According to extensive experimental findings, the Ginzburg temperature $t_{G}$ for ionic fluids differs substantially from that of nonionic fluids [Schröer W., Weigärtner H. 2004 {\it Pure Appl. Chem.} {\bf 76} 19]. A theoretical investigation of this outcome is proposed here by a mean field analysis of the interplay of short and long range interactions on the value of $t_{G}$. We consider a quite general continuous charge-asymmetric model made of charged hard spheres with additional short-range interactions (without electrostatic interactions the model belongs to the same universality class as the 3D Ising model). The effective Landau-Ginzburg Hamiltonian of the full system near its gas-liquid critical point is derived from which the Ginzburg temperature is calculated as a function of the ionicity. The results obtained in this way for $t_{G}$ are in good qualitative and sufficient quantitative agreement with available experimental data.
A field theoretic representation of the classical partition function is derived for a system composed of a mixture of anisotropic and isotropic mobile charges that interact {\sl via} long range Coulomb and short range nematic interactions. The field theory is then solved on a saddle-point approximation level, leading to a coupled system of Poisson-Boltzmann and Maier-Saupe equations. Explicit solutions are finally obtained for a rod-like counterion-only system in proximity of a charged planar wall, generalizing the standard Gouy-Chapman results. The nematic order parameter profile, the counter…
We study the order-disorder transition in two-dimensional incompressible systems of motile particles with alignment interactions through extensive numerical simulations of the incompressible Toner-Tu (ITT) field theory and a detailed finite-size scaling (FSS) analysis. The transition looks continuous in the explored parameter space, but the effective susceptibility exponent $γ/ν$ and the dynamic exponent $z$ exhibit a strong, non-monotonic variation on the system size in the form of double crossovers. At small sizes, mean-field exponents are observed for the homogeneous $k=0$ mode whereas spat…
We investigate a well-known phenomenon of the appearance of the crossover points, corresponding to the intersections of the solubility isotherms of the solid compound in supercritical fluid. Opposed to the accepted understanding of the existence of two fixed crossover points, which confine the region of the inverse isobaric temperature dependence of the solubility, we have found that these points tend to shift with the change of the temperature and in the limit of the certain threshold value they converge to a single point. We demonstrate this analyzing the solubility data of a set of poorly s…
The conventional (Zwanzig-Mountain) expressions for instantaneous elastic moduli of simple fluids predict their divergence as the limit of hard sphere (HS) interaction is approached. However, elastic moduli of a true HS fluid are finite. Here we demonstrate that this paradox reveals the soft- to hard-sphere crossover in fluid excitations and thermodynamics. With extensive \emph{in-silico} study of fluids with repulsive power-law interactions ($\propto r^{-n}$), we locate the crossover at $n\simeq 10-20$ and develop a simple and accurate model for the HS regime. The results open novel prospects…
Dusty plasmas represent a powerful playground to study the collective dynamics of strongly coupled systems with important interdisciplinary connections to condensed matter physics. Due to the pure Yukawa repulsive interaction between dust particles, dusty plasmas do not display a traditional liquid-vapor phase transition, perfectly matching the definition of a supercritical fluid. Using molecular dynamics simulations, we verify the supercritical nature of dusty plasmas and reveal the existence of a dynamical liquid-like to gas-like crossover which perfectly matches the salient features of the …
Quenched Dipole Pairs in Viscous Fluid Membranes across the Saffman Crossover: Integrable Hamiltonian Dynamics
Birla Institute of Technology and Science, Pilani（比拉理工学院）；University of Wisconsin-Madison（威斯康星大学麦迪逊分校）；Indian Institute of Technology Bombay（印度孟买理工学院）；Stanford University（斯坦福大学）；Massachusetts Institute of Technology（麻省理工学院）；Indian Statistical Institute（印度统计研究所）；Indian Institute of Technology Kharagpur（印度卡拉格普尔理工学院）
Electric-field-induced oscillations in ionic fluids: a unified formulation of modified Poisson-Nernst-Planck models and its relevance to correlation function analysis
