We show that when the thermal wavelength is comparable to the spatial size of a system, thermodynamic observables like Pressure and Volume have quantum fluctuations that cannot be ignored. They are now represented by operators; conventional (classical) thermodynamics is no longer applicable. We continue the work in earlier papers where quantization rules for thermodynamics were developed by analogy with optics and mechanics, by working out explicitly the quantum theory of van der Waals gases. We find a wave equation satisfied by the thermodynamic wave function as well as solutions ({\em coherent states}) that are centered at the classical equations of state. The probability of departure from the classical theory is dependent on a parameter $σ$ which is a property of the gas molecule.
The thermodynamic properties of ideal quantum gases are derived solely from dimensional arguments, the Pauli principle and thermodynamic relations, without resorting to statistical mechanics.
In this paper, the effects of boundary and connectivity on ideal gases in two-dimensional confined space and three-dimensional tubes are discussed in detail based on the analytical result. The implication of such effects on the mesoscopic system is also revealed.
The particle and current densities are shown to display damping and undergo decoherence in ideal quantum gases. The damping is read off from the equations of motion reminiscent of the Navier-Stokes equations and shows some formal similarity with Landau damping. The decoherence leads to consistent density and current histories with characteristic length and time scales given by the ideal gas.
The virial expansion of ideal quantum gases reveals some interesting and amusing properties when considered as a function of dimensionality $d$. In particular, the convergence radius $ρ_c(d)$ of the expansion is particulary large at {\em exactly\/} $d=3$ dimensions, $ρ_c(3) = 7.1068\ldots \times \lim_{d\to3} ρ_c(d)$. The same phenomenon occurs in a few other special (non-integer) dimensions. We explain the origin of these facts, and discuss more generally the structure of singularities governing the asymptotic behavior of the ideal gas virial expansion.
We have analytically explored thermodynamics of free Bose and Fermi gases for the entire range of temperature, and have extended the same for harmonically trapped cases. We have obtained approximate chemical potentials of the quantum gases in closed forms of temperature so that the thermodynamic properties of the quantum gases become plausible specially in the intermediate regime between the classical and quantum limits.
The equation of state for a two-dimensional hard-sphere gas is difficult to calculate by usual methods. In this paper we develop an approach for calculating the equation of state of hard-sphere gases, both for two- and three-dimensional cases. By regarding a hard-sphere gas as an ideal gas confined in a container with a multi-core (excluded sphere) boundary, we treat the hard-sphere interaction in an interacting gas as the boundary effect on an ideal quantum gas; this enables us to treat an interacting gas as an ideal one. We calculate the equation of state for a three-dimensional hard-sphere …
We formulate an approximate thermodynamic theory of the phase transition in driven lattice gases with attractive nearest-neighbor interactions. We construct the van der Waals equation of state for a driven system where a nonequilibrium chemical potential can be expressed as a function of density and driving field. A Maxwell's construction leads to the phase transition from a homogeneous fluid phase to the coexisting phases of gas and liquid.
We present a new method of obtaining nonlinear integral equations characterizing the thermodynamics of one-dimensional multi-component gases interacting via a delta-function potential. In the case of the repulsive two-component Bose gas we obtain a simple system of two NLIE allowing for an efficient numerical implementation in contrast with the infinite number of coupled equations obtained by employing the Thermodynamic Bethe Ansatz. Our technique makes use of the Quantum Transfer Matrix and the fact that in a certain continuum limit multi-component gases can be obtained from appropriate aniso…
We explore driven lattice gases for the existence of an intensive thermodynamic variable which could determine "equilibration" between two nonequilibrium steady-state systems kept in weak contact. In simulations, we find that these systems satisfy surprisingly simple thermodynamic laws, such as the zero-th law and the fluctuation-response relation between the particle-number fluctuation and the corresponding susceptibility remarkably well. However at higher densities, small but observable deviations from these laws occur due to nontrivial contact dynamics and the presence of long-range spatial…
We discuss magnetism in spinor quantum gases theoretically and experimentally with emphasis on temporal dynamics of the spinor order parameter in the presence of an external magnetic field. In a simple coupled Gross-Pitaevskii picture we observe a dramatic suppression of spin dynamics due to quadratic Zeeman ''dephasing''. In view of an inhomogeneous density profile of the trapped condensate we present evidence of spatial variations of spin dynamics. In addition we study spinor quantum gases as a model system for thermodynamics of Bose-Einstein condensation. As a particular example we present …
In this paper we show that for a non-ideal Bose gas there exists an upper limit on the transition temperature above which Bose-Einstein condensation cannot occur regardless of the pressure applied. Such upper limits for some realistic Bose gases are estimated. This result implies that there may also exist an upper limit on the transition temperature of superconductors.
We investigate the fluctuations of the condensate in the ideal and weakly interacting Bose gases confined in a box of volume V within canonical ensemble. Canonical ensemble is developed to describe the behavior of the fluctuations when different methods of approximation to the weakly interacting Bose gases are used. Research shows that the fluctuations of the condensate exhibit anomalous behavior for the interacting Bose gas confined in a box.
We analytically determine the dynamical properties of two dimensional field driven Lorentz gases within the thermodynamic formalism. For dilute gases subjected to an iso-kinetic thermostat, we calculate the topological pressure as a function of a temperature-like parameter $\ba$ up to second order in the strength of the applied field. The Kolmogorov-Sinai entropy and the topological entropy can be extracted from a dynamical entropy defined as a Legendre transform of the topological pressure. Our calculations of the Kolmogorov-Sinai entropy exactly agree with previous calculations based on a Lo…
We calculate the systematic average speed of the adiabatic piston and a thermal Brownian motor, introduced in [Van den Broeck, Kawai and Meurs, \emph{Microscopic analysis of a thermal Brownian motor}, to appear in Phys. Rev. Lett.], by an expansion of the Boltzmann equation and compare with the exact numerical solution.
An operator that governs the discrete time evolution of the velocity distribution of an out-of-equilibrium ideal gas will be presented. This nonlinear map, which conserves the momentum and the energy of the ideal gas, has the Maxwellian Velocity Distribution (MVD) as an asymptotic equilibrium. Moreover, the system displays the increasing of the entropy during the decay to the MVD.
We investigate perturbative thermodynamic geometry of nonextensive ideal Classical, Bose and Fermi gases.We show that the intrinsic statistical interaction of nonextensive Bose (Fermi) gas is attractive (repulsive) similar to the extensive case but the value of thermodynamic curvature is changed by nonextensive parameter. In contrary to the extensive ideal classical gas, the nonextensive one may be divided to two different regimes. According to deviation parameter of the system to the nonextensive case, one can find a special value of fugacity, $z^{*}$, where the sign of thermodynamic curvatur…
The role of thermodynamics in deriving constitutive equations is unique, and various approaches have been developed in the last decades. In the present paper, the frameworks of Extended Irreversible Thermodynamics (EIT) and Non-Equilibrium Thermodynamics with Internal Variables (NET-IV) are discussed and compared to each other on the basis of a particular problem of rarefied gases. In this comparison, both theoretical and experimental aspects are taken into account. Eventually, an experiment by Meyer and Sessler covering a wide range of pressures and frequencies is investigated. Here, concentr…
We investigate theoretically the properties of an ideal trapped gas in a time-dependent harmonic potential. Using a scaling formalism, we are able to present simple analytical results for two important classes of experiments: free expansion of the gas upon release of the trap; and the response of the gas to a harmonic modulation of the trapping potential is investigated. We present specific results relevant to current experiments on trapped Fermions.
The entropy-temperature curves are calculated for non-interacting Bose and Fermi gases in a 3D optical lattice. These curves facilitate understanding of how adiabatic changes in the lattice depth affect the temperature, and we demonstrate regimes where the atomic sample can be significantly heated or cooled by the loading process. We assess the effects of interactions on a Bose gas in a deep optical lattice, and show that interactions ultimately limit the extent of cooling that can occur during lattice loading.
We theoretically examine equilibrium properties of the harmonically trapped ideal Bose and Fermi gases in the quantum degeneracy regime. We analyze thermodynamic characteristics of gases with a finite number of atoms by means of the known semiclassical approach and perform comparison with exact numerical results. For a Fermi gas, we demonstrate deviations in the Fermi energy values originating from a discrete level structure and show that these are observable only for a small number of particles. For a Bose gas, we observe characteristic softening of phase transition features, which contrasts …
We consider two-dimensional imperfect attractive Fermi and repulsive Bose gases consisting of spinless point particles whose total interparticle interaction energy is represented by $a N^2/2 V$ with $a=-a_{F}\leq 0$ for fermions, and $a=a_{B}\geq 0$ for bosons. We show that in spite of the attraction the thermodynamics of $d=2$ imperfect Fermi gas remains well defined for $0 \leq a_{F}\leq a_{0}=h^2/2πm$, and is exactly the same as the one of the repulsive imperfect Bose gas with $a_{B}=a_{0}-a_{F}$. In particular, for $a_{F}=a_{0}$ one observes the thermodynamic equivalence of the attractive …
The fluctuation-dissipation theorem together with the exact density response spectrum for ideal quantum gases has been utilized to yield a new expression for the static structure factor, which we use to derive exact analytical expressions for the temperature{dependent pair distribution function g(r) of the ideal gases. The plots of bosonic and fermionic g(r) display "Bose pile" and "Fermi hole" typically akin to bunching and antibunching as observed experimentally for ultracold atomic gases. The behavior of spin-scaled pair correlation for fermions is almost featureless but bosons show a rich …
We show that the recently discovered thermodynamic equivalence between noninteracting Bose and Fermi gases in two dimensions, and between one-dimensional Bose and Fermi systems with linear dispersion, both in the grand-canonical ensemble, are special cases of a larger class of equivalences of noninteracting systems having an energy-independent single-particle density of states. We also conjecture that the same equivalence will hold in the grand-canonical ensemble for any noninteracting quantum gas with a discrete ladder-type spectrum whenever $σΔ/ N k_{\rm B} T$ is small, where $N$ is the aver…
In Nonequilibrium Thermodynamics and Information Theory, the relative entropy (or, KL divergence) plays a very important role. Consider a Hölder Jacobian $J$ and the Ruelle (transfer) operator $\mathcal{L}_{\log J}.$ Two equilibrium probabilities $μ_1$ and $μ_2$, can interact via a discrete-time {\it Thermodynamic Operation} described by the action {\it of the dual of the Ruelle operator} $ \mathcal{L}_{\log J}^*$. We argue that the law $μ\to \mathcal{L}_{\log J}^*(μ)$, producing nonequilibrium, can be seen as a Thermodynamic Operation after showing that it's a manifestation of the Second Law …
Limits of classical constitutive laws such as Fourier and Navier-Stokes equations are discovered since decades. However, the proper extensions -- generalizations of these are not unique. They differ in the underlying physical principles and in modeling capabilities. In this paper, two different theories are discussed and compared to each other, namely the kinetic theory-based Rational Extended Thermodynamics (RET) and non-equilibrium thermodynamics with internal variables (NET-IV). First, the paper starts with the case of rigid heat conductors summarizing the result achieved so far. Then a typ…
The effects of low dimensionality on the thermodynamics of a Fermi gas trapped by isotropic power law potentials are analyzed. Particular attention is given to different characteristic temperatures that emerge, at low dimensionality, in the thermodynamic functions of state and in the thermodynamic susceptibilities (isothermal compressibility and specific heat). An energy-entropy argument that physically favors the relevance of one of these characteristic temperatures, namely, the non vanishing temperature at which the chemical potential reaches the Fermi energy value, is presented. Such an arg…
In this work, a new model in kinetic gas theory for deriving the Maxwellian Velocity Distribution (MVD) is proposed. We construct an operator that governs the discrete time evolution of the velocity distribution. This operator, which conserves the momentum and the energy of the ideal gas, has the MVD as a fixed point. Moreover, for any initial out-of-equilibrium velocity distribution, it is shown that the gas decays to the equilibrium distribution, that is, to the MVD.
The thermodynamic properties of two-component Fermi gases with divergent scattering length is investigated and the transition temperature for the emergence of a stable dimeric gas is obtained by a simple theoretical model where the unique property of the dimers (i.e. fermionic atom pairs) with divergent scattering length is considered. Below the transition temperature, through the investigation of the overall entropy for the mixture gas of fermionic atoms and dimers, we calculate the relation between the energy and temperature of the system. In the limit of zero temperature, based on the chemi…
Thermodynamic length is a metric distance between equilibrium thermodynamic states that asymptotically bounds the dissipation induced by a finite time transformation of a thermodynamic system. By means of thermodynamic length, we first evaluate the departures from ideal to real gases in geometric thermodynamics with and without Legendre invariance. In particular, we investigate ideal and real gases in the Ruppeiner and geometrothermodynamic formalisms. Afterwards, we formulate a strategy to relate thermodynamic lengths to efficiency of thermodynamic systems in both the aforementioned framework…
The issue of the Gibbs paradox is that when considering mixing of two gases within classical thermodynamics, the entropy of mixing appears to be a discontinuous function of the difference between the gases: it is finite for whatever small difference, but vanishes for identical gases. The resolution offered in the literature, with help of quantum mixing entropy, was later shown to be unsatisfactory precisely where it sought to resolve the paradox. Macroscopic thermodynamics, classical or quantum, is unsuitable for explaining the paradox, since it does not deal explicitly with the difference bet…
Recursion formulae of the N-particle partition function, the occupation numbers and its fluctuations are given using the single-particle partition function. Exact results are presented for fermions and bosons in a common one-dimensional harmonic oscillator potential, for the three-dimensional harmonic oscillator approximations are tested. Applications to excited nuclei and Bose-Einstein condensation are discussed.
For a class of nonequilibrium systems, called driven lattice gases, we study what happens when two systems are kept in contact and allowed to exchange particles with the total number of particles conserved. Both for attractive and repulsive nearest-neighbor interactions among particles and for a wide range of parameter values, we find that, to a good approximation, one could define an intensive thermodynamic variable, like equilibrium chemical potential, which determines the final steady state for two initially separated driven lattice gases brought into contact. However, due to nontrivial con…
Using a field-theoretic approach, we systematically generalize the usual semiclassical approximation for a harmonically trapped ideal Bose gas in such a way that its range of applicability is essentially extended. With this we can analytically calculate thermodynamic properties even for small particle numbers. In particular, it now becomes possible to determine the critical temperature as well as the temperature dependence of both heat capacity and condensate fraction in low-dimensional traps, where the standard semiclassical approximation is not even applicable.
The thermodynamics framework of an interacting quantum gas trapped by an arbitrary external potential is reviewed. We show that for each confining potential, in the thermodynamic limit, there emerge "generalized" volume and pressure variables ${\cal V}$ and ${\cal P}$, that replace the usual volume and hydrostatic pressure of a uniform system. This scheme is validated with the derivation of the virial expansion of the grand potential. We show that this approach yields experimentally amenable procedures to find the equation of state of the fluid, ${\cal P} = {\cal P}({\cal V}/N,T)$ with $N$ the…
It is shown that the equations for pressure, entropy and the isochoric heat capacity obtained by using generalization of the equilibrium thermodynamics in fractional derivatives in the paper mentioned above are approximate, the comparison of the equations with the experimental (tabulated) data for Neon and Argon made in the paper is incorrect, and the conclusions of the paper made on the basis of the comparison could be incorrect. The conditions for validity of the equations are established. It is also established that the question about a physical sense of the exponent of the derivative of a …
A relativistic version of the rational extended thermodynamics of polyatomic gases based on a new hierarchy of moments that takes into account the total energy composed by the rest energy and the energy of the molecular internal mode is proposed. The moment equations associated with the Boltzmann-Chernikov equation are derived, and the system for the first $15$ equations is closed by the procedure of the maximum entropy principle and by using an appropriate BGK model for the collisional term. The entropy principle with a convex entropy density is proved in a neighborhood of equilibrium state, …
We use the non-equilibrium statistical field theory for classical particles recently developed by Mazenko and Das and Mazenko, together with the free generating functional for particles initially correlated in phase space derived in Bartelmann et al. to study the impact of initial correlations on the equation of state of real gases. We first show that we can reproduce the well known van der Waals equation of state for uncorrelated initial conditions using this approach. We then impose correlated initial conditions and study their qualitative and quantitative effect on the equation of state of …
To be useful, steady state thermodynamics (SST) must be self-consistent and have predictive value. Although consistency of SST was recently verified for driven lattice gases under global weak exchange, I show here that it does not predict the coexisting densities in athermal stochastic lattice gases under a nonuniform drive. I consider the lattice gas with nearest-neighbor exclusion on the square lattice, with nearest-neighbor hopping (NNE dynamics), and with hopping to both nearest and next-nearest neighbors (NNE2 dynamics). Part of the system is subject to a drive $D$ that favors hopping alo…
We theoretically study the collective excitations of an ideal gas confined in an isotropic harmonic trap. We give an exact solution to the Boltzmann-Vlasov equation; as expected for a single-component system, the associated mode frequencies are integer multiples of the trapping frequency. We show that the expressions found by the scaling ansatz method are a special case of our solution. Our findings, however, are most useful in case the trap contains more than one phase: we demonstrate how to obtain the oscillation frequencies in case an interface is present between the ideal gas and a differe…
We consider a one-dimensional gas of positive and negative unit charges interacting via a logarithmic potential, which is in thermal equilibrium at the (dimensionless) inverse temperature $β$. In a previous paper [Samaj, L.: J. Stat. Phys. 105, 173-191 (2001)], the exact thermodynamics of the unrestricted log-gas of pointlike charges was obtained using an equivalence with a (1+1)-dimensional boundary sine-Gordon model. The present aim is to extend the exact study of the thermodynamics to the log-gas on a line with alternating $\pm$ charges. The formula for the ordered grand partition function …
Using a collective coordinate numerical optimization procedure, we construct ground-state configurations of interacting particle systems in various space dimensions so that the scattering of radiation exactly matches a prescribed pattern for a set of wave vectors. We show that the constructed ground states are, counterintuitively, disordered (i.e., possess no long-range order) in the infinite-volume limit. We focus on three classes of configurations with unique radiation scattering characteristics: (i)``stealth'' materials, which are transparent to incident radiation at certain wavelengths; (i…
We calculate numerically and analytically the fluctuations of the fermionic condensate and of the number of particles above the condensate for systems of constant density of states. We compare the canonical fluctuations, obtained from the equivalent Bose condensate fluctuation, with the grandcanonical fermionic calculation. The fluctuations of the condensate are almost the same in the two ensembles, with a small correction comming from the total particle number fluctuation in the grandcanonical ensemble. On the other hand the number of particles above the condensate and its fluctuation is inse…
In an ideal Bose gas that is driven into a steady state far from thermal equilibrium, a generalized form of Bose condensation can occur. Namely, the single-particle states unambiguously separate into two groups: the group of Bose-selected states, whose occupations increase linearly with the total particle number, and the group of all other states whose occupations saturate [Phys. Rev. Lett. 111, 240405 (2013)]. However, so far very little is known about how the number of Bose-selected states depends on the properties of the system and its coupling to the environment. The answer to this questio…
The mean ground state occupation number and condensate fluctuations of interacting and non-interacting Bose gases confined in a harmonic trap are considered by using a canonical ensemble approach. To obtain the mean ground state occupation number and the condensate fluctuations, an analytical description for the probability distribution function of the condensate is provided directly starting from the analysis of the partition function of the system. For the ideal Bose gas, the probability distribution function is found to be a Gaussian one for the case of the harmonic trap. For the interactin…
The ideal uniform two-dimensional (2D) Fermi and Bose gases are considered both in the thermodynamic limit and the finite case. We derive May's Theorem, viz. the correspondence between the internal energies of the Fermi and Bose gases in the thermodynamic limit. This results in both gases having the same heat capacity. However, as we shall show, the thermodynamic limit is never truly reached in two dimensions and so it is essential to consider finite-size effects. We show in an elementary manner that for the finite 2D Bose gas, a pseudo-Bose-Einstein condensate forms at low temperatures, incom…
In the paper, the principal aspects of the mathematical theory of equilibrium thermodynamics are distinguished. It is proved that the points of degeneration of a Bose gas of fractal dimension in the momentum space coincide with critical points or real gases, whereas the jumps of critical indices and the Maxwell rule are related to the tunnel generalization of thermodynamics. Semiclassical methods are considered for the tunnel generalization of thermodynamics and also for the second and ultrasecond quantization (operators of creation and annihilation of pairs). To every pure gas there correspon…
Recently, Pennisi and Ruggeri [J Stat Phys 179, 231-246 (2020)] consider the classical limit of the relativistic theory of moments associated with the Boltzmann-Chernikov equation truncated at a tensorial index $N+1$ and they proved that there exists a unique possible choice of the moments in the classical case for a given $N$ both for monatomic and polyatomic gases. In particular, in polyatomic gases, there exists a new hierarchy of moments that is more general than the one considered in the recent literature. As consequence, when $N=2$, in the classical limit, there is a theory with $15$ fie…
I investigate the possibility of condensation in ideal Fermi systems of general single particle density of states. For this I calculate the probability $w_{N_0}$ of having exactly $N_0$ particles in the condensate and analyze its maxima. The existence of such maxima at macroscopic values of $N_0$ indicates a condensate. An interesting situation occurs for example in 1D systems, where $w_{N_0}$ may have two maxima. One is at $N_0=0$ and another one may exist at finite $N_0$ (for temperatures bellow a certain condensation temperature). This suggests the existence of a first order phase transitio…
We report a formula for the dry adiabatic lapse rate that depends on the compressibility factor and the adiabatic curves. Then, to take into account the non-ideal behavior of the gases, we consider molecules that can move, rotate, and vibrate and the information of molecular interactions through the virial coefficients. We deduce the compressibility factor in its virial expansion form and the adiabatic curves within the virial expansion up to any order. With this information and to illustrate the mentioned formula, we write the lapse rate for the ideal gas, and the virial expansion up to the s…
We present analytical formulae for the first and second derivatives of the Helmholtz free energy of non-relativistic ideal Fermi-gas. Important thermodynamic quantities such as heat capacity, sound velocity, heat capacity ratio and others can be easily expressed through the derivatives. We demonstrate correct ideal Boltzmann gas and low--temperature Fermi-gas asymptotes and derive corrections to thermodynamic functions for these limiting cases. Numerical computations of thermodynamic properties of ideal Fermi-gas can be accurately performed using the developed freely available Python module if…
Using mean-field theory for the Bardeen-Cooper-Schriefer (BCS) to the Bose-Einstein condensate (BEC) crossover we investigate the ground state thermodynamic properties of an interacting homogeneous Fermi gas. The interatomic interactions modeled through a finite range potential allows us to explore the entire region from weak to strong interacting regimes with no approximations. To exhibit the thermodynamic behavior as a function of the potential parameters in the whole crossover region, we concentrate in studying the contact variable, the thermodynamic conjugate of the inverse of the s-wave s…
We study the thermodynamic properties of an ideal gas of fermions in a harmonic oscillator confining potential. The analogy between this problem and the de Haas-van Alphen effect is discussed and used to obtain analytical results for the chemical potential and specific heat in the case of both isotropic and anisotropic potentials. Step-like behaviour in the chemical potential, first noted in numerical studies, is obtained analytically and shown to result in an oscillatory behaviour of the specific heat when the particle number is varied. The origin of these oscillations is that part of the the…
We derive an expression for the reduced density matrices of ideal Bose and Fermi gases in the canonical ensemble, which corresponds to the Bloch--De Dominicis (or Wick's) theorem in the grand canonical ensemble for normal-ordered products of operators. Using this expression, we study one- and two-body correlations of homogeneous ideal gases with $N$ particles. The pair distribution function $g^{(2)}(r)$ of fermions clearly exhibits antibunching with $g^{(2)}(0)=0$ due to the Pauli exclusion principle at all temperatures, whereas that of normal bosons shows bunching with $g^{(2)}(0)\approx 2$, …
The ideal gas laws are derived from the democritian concept of corpuscles moving in vacuum plus a principle of simplicity, namely that these laws are independent of the laws of motion aside from the law of energy conservation. A single corpuscle in contact with a heat bath and submitted to a $z$ and $t$-invariant force $-w$ is considered, in which case corpuscle distinguishability is irrelevant. The non-relativistic approximation is made only in examples. Some of the end results are known but the method appears to be novel. The mathematics being elementary the present paper should facilitate t…
We consider a heavy piston in an infinite cylinder surrounded by ideal gases on both sides. The piston moves under elastic collisions with gas atoms. We assume here that the gases always exert equal pressures on the piston, hence the piston remains at the so called mechanical equilibrium. However, the temperatures and densities of the gases may differ across the piston. In that case some earlier studies by Gruber, Piasecki and others reveal a very slow motion (drift) of the piston in the direction of the hotter gas. At the same time the hotter gas slowly transfers its energy (heat) across the …
