A dynamical treatment of Markovian diffusion is presented and several applications discussed. The stochastic interpretation of quantum mechanics is considered within this framework. A model for Brownian movement which includes second order quantum effects is derived.
We demonstrate the relevance of complex Gaussian stochastic processes to the stochastic state vector description of non-Markovian open quantum systems. These processes express the general Feynman-Vernon path integral propagator for open quantum systems as the classical ensemble average over stochastic pure state propagators in a natural way. They are the coloured generalization of complex Wiener processes in quantum state diffusion stochastic Schrodinger equations.
Capturing non-Markovian dynamics of open quantum systems is generally a challenging problem, especially for strongly-interacting many-body systems. In this work, we combine recently developed non-Markovian quantum state diffusion techniques with tensor network methods to address this challenge. As a first example, we explore a Hubbard-Holstein model with dissipative phonon modes, where this new approach allows us to quantitatively assess how correlations spread in the presence of non-Markovian dissipation in a 1D many-body system. We find regimes where correlation growth can be enhanced by the…
We solve two long standing problems for stochastic descriptions of open quantum system dynamics. First, we find the classical stochastic processes corresponding to non-Markovian quantum state diffusion and non-Markovian quantum jumps in projective Hilbert space. Second, we show that the diffusive limit of non-Markovian quantum jumps can be taken on the projective Hilbert space in such a way that it coincides with non-Markovian quantum state diffusion. However, the very same limit taken on the Hilbert space leads to a completely new diffusive unraveling, which we call non-Markovian quantum diff…
Non-Markovian dynamics is studied for two interacting quibts strongly coupled to a dissipative bosonic environment. For the first time, we have derived the non-Markovian quantum state diffusion (QSD) equation for the coupled two-qubit system without any approximations, and in particular, without the Markov approximation. As an application and illustration of our derived time-local QSD equation, we investigate the temporal behavior of quantum coherence dynamics. In particular, we find a strongly non-Markovian regime where entanglement generation is significantly modulated by the environmental m…
We provide an analysis on non-Markovian quantum evolution based on the spectral properties of dynamical maps. We introduce the dynamical analog of entanglement witness to detect non-Markovianity and we illustrate its behaviour with several instructive examples. It is shown that for a certain class of dynamical maps the shape of the body of accessible states provides a simple non-Markovianity witness.
We present a perturbation theory for non-Markovian quantum state diffusion (QSD), the theory of diffusive quantum trajectories for open systems in a bosonic environment [Physical Review {\bf A 58}, 1699, (1998)]. We establish a systematic expansion in the ratio between the environmental correlation time and the typical system time scale. The leading order recovers the Markov theory, so here we concentrate on the next-order correction corresponding to first-order non-Markovian master equations. These perturbative equations greatly simplify the general non-Markovian QSD approach, and allow for e…
Markovianity of the quantum open system processes is a topic of the considerable current interest. Typically, invertibility is assumed to be non-essential for Markovianity of the open-quantum-system dynamical maps. Nevertheless, in this paper we distinguish a class of physically important dynamical maps (processes) for which invertibility is a necessary condition for Markovianity. Since every quantum-state tomography directly provides information on invertibility of the map, no optimization procedure is necessary for determining non-Markovianity regarding the considered class of dynamical proc…
In this paper, we use the quantum state diffusion (QSD) equation to implement the Uhrig dynamical decoupling (UDD) to a three-level quantum system coupled to a non-Markovian reservoir comprising of infinite numbers of degrees of freedom. For this purpose, we first reformulate the non-Markovian QSD to incorporate the effect of the external control fields. With this stochastic QSD approach, we demonstrate that an unknown state of the three-level quantum system can be universally protected against both colored phase and amplitude noises when the control-pulse sequences and control operators are p…
We present a nonlinear stochastic Schroedinger equation for pure states describing non-Markovian diffusion of quantum trajectories. It provides an unravelling of the evolution of a quantum system coupled to a finite or infinite number of harmonic oscillators, without any approximation. Its power is illustrated by several examples, including measurement-like situations, dissipation, and quantum Brownian motion. In some examples, we treat the environment phenomenologically as an infinite reservoir with fluctuations of arbitrary correlation. In other examples the environment consists of a finite …
Two perturbation methods for the non-Markovian quantum state diffusion (NMQSD) equation are investigated. The first perturbation method under investigation is based on a functional expansion of the NMQSD equation, while the second one expands the NMQSD equation in terms of the coupling strength. We have compared the advantages of the two methods based on bipartite systems where the accuracy of both perturbation methods can be examined by comparing the approximations with the exact solutions. Additionally, we provide an analytical solution for a special family of system's initial states, and th…
We find dynamical invariants for open quantum systems described by the non-Markovian quantum state diffusion (QSD) equation. In stark contrast to closed systems where the dynamical invariant can be identical to the system density operator, these dynamical invariants no longer share the equation of motion for the density operator. Moreover, the invariants obtained with from bi-orthonormal basis can be used to render an exact solution to the QSD equation and the corresponding non-Markovian dynamics without using master equations or numerical simulations. Significantly we show that we can apply t…
Identifying non-Markovianity with non-divisibility, we propose a measure for non-Markovinity of quantum process. Three examples are presented to illustrate the non-Markovianity, measure for non-Markovianity is calculated and discussed. Comparison with other measures of non-Markovianity is made. Our non-Markovianity measure has the merit that no optimization procedure is required and it is finite for any quantum process, which greatly enhances the practical relevance of the proposed measure.
Non-Markovian quantum state diffusion (NMQSD) is an exact method for calculating the reduced density matrix of an arbitrary subsystem interacting linearly with the radiation field. Applications of the theory have however been few due to the intractable nature of the variational-differential NMQSD evolution equation. Recently, we argued that the variational-differential equation can be rewritten as an integrodifferential equation which can be readily solved numerically. This manuscript provides an explicit derivation of the modified equations. Applications to intermittent fluorescence in $^{24}…
We investigate the relationship between non-Markovianity and the effectiveness of a dynamical decoupling protocol for qubits undergoing pure dephasing. We consider an exact model in which dephasing arises due to a bosonic environment with a spectral density of the Ohmic class. This is parametrised by an Ohmicity parameter by changing which we can model both Markovian and non-Markovian environments. Interestingly, we find that engineering a non-Markovian environment is detrimental to the efficiency of the dynamical decoupling scheme, leading to a worse coherence preservation. We show that each …
In this work we develop a numerical framework to investigate the renormalization of the non-Markovian dynamics of an open quantum system to which dynamical decoupling is applied. We utilize a non-Markovian master equation which is derived from the non-Markovian quantum trajectories formalism. It contains incoherent Markovian dynamics and coherent Schrödinger dynamics as its limiting cases and is capable of capture the transition between them. We have performed comprehensive simulations for the cases in which the system is either driven by the Ornstein-Uhlenbeck noise or or is described by the …
The system-environment interaction is simulated by light propagating in coupled photonic waveguides. The profile of the electromagnetic field provides intuitive physical insight to study the Markovian and non-Markovian dynamics of open quantum systems. The transition from non-Markovian to Markovian process is demonstrated by increasing the size of environment, as the energy evolution changes from oscillating to an exponential decay, and the revival period increases. Moreover, the dynamical decoupling with a sequence of phase modulations is introduced to such a photonic open system to form a ba…
We analyse the role played by system-environment correlations in the emergence of non-Markovian dynamics. By working within the framework developed in Breuer et al., Phys. Rev. Lett. 103, 210401 (2009), we unveil a fundamental connection between non-Markovian behaviour and dynamics of system-environment correlations. We derive an upper bound to the rate of change of the distinguishability between different states of the system that explicitly depends on the development and establishment of correlations between system and environment. We illustrate our results using a fully solvable spin-chain …
We consider the effect of broadband decoherence on the performance of refocusing sequences, having in mind applications of dynamical decoupling in concatenation with quantum error correcting codes as the first stage of coherence protection. Specifically, we construct cumulant expansions of effective decoherence operators for a qubit driven by a pulse of a generic symmetric shape, and for several sequences of $π$- and $π/2$-pulses. While, in general, the performance of soft pulses in decoupling sequences in the presence of Markovian decoherence is worse than that of the ideal $δ$-pulses, it can…
We identify a set of dynamical maps of open quantum system, and refer to them as "$ ε$-Markovian" maps. It is constituted of maps which, in a higher dimensional system-environment Hilbert space, possibly violate Born approximation but only a "little". We characterize the "$ε$-nonmarkovianity" of a general dynamical map by the minimum distance of that map from the set of $ε$-Markovian maps. We analytically derive an inequality which gives a bound on the $ ε$-nonmarkovianity of the dynamical map, in terms of an entanglement-like resource generated between the system and its "immediate" environme…
It is known that the time evolution of a subsystem from an initial state to two later times, t1, t2 (t2 > t1), are both completely positive (CP) but it is shown here that in the intermediate times between t1 and t2, in general, it need not be CP. This reveals the key to the Markov (if CP) and nonMarkov (if NCP) avataras of the intermediate dynamics. This is brought out based on A and B dynamical maps - without resorting to Master equation approach. The choice of tensor product form for the global initial state points towards the system-environment interaction dynamics as the sole cause for Mar…
One of the most important topics in the study of the dynamics of open quantum system is information exchange between system and environment. Based on the features of a back-flow information from an environment to a system, an approach is provided to detect non-Markovianity for unital dynamical maps. The method takes advantage of non-contractive property of the von Neumann entropy under completely positive and trace preserving unital maps. Accordingly, for the dynamics of a single qubit as an open quantum system, the sign of the time-derivative of the density matrix eigenvalues of the system de…
We construct a non-Markovian canonical dynamical map that accounts for systems correlated with the environment. The physical meaning of not completely positive maps is studied to obtain a theory of non-Markovian quantum dynamics. The relationship between inverse maps and correlations with the environment is established. A generalized non-Markovian master equation is derived from the canonical dynamical map that goes beyond the Kossakowski-Lindblad Markovian master equation. Non-equilibrium quantum thermodynamics can be be studied within this theory.
We investigate the dynamical information exchange between a two-state system and its environment which is measured by von Neumann entropy. It is found that in the underdamping regime, the entropy dynamics exhibits an extremely non-Markovian oscillation-hump feature, in which oscillations manifest quantum coherence and a hump of envelop demonstrates temporal memory of bath. It indicates that the process of entropy exchange is bidirectional. When the coupling strength increases a certain threshold, the hump along with ripple disappears, which is indicative of the coherent-incoherent dynamical cr…
We theoretically study the dynamical dephasing of a quantum two level system interacting with an environment exhibiting non-Markovian random telegraph fluctuations. The time evolution of the conditional probability of the environmental noise is governed by a generalized master equation depending on the environmental memory effect. The expression of the dephasing factor is derived exactly which is closely associated with the memory kernel in the generalized master equation for the conditional probability of the environmental noise. In terms of three important types memory kernels, we discuss th…
Quantum dynamical maps provide suitable mathematical representation of quantum evolutions. It is the very notion of complete positivity which provides a proper mathematical representation of quantum evolution and gives rise to the powerful generalization of unitary evolution of closed Hamiltonian systems. A prominent example of quantum evolution of an open system is a Markovian semigroup. In what follows, we analyze both the semigroups of positive and completely positive maps. In the latter case the dynamics is governed by the celebrated Gorini-Kossakowski-Lindblad-Sudarshan (GKLS) Master Equa…
We address the dynamics of continuous-time quantum walks on one-dimensional disordered lattices inducing dynamical noise in the system. Noise is described as time-dependent fluctuations of the tunneling amplitudes between adjacent sites, and attention is focused on non-Gaussian telegraph noise, going beyond the usual assumption of fast Gaussian noise. We observe the emergence of two different dynamical behaviors for the walker, corresponding to two opposite noise regimes: slow noise (i.e. strong coupling with the environment) confines the walker into few lattice nodes, while fast noise (weak c…
The transient dynamics of quantum coherence of Gaussian states are investigated. The state is coupled to an external environment which can be described by a Fano-Anderson type Hamiltonian. Solving the quantum Langevin equation, we obtain the Greens functions which are used to compute the time evolved first and second moments of the quadrature operators. From the quadrature operator moments, we construct the covariance matrix which is used to measure the coherence in the system. The coherence is measured using the relative entropy of coherence measure. We consider three different classes of spe…
We obtain the analytical expression for the Kraus decomposition of the quantum map of an environment modeled by an arbitrary quadratic fermionic Hamiltonian acting on one or two qubits, and derive simple functions to check the non-positivity of the intermediate map. These functions correspond to two different sufficient criteria for non-Markovianity. In the particular case of an environment represented by the Ising Hamiltonian, we discuss the two sources of non-Markovianity in the model, one due to the finite size of the lattice, and another due to the kind of interactions.
It is known that the dynamical evolution of a system, from an initial tensor product state of system and environment, to any two later times, t1,t2 (t2>t1), are both completely positive (CP) but in the intermediate times between t1 and t2 it need not be CP. This reveals the key to the Markov (if CP) and nonMarkov (if it is not CP) avataras of the intermediate dynamics. This is brought out here in terms of the quantum stochastic map A and the associated dynamical map B -- without resorting to master equation approaches. We investigate these features with four examples which have entirely differ…
We address the dynamics of quantum correlations in continuous variable open systems and analyze the evolution of bipartite Gaussian states in independent noisy channels. In particular, upon introducing the notion of dynamical path through a suitable parametrization for symmetric states, we focus attention on phenomena that are common to Markovian and non-Markovian Gaussian maps under the assumptions of weak coupling and secular approximation. We found that the dynamical paths in the parameter space are universal, that is they do depend only on the initial state and on the effective temperature…
Non-Markovian quantum state diffusion (NMQSD) is a non-relativistic but otherwise exact theory which expresses the reduced density matrix of an arbitrary subsystem, interacting linearly with an uncoupled harmonic oscillator bath, as an average of diadics formed from state vectors which obey stochastic variational-differential equations. The vacuum radiation field can be represented as such an oscillator bath, and so this model is in widespread use in quantum optics. Prior to the development of NMQSD, exact subsystem solutions could only be obtained in a few special cases (e.g. spin-1/2, harmon…
A dynamical decoupling scheme for the deterrence of errors in the non-Markovian (usually corresponding to low temperature, short time, and strong coupling) regimes suitable for qubits constructed out of a multilevel structure is studied. We use the effective spin-boson model (ESBM) introduced recently [K. Shiokawa and B. L. Hu, Phys. Rev. A70, 062106 (2004)] as a low temperature limit of the quantum Brownian oscillator model, where one can obtain exact solutions for a general environment with colored noises. In our decoupling scheme a train of pairs of strong pulses are used to evolve the inte…
We present a methodology for simulating multi-dimensional electronic spectra of molecular aggregates with coupling of electronic excitation to a structured environment using the stochastic non-Markovian quantum state diffusion (NMQSD) method in combination with perturbation theory for the response functions. A crucial aspect of our approach is that we propagate the NMQSD equation in a doubled system Hilbert space, but with the same noise. We demonstrate that our approach shows fast convergence with respect to the number of stochastic trajectories, providing a promising technique for numerical …
Convex combinations of the completely positive (CP) as well as CP-divisible, continuous time dynamical maps arising from collision models are investigated. While the individual maps are both CP and Markovian we find that convex combinations remain CP but not necessarily Markovian. Examples of such combinations for qubit dynamical maps arising from collisional models are worked out and the invertibility, CP-divisibility, P-divisibility as well as Markovian properties of such maps are explored.
It is shown that the fidelity of the dynamically evolved system with its earlier time density matrix provides a signature of non-Markovian dynamics. Also, the fidelity associated with the initial state and the dynamically evolved state is shown to be larger in the non-Markovian evolution compared to that in the corresponding Markovian case. Starting from the Kraus representation of quantum evolution, the Markovian and non-Markovian features are discerned in its short time structure. These two features are in concordance with each other and they are illustrated with the help of four models of i…
Quantum non-Markovianity of channels can be produced by mixing Markovian channels, as observed recently by various authors. We consider an analogous question of whether singularities of the channel can be produced by mixing non-singular channels, i.e., ones that lack them. Here we answer the question in the negative in the context of qubit Pauli channels. On the other hand, mixing channels with a singularity can lead to the elimination of singularities in the resultant channel. We distinguish between two types of singular channels, which lead under mixing to broadly quite different properties …
A quantum Markovian activated atom-surface diffusion model with interacting adsorbates is proposed for the intermediate scattering function, which is shown to be complex-valued and factorizable into a classical-like and a quantum-mechanical factor. Applications to the diffusion of Na atoms on flat (weakly corrugated) and corrugated-Cu(001) surfaces at different coverages and surface temperatures are analyzed. Quantum effects are relevant to diffusion at low surface temperatures and coverages even for relatively heavy particles, such as Na atoms, where transport by tunneling is absent.
Non-Markovian quantum state diffusion (NMQSD) provides a powerful approach to the dynamics of an open quantum system in bosonic environments. Here we develop an NMQSD method to study the open quantum system in fermionic environments. This problem involves anticommutative noise functions (i.e., Grassmann variables) that are intrinsically different from the noise functions of bosonic baths. We obtain the NMQSD equation for quantum states of the system and the non-Markovian master equation. Moreover, we apply this NMQSD method to single and double quantum-dot systems.
We introduce a non-Markovianity measure for continuous variable open quantum systems based on the idea put forward in H.-P. Breuer et al., Phys. Rev. Lett.\textbf{103}, 210401 (2009), i.e., by quantifying the flow of information from the environment back to the open system. Instead of the trace distance we use here the fidelity to assess distinguishability of quantum states. We employ our measure to evaluate non-Markovianity of two paradigmatic Gaussian channels: the purely damping channel and the quantum Brownian motion channel with Ohmic environment. We consider different classes of Gaussian…
The impossibility of an indeterministic evolution for standard relativistic quantum field theories, that is, theories in which all fields satisfy the condition that the generators of spacetime translation have spectrum in the forward light-cone, is demonstrated. The demonstration proceeds by arguing that a relativistically invariant theory must have a stable vacuum, and then showing that stability of the vacuum, together with the requirements imposed by relativistic causality, entails deterministic evolution, if all degrees of freedom are standard degrees of freedom.
We introduce a generalized approach to characterize the non-Markovianity of quantum dynamical maps via breakdown of monotonicity of thermodynamic functions. By adopting an entropy-based formulation of quantum thermodynamics, we use the relationship between heat and entropy to propose a measure of non-Markovianity based on the heat flow for single-qubit quantum evolutions. This measure can be applied for unital dynamical maps that do not invert the sign of the internal energy. Under certain conditions, it can also be extended for other thermodynamic functions, such as internal energy and work f…
The non-Markovian dynamics of a charged particle linearly coupled to a neutral bosonic heat bath is investigated in an external uniform magnetic field. The analytical expressions for the time-dependent and asymptotic friction and diffusion coefficients, cyclotron frequencies, variances of the coordinate and momentum, and orbital magnetic moments are derived. The role of magnetic field in the dissipation and diffusion processes is illustrated by several examples in the low- and high-temperature regimes. The localization phenomenon for a charged particle is observed. The orbital diamagnetism of …
Recently we pointed out the so-called Local Time Scheme as a novel approach to quantum foundations that solves the preferred pointer-basis problem. In this paper we introduce and analyze in depth a rather non-standard dynamical map that is imposed by the scheme. On one hand, the map does not allow for introducing a properly defined generator of the evolution nor does it represent a quantum channel. On the other hand, the map is linear, positive, trace preserving and unital as well as completely positive, but is not divisible and therefore non-Markovian. Nevertheless, we provide quantitative cr…
The "correlated-projection technique" has been successfully applied to derive a large class of highly non Markovian dynamics, the so called non Markovian generalized Lindblad type equations or Lindblad rate equations. In this article, general unravellings are presented for these equations, described in terms of jump-diffusion stochastic differential equations for wave functions. We show also that the proposed unravelling can be interpreted in terms of measurements continuous in time, but with some conceptual restrictions. The main point in the measurement interpretation is that the structure i…
The fully quantized model of double qubits coupled to a common bath is solved using the quantum state diffusion (QSD) approach in the non-Markovian regime. We have established the explicit time-local non-Markovian QSD equations for the two-qubit dissipative and dephasing models. Diffusive quantum trajectories are applied to the entanglement estimation of two-qubit systems in a non-Markovian regime. In both cases, non-Markovian features of entanglement evolution are revealed through quantum diffusive unravellings in the system state space.
In the weak-coupling limit approach to open quantum systems, the presence of the bath is eliminated and accounted for by a master equation that introduces dissipative contributions to the system reduced dynamics. Within this framework, there are no bath entropy contributions to the entropy balance. We show that, as a consequence, the entropy production fails to be positive for a class of physically legitimate (i.e., completely positive and trace preserving) non-Markovian dynamical maps. Moreover, in the absence of the semigroup property, if the reduced dynamics has a thermal asymptotic state, …
Non-Markovian Quantum State Diffusion (NMQSD) has turned out to be an efficient method to calculate excitonic properties of aggregates composed of organic chromophores, taking into account the coupling of electronic transitions to vibrational modes of the chromophores. NMQSD is an open quantum system approach that incorporates environmental degrees of freedom (the vibrations in our case) in a stochastic way. We show in this paper that for linear optical spectra (absorption, circular dichroism) no stochastics is needed, even for finite temperatures. Thus, the spectra can be obtained by propagat…
We construct a dynamical map which is not positive divisible and does not present information backflow either (as measured by trace norm quantifiers). It is formulated for a qutrit system undergoing noninvertible dynamics. This provides an evidence that the two definitions of quantum Markovianity based on absence of information backflow and positive divisibility are nonequivalent for general noninvertible dynamical maps
We provide further characterization of non-Markovian quantum dynamics based on the concept of divisible dynamical maps. In analogy to entanglement witness we propose a non-Markovianity witness and introduce the corresponding measure of non-Markovianity. We also provide characterization of non-Markovianity in terms of entropic quantities, fidelity and Wigner-Yanase-Dyson skew information.
We consider quantum stochastic processes and discuss a level 2.5 large deviation formalism providing an explicit and complete characterisation of fluctuations of time-averaged quantities, in the large-time limit. We analyse two classes of quantum stochastic dynamics, within this framework. The first class consists of the quantum jump trajectories related to photon detection; the second is quantum state diffusion related to homodyne detection. For both processes, we present the level 2.5 functional starting from the corresponding quantum stochastic Schrödinger equation and we discuss connection…