The theoretical aspects of spin-rotation coupling are presented. The approach is based on the general covariance principle. It is shown that the gyrogravitational ratio of the bare spin-1/2 and the spin-1 particles is equal unity. That is why spin couples with rotation as an ordinary angular momentum. This result is the rigorous substantiation of the cranking model. To observe the phenomenon, the experiment with hydrogen-like ions in a storage ring is suggested. It is found that the splitting of the $1 ^2!S_{1/2}, F=1/2$ hyperfine state of the $^{140}{\rm Pr}^{58+}$ and $^{142}{\rm Pm}^{60+}$ ions circulating in the storage ring ESR in Darmstadt along a helical trajectory is about 4.5 MHz. We argue that such splitting can be experimentally determined by means of the ionic interferometry.
The hyperfine structure splittings are determined for all five bound $S(L = 0)-$states in the three symmetric muonic molecular ions: $ppμ, ddμ$ and $ttμ$. The expectation values of all interparticle delta-functions used in our calculations have been determined in recent highly accurate computations.
The hyperfine structure splittings of the ground states of the $pdμ, ptμ$ and $dtμ$ ions are determined with the use of highly accurate expectation values of the interparticle delta-functions obtained in recent computations. The corresponding hyperfine structure splittings, e.g., $Δ_{12} =$ 1.3400149$\cdot 10^7$ $MHz$ and $Δ_{23} =$ 3.3518984$\cdot 10^7$ $MHz$ for the $ptμ$ ion, can directly be measured in modern experiments.
By solving the two-body Schordinger equation in a very high precise nonperturbative numerical (NPnum) way, we reexamine the contributions of fine, hyperfine structure splittings of muonic hydrogen based on the Breit potential. The comparison of our results with those by the first order perturbative theory ($^{1st}$PT) in the literature shows, when the structure of proton is considered, the differences between the results by the $^{1st}$PT and NPnum methods are small for the fine and hyperfine splitting of $2P$ state, while are about $-0.009$ meV and $0.08$ meV for the $F=1$ and total hyperfine…
We have investigated the correction to the hyperfine structure of heavy multicharged ions, which is connected with the nuclear-polarization effect caused by the unpaired bound electron. Numerical calculations are performed for hydrogenlike ions taking into account the dominant collective nuclear excitations. The correction defines the ultimate limit of precision in accurate theoretical predictions of the hyperfine-structure splittings.
Relativistic self-consistent-field calculations of the radial hyperfine integrals have been performed in the 4d-shell element ions. The comparison with available experimental results gives an estimate of configuration interaction effects in the hyperfine interaction in these ions. The results can also be used to derive nuclear moments from laserspectroscopic measurements of radioactive isotopes. PACS Numbers: 31.15.Ne, 31.30.Gs, 32.10.Fn
We present the leading-order prediction of baryon chiral perturbation theory for the proton polarizability contribution to the 2S hyperfine splitting in muonic hydrogen, and compare with the results of dispersive calculations.
We present a precise determination of the polarizability and other proton structure dependent contributions to the hydrogen hyperfine splitting, based heavily on the most recent published data on proton spin dependent structure functions from the EG1 experiment at the Jefferson Laboratory. As a result, the total calculated hyperfine splitting now has a standard deviation slightly under 1 part-per-million, and is about 1 standard deviation away from the measured value. We also present results for muonic hydrogen hyperfine splitting, taking care to ensure the compatibility of the recoil and pola…
We show that the non-spherical charge distribution of the proton manifests itself in hydrogen hyperfine splitting as an increase (in absolute value) of the proton Zemach radius and polarization contributions.
The one-loop self-energy correction to the hyperfine structure splitting of the 1s and 2s states of hydrogenlike ions is calculated both for the point and finite nucleus. The results of the calculation are combined with other corrections to find the ground state hyperfine splitting in lithiumlike ^{209}Bi^{80+} and ^{165}Ho^{64+}.
Hyperfine structures of the triplet $n^3S-$states in the four-electron Be-atom(s) and Be-like ions are considered. It is shown that to determine the hyperfine structure splitting in such atomic systems one needs to know the triplet electron density at the central atomic nucleus $ρ_T(0)$. We have developed the procedure which allows allows one to determine such an electron density $ρ_T(0)$ for arbitrary four-electron atoms and ions.
We present the derivation of the formulas for the proton structure-dependent terms in the hyperfine splitting of muonic hydrogen. We use compatible conventions throughout the calculations to derive a consistent set of formulas that reconcile differences between our results and some specific terms in earlier work. Convention conversion corrections are explicitly presented, which reduce the calculated hyperfine splitting by about 46 ppm. We also note that using only modern fits to the proton elastic form factors gives a smaller than historical spread of Zemach radii and leads to a reduced uncert…
We present a high-precision calculation of the recoil--finite-size correction to the hyperfine splitting (HFS) in muonic and electronic hydrogen based on nucleon electromagnetic form factors obtained from dispersion theory. This will help guide the upcoming searches of the HFS transition in muonic hydrogen, and will allow a precise determination of the polarizability and Zemach radius contributions when this transition is found.
An angle-resolved x-ray spectroscopic scheme is presented for determining the hyperfine splitting of highly charged ions. For helium-like ions, in particular, we propose to measure either the angular distribution or polarization of the $1s2p~^{3}P_{1}, F \rightarrow 1s^{2}~^{1}S_{0}, F_{f}$ emission following the stimulated decay of the initial $1s2s~^{1}S_{0}, F_{i}$ level. It is found that both the angular and polarization characteristics of the emitted x-ray photons strongly depends on the (relative) \textit{splitting} of the partially overlapping hyperfine $1s2p~^{3}P_{1}, F$ resonances an…
The ground state hyperfine splitting values and the transition probabilities between the hyperfine structure components of high Z lithiumlike ions are calculated in the range $Z=49-83$. The relativistic, nuclear, QED and interelectronic interaction corrections are taken into account. It is found that the Bohr-Weisskopf effect can be eliminated in a combination of the hyperfine splitting values of the hydrogenlike and lithiumlike ions of an isotope. This gives a possibility for testing the QED effects in a combination of the strong electric and magnetic fields of the heavy nucleus. Using the ex…
In this paper, we used the multiconfiguration Dirac-Fock method to compute with high precision the influence of the hyperfine interaction on the $[Ar]3d^{10} 4s4p ^3P_0$ level lifetime in Zn-like ions for stable and some quasi-stable isotopes of nonzero nuclear spin between Z=30 and Z=92. The influence of this interaction on the $[Ar]3d^{10} 4s4p ^3P_1 - [Ar]3d^{10} 4s4p ^3P_0$ separation energy is also calculated for the same ions.
A complete effective Hamiltonian for relativistic corrections at orders $mα^6$ and $mα^6(m/M)$ in a one-electron molecular system is derived from the NRQED Lagrangian. It includes spin-independent corrections to the energy levels and spin-spin scalar interactions contributing to the hyperfine splitting, both of which had been studied previously. In addition, corrections to electron spin-orbit and spin-spin tensor interactions are newly obtained. This allows improving the hyperfine structure theory in the hydrogen molecular ions. Improved values of the spin-orbit hyperfine coefficient are calcu…
We investigate the influence of the spatial extent of the proton magnetization and charge densities on the 2S hyperfine splitting in muonic hydrogen. The use of a non-perturbative relativistic Dirac approach leads to corrections of 15% to values obtained from the perturbative treatment encapsulated by the Zemach radius, which surpass the next-leading order contribution in the perturbation series by an order of magnitude.
The ground-state hyperfine splitting values of high-Z boronlike ions are calculated. Calculation of the interelectronic-interaction contribution is based on a combination of the 1/Z perturbation theory and the large-scale configuration-interaction Dirac-Fock-Sturm method. The screened QED corrections are evaluated utilizing an effective screening potential approach. Total hyperfine splitting energies are presented for several B-like ions of particular interest: {}^{45}Sc{}^{16+}, {}^{57}Fe{}^{21+}, {}^{207}Pb{}^{77+}, and {}^{209}Bi{}^{78+}. For lead and bismuth the experimental values of the …
We provide an accurate evaluation of the two-photon exchange correction to the hyperfine splitting of S energy levels in muonic hydrogen exploiting the corresponding measurements in electronic hydrogen. The proton structure uncertainty in the calculation of $α^5$ contribution is sizably reduced.
Energy levels, hyperfine interaction constants, and Landé $g_J$-factors are reported for n=2 states in beryllium-, boron-, carbon-, and nitrogen-like ions from relativistic configuration interaction calculations. Valence, core-valence, and core-core correlation effects are taken into account through single and double-excitations from multireference expansions to increasing sets of active orbitals. A systematic comparison of the calculated hyperfine interaction constants is made with values from the available literature.
The ground state hyperfine splitting values of high Z hydrogenlike ions are calculated. The relativistic, nuclear and QED corrections are taken into account. The nuclear magnetization distribution correction (the Bohr-Weisskopf effect) is evaluated within the single particle model with the g_{S}-factor chosen to yield the observed nuclear moment. An additional contribution caused by the nuclear spin-orbit interaction is included in the calculation of the Bohr-Weisskopf effect. It is found that the theoretical value of the wavelength of the transition between the hyperfine splitting components …
We study the hydrogen and muonic hydrogen within an effective field theory framework. We perform the matching between heavy baryon effective theory coupled to photons and leptons and the relevant effective field theory at atomic scales. This matching can be performed in a perturbative expansion in alpha, 1/m_p and the chiral counting. We then compute the O(m_{l_i}^3 alpha^5/m_p^2 x logarithms) contribution (including the leading chiral logarithms) to the Hyperfine splitting and compare with experiment. They can explain about 2/3 of the difference between experiment and the pure QED prediction …
The status of experimental measurements and theoretical calculations of the hyperfine induced 2s2p 3P0 -> 2s2 1S0 transition rate in Be-like ions is reviewed. Possible reasons, such as external electromagnetic fields and competing E1M1 two-photon transitions, for presently existing significant discrepancies between experiment and theory are discussed. Finally, directions for future research are outlined.
The rigorous QED evaluation of the one- and two-photon exchange corrections to the ground-state hyperfine splitting in Li-like ions is presented for the wide range of nuclear charge number $Z= 7 - 82$. The calculations are carried out in the framework of the extended Furry picture, i.e., with inclusion of the effective local screening potential in the zeroth-order approximation. The interelectronic-interaction contributions of the third and higher orders are taken into account in the framework of the Breit approximation employing the recursive perturbation theory. In comparison to the previous…
We obtain a model-independent prediction for the two-photon exchange contribution to the hyperfine splitting in muonic hydrogen. We use the relation of the Wilson coefficients of the spin-dependent dimension-six four-fermion operator of NRQED applied to the electron-proton and to the muon-proton sectors. Their difference can be reliably computed using chiral perturbation theory, whereas the Wilson coefficient of the electron-proton sector can be determined from the hyperfine splitting in hydrogen. This allows us to give a precise model-independent determination of the Wilson coefficient for th…
We apply relativistic many-body methods to compute static differential polarizabilities for transitions inside the ground-state hyperfine manifolds of monovalent atoms and ions. Knowing this transition polarizability is required in a number of high-precision experiments, such as microwave atomic clocks and searches for CP-violating permanent electric dipole moments. While the traditional polarizability arises in the second-order of interaction with the externally-applied electric field, the differential polarizability involves additional contribution from the hyperfine interaction of atomic el…
The hyperfine induced $2s2p ^3P_0, ^3P_2 \to 2s^2 ^1S_0$ E1 transition probabilities of Be-like ions were calculated using grasp2K based on multi-configuration Dirac-Fock method and HFST packages. It was found that the hyperfine quenching rates are strongly affected by the interference for low-Z Be-like ions, especially for $2s2p ^3P_0 \to 2s^2 ^1S_0$ transition. In particular, the trends of interference effects with atomic number $Z$ in such two transitions are not monotone. The strongest interference effect occurs near Z=7 for $2s2p ^3P_0 \to 2s^2 ^1S_0$ E1 transition, and near Z=9 for $2s2p…
In this work, we consider the thermal correction to the hyperfine interaction in hydrogen, deuterium, and the $^3$He$^+$ ion. This correction is effectively described by one-loop Feynman graphs in the framework of the quantum electrodynamics theory for bound states at a finite temperature. A simple analysis shows the importance of the obtained results for future prospects for measuring hyperfine splitting. In addition, the application for testing the time variation of fundamental constants is briefly discussed.
The linear polarization of the characteristic photon emission from few-electron ions is studied for its sensitivity with regard to the nuclear spin and magnetic moment of the ions. Special attention is paid, in particular, to the K$α_1$ ($1s 2p_{3/2} ^{1,3}P_{1,2} \to 1s^2 ^1S_0$) decay of selected helium-like ions following the radiative electron capture into initially hydrogen-like species. Based on the density matrix theory, a unified description is developed that includes both, the many-electron and hyperfine interactions as well as the multipole-mixing effects arising from the expansion o…
A rigorous evaluation of the two-photon exchange corrections to the hyperfine structure in lithiumlike heavy ions is presented. As a result, the theoretical accuracy of the specific difference between the hyperfine splitting values of H- and Li-like Bi ions is significantly improved. This opens a possibility for the stringent test of the many-electron QED effects on a few percent level in the strongest electromagnetic field presently available in experiments.
We reevaluate the Zemach, recoil and polarizability corrections to the hyperfine splitting in muonic hydrogen expressing them through the low-energy proton structure constants and obtain the precise values of the Zemach radius and two-photon exchange (TPE) contribution. The uncertainty of TPE correction to S energy levels in muonic hydrogen of 105 ppm exceeds the ppm accuracy level of the forthcoming 1S hyperfine splitting measurements at PSI, J-PARC and RIKEN-RAL.
Hyperfine induced $1s2s ^1S_0 \to 1s^2 ^1S_0$ M1 transition probabilities of He-like ions have been calculated from relativistic configuration interaction wavefunctions including the frequency independent Breit interaction and QED effects. Present results for {$^{151}$}Eu and {$^{155}$}Gd are in good agreement with previous calculations [Phys. Rev. A {\bf 63}, 054105 (2001)]. Electronic data are given in terms of a general scaling law in $Z$ that, given isotopic nuclear spin and magnetic moment, allows hyperfine induced decay rates to be estimated for any isotope. The results should be helpful…
We have applied an optical method to the measurement of the 2S hyperfine interval in atomic hydrogen. The interval has been measured by means of two-photon spectroscopy of the 1S-2S transition on a hydrogen atomic beam shielded from external magnetic fields. The measured value of the 2S hyperfine interval is equal to 177 556 860(15) Hz and represents the most precise measurement of this interval to date. The theoretical evaluation of the specific combination of 1S and 2S hyperfine intervals D_21 is in moderately good agreement with the value for D_21 deduced from our measurement.
The fully relativistic theory of the Zeeman splitting of the $1s$ hyperfine structure levels in hydrogenlike ions is considered for the magnetic field magnitude in the range from 1 to 10 T. The second-order corrections to the Breit -- Rabi formula are calculated and discussed. The results can be used for a precise determination of nuclear magnetic moments from $g$ factor experiments.
The screened QED corrections of the first orders in αand 1/Z to the g factor and the hyperfine splitting of lithiumlike ions are evaluated within ab initio quantum electrodynamical approach. The complete gauge-invariant set of the two-electron self-energy diagrams in the presence of the magnetic field and a dominant part of the two-electron vacuum-polarization diagrams are calculated. The most accurate values of the g factor of Li-like lead and uranium are presented. The theoretical prediction for the specific difference of the hyperfine splittings of H- and Li-like bismuth is improved.
The hyperfine structures of the $2\,^3\!S_1$ and $2\,^3\!P_J$ states of the $^7$Be$^{2+}$ and $^9$Be$^{2+}$ ions are investigated within the framework of the nonrelativistic quantum electrodynamics (NRQED). The uncertainties of present hyperfine splitting results of $^9$Be$^{2+}$ are in the order of several tens of ppm, where two orders of magnitude improvement over the previous theory and experiment values has been achieved. The contribution of nuclear electric quadrupole moment to hyperfine splitting of $^7$Be$^{2+}$ has been studied. A scheme for determining the properties of Be nuclei in t…
An overview is presented of laser spectroscopy experiments with cold, trapped, highly-charged ions, which will be performed at the HITRAP facility at GSI in Darmstadt (Germany). These high-resolution measurements of ground state hyperfine splittings will be three orders of magnitude more precise than previous measurements. Moreover, from a comparison of measurements of the hyperfine splittings in hydrogen- and lithium-like ions of the same isotope, QED effects at high electromagnetic fields can be determined within a few percent. Several candidate ions suited for these laser spectroscopy studi…
Theoretical investigations of the hyperfine structure of the hydrogen molecular ion (one electron and two protons) are discussed. The nuclear spin-rotation interaction has been found to be of the same sign as in the hydrogen molecule and the hyperfine transition frequencies can be accurately predicted. With measurements of the hyperfine structure of the deuterium molecular ion (or of HD+) it should be possible to obtain a value of the deuteron quadrupole moment that could be compared with the values obtained from the deuterium molecule and from nuclear theory.
We consider the proton structure corrections to hydrogen ground-state hyperfine structure, focusing on a state-of-the-art evaluation of the inelastic nucleon corrections--the polarizability corrections--using analytic fits to the most recent data. We find a value for the fractional correction Delta_{pol} of 1.3 \pm 0.3 ppm. This is 1--2 ppm smaller than the value of Delta_{pol}$ one would deduce using hyperfine splitting data and elastic proton structure corrections obtained from modern form factor fits. In addition, we discuss the derivations of the relevant formulas, paying attention to lept…
The hyperfine splitting in hydrogenlike $^{209}$Bi, $^{203}$Tl, and $^{205}$Tl is calculated with the nuclear magnetization determined from experimental data on the hyperfine splitting in the corresponding muonic atoms. The single-particle and configuration-mixing nuclear models are considered. The QED corrections are taken into account for both electronic and muonic atoms. The obtained results are compared with other calculations and with experiment.
The 7 standard deviations between the proton rms charge radius from muonic hydrogen and the CODATA-10 value from hydrogen spectroscopy and electron-scattering has caused considerable discussions. Here, we review the theory of the 2S-2P Lamb shift and 2S hyperfine splitting in muonic hydrogen combining the published contributions and theoretical approaches. The prediction of these quantities is necessary for the determination of both proton charge and Zemach radii from the two 2S-2P transition frequencies measured in muonic hydrogen.
We make precise calculation of hyperfine structure of $S$-states in muonic ions of lithium, beryllium and boron in quantum electrodynamics. Corrections of orders $α^5$ and $α^6$ due to the vacuum polarization, nuclear structure and recoil in first and second orders of perturbation theory are taken into account. We obtain estimates of the total values of hyperfine splittings which can be used for a comparison with future experimental data.
We find a new correction to the hydrogen atom ground state hyperfine energy levels splitting in magnetic field. It can be interpreted as magnetic focusing of the wave function at the origin. The effect might be within the reach of experiment.
We measured the ground-state hyperfine splitting of trapped ${}^{113}$Cd${}^{+}$ ions to be 15199862855.02799(27) Hz with a fractional uncertainty of $1.8\times10^{-14}$. The ions were trapped and laser-cooled in a linear quadrupole Paul trap. The fractional frequency stability was measured to be ${4.2} \times 10^{-13}/\sqrtτ $, obtained from Ramsey fringes of high signal-to-noise ratio and taken over a measurement time of nearly 5 hours, which is close to the short-term stability limit estimated from the Dick effect. Our result is consistent with previous reported values, but the measurement …
The hyperfine splitting of the ground state of H-, Li-, and B-like ions is investigated in details within the range of nuclear numbers Z = 7-28. The rigorous QED approach together with the large-scale configuration-interaction Dirac-Fock-Sturm method are employed for the evaluation of the interelectronic-interaction contributions of first and higher orders in 1/Z. The screened QED corrections are evaluated to all orders in (αZ) utilizing an effective potential approach. The influence of nuclear magnetization distribution is taken into account within the single-particle nuclear model. The speci…
The current status of the determination of corrections to the hyperfine splitting of the ground state in hydrogen is considered. Improved calculations are provided taking into account the most recent value for the proton charge radius. Comparing experimental data with predictions for the hyperfine splitting, the Zemach radius of the proton is deduced to be $1.045(16)$ fm. Employing exponential parametrizations for the electromagnetic form factors we determine the magnetic radius of the proton to be $0.778(29)$ fm. Both values are compared with the corresponding ones derived from the data obtai…
The ground state hyperfine splitting of light muon-electron ions of lithium, beryllium, boron and helium is calculated on the basis of analytical perturbation theory in terms of small parameters of the fine structure constant and electron-muon mass ratio. The corrections of vacuum polarization, nuclear structure and recoil effects and electron vertex corrections are taken into account. The dependence of the corrections on the nucleus charge Z is studied. The obtained total values of hyperfine splitting intervals can be used for comparison with future experimental data.
The usefulness of study of hyperfine splitting in the hydrogen atom is limited on a level of 10 ppm by our knowledge of the proton structure. One way to go beyond 10 ppm is to study a specific difference of the hyperfine structure intervals 8 Delta nu_2 - Delta nu_1. Nuclear effects for are not important this difference and it is of use to study higher-order QED corrections.
The hyperfine splitting of the ground state of selected B-like ions within the range of nuclear charge numbers $Z=49-83$ is investigated in detail. The rigorous QED approach together with the large-scale configuration-interaction Dirac-Fock-Sturm method are employed for the evaluation of the interelectronic-interaction contributions of first and higher orders in $1/Z$. The screened QED corrections are evaluated to all orders in $αZ$ by using an effective potential. The influence of nuclear magnetization distribution is taken into account within the single-particle nuclear model.
The largest contributions to the $n=2$ Lamb-shift, fine structure interval and $2s$ hyperfine structure of muonic hydrogen are calculated by exact numerical evaluations of the Dirac equation, rather than by a perturbation expansion in powers of $1/c$, in the framework of non-relativistic quantum electrodynamics. Previous calculations and the validity of the perturbation expansion for light elements are confirmed. The dependence of the various effects on the nuclear size and model are studied
We consider a simplified model of the optical multi-pass cavity that is being currently developed by the FAMU collaboration for the measurement of the hyperfine splitting in the ground state of muonic hydrogen and of the Zemach radius of the proton. The model is focused on the time distribution of the events of laser-stimulated hyperfine transitions in the muonuc atom and may be helpful in the preliminary design of the FAMU experimental set-up and, more generally, in the optimization of multi-pass optical cavities for experiments with pulsed lasers.
The hyperfine induced $4f^{14}5s5p~^3\mathrm{P}^o_{0,2}~-~4f^{14}5s^2~^1\mathrm{S}_0$ transition probabilities for highly charged Sm-like ions are calculated in the framework of the multi-configuration Dirac-Hartree-Fock method. Electron correlation, the Breit interaction and quantum electrodynamical (QED) effects are taken into account. For ions ranging from $Z=79$ to $Z=94$, $4f^{14}5s5p~^3\mathrm{P}^o_{0}$ is the first excited state, and the hyperfine induced transition is an dominant decay channel. For the $4f^{14}5s5p~^3\mathrm{P}^o_{2}$ state, the hyperfine induced transition (HIT) rates…
The ASACUSA collaboration is developing a polarized beam of antihydrogen atoms to precisely determine the ground-state hyperfine structure for studies of CPT and Lorentz invariance. Using a beam of ordinary hydrogen, measurements of both the $σ$ and $π$-transition have been performed, investigating orientation-dependent SME coefficients. Furthermore a first hyperfine experiment with a beam of deuterium is being prepared.
NRQED approach to the fine and hyperfine structure corrections of order m$α$ 6 and m$α$ 6 (m/M)-Application to the hydrogen atom The NRQED approach is applied to the calculation of relativistic corrections to the fine and hyperfine structure of hydrogenlike atoms at orders m$α$ 6 and m$α$ 6 (m/M). Results are found to be in agreement with those of the relativistic theory. This confirms that the derived NRQED effective potentials are correct, and may be used for studying more complex atoms or molecules. Furthermore, we verify the equivalence between different forms of the NRQED Lagrangian used …
Energy levels, magnetic dipole, and electric quadrupole hyperfine structure of the superheavy element rutherfordium (Rf, $Z$=104) and its first three ions are calculated using a combination of the configuration interaction, coupled-cluster single-doubles, and many-body perturbation theory techniques. The results are to be used in future interpretations of the measurements in terms of nuclear magnetic dipole and electric quadrupole momenta. To have a guide on the accuracy of the study, we perform similar calculations for hafnium (Hf, $Z$=72) and its ions. Hf is a lighter analog of Rf with a sim…
We calculate hyperfine structure intervals $ΔE^{hfs}(2P_{1/2})$ and $ΔE^{hfs}(2P_{3/2})$ for P-states in muonic ions of lithium, beryllium and boron. To construct the particle interaction operator in momentum space we use the tensor method of projection operators on states with definite quantum numbers of total atomic momentum F and total muon momentum j. We take into account vacuum polarization, relativistic, quadruple and structure corrections of orders $α^4$, $α^5$ and $α^6$. The obtained numerical values of hyperfine splittings can be used for a comparison with future experimental data of …
Advanced techniques for manipulation of internal states, standard in atomic physics, are demonstrated for a charged molecular species for the first time. We address individual hyperfine states of ro-vibrational levels of a diatomic ion by optical excitation of individual hyperfine transitions, and achieve controlled transfer of population into a selected hyperfine state. We use molecular hydrogen ions (HD^{+}) as a model system and employ a novel frequency-comb-based, continuous-wave 5 \mum laser spectrometer. The achieved spectral resolution is the highest obtained so far in the optical domai…
