We demonstrate the relevance of complex Gaussian stochastic processes to the stochastic state vector description of non-Markovian open quantum systems. These processes express the general Feynman-Vernon path integral propagator for open quantum systems as the classical ensemble average over stochastic pure state propagators in a natural way. They are the coloured generalization of complex Wiener processes in quantum state diffusion stochastic Schrodinger equations.
A dynamical treatment of Markovian diffusion is presented and several applications discussed. The stochastic interpretation of quantum mechanics is considered within this framework. A model for Brownian movement which includes second order quantum effects is derived.
Capturing non-Markovian dynamics of open quantum systems is generally a challenging problem, especially for strongly-interacting many-body systems. In this work, we combine recently developed non-Markovian quantum state diffusion techniques with tensor network methods to address this challenge. As a first example, we explore a Hubbard-Holstein model with dissipative phonon modes, where this new approach allows us to quantitatively assess how correlations spread in the presence of non-Markovian dissipation in a 1D many-body system. We find regimes where correlation growth can be enhanced by the…
We solve two long standing problems for stochastic descriptions of open quantum system dynamics. First, we find the classical stochastic processes corresponding to non-Markovian quantum state diffusion and non-Markovian quantum jumps in projective Hilbert space. Second, we show that the diffusive limit of non-Markovian quantum jumps can be taken on the projective Hilbert space in such a way that it coincides with non-Markovian quantum state diffusion. However, the very same limit taken on the Hilbert space leads to a completely new diffusive unraveling, which we call non-Markovian quantum diff…
Non-Markovian dynamics is studied for two interacting quibts strongly coupled to a dissipative bosonic environment. For the first time, we have derived the non-Markovian quantum state diffusion (QSD) equation for the coupled two-qubit system without any approximations, and in particular, without the Markov approximation. As an application and illustration of our derived time-local QSD equation, we investigate the temporal behavior of quantum coherence dynamics. In particular, we find a strongly non-Markovian regime where entanglement generation is significantly modulated by the environmental m…
We present a perturbation theory for non-Markovian quantum state diffusion (QSD), the theory of diffusive quantum trajectories for open systems in a bosonic environment [Physical Review {\bf A 58}, 1699, (1998)]. We establish a systematic expansion in the ratio between the environmental correlation time and the typical system time scale. The leading order recovers the Markov theory, so here we concentrate on the next-order correction corresponding to first-order non-Markovian master equations. These perturbative equations greatly simplify the general non-Markovian QSD approach, and allow for e…
In this paper, we use the quantum state diffusion (QSD) equation to implement the Uhrig dynamical decoupling (UDD) to a three-level quantum system coupled to a non-Markovian reservoir comprising of infinite numbers of degrees of freedom. For this purpose, we first reformulate the non-Markovian QSD to incorporate the effect of the external control fields. With this stochastic QSD approach, we demonstrate that an unknown state of the three-level quantum system can be universally protected against both colored phase and amplitude noises when the control-pulse sequences and control operators are p…
We present a nonlinear stochastic Schroedinger equation for pure states describing non-Markovian diffusion of quantum trajectories. It provides an unravelling of the evolution of a quantum system coupled to a finite or infinite number of harmonic oscillators, without any approximation. Its power is illustrated by several examples, including measurement-like situations, dissipation, and quantum Brownian motion. In some examples, we treat the environment phenomenologically as an infinite reservoir with fluctuations of arbitrary correlation. In other examples the environment consists of a finite …
Two perturbation methods for the non-Markovian quantum state diffusion (NMQSD) equation are investigated. The first perturbation method under investigation is based on a functional expansion of the NMQSD equation, while the second one expands the NMQSD equation in terms of the coupling strength. We have compared the advantages of the two methods based on bipartite systems where the accuracy of both perturbation methods can be examined by comparing the approximations with the exact solutions. Additionally, we provide an analytical solution for a special family of system's initial states, and th…
We find dynamical invariants for open quantum systems described by the non-Markovian quantum state diffusion (QSD) equation. In stark contrast to closed systems where the dynamical invariant can be identical to the system density operator, these dynamical invariants no longer share the equation of motion for the density operator. Moreover, the invariants obtained with from bi-orthonormal basis can be used to render an exact solution to the QSD equation and the corresponding non-Markovian dynamics without using master equations or numerical simulations. Significantly we show that we can apply t…
Non-Markovian quantum state diffusion (NMQSD) is an exact method for calculating the reduced density matrix of an arbitrary subsystem interacting linearly with the radiation field. Applications of the theory have however been few due to the intractable nature of the variational-differential NMQSD evolution equation. Recently, we argued that the variational-differential equation can be rewritten as an integrodifferential equation which can be readily solved numerically. This manuscript provides an explicit derivation of the modified equations. Applications to intermittent fluorescence in $^{24}…
Non-Markovian quantum state diffusion (NMQSD) is a non-relativistic but otherwise exact theory which expresses the reduced density matrix of an arbitrary subsystem, interacting linearly with an uncoupled harmonic oscillator bath, as an average of diadics formed from state vectors which obey stochastic variational-differential equations. The vacuum radiation field can be represented as such an oscillator bath, and so this model is in widespread use in quantum optics. Prior to the development of NMQSD, exact subsystem solutions could only be obtained in a few special cases (e.g. spin-1/2, harmon…
We present a methodology for simulating multi-dimensional electronic spectra of molecular aggregates with coupling of electronic excitation to a structured environment using the stochastic non-Markovian quantum state diffusion (NMQSD) method in combination with perturbation theory for the response functions. A crucial aspect of our approach is that we propagate the NMQSD equation in a doubled system Hilbert space, but with the same noise. We demonstrate that our approach shows fast convergence with respect to the number of stochastic trajectories, providing a promising technique for numerical …
A quantum Markovian activated atom-surface diffusion model with interacting adsorbates is proposed for the intermediate scattering function, which is shown to be complex-valued and factorizable into a classical-like and a quantum-mechanical factor. Applications to the diffusion of Na atoms on flat (weakly corrugated) and corrugated-Cu(001) surfaces at different coverages and surface temperatures are analyzed. Quantum effects are relevant to diffusion at low surface temperatures and coverages even for relatively heavy particles, such as Na atoms, where transport by tunneling is absent.
Non-Markovian quantum state diffusion (NMQSD) provides a powerful approach to the dynamics of an open quantum system in bosonic environments. Here we develop an NMQSD method to study the open quantum system in fermionic environments. This problem involves anticommutative noise functions (i.e., Grassmann variables) that are intrinsically different from the noise functions of bosonic baths. We obtain the NMQSD equation for quantum states of the system and the non-Markovian master equation. Moreover, we apply this NMQSD method to single and double quantum-dot systems.
The non-Markovian dynamics of a charged particle linearly coupled to a neutral bosonic heat bath is investigated in an external uniform magnetic field. The analytical expressions for the time-dependent and asymptotic friction and diffusion coefficients, cyclotron frequencies, variances of the coordinate and momentum, and orbital magnetic moments are derived. The role of magnetic field in the dissipation and diffusion processes is illustrated by several examples in the low- and high-temperature regimes. The localization phenomenon for a charged particle is observed. The orbital diamagnetism of …
The fully quantized model of double qubits coupled to a common bath is solved using the quantum state diffusion (QSD) approach in the non-Markovian regime. We have established the explicit time-local non-Markovian QSD equations for the two-qubit dissipative and dephasing models. Diffusive quantum trajectories are applied to the entanglement estimation of two-qubit systems in a non-Markovian regime. In both cases, non-Markovian features of entanglement evolution are revealed through quantum diffusive unravellings in the system state space.
The "correlated-projection technique" has been successfully applied to derive a large class of highly non Markovian dynamics, the so called non Markovian generalized Lindblad type equations or Lindblad rate equations. In this article, general unravellings are presented for these equations, described in terms of jump-diffusion stochastic differential equations for wave functions. We show also that the proposed unravelling can be interpreted in terms of measurements continuous in time, but with some conceptual restrictions. The main point in the measurement interpretation is that the structure i…
Non-Markovian dynamics detection is one of the most popular subjects in the quantum information science. In this paper, a linear-entropy-based non-Markovianity witness scheme is constructed. The positive definiteness of the Choi state will be broken in the non-Markovian evolution, which can be witnessed by its linear entropy. Thus, the linear entropy of the Choi state can be used to witness the non-Markovian dynamics. The effectiveness of the proposed method is verified by an example of the pure dephasing channel. Also, it is shown that this method can be extended to the one based on Rényi ent…
Non-Markovian Quantum State Diffusion (NMQSD) has turned out to be an efficient method to calculate excitonic properties of aggregates composed of organic chromophores, taking into account the coupling of electronic transitions to vibrational modes of the chromophores. NMQSD is an open quantum system approach that incorporates environmental degrees of freedom (the vibrations in our case) in a stochastic way. We show in this paper that for linear optical spectra (absorption, circular dichroism) no stochastics is needed, even for finite temperatures. Thus, the spectra can be obtained by propagat…
We consider quantum stochastic processes and discuss a level 2.5 large deviation formalism providing an explicit and complete characterisation of fluctuations of time-averaged quantities, in the large-time limit. We analyse two classes of quantum stochastic dynamics, within this framework. The first class consists of the quantum jump trajectories related to photon detection; the second is quantum state diffusion related to homodyne detection. For both processes, we present the level 2.5 functional starting from the corresponding quantum stochastic Schrödinger equation and we discuss connection…
In this paper we present a linear quadratic Gaussian (LQG) feedback control strategy for a class of linear non-Markovian quantum systems. The feedback control law is designed based on the estimated states of a whitening quantum filter for an augmented Markovian model of the non-Markovian open quantum systems. In this augmented Markovian model, an ancillary system plays the role of internal modes of the environment converting white noise into Lorentzian noise and a principal system obeys non-Markovian dynamics due to the direct interaction with the ancillary system. The simulation results show …
We develop a theory of linear witnesses for detecting non-Markovianity, based on the geometric structure of the set of Choi states for all Markovian evolutions having Lindblad type generators. We show that the set of all such Markovian Choi states form a convex and compact set under the small time interval approximation. Invoking geometric Hahn-Banach theorem, we construct linear witnesses to separate a given non-Markovian Choi state from the set of Markovian Choi states. We present examples of such witnesses for dephasing channel and Pauli channel in case of qubits. We further investigate the…
We present a stochastic approach for the description of the quantum dynamics of open system in a fermionic environment (bath). The full quantum evolution as provided by the Schrodinger equation is reformulated exactly as a probabilistic average over the so-called dressed quantum trajectories. The latter are defined as follows. The fermionic environment can be represented as a fermi sea whose "surface" is covered by the ripples of quantum fluctuations. If we consider these fluctuations in the basis of the particle-hole coherent states, then these fluctuations produce a classical particle-hole n…
We investigate the non-Markovian quantum dynamics of a hybrid open system consisting of one qubit and one qutrit by employing a stochastic Schrödinger equation to generate diffusive quantum trajectories. We have established an exact quantum state diffusion (QSD) equation for the dissipative qubit-qutrit system coupled to a bosonic heat bath at zero temperature. As an important application, the non-Markovian QSD equation is employed to simulate the entanglement decay and generation measured by negativity. Finally, some steady state properties of the hybrid system are also discussed.
Absorption spectra of small molecular aggregates (oligomers) are considered. The dipole-dipole interaction between the monomers leads to shifts of the oligomer spectra with respect to the monomer absorption. The line-shapes of monomer as well as oligomer absorption depend strongly on the coupling to vibrational modes. Using a recently developed approach [Roden et. al, PRL 103, 058301] we investigate the length dependence of spectra of one-dimensional aggregates for various values of the interaction strength between the monomers. It is demonstrated, that the present approach is well suited to d…
An open quantum system with multiple levels coupled to a bosonic environment at zero temperature is investigated systematically using the non-Markovian quantum-state-diffusion (QSD) method [W. T. Strunz, L. Diósi, and N. Gisin, Phys. Rev. Lett. 82, 1801 (1999)]. We have established exact time-local QSD equations for a set of interesting multilevel open systems, including high-spin systems, multiple-transition atomic models, and multilevel atomic models driven by time-dependent external fields. These exact QSD equations have paved the way to evaluate the dynamics of open multilevel atomic syste…
We study a driven two-state system interacting with a structured environment. We introduce the non-Markovian master equation ruling the system dynamics, and we derive its analytic solution for general reservoir spectra. We compare the non-Markovian dynamics of the Bloch vector for two classes of reservoir spectra: the Ohmic and the Lorentzian reservoir. Finally, we derive the analytic conditions for complete positivity with and without the secular approximation. Interestingly, the complete positivity conditions have a transparent physical interpretation in terms of the characteristic timescale…
We investigate the effect of counter-rotating-wave terms on the non-Markovianity in quantum open systems by employing the hierarchical equations of motion in the framework of the non-Markovian quantum state diffusion approach. As illustrative examples, the non-Markovian memory effect of a qubit embedded in a bosonic and a fermionic environment at zero temperature are analyzed. It is found that the counter-rotating-wave terms are able to enhance the observed non-Markovianity no matter the environment is composed of bosons or fermions. This result suggests that the rotating-wave approximation ma…
The interplay between non-Markovian dynamics and driving fields in the survival of entanglement between two non-degenerate oscillators is considered here. Based on exact analytical results for the non-Markovian dynamics of two parametrically coupled non-degenerate oscillators in contact to non-identical independent thermal baths, the out-of-equilibrium quantum limit derived in [Phys. Rev. Lett. 105, 180501 (2010)] is generalized to the non-Markovian regime. Specifically, it is shown that non-Markovian dynamics, when compared to the Markovian case, allow for the survival of stationary entanglem…
The non-Markovian dynamics of a three-level quantum system coupled to a bosonic environment is a difficult problem due to the lack of an exact dynamic equation such as a master equation. We present for the first time an exact quantum trajectory approach to a dissipative three-level model. We have established a convolutionless stochastic Schrödinger equation called time-local quantum state diffusion (QSD) equation without any approximations, in particular, without Markov approximation. Our exact time-local QSD equation opens a new avenue for exploring quantum dynamics for a higher dimensional q…
In this note, we are concerned with dark modes in a class of non-Markovian open quantum systems. Based on a microscopic model, a time-convoluted linear quantum stochastic differential equation and an output equation are derived to describe the system dynamics. The definition of dark modes is given building on the input-output structure of the system. Then, we present a necessary and sufficient condition for the existence of dark modes. Also, the problem of dark mode synthesis via Hamiltonian engineering is constructively solved and an example is presented to illustrate our results.
Exact expressions are derived for the intermediate scattering function (ISF) of a quantum particle diffusing in a harmonic potential and linearly coupled to a harmonic bath. The results are valid for arbitrary strength and spectral density of the coupling. The general, exact non-Markovian result is expressed in terms of the classical velocity autocorrelation function, which represents an accumulated phase during a scattering event. The imaginary part of the exponent of the ISF is proportional to the accumulated phase, which is an antisymmetric function of the correlation time $t$. The expressi…
In this paper, the non-Markovian quantum dynamics of a coupled $N$-cavity model is studied based on the quantum state diffusion (QSD) approach. The time-local Diósi-Gisin-Strunz equation and the corresponding exact master equation are derived for the model consisting of a coupled cavity array. The resulting QSD equation serves as a stochastic solution to a genuine $N$-partite continuous-variable (CV) system. Several non-Markovian effects are studied in two interesting examples -- two-cavity and three-cavity, under different boundary conditions. We have shown that the environment-memory can fac…
Physicists are attracted to open-system dynamics, how quantum systems evolve, and how they can protected from unnecessary environmental noise, especially environmental memory effects are not negligible, as with non-Markovian approximations. There are several methods to solve master equation of non-Markovian cases, we obtain the solutions of quantum-state-diffusion equation for a two qubit system using perturbation method, which under influence of various types of environmental noises, i.e., relaxation, dephasing and mix of them. We found that mixing these two types of noises benefit the quantu…
Relying on an exact time evolution scheme, we identify a novel transient energy transfer phe- nomenon in an exactly-solvable quantum microscopic model consisting of a three-level system coupled to two non-Markovian zero-temperature bosonic baths through two separable quantum channels. The dynamics of this model can be solved exactly using the quantum-state-diffusion equation formalism, demonstrating finite intervals of unidirectional energy flow across the system, typically, from the non-Markovian environment towards the more Markovian bath. Furthermore, when introducing a spatial asymmetry in…
In many molecular systems one encounters the situation where electronic excitations couple to a quasi-continuum of phonon modes. That continuum may be highly structured e.g. due to some weakly damped high frequency modes. To handle such a situation, an approach combining the non-Markovian quantum state diffusion (NMQSD) description of open quantum systems with an efficient but abstract approximation was recently applied to calculate energy transfer and absorption spectra of molecular aggregates [Roden, Eisfeld, Wolff, Strunz, PRL 103 (2009) 058301]. To explore the validity of the used approxim…
Non-Markovian environment induced chaos in optomechanical system
Fujian Key Laboratory of Quantum Information and Quantum Optics (Fuzhou University)（福建量子信息与量子光学重点实验室（福州大学））；Department of Physics, Fuzhou University（福州大学物理系）
A wide class of exact master equations for a multiple qubit system can be explicitly constructed by using the corresponding exact non-Markovian quantum state diffusion equations. These exact master equations arise naturally from the quantum decoherence dynamics of qubit system as a quantum memory coupled to a collective colored noisy source. The exact master equations are also important in optimal quantum control, quantum dissipation and quantum thermodynamics. In this paper, we show that the exact non-Markovian master equation for a dissipative N-qubit system can be derived explicitly from th…
Non-Markovian dynamics of two interacting two-level qubits coupled to a bosonic bath was previously studied using the quantum-state-diffusion (QSD) equation, where a stochastic state is used to describe the system. In this study, we provide another perspective on this system by deriving the analytic form of the master equation, which describes the system with a reduced density matrix. Then, we validate the master equation by examining entanglement generation and state purity. In addition, with the master equation, we observe the effects from first-order noise and notice that a good asymptotic …
Dynamical decoupling as a quantum control strategy aims at suppressing quantum decoherence adopting the popular philosophy that the disorder in the unitary evolution of the open quantum system caused by environmental noises should be neutralized by a sequence of ordered or well-designed external operations acting on the system. This work studies the solution of quantum-state-diffusion equations by mixing two channels of environmental noises, i.e., relaxation (dissipation) and dephasing. It is interesting to find in two-level and three-level atomic systems that a non-Markovian relaxation or dis…
We extend the non-Markovian quantum state diffusion (QSD) equation to open quantum systems which exhibit multi-channel coupling to a harmonic oscillator reservoir. Open quantum systems which have multi-channel reservoir coupling are those in which canonical transformation of reservoir modes cannot reduce the number of reservoir operators appearing in the interaction Hamiltonian to one. We show that the non-Markovian QSD equation for multi-channel reservoir coupling can, in some cases, lead to an exact master equation which we derive. We then derive the exact master equation for the three-level…
We consider the two-level system approximation of a single emitter driven by a continuous laser pump and simultaneously coupled to the electromagnetic vacuum and to a thermal reservoir beyond the Markovian approximation. We discuss the connection between a rigorous microscopic theory and the phenomenological spectral diffusion approach, used to model the interaction of the emitter with the thermal bath, and obtained analytic expressions relating the thermal correlation function to the single emitter photon statistics.
We develop a systematic and efficient approach for numerically solving the non-Markovian quantum state diffusion equations for open quantum systems coupled to an environment up to arbitrary orders of noises or coupling strengths. As an important application, we consider a real-time simulation of a spin-boson model in a strong coupling regime that is difficult to deal with using conventional methods. We show that the non-Markovian stochastic Schrödinger equation can be efficiently implemented as a real--time simulation for this model, so as to give an accurate description of spin-boson dynamics…
The linear and the nonlinear non-Markovian quantum state diffusion equation (NMQSD) are well known tools for the description of certain non-Markovian open quantum systems. In this work, we systematically investigate whether the normalized linear NMQSD or the nonlinear NMQSD solutions can be generated by means of a time-continuous measurement. By considering any conceivable measurement scheme in the framework of instruments, we derive a necessary criterion for a measurement interpretation of both equations. Concrete examples show that the normalized linear NMQSD solutions are realizable only in…
The reduced dynamics of a quantum system interacting with a linear heat bath finds an exact representation in terms of a stochastic Schr{ö}dinger equation. All memory effects of the reservoir are transformed into noise correlations and mean-field friction. The classical limit of the resulting stochastic dynamics is shown to be a generalized Langevin equation, and conventional quantum state diffusion is recovered in the Born--Markov approximation. The non-Markovian exact dynamics, valid at arbitrary temperature and damping strength, is exemplified by an application to the dissipative two-state …
Characterizing those quantum channels that correspond to Markovian time evolutions is an open problem in quantum information theory, even different notions of quantum Markovianity exist. One such notion is that of infinitesimal Markovian divisibility for quantum channels introduced in arXiv:math-ph/0611057. Whereas there is a complete characterization for infinitesimal Markovian divisible qubit channels, no necessary or sufficient criteria are known for higher dimensions, except for necessity of non-negativity of the determinant. We describe how to extend the notion of infinitesimal Markovian …
A long-standing open problem in non-Markovian quantum state diffusion (QSD) approach to open quantum systems is to establish the non-Markovian QSD equations for multiple qubit systems. In this paper, we settle this important question by explicitly constructing a set of exact time-local QSD equations for $N$-qubit systems. Our exact time-local (convolutionless) QSD equations have paved the way towards simulating quantum dynamics of many-body open systems interacting with a common bosonic environment. The applicability of this multiple-qubit stochastic equation is exemplified by numerically solv…
We investigate the Markovian and non-Markovian dynamics of Gaussian quantum channels, exploiting a recently introduced necessary and sufficient criterion and the ensuing measure of non-Markovianity based on the violation of the divisibility property of the dynamical map. We compare the paradigmatic instances of Quantum Brownian motion (QBM) and Pure Damping (PD) channels, and for the former we find that the exact dynamical evolution is always non-Markovian in the finite-time as well as in the asymptotic regimes, for any nonvanishing value of the non-Markovianity parameter. If one resorts to th…
