We present the phase diagram of the frustrated ferromagnetic S=1/2 Heisenberg J_1-J_2 chain in a magnetic field, obtained by large scale exact diagonalizations and density matrix renormalization group simulations. A vector chirally ordered state, metamagnetic behavior and a sequence of spin-multipolar Luttinger liquid phases up to hexadecupolar kind are found. We provide numerical evidence for a locking mechanism, which can drive spiral states towards spin-multipolar phases, such as quadrupolar or octupolar phases. Our results also shed light on previously discovered spin-multipolar phases in two-dimensional $S=1/2$ quantum magnets in a magnetic field.
Recently, it has been shown that spin nematic (quadrupolar) or higher multipolar correlation functions exhibit a quasi long-range order in the wide region of the field-induced Tomonaga-Luttinger-liquid (TLL) phase in spin-1/2 zigzag chains. In this paper, we point out that the temperature dependence of the NMR relaxation rate 1/T_1 in these multipolar TLLs is qualitatively different from that in more conventional TLLs of one-dimensional quantum magnets (e.g., the spin-1/2 Heisenberg chain); 1/T_1 decreases with lowering temperature in multipolar TLL. We also discuss low-energy features in spin…
We study the one-dimensional spin-1/2 Heisenberg chain with competing ferromagnetic nearest-neighbor J_1 and antiferromagnetic next-nearest-neighbor J_2 exchange couplings in the presence of magnetic field. We use both numerical approaches (the density matrix renormalization group method and exact diagonalization) and effective field-theory approach, and obtain the ground-state phase diagram for wide parameter range of the coupling ratio J_1/J_2. The phase diagram is rich and has a variety of phases, including the vector chiral phase, the nematic phase, and other multipolar phases. In the vect…
The $J_1-J_2$ spin chain model with nearest neighbor $J_1$ and next nearest neighbor anti-ferromagnetic $J_2$ interaction is one of the most popular frustrated magnetic models. This model system has been extensively studied theoretically and applied to explain the magnetic properties of the real low-dimensional materials. However, existence of different phases for the $J_1-J_2$ model in an axial magnetic field $h$ is either not understood or has been controversial. In this paper we show the existence of higher order $p>4$ multipolar phase near the critical point $(J_2/J_1)_c=-0.25$. The criter…
It is generally difficult to experimentally distinguish magnetic multipolar orders in spin systems. Recently, it was proposed that the temperature dependence of the nuclear magnetic resonance relaxation rate 1/T_1 can involve an indirect, but clear signature of the field-induced spin nematic or multipolar Tomonaga-Luttinger (TL) liquid phase [Phys. Rev. B79, 060406(R) (2009)]. In this paper, we evaluate accurately the field and temperature dependence of 1/T_1 in spin-1/2 frustrated J1-J2 chains combining field-theoretical techniques with numerical data. Our results demonstrate that isotherms o…
In the spin-1/2 frustrated chain with nearest-neighbor ferromagnetic exchange J1 and next-nearest-neighbor antiferromagnetic exchange J2 under magnetic field, magnetic multipolar-liquid (quadrupolar, octupolar, and hexadecapolar) phases are widely expanded from the saturation down to a low-field regime. Recently, we have clarified characteristic temperature and field dependence of the NMR relaxation rate 1/T_1 in the quadrupolar phase. In this paper, we examine those of 1/T_1 in the octupolar phase combining field theoretical method with numerical data. The relevance of the results to quasi on…
Coupled frustrated spin-1/2 chains in high magnetic fields described within the ferro- antiferromagnetic J1-J2 Heisenberg model are studied by the DMRG, the hard core boson, and the spin wave theory approaches. Multipolar phases related to magnon bound states are destroyed (supported) by weak antiferromagnetic (ferromagnetic) interchain couplings Jic. We show that quantum spin nematics might be found for LiVCuO4 whereas for Li(Na)Cu2O2 it is prevented by a sizeable antiferromagnetic Jic. Also for Li2ZrCuO4 with a small antiferromagnetic Jic expected triatic or quartic phases are unlikely, too.…
The frustrated one-dimensional (1D) quantum magnet LiCuSbO$_4$ is one rare realization of the $J_1-J_2$ spin chain model with an easily accessible saturation field, formerly estimated to 12~T. Exotic multipolar nematic phases were theoretically predicted in such compounds just below the saturation field, but without unambiguous experimental observation so far. In this paper we present extensive experimental research of the compound in the wide temperature (30mK$-$300K) and field (0$-$13.3T) range by muon spin rotation ($μ$SR), $^7$Li nuclear magnetic resonance (NMR) and magnetic susceptibility…
Two geometrically frustrated pyrochlore stannates, undergoing long range magnetic order below 1K, were investigated at very low temperature. Anomalies in the behaviour of hyperfine quantities are found, by 155Gd Mossbauer spectroscopy in Gd2Sn2O7 and by low temperature specific heat measurements in Tb2Sn2O7. They are interpreted in terms of fluctuations of the correlated Gd or Tb spins, using a model two-level system (the nuclear spins) submitted to a randomly fluctuating (hyperfine) field.
The frustrated isotropic $J_1-J_2$ model with ferromagnetic $J_1$ and anti-ferromagnetic $J_2$ interactions in presence of an axial magnetic field shows many exotic phases, such as vector chiral and multipolar phases. The existing studies of the phase boundaries of these systems are based on the indirect evidences such as correlation functions {\it etc}. In this paper, the phase boundaries of these exotic phases are calculated based on order parameters and jumps in the magnetization. In the strong magnetic field, $Z_2$ symmetry is broken, therefore, order parameter of the vector chiral phase i…
We present an experimental study of the magnetic structure and dynamics of two frustrated hyperkagome compounds, Gd3Ga5O12 and Gd3Al5O12. It has previously been shown that Gd3Ga5O12 exhibits long-range correlations of multipolar directors, that are formed from antiferromagnetic spins on loops of ten ions. Using neutron diffraction and Reverse Monte Carlo simulations we prove the existence of similar magnetic correlations in Gd3Al5O12, showing the ubiquity of these complex structures in frustrated hyperkagome materials. Using inelastic neutron scattering we shed further light on the director st…
A classic route for destroying long-lived electronic quasiparticles in a weakly interacting Fermi liquid is to couple them to other low-energy degrees of freedom that effectively act as a bath. We consider here the problem of electrons scattering off the spin fluctuations of a geometrically frustrated antiferromagnet, whose non-linear Landau-Lifshitz dynamics, which remains non-trivial at all temperatures, we model in detail. At intermediate temperatures and in the absence of any magnetic ordering, the fluctuating local-moments lead to a non-trivial angular anisotropy of the scattering-rate al…
The spin-nematic phase is an intriguing state of matter that lacks usual long-range dipolar order, yet it exhibits higher multipolar order. This makes its detection extremely difficult and controversial. Recently, nuclear magnetic resonance (NMR) has been proposed as one of the most suitable techniques to confirm its existence. We report a $^{17}$O NMR observation of the reduction of the local magnetization in the polarized state of the frustrated spin-1/2 chain $β$-TeVO$_4$, which was previously proposed to be a fingerprint of the spin-nematic behavior. However, our detailed study shows that …
For the last few decades, researchers have been intrigued by multipolar ordering phenomena while looking for the related quantum criticality in the heavy-fermion Kondo system Ce$_{1-x}$La$_{x}$B$_6$. However, critical phenomena induced by substitution level ($x$), temperature ($T$), and magnetic field ($B$) are poorly understood despite a large collection of experimental results is available. In this work, we present $T$-$B$, $x$-$T$, and $x$-$B$ phase diagrams of Ce$_{1-x}$La$_x$B$_6$ ($\mathbf{B}\parallel[110]$). These are completed by analyzing heat capacity, magnetocaloric effect (MCE), an…
We present a comprehensive macroscopic thermodynamic study of the quasi-one-dimensional (1D) $s = \tfrac{1}{2}$ frustrated spin-chain system linarite. Susceptibility, magnetization, specific heat, magnetocaloric effect, magnetostriction, and thermal-expansion measurements were performed to characterize the magnetic phase diagram. In particular, for magnetic fields along the b axis five different magnetic regions have been detected, some of them exhibiting short-range-order effects. The experimental magnetic entropy and magnetization are compared to a theoretical modelling of these quantities u…
Modern theories of quantum magnetism predict exotic multipolar states in weakly interacting strongly frustrated spin-1/2 Heisenberg chains with ferromagnetic nearest neighbor (NN) inchain exchange in high magnetic fields. Experimentally these states remained elusive so far. Here we report the evidence for a long-sought magnetic field-induced nematic state arising above a field of $\sim 13$ T in the edge-sharing chain cuprate LiSbCuO$_4$ $\equiv$ LiCuSbO$_4$. This interpretation is based on the observation of a field induced spin-gap in the measurements of the $^7$Li NMR spin relaxation rate $T…
Frustrated spin-1/2 chains, despite the apparent simplicity, exhibit remarkably rich phase diagram comprising vector-chiral (VC), spin-density-wave (SDW) and multipolar/spin-nematic phases as a function of the magnetic field. Here we report a study of $β$-TeVO$_4$, an archetype of such compounds, based on magnetization and neutron diffraction measurements up to 25 T. We find the transition from the helical VC ground state to the SDW state at $\sim$3 T for the magnetic field along the $a$ and $c$ crystal axes, and at $\sim$9 T for the field along the $b$ axis. The high-field (HF) state, existin…
We report the magnetic and calorimetric measurements in single crystal samples of the square lattice $J_{1}-J_{2}$ quantum antiferromagnet BaCdVO(PO$_4$)$_2$. An investigation of the scaling of magnetization reveals a "dimensionality reduction" indicative of a strong degree of geometric frustration. Below a characteristic temperature of $T^{\ast}\simeq150$~mK we observe the emergence of an additional strongly fluctuating quantum phase close to full magnetic saturation. It is separated from the magnetically ordered state by first- and second-order phase transitions, depending on the orientation…
Magnetic order is usually associated with well-defined magnon excitations. Exotic magnetic fluctuations with fractional, topological or multipolar character, have been proposed for radically different forms of magnetic matter such as spin-liquids. As a result, considerable efforts have searched for, and uncovered, low-spin materials with suppressed dipolar order at low temperatures. Here, we report neutron-scattering experiments and quantitative theoretical modeling of an exceptional spin-1 system -- the uniaxial triangular magnet FeI2 -- where a bright and dispersive band of mixed dipolar-qua…
When magnetic order is suppressed by frustrated interactions, spins form a highly correlated fluctuating "spin liquid" state down to low temperatures. Magnetic order of local moments can also be suppressed when they are fully screened by conduction electrons through the Kondo effect. Thus, the combination of strong geometrical frustration and Kondo screening may lead to novel types of quantum phase transitions. We report low-temperature thermodynamic measurements on the frustrated Kondo lattice Pr$_2$Ir$_2$O$_7$, which displays a chiral spin liquid state below 1.5 K due to the frustrated inter…
Frustration refers to competition between different interactions that cannot be simultaneously satisfied, a familiar feature in many magnetic solids. Strong frustration results in highly degenerate ground states, and a large suppression of ordering by fluctuations. Key challenges in frustrated magnetism are characterizing the fluctuating spin-liquid regime and determining the mechanism of eventual order at lower temperature. Here, we study a model of a diamond lattice antiferromagnet appropriate for numerous spinel materials. With sufficiently strong frustration a massive ground state degenera…
Time reversal protected three dimensional (3D) topological paramagnets are magnetic analogs of the celebrated 3D topological insulators. Such paramagnets have a bulk gap, no exotic bulk excitations, but non-trivial surface states protected by symmetry. We propose that frustrated spin-1 quantum magnets are a natural setting for realising such states in 3D. We describe a physical picture of the ground state wavefunction for such a spin-1 topological paramagnet in terms of loops of fluctuating Haldane chains with non-trivial linking phases. We illustrate some aspects of such loop gases with simpl…
In rare-earth compounds with valence fluctuation, the proximity of the 4f level to the Fermi energy leads to instabilities of the charge configuration and the magnetic moment. Here, we provide direct experimental evidence for an induced magnetic polarization of the Eu$^{3+}$ atomic shell with J=0, due to intra-atomic exchange and spin-orbital coupling interactions with Eu$^{2+}$ atomic shell. By applying external pressure, a transition from antiferromagnetic to a fluctuating behavior in a EuNiGe$_3$ single crystals is probed. Magnetic polarization is observed for both valence states of Eu$^{2+…
Spin liquids are exotic phases of matter that often support emergent gauge fields and quasi-particle excitations. While spin liquids are commonly known for remaining disordered, their definition has been extended to include phases with broken symmetry corresponding to (partial) long-range order, such as chiral and nematic spin liquids for example. For Coulomb spin liquids, this ordering can be quantitatively understood via a Helmholtz decomposition between divergence-free and divergence-full terms. This phenomenon has been coined fragmentation, where spin degrees of freedom fragment into two c…
We propose a universal non-linear sigma model field theory for one dimensional frustrated ferromagnets, which applies in the vicinity of a "quantum Lifshitz point", at which the ferromagnetic state develops a spin wave instability. We investigate the phase diagram resulting from perturbations of the exchange and of magnetic field away from the Lifshitz point, and uncover a rich structure with two distinct regimes of different properties, depending upon the value of a marginal, dimensionless, parameter of the theory. In the regime relevant for one dimensional systems with low spin, we find a me…
ZnCr2O4 undergoes a first order spin-Peierls-like phase transition at 12.5 K from a cubic spin liquid phase to a tetragonal Neel state. Using powder diffraction and single crystal polarized neutron scattering, we determined the complex spin structure of the Neel phase. This phase consisted of several magnetic domains with different characteristic wave vectors. This indicates that the tetragonal phase of ZnCr2O4 is very close to a critical point surrounded by many different Neel states. We have also studied, using elastic and inelastic neutron scattering techniques, the effect of nonmagnetic di…
Motivated by recent neutron scattering experiments in Fe-based superconductors, we study how the magnetic resonance in the superconducting state is affected by the simultaneous presence of either static or fluctuating magnetic orders using the random phase approximation. We find that for the underdoped materials with coexisting superconducting and antiferromagnetic orders, spin rotational symmetry is explicitly broken at the ordering momentum $Q_1 = (π,0)$. Only the longitudinal susceptibility exhibits the resonance mode, whereas a spin-wave Goldstone mode develops in the transverse component.…
Anomalous Hall and Nernst effects driven by static and fluctuating spin chiralities on Kagome lattice
School of Physical Sciences, University of Chinese Academy of Sciences（中国科学院大学物理科学学院）；School of Electronic, Electrical and Communication Engineering, University of Chinese Academy of Sciences（中国科学院大学电子电气与通信工程学院）；Institute of Theoretical Physics, Chinese Academy of Sciences（中国科学院理论物理研究所）；Kavli Institute for Theoretical Sciences, University of Chinese Academy of Sciences（中国科学院大学科维理理论科学研究所）
We perform a general study of spin ordering on the pyrochlore lattice with a 3:1 proportionality of two spin polarizations. Equivalently, this describes valence bond solid conformations of a quantum dimer model on the diamond lattice. We determine the set of likely low temperature ordered phases, on the assumption that the ordering is weak, i.e the system is close to a ``U(1)'' quantum spin liquid in which the 3:1 proportionality is maintained but the spins are strongly fluctuating. The nature of the 9 ordered states we find is determined by a ``projective symmetry'' analysis. All the phases e…
Thermodynamic quantities and correlation functions (CFs) of the classical antiferromagnet on the checkerboard lattice are studied for the exactly solvable infinite-component spin-vector model, $D \to \infty$. In contrast to conventional two-dimensional magnets with continuous symmetry showing extended short-range order at distances smaller than the correlation length, $r \lesssim ξ_c \propto \exp(T^*/T)$, correlations in the checkerboard-lattice model decay already at the scale of the lattice spacing due to the strong degeneracy of the ground state characterized by a macroscopic number of stro…
We consider a quantum two-dimensional O(N)xO(2)/O(N-2)xO(2) nonlinear sigma model for frustrated spin systems and formulate its 1/N-expansion which involves fluctuating scalar and vector fields describing kinematic and dynamic interactions, respectively. The ground state phase diagram of this model is obtained within the 1/N-expansion and 2+εrenormalization group approaches. The temperature dependence of correlation length in the renormalized classical and quantum critical regimes is discussed. In the region of the symmetry broken ground state ρ_in<ρ_out, χ_in<χ_out (rho_in,out and chi_in,out …
We study classical $J_1$-$J_2$ models with distinct spin degrees of freedom on a honeycomb lattice. For the XY and Heisenberg spins, the system develops a spiral spin liquid (SSL) that is a thermal cooperative paramagnetic regime with spins fluctuating around the spiral contours in the momentum space, and at low temperatures supports a vector spin-chirality order despite the absence of long-range magnetic order. In a strong contrast, for the Ising moments, the low-temperature spin correlation forms a reciprocal "kagomé" structure in the momentum space that resembles the SSL behaviors and persi…
PbCuTe2O6 is a rare example of a spin liquid candidate featuring a three dimensional magnetic lattice. Strong geometric frustration arises from the dominant antiferromagnetic interaction which generates a hyperkagome network of Cu2+ ions although additional interactions enhance the magnetic lattice connectivity. Through a combination of magnetization measurements and local probe investigation by NMR and muSR down to 20 mK, we provide a robust evidence for the absence of magnetic freezing in the ground state. The local spin susceptibility probed by the NMR shift hardly deviates from the macrosc…
We present combined experimental and theoretical investigation of the low-frequency ESR dynamics in the ordered phases of magnetic mineral linarite. This material consists of weakly coupled spin-1/2 chains of copper ions with frustrated ferro- and antiferromagnetic interactions. In zero magnetic field, linarite orders into a spiral structure and exhibits a peculiar magnetic phase diagram sensitive to the field orientation. The resonance frequencies and their field dependence are analyzed combining microscopic and macroscopic theoretical approaches and precise values of magnetic anisotropy cons…
We report x-ray diffraction, magnetic susceptibility, heat capacity, $^{1}$H nuclear magnetic resonance (NMR), and muon spin relaxation ($μ$SR) measurements, as well as density-functional band-structure calculations for the frustrated $S=3/2$ triangular lattice Heisenberg antiferromagnet (TLHAF) $α$-HCrO$_{2}$ (trigonal, space group: $R\bar{3}m$). This compound undergoes a clear magnetic transition at $T_{\rm N} \simeq 22.5$~K, as seen from the drop in the muon paramagnetic fraction and concurrent anomalies in the magnetic susceptibility and specific heat. Local probes (NMR and $μ$SR) reveal a…
Giant anomalous Hall conductivity in frustrated magnet EuCo2Al9
Zhejiang University of Technology（浙江工业大学）；Zhejiang University（浙江大学）；Center for High Pressure Science & Technology Advanced Research（高压科学先进研究中心）；Renmin University of China（中国人民大学）；China Institute of Atomic Energy（中国原子能科学研究院）；Peking University（北京大学）；Huazhong University of Science and Technology（华中科技大学）；Songshan Lake Materials Laboratory（松山湖材料实验室）；Hefei National Laboratory（合肥国家实验室）；Nanjing University（南京大学）
Magnetoelectric coupling in helical multiferroics allows to steer spin order with electric fields. Here we show theoretically that in a helical multiferroic chain quantum information processing as well as quantum phases are highly sensitive to electric (E) field. Applying E-field, the quantum state transfer fidelity can be increased and made directionally dependent. We also show that E field transforms the spin-density-wave/nematic or multipolar phases of frustrated ferromagnetic spin-1/2 chain in chiral phase with a strong magnetoelectric coupling. We find sharp reorganization of the entangle…
We report the local probe investigation of a frustrated antiferromagnet Pr$_3$BWO$_9$ with the distorted kagome lattice. Absence of magnetic order or spin freezing is indicated by the spectral analysis down to 0.3 K and specific heat measurements down to 0.09 K. The Knight shifts show an upturn behavior with the sample cooling down, which is further suppressed by external field. For the spin dynamics, gapped spin excitation is observed from the temperature dependence of spin-lattice relaxation rates, with the gap size proportional to the applied magnetic field intensity. Comparatively, an unex…
Ba$_3$Mn$_2$O$_8$ is a geometrically frustrated spin dimer compound. We investigate the effect of site disorder on the zero field phase diagram of this material by considering the solid solution Ba$_{3}$(Mn$_{1-x}$V$_{x}$)$_{2}$O$_{8}$, where nonmagnetic V$^{5+}$ ions partially substitute magnetic Mn$^{5+}$ ions. This substitution results in unpaired $S=1$ moments for half-substituted dimers, which are ungapped and therefore susceptible to types of magnetic order not present in the parent compound. AC susceptibility measurements of compositions between $x=0.046$ and $x=0.84$ show a sharp frequ…
Fluctuation dynamics in magnetization plateaux are a relatively poorly explored area in frustrated magnetism. Here we use muon spin relaxation to determine the fluctuation timescale and associated field distribution width in the partial magnetization plateau of Ca3Co2O6. The muon spin relaxation rate has a simple and characteristic field dependence which we model and by fitting to the data at 15 K extract a fluctuation timescale tau = 880(30) ps and a field distribution width Delta = 40.6(3) mT. Comparison with previous results on Ca3Co2O6 suggests that this fluctuation timescale can be associ…
We illustrate how the tensorial kernel support vector machine (TK-SVM) can probe the hidden multipolar orders and emergent local constraint in the classical kagome Heisenberg antiferromagnet. We show that TK-SVM learns the finite-temperature phase diagram in an unsupervised way. Moreover, in virtue of its strong interpretability, it identifies the tensorial quadrupolar and octupolar orders, which define a biaxial $D_{3h}$ spin nematic, and the local constraint that underlies the selection of coplanar states. We then discuss the disorder hierarchy of the phases, which can be inferred from both …
Exotic magnetism and persistent spin dynamics in a frustrated Jeff = 1/2 triangular lattice antiferromagnet
Indian Institute of Technology Madras（印度马德拉斯理工学院）；Jožef Stefan Institute（约瑟夫·斯特凡研究所）；Faculty of Mathematics and Physics, University of Ljubljana（卢布尔雅那大学数学物理学院）；ISIS facility, Rutherford Appleton Laboratory（鲁瑟福阿普尔顿实验室ISIS设施）
CePdAl is a prototypical frustrated Kondo lattice with partial long-range order (LRO) at $T_\mathrm{N}=2.7$ K. Previous bulk experiments under hydrostatic pressure found signatures for a quantum critical regime that extends from $p_\mathrm{c} \approx 0.9$ GPa, where LRO disappears, up to $\sim 1.7$ GPa. We employed extensive muon spin relaxation and rotation ($μ$SR) experiments under pressure. The continuous and complete suppression of LRO at $p_\mathrm{c}$ is confirmed. Above $T_\mathrm{N}(p)$ and beyond $p_\mathrm{c}$, an additional crossover scale $T^\ast(p)$ characterizes the change from p…
The hidden ordered state of the frustrated pyrochlore oxide Tb$_{2+x}$Ti$_{2-x}$O$_{7+y}$ is possibly one of the two electric multipolar, or quadrupolar, states of the effective pseudospin-1/2 Hamiltonian derived from crystal-field ground state doublets of non-Kramers Tb$^{3+}$ ions. These long-range orders are antiparallel or parallel alignments of transverse pseudospin components representing electric quadrupole moments, which cannot be observed as magnetic Bragg reflections by neutron scattering. However pseudospin waves of these states are composite waves of the magnetic-dipole and electri…
The emergent behavior of spin liquids that are born out of geometrical frustration makes them an intriguing state of matter. We show that in the quantum kagome antiferromagnet ZnCu$_3$(OH)$_6$SO$_4$ several different correlated, yet fluctuating states exist. By combining complementary local-probe techniques with neutron scattering, we discover a crossover from a critical regime into a gapless spin-liquid phase with decreasing temperature. An additional unconventional instability of the latter phase leads to a second, distinct spin-liquid state that is stabilized at the lowest temperatures. We …
Neutron scattering experiments on a polycrystalline sample of the frustrated pyrochlore magnet Tb2Ti2O7, which does not show any magnetic order down to 50 mK, have revealed that it shows condensation behavior below 0.4 K from a thermally fluctuating paramagnetic state to a spin-liquid ground-state with quantum spin fluctuations. Energy spectra change from quasielastic scattering to a continuum with a double-peak structure at energies of 0 and 0.8 K in the spin-liquid state. Specific heat shows an anomaly at the crossover temperature.
Quantum magnetic properties in a geometrically frustrated lattice of spin-1/2 magnet, such as quantum spin liquid or solid and the associated spin fractionalization, are considered key in developing a new phase of matter. The feasibility of observing the quantum magnetic properties, usually found in geometrically frustrated lattice of spin-1/2 magnet, in a perovskite material with controlled disorder is demonstrated. It is found that the controlled chemical disorder, due to the chemical substitution of Ru ions by Co-ions, in a simple perovskite CaRuO3 creates a random prototype configuration o…
Two B-site ordered double perovskites, La2LiMoO6 and Ba2YMoO6, based on the S = 1/2 ion, Mo5+, have been investigated in the context of geometric magnetic frustration. Powder neutron diffraction, heat capacity, susceptibility, muon spin relaxation(_SR), and 89Y NMR- including MAS NMR- data have been collected. La2LiMoO6 deviates strongly from simple Curie-Weiss paramagnetic behavior below 150K and zero-field cooled/ field cooled (ZFC/FC)irreversibility occurs below 20K with a weak, broad susceptibility maximum near 5K in the ZFC data. A Curie-Weiss fit shows a reduced mu_eff=1.42μ_B, (spin onl…
Building a full understanding of the complex magnetism in the rare-earth pyrochlore iridates, A2Ir2O7, is an ongoing issue in condensed matter physics. The possibility of two interpenetrating and interacting frustrated magnetic pyrochlore sublattices, connected with the strong spin-orbit coupling of the 5d Ir4+ ion, lends itself to a wide array of potential electronic and magnetic states. In this paper, we present longitudinal field and zero field muSR measurements of Er2Ir2O7. The muSR response of Er2Ir2O7 is dominated by the strong fluctuating fields of the Er3+ (J = 15/2) moments, showing a…
