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arXiv 0705.1623cond-mat.mtrl-sci
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预测结晶和熔化温度的简单模型及其对受限体积中相变的影响

A simple model for predicting crystallization and melting temperatures, and its implications for phase transitions in confined volumes

Sharon Cooper, Catherine Nicholson, Jian Liu

摘要:

我们提出了一个简单的统一模型的结晶和熔化温度,通过显示均匀的成核和相变驱动增厚预先存在的表面层的限制条件的更一般的异相成核的情况下。此外,在一级近似下,所有这些过程都可以用扩展的经典成核理论来描述。该模型也可以适用于相变温度在有限的体积,提供可靠的值的系统内的界面张力是可确定的。然后可以预测任何转化途径的预期熔融和结晶温度。

英文摘要:

We present a simple unifying model for crystallization and melting temperatures by showing that homogeneous nucleation and phase transformations driven by thickening of pre-existing surface layers are limiting conditions of the more general heterogeneous nucleation case. Furthermore, to a first approximation all these processes can be described by an extended classical nucleation theory. The model can also be applied to phase transition temperatures in confined volumes, provided reliable values for the interfacial tensions within the systems are determinable. The expected melting and crystallization temperature for any transformation pathway can then be predicted.

机构、总结、中文摘要均由AI分析而来,可能存在错误,请以论文正文为准。

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