We present a simple unifying model for crystallization and melting temperatures by showing that homogeneous nucleation and phase transformations driven by thickening of pre-existing surface layers are limiting conditions of the more general heterogeneous nucleation case. Furthermore, to a first approximation all these processes can be described by an extended classical nucleation theory. The model can also be applied to phase transition temperatures in confined volumes, provided reliable values for the interfacial tensions within the systems are determinable. The expected melting and crystallization temperature for any transformation pathway can then be predicted.
Melting and crystallization of Sn, Bi and Pb nanoparticles in contact with Al
研究了过冷度对Bi、Sn、Pb纳米粒子在铝基体上和铝层间结晶度的影响。它已被证明是有效的分层膜系统的使用的限制过冷度的研究中的颗粒基体系统与共晶型的相互作用之间的组分。所得结果进行了讨论,并与文献数据进行了比较。- Predstavleny rezultaty issledovanij pereohlazhdenij pri kristallizacii nanorazmernyh随机Bi,Sn i Pb na Al podlozhke i mezhdu sloyami alyuminiya. Pokazana effektivnost is polzovaniya sloistyh plenochnyh system dlya issledovaniya predelnogo pereohlazhdeniya v systemah chastica-matrica s evtekticheskim tipom vzaimodejstviya mezhdu componentami. Poluchennye rezultaty obsuzhdeny i sopostavleny s literaturnymi dannymi.
Continuous melting and thermal-history-dependent freezing in the confined Na-K eutectic alloy
23 Na NMR研究的Na-K共晶合金嵌入到多孔玻璃与7 nm的孔表明,熔化的Na 2K限制的纳米粒子是一个连续的过程中,平稳变化的奈特位移的窄共振线和核自旋弛豫之间的结晶和液体状态。在熔化时出现的中间状态是稳定的并且比液态更有利。根据冷却的初始温度,逆凝固转变可以是急剧的,如在一级转变或连续的。结果表明,修正的理论预测的熔化和冻结转变在受限的几何形状。
Competing crystallization pathways and cold crystallization kinetics in 10OS5 liquid crystal
Institute of Nuclear Physics, Polish Academy of Sciences(波兰科学院核物理研究所);Faculty of Science, University of Siedlce(谢德尔采大学理学院);Research Center for Thermal and Entropic Science, Graduate School of Science, Osaka University(大阪大学理学研究科热与熵科学研究中心)
Cooperative effects of membrane confinement and gelation on PEG crystallization pathway
The University of Tokyo(东京大学);Komaba Institute for Science, Graduate School of Arts and Sciences, The University of Tokyo(东京大学综合文化研究科驹场科学研究所);Institute of Industrial Science, The University of Tokyo(东京大学工业科学研究所)
Molecular Dynamics Computer Simulation of Crystal Growth and Melting in Al50Ni50
采用分子动力学方法模拟了Al 50 Ni 50的熔化和晶化过程,采用嵌入原子型势模拟颗粒间的相互作用。模拟板状几何结构中的系统,其中在细长模拟箱中间的AlNi的B2相通过两个平面界面与液相分离,从而考虑(100)晶体取向。通过确定界面速度的温度依赖性,提供熔化温度的准确估计。动力学增长系数k= 0.0025m/s/K,比最近单组分金属模拟研究中的结果小两个数量级。经典的Wilson-Frenkel模型不能定量描述晶体生长动力学。我们认为,这是由于忽略了扩散过程中的液晶界面。
Formation and Thermodynamic Behavior of THF-Water Hydrates in Confined Mesoporous Media
Institute of Physics of Rennes, CNRS-University of Rennes 1(雷恩物理研究所,法国国家科学研究中心-雷恩第一大学);Laboratoire Léon Brillouin(莱昂·布里渊实验室);Institut des Sciences moléculaires, UMR5255 CNRS – Université de Bordeaux(分子科学研究所,法国国家科学研究中心-波尔多大学)
Lattice Matching Dictates the Growth Mode and Quality of Deuterium Crystallization in Confined Spherical Shells
Southwest University of Science and Technology(西南科技大学);Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences(中国科学院物理研究所凝聚态物理国家实验室);College of Materials Science and Opto-Electronic Technology, University of Chinese Academy of Sciences(中国科学院大学材料科学与光电技术学院);School of Materials and Chemistry, Southwest University of Science and Technology(西南科技大学材料与化学学院);National Key Laboratory for Shock Wave and Detonation Physics Research, Institute of Fluid Physics, China Academy of Engineering Physics(中国工程物理研究院流体物理研究所冲击波与爆轰物理全国重点实验室)
Unconventional crystallization pathway bypassing the intermediate cubic phase in phase-change superlattices
State Key Laboratory of Integrated Optoelectronics, College of Electronic Science and Engineering, Jilin University(吉林大学电子科学与工程学院集成光电子学国家重点实验室);School of Integrated Circuits, Huazhong University of Science and Technology(华中科技大学集成电路学院);Department of Physics, Applied Physics, and Astronomy, Rensselaer Polytechnic Institute(伦斯勒理工学院物理、应用物理和天文学系)