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arXiv quant-ph/9902007quant-phchao-dynnlin.CDphysics.atom-ph

Semiclassical Calculation of Transition Matrix Elements for Atoms in External Fields

J. Main, G. Wunner

英文摘要:

Closed orbit theory is generalized to the semiclassical calculation of cross-correlated recurrence functions for atoms in external fields. The cross-correlation functions are inverted by a high resolution spectral analyzer to obtain the semiclassical eigenenergies and transition matrix elements. The method is demonstrated for dipole transitions of the hydrogen atom in a magnetic field. This is the first semiclassical calculation of individual quantum transition strengths from closed orbit theory.

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