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arXiv 0812.4766cond-mat.stat-mech
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稀有流体的热力学行为是否符合对应态原理?

Is the thermodynamic behavior of the noble fluids consistent with the Principle of Corresponding States?

V. L. Kulinskii, N. P. Malomuzh, O. I. Matvejchuk

摘要:

讨论了对应态原理对稀有流体的适用性。给出了氩、氪等重惰性气体中液相二聚化的热力学证据,这些证据表现为偏离PCS。分析了熵和密度的直线直径的行为。它表明,这些特性是非常敏感的二聚过程中发生的重惰性气体的液相。

英文摘要:

The applicability of the Principle of Corresponding States (PCS) for the noble fluids is discussed. We give the thermodynamic evidences for the dimerization of the liquid phase in heavy noble gases like argon, krypton etc. which manifest itself in deviation from the PCS. The behavior of the rectilinear diameter of the entropy and the density is analyzed. It is shown that these characteristics are very sensitive to the dimerization process which takes place in the liquid phase of heavy noble gases.

机构、总结、中文摘要均由AI分析而来,可能存在错误,请以论文正文为准。

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