrupole-resonance spectrum, and nuclear-spin-lattice-relaxation time ($T_1$) on the pressure ($P$)- induced heavy-fermion (HF) superconductor CeRhIn$_5$. The temperature ($T$) dependence of $1/T_1$ at $P$ = 1.6 GPa has revealed that antiferromagnetism (AFM) and superconductivity (SC) coexist microscopically, exhibiting the respective transition at $T_N = 2.8$ K and $T^{MF}_c$ = 0.9 K. It is demonstrated that SC does not yield any trace of gap opening in low-lying excitations below $T_c^{onset} = 2$ K, but $T_c^{MF} = 0.9$ K, fo…
We report $^{115}$In nuclear-quadrupole-resonance (NQR) measurements of the pressure($P$)-induced superconductor CeRhIn$_5$ in the antiferromagnetic (AF) and superconducting (SC) states. In the AF region, the internal field $H_{int}$ at the In site is substantially reduced from $H_{int}=1.75$ kOe at P=0 to 0.39 kOe at $P=1.23$ GPa, while the Néel temperature slightly changes with increasing $P$. This suggests that either the size in the ordered moment $M_{Q}(P)$ or the angle $θ(P)$ between the direction of $M_{Q}(P)$ and the tetragonal $c$ axis is extrapolated to zero at $P^*=1.6 \pm 0.1$ GPa …
We report on systematic evolutions of antiferromagnetic (AFM) spin fluctuations and unconventional superconductivity (SC) in heavy-fermion (HF) compounds CeRh$_{1-x}$Ir$_{x}$In$_5$ via $^{115}$In nuclear-quadrupole-resonance (NQR) experiment. The measurements of nuclear spin-lattice relaxation rate $1/T_1$ have revealed the marked development of AFM spin fluctuations as a consequence of approaching an AFM ordered state with increasing Rh content. Concomitantly the superconducting transition temperature $T_{\rm c}$ and the energy gap $Δ_0$ increase drastically from $T_{\rm c} = 0.4$ K and $2Δ_0…
We report 75As-NQR/NMR studies on the oxygen-deficient iron(Fe)-based oxypnictide superconductors LaFeAsO_{0.6} (T_c=28 K) along with the results on LaFeAsO, LaFeAsO_{0.75}(T_c=20 K) and NdFeAsO_{0.6}(T_c=53 K). Nuclear spin-lattice relaxation rate 1/T_1 of 75As NQR at zero field on LaFeAsO_{0.6} has revealed a T^3 dependence below T_c upon cooling without the coherence peak just below T_c, evidencing the unconventional superconducting state with the line-node gap. We have found an intimate relationship between the nuclear quadrupole frequencyof 75As and T_c for four samples used in this study…
We report the discovery of exotic superconductivity (SC) and novel magnetism in heavy-fermion (HF) compounds, CeCu$_2$Si$_2$, CeRhIn$_5$ and CeIn$_3$ through nuclear-quadrupole-resonance (NQR) measurements under pressure ($P$). The exotic SC in a homogeneous CeCu$_2$Si$_2$ revealed antiferromagnetic critical fluctuations at the border to antiferromagnetism (AFM) or marginal AFM. The uniform mixed phase of SC and AFM in CeCu$_2$(Si$_{1-x}$Ge$_x$)$_2$ emerges on a microscopic level, once a tiny amount of 1%Ge($x=0.01$) is substituted for Si to expand its lattice. The application of minute pressu…
Nonreciprocal responses of noncentrosymmetric quantum materials attract recent intensive interests, which is essential for the rectification function in diodes. A recent breakthrough is the discovery of superconducting diode effect. The principle to enlarge rectification effect is highly desired to guide the design of superconducting diode. Here, we study theoretically the Josephson junction S/FI/S (S: $d$-wave superconductor, FI: ferromagnetic insulator) on the surface of a topological insulator (TI). The simultaneous existence of $\sinφ$, $\cosφ$ and $\sin 2φ$ terms with almost the same orde…
Determination of the symmetry property of superconducting gaps has been a central issue in studies to understand the mechanisms of unconventional superconductivity. Although it is often difficult to completely achieve the aforementioned goal, the existence of superconducting nodes, one of the few important experimental signatures of unconventional superconductivity, plays a vital role in exploring the possibility of unconventional superconductivity. The interplay between superconducting nodes and topology has been actively investigated, and intensive research in the past decade has revealed va…
We report on a pressure-induced evolution of exotic superconductivity and spin correlations in CeIr(In$_{1-x}$Cd$_{x}$)$_5$ by means of In-Nuclear-Quadrupole-Resonance (NQR) studies. Measurements of an NQR spectrum and nuclear-spin-lattice-relaxation rate $1/T_1$ have revealed that antiferromagnetism induced by the Cd-doping emerges locally around Cd dopants, but superconductivity is suddenly induced at $T_c$ = 0.7 and 0.9 K at 2.34 and 2.75 GPa, respectively. The unique superconducting characteristics with a large fraction of the residual density of state at the Fermi level that increases wit…
We report 75As-nuclear quadrupole resonance (NQR) studies on (Ca_4Al_2O_{6-y})(Fe_2As_2) with Tc=27K, which unravel unique normal-state properties and point to unconventional nodeless superconductivity (SC). Measurement of nuclear-spin-relaxation rate 1/T_1 has revealed a significant development of two dimensional (2D) antiferromagnetic (AFM) spin fluctuations down to Tc, in association with the fact that FeAs layers with the smallest As-Fe-As bond angle are well separated by thick perovskite-type blocking layer. Below Tc, the temperature dependence of 1/T_1 without any trace of the coherence …
