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arXiv quant-ph/9804004quant-ph
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凝聚相化学体系中量子退相干时间与溶剂化动力学的关系

Relationship between quantum decoherence times and solvation dynamics in condensed phase chemical systems

Oleg V. Prezhdo, Peter J. Rossky

摘要:

在高斯波包近似下,导出了溶质/水浴体系的量子相干性损失与短时溶剂响应的时间尺度之间的关系.退相干和溶剂响应时间被示出为彼此成正比,由系统浴耦合中的热能波动的比值给出的比例系数。该关系允许从发达的实验方法预测的凝聚相化学系统的退相干时间。

英文摘要:

A relationship between the time scales of quantum coherence loss and short-time solvent response for a solute/bath system is derived for a Gaussian wave packet approximation for the bath. Decoherence and solvent response times are shown to be directly proportional to each other, with the proportionality coefficient given by the ratio of the thermal energy fluctuations to the fluctuations in the system-bath coupling. The relationship allows the prediction of decoherence times for condensed phase chemical systems from well developed experimental methods.

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