Decoherence effects on quantum and classical dynamics in reactive scattering are examined using a Caldeira-Leggett type model. Through a study of dynamics of the collinear H+H2 reaction and the transmission over simple one-dimensional barrier potentials, we show that decoherence leads to improved agreement between quantum and classical reaction and transmission probabilities, primarily by increasing the energy dispersion in a well defined way. Increased potential nonlinearity is seen to require larger decoherence in order to attain comparable quantum-classical agreement.
The use of rotational degrees of freedom of quantum systems in quantum technologies is limited by environmental effects under decoherence mechanism. Here, we study the mechanism of decoherence based on a new formalism of elastic scattering for a nonspherical quantum system prepared in a superposition of rotational degrees of freedom. We show that for a dielectric ellipsoid immersed in an environment composed of thermal photons the rotational decoherence rate depends on the angular differences between the two configurations of the system and the seventh power of the temperature which is differe…
It is shown that, through a super-radiant Rayleigh scattering, a strong far off-resonant pump laser applied to a Bose-Einstein condensates(BEC) can induce a non-demolition coupling of the many-mode quantized vacuum field to the BEC. This effective interaction will force the total system of the BEC plus the light field to evolve from a factorized initial state to an ideal entangled state and thus result in the quantum decoherence in the BEC. Since the effective coupling coefficients are mainly determined by the Rabi frequency of the pump laser, the quantum decoherence process can be controlled …
We explore coherent control of Penning and associative ionization in cold collisions of metastable He$^*({2}^3\text{S})$ atoms via the quantum interference between different states of the He$_2^*$ collision complex. By tuning the preparation coefficients of the initial atomic spin states, we can benefit from the quantum interference between molecular channels to maximize or minimize the cross sections for Penning and associative ionization. In particular, we find that we can enhance the ionization ratio by 30% in the cold regime. This work is significant for the coherent control of chemical re…
We study the interference of C70 fullerenes in a Talbot-Lau interferometer with a large separation between the diffraction gratings. This permits the observation of recurrences of the interference contrast both as a function of the de Broglie wavelength and in dependence of the interaction with background gases. We observe an exponential decrease of the fringe visibility with increasing background pressure and find good quantitative agreement with the predictions of decoherence theory. From this we extrapolate the limits of matter wave interferometry and conclude that the influence of collisio…
We provide a "first principles" description of scattering from open quantum systems subject to a Lindblad-type dynamics. In particular we consider the case that the duration of the scattering process is of similar order as the decoherence time of the scatterer. Under rather general conditions, the derivations lead to the the following new result: The irreversible time-evolution may cause a reduction of the system's transition rate being effectuated by scattering. This is tantamount to a shortfall of scattering intensity. The possible connection with striking experimental results of neutron and…
A theoretical model describing the Raman scattering process in atomic vapors is constructed. The treatment investigates the low-excitation regime suitable for modern experimental applications. Despite the incorporated decoherence effects (possibly mode dependent) it allows for a direct separation of the time evolution from the spatial degrees of freedom. The impact of noise on the temporal properties of the process is examined. The model is applied in two experimentally relevant situations of ultra-cold and room-temperature atoms. The spatial eigenmodes of the Stokes photons and their coupling…
Using non-relativistic many body quantum field theory, a master equation is derived for the reduced density matrix of a dilute gas of massive particles undergoing scattering interactions with an environment of light particles. The dynamical variable that naturally decoheres (the pointer basis) is essentially the local number density of the dilute gas. Earlier master equations for this sort of system (such as that derived by Joos and Zeh) are recovered on restricting to the one-particle sector for the distinguished system. The derivation shows explicitly that the scattering environment stores i…
We experimentally and theoretically investigate the scattering of a photonic quantum field from another stored in a strongly interacting atomic Rydberg ensemble. Considering the many-body limit of this problem, we derive an exact solution to the scattering-induced spatial decoherence of multiple stored photons, allowing for a rigorous understanding of the underlying dissipative quantum dynamics. Combined with our experiments, this analysis reveals a correlated coherence-protection process in which the scattering from one excitation can shield all others from spatial decoherence. We discuss how…
The mechanism of decoherence for a quantum system with rotational degrees of freedom is studied. From a simple model of elastic scattering, we show that the non-diagonal density matrix elements of the system exponentially decay. The decay rate depends on the difference of scattering amplitudes for different rotational configurations, leading to the gradual loss of quantum coherence between the pointer states in the system orientational space. For a dielectric ellipsoid immersed in a photon-gas environment (assuming no absorption), the decay rate is found to be proportional to the seventh power…
We present theoretical and experimental studies of the decoherence of hyperfine ground-state superpositions due to elastic Rayleigh scattering of light off-resonant with higher lying excited states. We demonstrate that under appropriate conditions, elastic Rayleigh scattering can be the dominant source of decoherence, contrary to previous discussions in the literature. We show that the elastic-scattering decoherence rate of a two-level system is given by the square of the difference between the elastic-scattering \textit{amplitudes} for the two levels, and that for certain detunings of the lig…
We analyze collisional decoherence of atoms or molecules prepared in a coherent superposition of nondegenerate internal states at ultralow temperatures and placed in an ultracold buffer gas. Our analysis is applicable for an arbitrary bath particle/tracer particle mass ratio. Both elastic and inelastic collisions contribute to decoherence. We obtain an expression relating the observable decoherence rate to pairwise scattering properties, specifically the low-temperature scattering amplitudes. We consider the dependence on the bath particle/tracer particle mass ratio for the case of light bath …
A phenomenological model of the time evolution of a particle wavepacket is presented that is subject to scattering event with small momentum transfer. It is suited for three dimensions and allows for an additional potential. For a random value of a phase parameter, it is equivalent to the decoherence by scattering off plane wave field states. Imposing some condition on the same phase parameter, the model delivers definite outcomes in a local pointer base. Common sense notions about the quantum-classical transition are readily obtained: Decoherent free particle solutions are localized constant-…
We consider two ultracold particles confined in spherically symmetric harmonic trap and interacting via isotropic potential with absorbing boundary conditions at short range that models reactive scattering. First, we apply the contact pseudopotential with complex scattering length and investigate the properties of eigenergies and eigenfunctions for different trap states as a function of real and imaginary part of the scattering length. In the analyzed case the eigenenergies take complex values, and their imaginary part can be interpreted in terms of decay rates. Then we introduce the model of …
Recent studies of the decoherence induced by the quantum nature of the laser field driving a two-state atom [J. Gea-Banacloche, Phys. Rev. A 65, 022308 (2002); S. J. van Enk and H. J. Kimble, Quantum Inf. and Comp. 2, 1 (2002)] have been questioned by Itano [W. M. Itano, Phys. Rev. A 68, 046301 (2003)] and the proposal made that all decoherence is due to spontaneous emission. We analyze the problem within the formalism of cascaded open quantum systems. Our conclusions agree with the Itano proposal. We show that the decoherence, nevertheless, may be divided into two parts--that due to forwards …
Motivated by trapping and cooling experiments with non-spherical nanoparticles, we discuss how their combined rotational and translational quantum state is affected by the interaction with a gaseous environment. Based on the quantum master equation in terms of orientation-dependent scattering amplitudes, we evaluate the localization rate for gas collisions off an anisotropic van der Waals-type potential and for photon scattering off an anisotropic dielectric. We also show how pure angular momentum diffusion arises from these open quantum dynamics in the limit of weak anisotropies.
In this study, we apply the monitoring master equation describing decoherence of internal states to an optically active molecule prepared in a coherent superposition of nondegenerate internal states interacting with thermal photons at low temperatures. We use vibrational Raman scattering theory up to the first chiral-sensitive contribution, i.e., the mixed electric-magnetic interaction, to obtain scattering amplitudes in terms of molecular polarizability tensors. The resulting density matrix is used to obtain elastic decoherence rates.
We describe a new mechanism of decoherence in excited atoms as a result of thermal particles scattering by the atomic nucleus. It is based on the idea that a single scattering will produce a sudden displacement of the nucleus, which will be perceived by the electron in the atom as an instant shift in the electrostatic potential. This will leave the atom's wave-function partially projected into lower-energy states which will lead to decoherence of the atomic state. The decoherence is calculated to increase with the excitation of the atom, making observation of the effect easier in Rydberg atoms…
A popular model of decoherence based on the linear coupling to harmonic oscillator heat baths is analized and shown to be inappropriate in the regime where decoherence dominates over energy dissipation, called pure decoherence regime. The similar mechanism essentially related to the energy conservation implies that, on the contrary to the recent conjectures, chaotic environments can be less efficient decoherers than regular ones. Finally, the elastic scattering mechanism is advocated as the simplest source of pure decoherence.
The quantum normal form approach to quantum transition state theory is used to compute the cumulative reaction probability for collinear exchange reactions. It is shown that for heavy atom systems like the nitrogen exchange reaction the quantum normal form approach gives excellent results and has major computational benefits over full reactive scattering approaches. For light atom systems like the hydrogen exchange reaction however the quantum normal approach is shown to give only poor results. This failure is attributed to the importance of tunnelling trajectories in light atom reactions that…
We experimentally investigate a superconducting qubit coupled to the end of an open transmission line, in a regime where the qubit decay rates to the transmission line and to its own environment are comparable. We perform measurements of coherent and incoherent scattering, on- and off-resonant fluorescence, and time-resolved dynamics to determine the decay and decoherence rates of the qubit. In particular, these measurements let us discriminate between non-radiative decay and pure dephasing. We combine and contrast results across all methods and find consistent values for the extracted rates. …
Recently, a static gravitational field, such as that of the Earth, was proposed as a new source of decoherence [1]. We study the conditions under which it becomes the dominant decoherence effect in typical interferometric experiments. The following competing sources are considered: spontaneous emission of light, absorption, scattering with the thermal photons and collisions with the residual gas. We quantify all these effects. As we will see, current experiments are off by several orders of magnitude. New ideas are needed in order to achieve the necessary requirements: having as large as syste…
Time-dependent density-matrix propagation is used to demonstrate, in a schematic model of an open quantum system, that the complex potential approach and the Lindblad dissipative dynamics are \emph{not} equivalent. While the former preserves coherence, it is destroyed in the Lindblad dissipative dynamics. Quantum decoherence is the key aspect that makes the difference between the two approaches, indicating that the complex potential model is inadequate for a consistent description of open quantum-system dynamics. It is suggested that quantum decoherence should always be explicitly included whe…
We ask and answer a basic question about the length scales involved in quantum decoherence: how far apart in space do two parts of a quantum system have to be, before a common quantum environment decoheres them as if they were entirely separate? We frame this question specifically in a cold atom context. How far apart do two populations of bosons have to be, before an environment of thermal atoms of a different species (`buffer gas') responds to their two particle numbers separately? An initial guess for this length scale is the thermal coherence length of the buffer gas; we show that a standa…
The quantum state of motion of a large and rotating polar molecule can lose coherence through the collisions with gas atoms. We show how the associated quantum master equation for the center of mass can be expressed in terms of the orientationally averaged differential and total scattering cross sections, for which we provide approximate analytic expressions. The master equation is then utilized to quantify collisional decoherence in a interference experiment with polar molecules.
We present the quantum master equation describing the coherent and incoherent dynamics of a rapidly rotating molecule in presence of a thermal background gas. The master equation relates the rate of rotational alignment decay and decoherence to the microscopic scattering amplitudes, which we calculate for anisotropic van der Waals scattering. For large rotational energies, we find excellent agreement of the resulting alignment decay rate with recent superrotor experiments.
A general connection between the characteristic function of a Lévy process and loss of coherence of the statistical operator describing the center of mass degrees of freedom of a quantum system interacting through momentum transfer events with an environment is established. The relationship with microphysical models and recent experiments is considered, focusing on the recently observed transition between a dynamics described by a compound Poisson process and a Gaussian process.
We study the effect of resonances near the threshold of low energy ($\varepsilon$) reactive scattering processes, and find an anomalous behavior of the $s$-wave cross sections. For reaction and inelastic processes, the cross section exhibits the energy dependence $σ\sim\varepsilon^{-3/2}$ instead of the standard Wigner's law threshold behavior $σ\sim\varepsilon^{-1/2}$. Wigner's law is still valid as $\varepsilon\rightarrow 0$, but in a narrow range of energies. We illustrate these effects with two reactive systems, a low-reactive system (H$_2$ + Cl) and a more reactive one (H$_2$ + F). We pro…
We present expressions demonstrating that collisional decoherence of ultracold atoms or molecules in a coherent superposition of non-degenerate quantum states is suppressed when both the real and imaginary parts of the scattering lengths for the states in the coherent superposition are equal. We show that the rate of collisional decoherence can be enhanced or suppressed by varying an external magnetic field near a Feshbach resonance. For some resonances, the suppression is very dramatic. We propose a method for measuring the scattering length of ultracold particles in excited quantum states ex…
We study the decoherence process associated with the scattering of stochastic gravitational waves. We discuss the case of macroscopic systems, such as the planetary motion of the Moon around the Earth, for which gravitational scattering is found to dominate decoherence though it has a negligible influence on damping. This contrast is due to the very high effective temperature of the background of gravitational waves in our galactic environment.
A fundamental question in the study of chemical reactions is how reactions proceed at a collision energy close to absolute zero. This question is no longer hypothetical: quantum degenerate gases of atoms and molecules can now be created at temperatures lower than a few tens of nanoKelvin. In this work we consider the benchmark ultracold reaction between, the most-celebrated ultracold molecule, KRb and K. For the first time we map out an accurate ab initio ground state potential energy surface of the KRbK complex in full dimensionality and report numerically exact quantum-mechanical reaction dy…
Progress in ultracold experiments with polar molecules requires a clear understanding of their interactions and reactivity at ultra-low collisional energies. Two important theoretical steps in this process are the characterization of interaction potentials between molecules and the modeling of reactive scattering mechanism. Here, we report on the {\it abinitio} calculation of isotropic and anisotropic van der Waals interaction potentials for polar KRb and RbCs colliding with each other or with ultracold atoms. Based on these potentials and two short-range scattering parameters we then develop …
A new micro-irreversible 3D theory of quantum multichannel scattering in the three-body system is developed. The quantum approach is constructed on the generating trajectory tubes which allow taking into account influence of classical non-integrability on the dynamical quantum system. It was shown that when the volume of classical chaos in phase space is larger than quantum sell in the main object of quantum system the wavefunction generates chaos (quantum chaos). The probability of quantum transitions is constructed for this case. On the example of collinear collision of Li+(FH) -> (LiF)+H sy…
We present an effective two-channel model for reactive collisions of cold atoms. It augments elastic molecular channels with an irreversible, inelastic loss channel. Scattering is studied with the distorted-wave Born approximation and yields general expressions for angular momentum resolved cross sections as well as two-body loss rates. Explicit expressions are obtained for piece-wise constant potentials. A pole expansion reveals simple universal shape functions for cross sections and two-body loss rates in agreement with the Wigner threshold laws. This is applied to collisions of metastable $…
Superselection rules induced by the interaction with the environment are a basis to understand the emergence of classical observables within quantum theory. The aim of this article is to investigate the decoherence effects, which lead to superselection sectors, with the help of exactly soluble Hamiltonian models. Starting from the examples of Araki and of Zurek more general models with scattering are presented for which the projection operators onto the induced superselection sectors do no longer commute with the Hamiltonian. The example of an environment given by a free quantum field indicate…
Various models have been proposed in which the Schrödinger equation is modified to account for a decay of spatial coherences of massive objects. While optomechanical systems and matter-wave interferometry with large clusters are promising candidates to test these models, we here show that using available techniques for atoms in optical lattices, some of these models can be efficiently tested. In particular, we compare unconventional decoherence due to quantum gravity as introduced by Ellis and co-workers [Phys. Lett. B ${\bf 221}$, 113 (1989)] and conventional decoherence due to scattering of …
We study the decoherence speed limit (DSL) of a single impurity atom immersed in a Bose-Einsteincondensed (BEC) reservoir when the impurity atom is in a double-well potential. We demonstrate how the DSL of the impurity atom can be manipulated by engineering the BEC reservoir and the impurity potential within experimentally realistic limits. We show that the DSL can be controlled by changing key parameters such as the condensate scattering length, the effective dimension of the BEC reservoir, and the spatial configuration of the double-well potential imposed on the impurity. We uncover the phys…
We study the decoherence process associated with the scattering of stochastic backgrounds of gravitational waves. We show that it has a negligible influence on HYPER-like atomic interferometers although it may dominate decoherence of macroscopic motions, such as the planetary motion of the Moon around the Earth.
The prospect of controlling entanglement in interacting quantum systems offers a myriad of technological and scientific promises, given the progress in experimental studies in systems such as ultracold trapped gases. This control is often challenging because of decoherence, the process by which environmental interactions create spurious entanglements that can destroy the desired entanglement. Considering the collisional decoherence that is relevant for quantum measurements utilizing scattering in one-dimensional trapped gases, here we derive a relationship between particle masses and wave pack…
By viewing current in the detecting lead of a spintronic device as being an ensemble of flowing spins corresponding to a mixed quantum state, where each spin itself is generally described by an improper mixture generated during the transport where it couples to other degrees of freedom due to spin-orbit (SO) interactions or inhomogeneous magnetic fields, we introduce the spin density operator associated with such current expressed in terms of the spin-resolved Landauer transmission matrix of the device. This formalism, which provides complete description of coupled spin-charge quantum transpor…
The coupled-channels density-matrix technique for nuclear reaction dynamics, which is based on the Liouville-von Neumann equation with Lindblad dissipative terms, is developed with the inclusion of full angular momentum couplings. It allows a quantitative study of the role and importance of quantum decoherence in nuclear scattering. Formulae of asymptotic observables that can reveal effects of quantum decoherence are given. A method for extracting energy-resolved scattering information from the time-dependent density matrix is introduced. As an example, model calculations are carried out for t…
We consider departures from hamiltonian dynamics in the evolution of neutral kaons due to their interactions with environment that generate entanglement among them. We propose a phenomenological model of stochastic re-scattering and estimate the coefficients of the effective hamiltonian and decoherence terms. Finally we analyze the interplay between the weak interaction and matter effects and propose the observables suitable to measure the matter characteristics of CPT violation and decoherence.
In this study, we achieved magnetic control of reactive scattering in an ultracold mixture of $^{23}$Na atoms and $^{23}$Na$^{6}$Li molecules. In most molecular collisions, particles react or are lost near short range with unity probability, leading to the so-called universal rate. By contrast, the Na{+}NaLi system was shown to have only $\sim4\%$ loss probability in a fully spin-polarized state. By controlling the phase of the scattering wave function via a Feshbach resonance, we modified the loss rate by more than a factor of $100$, from far below to far above the universal limit. The result…
Extracting macroscopic properties of a system from microscopic interactions has always been an interesting topic with the most diverse applications. Here, we use the quantum Boltzmann equation to investigate the density matrix evolution of a system of nucleons. Using the quantum field theory tools for constructing the density matrix operators and calculating the interactions is the main advantage of this equation. The right-hand side of this equation involves forward scattering and usual collision terms. As examples of application, we calculate the standard Bloch equations for the nucleon syst…
We study the effect of the scattering of gravitational waves on planetary motions, say the motion of the Moon around the Earth. Though this effect has a negligible influence on dissipation, it dominates fluctuations and the associated decoherence mechanism, due to the very high effective temperature of the background of gravitational waves in our galactic environment.
The goal of this short note is to show that the formulas I derived originally in [Phys. Rev. A 65, 022308 (2002)] regarding the errors introduced in quantum logical operations by the quantum nature of the control fields apply even in the situation discussed recently by Ozeri et al. in quant-ph/0502063, where the decoherence-inducing spontaneous Raman scattering is considerably suppressed.
We present and discuss a general density-matrix description of energy-dissipation and decoherence phenomena in open quantum systems, able to overcome the intrinsic limitations of the conventional Markov approximation. In particular, the proposed alternative adiabatic scheme does not threaten positivity at any time. The key idea of our approach rests in the temporal symmetrization and coarse graining of the scattering term in the Liouville-von Neumann equation, before applying the reduction procedure over the environment degrees of freedom. The resulting dynamics is genuinely Lindblad-like and …
Cross sections resulting from scattering that proceeds via an intermediate resonance are shown to be exceptionally controllable using a coherent superposition of only two intial states. Full quantum computations on F+HD(v=0;j=0,1) --> H+DF, D+HF, which exhibits a resonance in one of the reactive channels, support the formal arguments, showing that control is indeed vast. In this case the ratio of reactive integral cross sections can be altered by a factor of 62 (compared to a noncoherent factor of only 3.3), while the ratio of reactive differential cross sections can be altered by a factor of …
We describe how quasiclassical relative positions of particles emerge in an initially delocalized quantum system as scattering of a probe beam is observed. We show that in the multiparticle case this localization in position space occurs via intermediate states that are quantum superpositions of spatial configurations. These superpositions are robust to consecutive scattering events, and scattering alone does not lead to their decoherence. Instead the free evolution of the system combines with scattering to destroy these superpositions, leading the particles to adopt classical-like positions r…
We investigate the presence of Feshbach resonances in ultracold alkali-dialkali reactive collisions. Quantum scattering calculations are performed on a new Na_3 quartet potential energy surface. An analysis of scattering features is performed through a systematic variation of the nonadditive three-body interaction potential. Our results should provide useful information for interpreting future atom-molecule collision experiments.
We review recent results on quantum reactive scattering from a phase space perspective. The approach uses classical and quantum versions of normal form theory and the perspective of dynamical systems theory. Over the past ten years the classical normal form theory has provided a method for realizing the phase space structures that are responsible for determining reactions in high dimensional Hamiltonian systems. This has led to the understanding that a new (to reaction dynamics) type of phase space structure, a {\em normally hyperbolic invariant manifold} (or, NHIM) is the "anchor" on which th…
We implement a simple feedback mechanism on a two-mode cavity QED system to preserve the Zeeman coherence of a ground state superposition that generates quantum beats on the second-order correlation function. Our investigation includes theoretical and experimental studies that show how to prevent a shift away from the Larmor frequency and associated decoherence caused by Rayleigh scattering. The protocol consists of turning off the drive of the system after the detection of a first photon and letting it evolve in the dark. Turning the drive back on after a pre-set time reveals a phase accumula…
We uncover two microscopic physical settings with significant pure spin decoherence. First, for quantum dots (QD) electrostatically confined in two-dimensional hole gas, decoherence comes from qubit spin-orbit (SO) coupling to phonons, whose decay due to free charge carriers in contacts is described by Ohmic weighted phonon spectral function. We derive significant SO interactions affecting holes with origin and symmetry distinct from that of conventionally considered Dresselhaus and Rashba terms. In the second setting of electron or hole QDs coupled to a linear chain of atoms, decoherence is d…
We investigate the effect of decoherence on Fano resonances in wave transmission through resonant scattering structures. We show that the Fano asymmetry parameter q follows, as a function of the strength of decoherence, trajectories in the complex plane that reveal detailed information on the underlying decoherence process. Dissipation and unitary dephasing give rise to manifestly different trajectories. Our predictions are successfully tested against microwave experiments using metal cavities with different absorption coefficients and against previously published data on transport through qua…
