arXivDaily arXiv每日学术速递 周一至周五更新
arXiv 2012.06172cond-mat.softcond-mat.stat-mech
收藏

Theory of inhomogeneous rod-like Coulomb fluids

Rudolf Podgornik

英文摘要:

A field theoretic representation of the classical partition function is derived for a system composed of a mixture of anisotropic and isotropic mobile charges that interact {\sl via} long range Coulomb and short range nematic interactions. The field theory is then solved on a saddle-point approximation level, leading to a coupled system of Poisson-Boltzmann and Maier-Saupe equations. Explicit solutions are finally obtained for a rod-like counterion-only system in proximity of a charged planar wall, generalizing the standard Gouy-Chapman results. The nematic order parameter profile, the counterion density profile and the electrostatic potential profile are interpreted within the framework of a nematic wetting layer with a (Donnan) potential difference.

机构、总结、中文摘要均由AI分析而来,可能存在错误,请以论文正文为准。

↑